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1.
Exploration and exploitation of groundwater in sedimentary areas are reasonably simple. However, the problem of salinity in coastal areas makes the job very difficult, especially when the freshwater aquifers are not extensive and are entrapped between saline aquifers. States along the eastern coast of India, particularly Orissa with respect to the Mahanadi basin, have acute problems with groundwater salinity. It has been possible to locate horizons of fresh groundwater entrapped between deep saline aquifers in the southwestern part of Mahanadi delta, with the help of deep resistivity soundings along the Delang-Puri profile. This finding has been validated through boreholes and checked with electrical logs of this region. Three freshwater aquifers have been detected: one at shallow depth between 20 and 60?m, the second in the depth range of 90??60?m, and the third in the fractured/weathered basement. The second freshwater aquifer has the most potential; it has a thickness range of 20??0?m and it could be exploited to overcome problematic salinity issues. In general, the depth to basement is variable and it increases seaward.  相似文献   

2.
Wadi Zerka Ma’in catchment area is located to the north east of the Dead Sea. It has two types of aquifers: (a) an upper unconfined aquifer and (b) a lower confined aquifer. The two aquifers are separated by a marl aquiclude. A major strike slip fault passes perpendicularly through the two aquifers and the aquiclude layer with embedded normal faults. The aim of the study was to specify the effect of the major strike slip fault on the groundwater chemistry. The spatial variability of the hydrochemical compositions and physiochemical parameters of the groundwater were investigated. It was found that the embedded normal faults, of the strike slip fault, form conduits that allow groundwater to flow from the lower aquifer to the upper aquifer, resulting in mixed groundwater. The ratio of mixing was estimated to be 94 % groundwater from the upper aquifer and 6 % from the lower aquifer. Since groundwater in the lower aquifer is around three times more saline than the upper aquifer, water mixing into the upper water aquifer generates a salinity hazard.  相似文献   

3.
TDEM (time domain electromagnetic) traverses in the Dead Sea (DS) coastal aquifer help to delineate the configuration of the interrelated fresh-water and brine bodies and the interface in between. A good linear correlation exists between the logarithm of TDEM resistivity and the chloride concentration of groundwater, mostly in the higher salinity range, close to that of the DS brine. In this range, salinity is the most important factor controlling resistivity. The configuration of the fresh–saline water interface is dictated by the hydraulic gradient, which is controlled by a number of hydrological factors. Three types of irregularities in the configuration of fresh-water and saline-water bodies were observed in the study area: 1. Fresh-water aquifers underlying more saline ones ("Reversal") in a multi-aquifer system. 2. "Reversal" and irregular residual saline-water bodies related to historical, frequently fluctuating DS base level and respective interfaces, which have not undergone complete flushing. A rough estimate of flushing rates may be obtained based on knowledge of the above fluctuations. The occurrence of salt beds is also a factor affecting the interface configuration. 3. The interface steepens towards and adjacent to the DS Rift fault zone. Simulation analysis with a numerical, variable-density flow model, using the US Geological Survey's SUTRA code, indicates that interface steepening may result from a steep water-level gradient across the zone, possibly due to a low hydraulic conductivity in the immediate vicinity of the fault. Electronic Publication  相似文献   

4.
In the coastal region of Bangladesh, groundwater is mainly used for domestic and agricultural purposes, but salinization of many groundwater resources limits its suitability for human consumption and practical application. This paper reports the results of a study that has mapped the salinity distribution in different aquifer layers up to a depth of 300 m in a region bordering the Bay of Bengal based on the main hydrochemistry and has investigated the origin of the salinity using Cl/Br ratios of the samples. The subsurface consists of a sequence of deltaic sediments with an alternation of more sandy and clayey sections in which several aquifer layers can be recognized. The main hydrochemistry shows different main water types in the different aquifers, indicating varying stages of freshening or salinization processes. The most freshwater, soft NaHCO3-type water with Cl concentrations mostly below 100 mg/l, is found in the deepest aquifer at 200–300 m below ground level (b.g.l.), in which the fresh/saltwater interface is pushed far to the south. Salinity is a main problem in the shallow aquifer systems, where Cl concentrations rise to nearly 8000 mg/l and the groundwater is mostly brackish NaCl water. Investigation of the Cl/Br ratios has shown that the source of the salinity in the deep aquifer is mixing with old connate seawater and that the saline waters in the more shallow aquifers do not originate from old connate water or direct seawater intrusion, but are derived from the dissolution of evaporite salts. These must have been formed in a tidal flat under influence of a strong seasonal precipitation pattern. Long dry seasons with high evaporation rates have evaporated seawater from inundated gullies and depressions, leading to salt precipitation, while subsequent heavy monsoon rains have dissolved the formed salts, and the solution has infiltrated in the subsoil, recharging groundwater.  相似文献   

