Preferential water loss from synthetic fluid inclusions |
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| Authors: | Donald L Hall S Michael Sterner |
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| Institution: | (1) Amoco Production Co., PO Box 3385, 74102 Tulsa, OK, USA;(2) Bayorisches Geoinstitut, Universität Bayreuth, Postfach 10 12 51, D-95440 Bayreuth, Germany |
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| Abstract: | A fundamental question in most fluid inclusion studies is whether inclusions behave as compositionally closed systems after trapping, and, thus, represent samples of the fluid phase(s) present in the system at the time of their formation. This question was addressed in high-temperature laboratory experiments with synthetic fluid inclusions in quartz and it was found that at 825°C the inclusions exhibited open-system behavior with respect to water. Synthetic salt-water fluid inclusions in quartz were reequilibrated for 12 hours to 35 days at 825° C in a dry argon atmosphere under 1.5 kbar confining pressure. These conditions created initial internal overpressures (P
int>
P
conf) of 1.5–4 kbar in the inclusions and differential water fugacities in the same sense i.e., fH2OfH2O. After 108 hours of reequilibration, preferential water loss had resulted in salinity increases as large as 22 wt% salt (e.g., from 57 to 79 wt% NaCl, as determined from measured temperatures of salt dissolution). Also, following reequilibration, a strong inverse correlation between salinity and inclusion volume was observed, and this trend became more pronounced with increasing reequilibration time. These observations, together with a lack of evidence for selective H2O removal via hydration reactions, suggest that water loss occurred by a diffusion-related mechanism. Fluxes of  4x10-11 g/cm2-s and diffusion coefficients on the order of 10-9 cm2/s are calculated for water loss from the inclusions. The calculated H2O diffusion coefficient is consistent with the determination of Blacic (1981) derived from hydrolytic weakening experiments, but is much larger than the value obtained by Giletti and Yund (1984) for volume diffusion of oxygen in isotope exchange experiments. These observations suggest that the mechanism of water loss from our synthetic fluid inclusions may have been pipe diffusion along dislocations, subgrain boundaries or other structural defects rather than bulk volume diffusion.The results of this study are relevant to the interpretation of fluid inclusions in quartz from several natural high-temperature environments where water fugacities of included and ambient fluids are known to have evolved along separate paths over geologic time. |
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