| 白德奎,朱霞萍,王艳艳,曾美兰.氧化锰、氧化铁、氧化铝对砷（Ⅲ）的吸附行为研究[J].岩矿测试,2010,29(1):55-60 |
| BAI De kui,ZHU Xia ping,WANG Yan yan,ZENG Mei lan.Study on Adsorption Behaviors of As(Ⅲ) by Manganese Oxide, Iron Oxide and Aluminium Oxide[J].Rock and Mineral Analysis,2010,29(1):55-60.DOI: |
| 氧化锰、氧化铁、氧化铝对砷（Ⅲ）的吸附行为研究 |
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| Study on Adsorption Behaviors of As(Ⅲ) by Manganese Oxide, Iron Oxide and Aluminium Oxide |
| 投稿时间：2009-04-14 修订日期：2009-06-25 |
| DOI： |
| 中文关键词: 氧化锰 氧化铁 氧化铝 砷 吸附 |
| 英文关键词: manganese oxide iron oxide aluminium oxide arsenic adsorption |
| 基金项目:广东省地质调查项目资助（1212010 511216-04-02-01） |
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| 摘要点击次数: 1547 |
| 全文下载次数: 1784 |
| 中文摘要: |
| 合成了氧化锰、氧化铁、氧化铝三种矿物，以氧化铁、氧化锰为吸附剂研究了pH值、离子强度和时间等因素对吸附As(Ⅲ)的影响，并讨论了氧化锰、氧化铁、氧化铝三种矿物对As(Ⅲ)的饱和吸附容量及等温吸附实验。pH值对氧化锰吸附As(Ⅲ)几乎不影响，对氧化铁吸附As(Ⅲ)在很大的范围内（pH为3.5～8.5）影响不大，离子强度对二者吸附As(Ⅲ)的影响不大，吸附反应在0.5 h左右达到吸附平衡。在优化吸附条件下氧化锰、氧化铁、氧化铝对As(Ⅲ)的饱和吸附容量分别为48.38 mg/g、23.70 mg/g、3.52 mg/g，三种合成矿物对As(Ⅲ)的饱和吸附容量：氧化锰>氧化铁>氧化铝。对实验数据进行Freundlich和Langmuir拟合，相关系数R均在0.98以上，吸附动力学符合Lagergren二级速率方程。 |
| 英文摘要: |
| Three minerals of manganese oxide, iron oxide and aluminium oxide were synthesized and the effects of pH value and ionic strength of the solution, adsorption equilibrium time on adsorption of As(Ⅲ) by manganese oxide and iron oxide were studied. And the saturated adsorption capacity and the isothermal adsorption of As(Ⅲ) by three minerals were also tested. The results showed that pH value had less influence on adsorption of As(Ⅲ) by manganese oxide and less influence on adsorption of As(Ⅲ) by iron oxide in pH range of 3.5～8.5. The results also showed that ionic strength had less effect on adsorption of As(Ⅲ) by iron oxide and manganese oxide. The adsorption equilibrium time was about half an hour. The order of the saturated adsorption capacity of As(Ⅲ) by three minerals was: manganese oxide>iron oxide>aluminium oxide with saturated adsorption capacities of 48.38 mg/g, 23.70 mg/g and 3.52 mg/g respectively under the optimized adsorption condition. The adsorption data were fitted by both Freundlich and Langmuir isotherm models with correlation coefficient of R>0.98 and adsorption kinetic data correlated well with Lagergren second kinetic equation. |
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