Thermal phase transition of potassium sulfate,K2SO4 |
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| Authors: | Michihiro Miyake Ichiro Minato Shin-ichi Iwai |
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| Institution: | 1. Research Laboratory of Engineering Materials, Tokyo Institute of Technology, O-Okayama, Meguro-ku, 152, Tokyo, Japan
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| Abstract: | The thermal phase transition of K2SO4 has been investigated by high temperature polarized light microscopy. K2SO4 undergoes a first-order transition at 587° C where the orthorhombic low temperature form (Pmcn) transforms into a hexagonal high temperature modification (P63/mmc). Prior to the beginning of the phase transition, K2SO4 shows an anomalous optical behavior. The crystal apparently becomes optically uniaxial twice at 338° and 425° C, respectively, and truly optically uniaxial at 587° C. The phase transition propagates through an intermediate temperature form, which is sandwiched between the low and the high temperature forms and moves in a definite direction, 〈130〉 (orthorhombic indices), in the vicinity of the phase transition. Passing through the phase transition point on cooling, dark belts crossing each other are observed which are a result of the transformation twins parallel to {110} and {130}. |
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