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Hydrogen concentration profiles in quartz determined by a nuclear reaction technique
Authors:G J Clark  C W White  D D Allred  B R Appleton  I S T Tsong
Institution:1. Solid State Division, Oak Ridge National Laboratory, 37830, Oak Ridge, TN, USA
2. Materials Research Laboratory, The Pennsylvania State University, 16802, University Park, PA, USA
Abstract:The nuclear reaction 19F(1H, αγ) 16O has been used to determine the hydrogen concentration in natural and synthetic quartz samples. The depth-profile of the hydrogen concentration in these samples has been determined in detail for the smoky and X o quartzes. These profiles exhibit a region of high hydrogen concentration in the near surface region (down to a depth of ~2000Å), with a lower concentration in the bulk of the sample. The results provide a plausible explanation for the substantial disagreement between previous hydrogen analysis in these quartzes by other techniques. Evidence for hydrogen mobility in crystalline quartz under ion beam bombardment is presented and discussed.
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