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Iodine-rich waters involved in supergene enrichment of the Mantos de la Luna argentiferous copper deposit,Atacama Desert,Chile
Authors:Martin Reich  Carlos Palacios  Macarena Alvear  Eion M Cameron  Matthew I Leybourne  Artur Deditius
Institution:(1) Departamento de Geología, Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Santiago, Chile;(2) Eion Cameron Geochemical Inc., 865 Spruce Ridge Road, Carp, Ontario, K0A 1L0, Canada;(3) Ocean Exploration, GNS Science, P.O. Box 30-368, Lower Hutt, New Zealand;(4) Department of Geological Sciences, University of Michigan, Ann Arbor, MI, USA;(5) Present address: CSIRO Division of Exploration and Mining, 26 Dick Perry Avenue, Kensington, WA 6151, Australia
Abstract:Recent studies have suggested the involvement of highly saline deep formation waters that modified preexisting Cu assemblages to form atacamite during supergene oxidation of Cu deposits in the Atacama region. In this report, we document the occurrence of (Ag–I) inclusions hosted by supergene chalcocite from Mantos de la Luna, an argentiferous Upper Jurassic stratabound Cu deposit in the Coastal Range of northern Chile. The presence of this unusual mineral assemblage indicates that iodargyrite precipitated from reducing iodine-rich waters, suggesting that the fluids involved in supergene enrichment of Cu deposits in the Coastal Range were more complex than previously thought. This suggests the prevalence of hyperarid conditions during the latest stages of supergene enrichment of the Mantos de la Luna Cu deposit in the Atacama region, supporting the notion that supergene enrichment processes in hyperarid areas are dynamic in nature and do not exclusively require the presence of meteoric water.
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