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自然水体生物膜、悬浮颗粒物和沉积物吸附铅、镉的热力学参数比较
引用本文:董德明,刘亮,高明,花修艺,李鱼.自然水体生物膜、悬浮颗粒物和沉积物吸附铅、镉的热力学参数比较[J].吉林大学学报(地球科学版),2006,36(5):847-850.
作者姓名:董德明  刘亮  高明  花修艺  李鱼
作者单位:吉林大学,环境与资源学院,长春,130012
摘    要:采用实验室模拟的方法研究了松花江自然水体生物膜、悬浮颗粒物和沉积物吸附铅、镉的热力学规律。根据吸附热力学参数(Γmax、k和Kd)综合比较3种固相物质的吸附能力,并讨论吸附能力存在差异的原因。结果表明:Langmuir型及Freundlich等温式可以很好地描述3种固相物质吸附热力学规律,三者吸附铅、镉的能力为生物膜>悬浮颗粒物>沉积物,生物膜、悬浮颗粒物和沉积物对铅的吸附能力均明显高于对镉的吸附能力。

关 键 词:生物膜  悬浮颗粒物  沉积物  吸附
文章编号:1671-5888(2006)05-0847-04
收稿时间:2005-10-10
修稿时间:2005年10月10日

Comparison of Adsorption Thermodynamics Parameters of Lead and Cadmium onto the Biofilm, Suspended Solids and Sediment
DONG De-ming,LIU Liang,GAO Ming,HUA Xiu-yi,LI Yu.Comparison of Adsorption Thermodynamics Parameters of Lead and Cadmium onto the Biofilm, Suspended Solids and Sediment[J].Journal of Jilin Unviersity:Earth Science Edition,2006,36(5):847-850.
Authors:DONG De-ming  LIU Liang  GAO Ming  HUA Xiu-yi  LI Yu
Institution:Collegeof Environment and Resources, Jilin University, Changchun 130012,China
Abstract:The adsorption thermodynamic characteristics of Pb and Cd onto natural biofilm, suspended solids and sediments collected from Songhua River were firstly investigated. The adsorption capacity of these three adsorbents was compared on the basis of adsorption thermodynamics parameters and the reasons of difference of adsorption capacity were also discussed. The results indicate that the classical Langmuir and Freundlich adsorption isotherm can be used to well describe the adsorption thermodyna- mics of Pb and Cd. The decreasing order of adsorption capacity of three adsorbents is in the decreasing order of biofilm, suspended solids and sediments and the adsorption capacity of Pb onto these adsorbents is significantly higher than that of Cd.
Keywords:biofilm  suspended solids  sediment  adsorption
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