Preparation and Measurement of Cassiterite for Sn Isotope Analysis |
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| Authors: | Ryan Mathur Wayne Powell Andrea Mason Linda Godfrey Junming Yao Mark E Baker |
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| Institution: | 1. Juniata College, Huntingdon, PA, USA;2. Brooklyn College of the City University of New York, Brooklyn, NY, USA;3. The Graduate Center of the City University of New York, New York City, NY, USA;4. Department of Earth and Planetary Science, American Museum of Natural History, New York, NY, USA;5. Rutgers University, Piscataway, NJ, USA;6. Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, China;7. University of Arizona, Geosciences Department, Tucson, AZ, USA |
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| Abstract: | Increased interest in the fractionation of Sn isotopes has led to the development of several techniques for preparing cassiterite (SnO2, the primary ore of Sn) for isotopic analysis. Two distinct methods have been applied in recent isotopic studies of cassiterite: (a) reduction to tin metal with potassium cyanide (KCN) at high temperature (800 °C), with subsequent dissolution in HCl, and (b) reduction to a Sn solution with hydriodic acid (HI) at low temperature (100 °C). This study compares the effectiveness and accuracy of these two methods and contributes additional methodological details. The KCN method consistently yielded more Sn (> 70% in comparison with < 5%), does not appear to fractionate Sn isotopes at high temperatures over a 2‐hour period and produced consistent Sn isotope values at flux mass ratios of ≥ 4:1 (flux to mineral) with a minimum reduction time of 40 min. By means of a distillation experiment, it was demonstrated that HI could volatilise Sn, explaining the consistently low yields by this method. Furthermore, the distillation generated Sn vapour, which is up to 0.38‰ per mass unit different from the starting material, the largest induced Sn fractionation reported to date. Accordingly, the HI method is not recommended for cassiterite preparation for Sn isotopic analysis. |
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| Keywords: | Sn isotope fractionation cassiterite reduction of Sn method distillation volatilisation of Sn |
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