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济南市新旧动能转换区浅层地下水硝酸盐污染特征
引用本文:成世才.济南市新旧动能转换区浅层地下水硝酸盐污染特征[J].中国煤炭地质,2021(2).
作者姓名:成世才
作者单位:中化地质矿山总局山东地质勘查院
基金项目:济南市地质环境勘查项目(JNCZ(TQ)-GK-2018-0008)。
摘    要:为查清济南市新旧动能转换先行区浅层地下水NO3-污染问题,对研究区7种污染源类型64件浅层地下水样品水质结果进行统计分析后认为:受人类活动影响,地下水中NO3-含量的高低往往与几种特定的水化学类型存在对应关系。4类主要污染源类型浅层地下水NO3-含量一般顺序为:垃圾渗滤液>禽畜养殖>生活污水>农业种植。垃圾渗滤液下渗导致的NO3-污染对应的主要地下水化学类型为HCO3·Cl-Na·Mg型,粪便渗滤液及尿液下渗主要对应产生HCO3·SO4-Na·Mg型、生活污水入渗对应产生HCO3·Cl-Na·Ca型,农业种植区主要对应HCO3-Na·Ca型。离子相关性分析表明,NO3-含量与Ca2+、Cl-存在相关关系。研究区以农业种植为主,大量氮素化肥和石灰等土壤改良剂的使用是导致浅层地下水NO3-与Ca2+相关的主要因素。NO3-与Cl-在地下水中同属较稳定离子,由长期的人类活动排放、入渗积累或蒸发浓缩富集,是一个地区人类活动密集程度和历史长度的综合反映,提出了NO3-与Cl-质量浓度联合评价地下水污染的基本方法。

关 键 词:黄河冲积平原  浅层地下水  NO3-污染  地下水水化学类型  离子相关性

Shallow Groundwater Nitrate Pollution Features in Jinan City Zone to Replace Old Growth Drivers with New Ones
Cheng Shicai.Shallow Groundwater Nitrate Pollution Features in Jinan City Zone to Replace Old Growth Drivers with New Ones[J].Coal Geology of China,2021(2).
Authors:Cheng Shicai
Institution:(Shandong Geological Exploration Institute,China Chemical Geology and Mine Bureau,Jinan,Shandong 250013)
Abstract:To identify shallow groundwater NO3-pollution issue in the Jinan City prior zone to replace old growth drivers with new ones has carried out statistical analysis for water quality tested results of 64 shallow groundwater samples from 7 pollution sources;the study has considered that impacted by human activities,groundwater NO3-content differences have existed correspondence with several specific hydrochemical types.General NO3-content sequence of 4 categories main pollution source type shallow groundwater is:waste percolation filtrate>livestock farming>domestic sewage>agricultural cultivation.Waste percolation filtrate down infiltration caused NO3-pollution corresponding main groundwater hydrochemical type is HCO3·Cl-Na·Mg type,feces percolation filtrate and urine down infiltration mainly corresponding HCO3·SO4-Na·Mg type,domestic sewage infiltration corresponding HCO3·Cl-Na·Ca type,agricultural cultivation mainly corresponding HCO3-Na·Ca type.Ion correlation analysis has shown that NO3-content and Ca2+,Cl-is correlated.Study area economy is mainly agricultural cultivation,the use of a massive nitrogen fertilizer and lime etc soil ameliorant is the main factor to cause correlation between NO3-and Ca2+in shallow groundwater.NO3-and Cl-both belong to rather stable ion,from human activities discharge chronically,infiltration build-up or evaporation enrichment,thus an integrated expression of human activities density and length of history in an area.The study has also proposed basic approach to assess groundwater pollution from NO3-and Cl-combined mass concentration.
Keywords:Huanghe alluvial plain  shallow groundwater  NO3-pollution  groundwater hydrochemical type  ion correlation
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