A Method for Rapid Determination of Re and Os Isotope Compositions Using ID‐MC‐ICP‐MS Combined with the Sparging Method |
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| Authors: | Tatsuo Nozaki Katsuhiko Suzuki Gregory Ravizza Jun‐Ichi Kimura Qing Chang |
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| Institution: | 1. Institute for Research on Earth Evolution, Japan Agency for Marine‐Earth Science and Technology, 2‐15 Natsushima‐Cho, Yokosuka City, Kanagawa 237‐0061, Japan;2. Submarine Resources Research Project, Japan Agency for Marine‐Earth Science and Technology, 2‐15 Natsushima‐Cho, Yokosuka City, Kanagawa 237‐0061, Japan;3. Precambrian Ecosystem Laboratory, Japan Agency for Marine‐Earth Science and Technology, 2‐15 Natsushima‐Cho, Yokosuka City, Kanagawa 237‐0061, Japan;4. Department of Geology and Geophysics, SOEST, University of Hawaii at Manoa, Honolulu, HI 96822, USA |
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| Abstract: | A simple, rapid method for the determination of Re and Os concentrations and isotope compositions using isotope dilution multi‐collector inductively coupled plasma‐mass spectrometry (ID‐MC‐ICP‐MS) combined with Carius tube digestion and sparging introduction of Os was developed. For Os measurement, four channeltron ion counters to detect different Os isotopes were used simultaneously, which led to a drastic reduction in the measurement time. Rhenium isotopes were measured by means of eight Faraday cups with solution nebulisation and an ultrasonic membrane desolvator. The representative 188Os count rate of an Os standard solution containing 50 pg of total Os was approximately 110000–120000 cps at the onset of measurement; the Re intensity of our in‐house 10 pg g?1 standard solution reached 1820 V/μg g?1 with a sample uptake rate of 95–99 μl min?1. These values indicate that the sensitivity of the method was sufficient even for samples with low Re and Os concentrations, such as chert. As the temporal variations of the amplification efficiency of the ion counters differed from one another, we adopted a sample‐calibrator bracketing method to correct the measured Re and Os isotope ratios. The Re and Os concentrations via the isotope dilution method and the 187Os/188Os ratios of two sedimentary rock reference materials (JMS‐2 and JCh‐1) on the basis of the isotope ratios determined by the MC‐ICP‐MS and by negative thermal ionisation mass spectrometry (N‐TIMS) were comparable within their ranges. Based on Os isotope measurement of the IAG reference material Durham Romil Os (DROsS)], the average difference from the recommended value and precision of Os isotope measurements by the sparging method in combination with multi‐ion‐counters were 0.72% and 0.76% 1RSD (%), n = 29], respectively. The precisions in the 187Os/188Os ratios 1RSD (%)] of JMS‐2, JCh‐1 and DROsS were 0.35–0.71, 1.56–3.31 and 0.99–1.28%, respectively, which depended on their Os ion intensities. No systematic difference was observed between the Re and Os geochemical compositions of JCh‐1 and JMS‐2 obtained by means of digestion with inverse aqua regia and CrO3‐H2SO4 solutions, suggesting that either acid solution can be used for the sparging method of sedimentary rock samples. As CrO3‐H2SO4 solution is believed to liberate predominantly the hydrogenous Re and Os fraction from organic‐rich sediment, the sparging method combined with CrO3‐H2SO4 digestion and multi‐ion‐counters in the mass spectrometry is expected to be a powerful tool for reconstructing the secular change in marine Os isotope compositions with high sample throughput. |
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| Keywords: | Re‐Os isotopes MC‐ICP‐MS multi‐ion‐counter sparging method geochemical reference materials isotopes du Re et de l’ Os MC‐ICP‐MS multi‐compteurs d’ ions mé thode de barbotage maté riaux gé ochimiques de ré fé rence |
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