CO2 solubility and solubility mechanisms in silicate melts at high pressures |
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| Authors: | G Brey |
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| Institution: | (1) Research School of Earth Sciences, Australian National University Canberra, Australia |
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| Abstract: | CO2 solubility has a slight negative temperature dependence in olivine melilitite at 30 kb with 9% CO2 dissolved at 1,450 °C, 8.5% at 1,550 °C and 8.3% at 1,650° C. CO2 is dissolved as the carbonate molecule (CO
3
2–
) only. Feldspar melts (albite-anorthite) dissolve much less CO2 at 30 kb (around 2%) with a slight increase with increasing anorthite content. A CO2 absorption peak in infrared spectra of albite-rich glasses diappears in favour of the CO
3
2–
peak with increasing anorthite content. It is inferred that CO2 was present as CO
3
2–
in albite-rich melts also, but reverts to CO2 during quenching because of bonding differences related to Ca2+ and Na+ in the melts. |
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| Keywords: | |
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