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A New Interlaboratory Characterisation of Silicon,Rare Earth Elements and Twenty‐Two Other Trace Element Concentrations in the Natural River Water Certified Reference Material SLRS‐6 (NRC‐CNRC)
Authors:Delphine Yeghicheyan  Dominique Aubert  Martine Bouhnik‐Le Coz  Jrme Chmeleff  Sophie Delpoux  Irina Djouraev  Guy Granier  Franois Lacan  Jean‐Luc Piro  Tristan Rousseau  Christophe Cloquet  Aurlie Marquet  Christophe Menniti  Catherine Pradoux  Rmi Freydier  Emmanoel Vieira da Silva‐Filho  Krzysztof Suchorski
Institution:Delphine Yeghicheyan,Dominique Aubert,Martine Bouhnik‐Le Coz,Jérôme Chmeleff,Sophie Delpoux,Irina Djouraev,Guy Granier,François Lacan,Jean‐Luc Piro,Tristan Rousseau,Christophe Cloquet,Aurélie Marquet,Christophe Menniti,Catherine Pradoux,Rémi Freydier,Emmanoel Vieira da Silva‐Filho,Krzysztof Suchorski
Abstract:The natural river water reference material SLRS‐6 (NRC‐CNRC) is the newest batch of a quality control material routinely used in many international environmental laboratories. This work presents a nine‐laboratory compilation of measurements of major and trace element concentrations and their related uncertainties, unavailable in the NRC‐CNRC certificate (B, Cs, Li, Ga, Ge, Hf, Nb, P, Rb, Rh, Re, S, Sc, Se, Si, Sn, Th, Ti, Tl, W, Y, Y, Zr and REEs). Measurements were mostly made using inductively coupled plasma‐mass spectrometry. The results are compared with equivalent data for the last batch of the material, SLRS‐5, measured simultaneously with SLRS‐6 in this study. In general, very low concentrations, close to the quantification limits, were found in the new batch. The Sr isotopic ratio is also reported.
Keywords:river water reference material  ICP‐MS     CRM     interlaboratory comparison  rare earth elements  trace elements
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