Abstract: | The Institute of Geophysical and Geochemical Exploration in China recently prepared ten biogeochemical certified reference samples GSB1‐10 (CRMs). The samples are primary agricultural products such as rice, wheat, corn, soybean, cabbage, spinach, tea, powder, chicken and apple. Lyophilisation technology and a high‐alumina ball mill were used to process the samples. Fourteen laboratories and hundreds analysts in China participated in the certification analysis. Over ten reliable analytical methods, predominately ICP‐MS, ICP‐AES and INAA, were used for analysing the samples for fifty‐nine elements. A total of 22477 determinations led to 5136 average data sets. Certified values of fifty‐four elements were assigned. |