Shoshonite and sub-alkaline magmas from an ultrapotassic volcano: Sr–Nd–Pb isotope data on the Roccamonfina volcanic rocks,Roman Magmatic Province,Southern Italy |
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| Authors: | Sandro Conticelli Sara Marchionni Davide Rosa Guido Giordano Elena Boari Riccardo Avanzinelli |
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| Institution: | 1.Dipartimento di Scienze della Terra,Università degli Studi di Firenze,Florence,Italy;2.Consiglio Nazionale delle Ricerche, Istituto di Geoscienze e Georisorse, Sezioni di Firenze,Florence,Italy;3.Dipartimento di Scienze Geologiche,Università di Roma III,Rome,Italy;4.Bristol Isotope Group, Department of Earth Sciences, Wills Memorial Building,University of Bristol,Bistol,UK |
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| Abstract: | The Roccamonfina volcano is characterised by two stages of volcanic activity that are separated by volcano-tectonic caldera
collapses. Ultrapotassic leucite-bearing rocks are confined to the pre-caldera stage and display geochemical characteristics
similar to those of other volcanoes in the Roman Province. After the major sector collapse of the volcano, occurred at ca.
400 ka, shoshonitic rocks erupted from cinder cones and domes both within the caldera and on the external flanks of the pre-caldera
Roccamonfina volcano. On the basis of new trace element and Sr–Nd–Pb isotope data, we show that the Roccamonfina shoshonitic
rocks are distinct from shoshonites of the Northern Roman Province, but are very similar to those of the Neapolitan volcanoes.
The last phases of volcanic activity erupted sub-alkaline magmas as enclaves in trachytic domes, and as lavas within the Monte
Santa Croce dome. Ultrapotassic rocks of the pre-caldera composite volcano are plagioclase-bearing leucitites characterised
by high levels of incompatible trace elements with an orogenic signature having troughs at Ba, Ta, Nb, and Ti, and peaks at
Cs, K, Th, U, and Pb. Initial values of 87Sr/86Sr range from 0.70926 to 0.70999, 143Nd/144Nd ranges from 0.51213 to 0.51217, while the lead isotope rations vary between 18.788–18.851 for 206Pb/204Pb, 15.685–15.701 for 207Pb/204Pb, and 39.048–39.076 for 208Pb/204Pb. Shoshonites show a similar pattern of trace element depletions and enrichments to the earlier ultrapotassic leucite-bearing
rocks but have a larger degree of differentiation and lower concentrations of incompatible trace elements. On the other hand,
shoshonitic rocks have Sr, Nd, and Pb isotopes consistently different than pre-caldera ultrapotassic leucite-bearing rocks.
87Sr/86Sr ranges from 0.70665 to 0.70745, 143Nd/144Nd ranges from 0.51234 to 0.51238, 206Pb/204Pb ranges from 18.924 to 19.153, 207Pb/204Pb ranges from 15.661 to 15.694, and 208Pb/204Pb ranges from 39.084 to 39.212. High-K calc-alkaline samples have intermediate isotopic values between ultrapotassic plagioclase
leucitites and shoshonites, but the lowest levels of incompatible trace element contents. It is argued that ultrapotassic
magmas were generated in a modified lithospheric mantle after crustal-derived metasomatism. Interaction between the metasomatic
agent and lithospheric upper mantle produced a low-melting point metasomatised veined network. The partial melting of the
veins alone produced pre-caldera leucite-bearing ultrapotassic magmas. It was possibly triggered by either post-collisional
isotherms relaxation or increasing T°C due increasing heat flow through slab tears. Shoshonitic magmas were generated by further melting, at higher temperature,
of the same metasomatic assemblage with addition 10–20% of OIB-like astenospheric mantle material. We suggest that addition
of astenospheric upper mantle material from foreland mantle, flowing through slab tearing after collision was achieved.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. |
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| Keywords: | Sr– Nd– Pb isotopes Plagioclase leucitite Shoshonite Sub-alkaline basaltic andesite Roccamonfina volcano Roman Magmatic Province Orogenic magmas Slab tearing Asthenospheric inflow |
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