5.
In the salinity affected lower Atrai floodplain aquifer in the NW Bangladesh, geoelectric resistivity survey and hydrochemical analysis are carried out with an aim to identify fresh and saline groundwater zones; investigate the status of salinity; evaluate hydrochemical processes involved and suggest management approaches for irrigation. Here a two-fold aquifer system, inter-layered by silt, clay and silty-clay aquitard and aquiclude is classified as: upper aquifer — spatially affected by salinity of varying degrees; and lower aquifer — generally characterized by high salinity. The aquifer with resistivity values greater than 69 Ωm is safe for irrigation use. Concentrations of major ions vary as: Ca2+>Na+>Mg2+>K+ and HCO3>Cl>NO3>SO4 2?. Groundwater is dominated by Na-Ca to Ca-Na, HCO3-Cl-SO4, Cl-SO4-HCO3 and Cl-SO4 2? facies where Ca2+, Mg2+, SO4 2?, HCO3 ?, Cl? and NO3 2? ion concentrations are statistically dominant and water is of Ca-Mg, HCO3-SO4-Cl and NO3 types. Geochemically, groundwater is hard and saline to fresh water type. Salinity increases with depth, but spatially towards the southern part. Groundwater quality is a product of water-rock interaction, direct mixing and marine spraying, or fall-out of airborne marine salts, where silicate weathering is the primary source of bivalent cations. Sediment provenance of alkaline earth silicates and higher concentrations of alkalis are derived from sources other than precipitation. In general partially or fully salinity affected upper and lower aquifers in the area except in its eastern part are not suitable for tubewell irrigation. As groundwater demand for irrigation is increasing, the saline water has progressively invaded relatively fresher parts of the aquifer by upconning. So, special salinity control management approaches can be adopted through engineering techniques such as groundwater abstraction optimization, as also through scientific behavioral approaches like groundwater demand management, salt tolerant crops production. In this context, surface water conservation and rain water harvesting for domestic and irrigational uses are recommended in the salinity affected area.  相似文献   

6.
The natural and pumping-induced controls on groundwater salinization in the coastal aquifers of North Carolina, USA, and the implications for the performance of a reverse osmosis (RO) desalination plant have been investigated. Since installation of the well field in the Yorktown aquifer in Kill Devil Hills of Dare County during the late 1980s, the groundwater level has declined and salinity of groundwater has increased from ??1,000 to ??2,500 mg/L. Geochemical and boron isotope analyses suggest that the salinity increase is derived from an upflow of underlying saline groundwater and not from modern seawater intrusion. In the groundwater of four wells supplying the plant, elevated boron and arsenic concentrations were observed (1.3?C1.4 mg/L and 8?C53 ??g/L, respectively). Major ions are effectively rejected by the RO membrane (96?C99% removal), while boron and arsenic are not removed as effectively (16?C42% and 54?C75%, respectively). In coming decades, the expected rise of salinity will be associated with higher boron content in the groundwater and consequently also in the RO-produced water. In contrast, there is no expectation of an increase in the arsenic content of the salinized groundwater due to the lack of increase of arsenic with depth and salinity in Yorktown aquifer groundwater.  相似文献   

7.
Unconsolidated sand, gravel and clay deposits near Beihai and in the Leizhou Peninsula in southern China form an unconfined aquifer, aquitard and a confined aquifer. Water and soil samples were collected from the two aquifers in the coastal Beihai area for the determination of chemical compositions, minerals and soluble ions. Hydrogeochemical modeling of three flow paths through the aquitard are carried out using PHREEQC to determine water–rock interactions along the flow paths. The results indicate that the dissolution of anorthite, fluorite, halite, rhodochrosite and CO2, and precipitation of potash feldspar and kaolinite may be occurring when groundwater leaks through the aquitard from the unconfined aquifer to the confined aquifer. Cation exchanges between Na and Ca can also happen along the flow paths.  相似文献   

8.
Coastal aquifers are considered as major sources for freshwater supply worldwide, especially in arid zones. The weak rainfall as well as the intensive extraction of groundwater from coastal aquifers reduce freshwater budget and create local water aquifer depression, causing both seawater intrusion and a threat to groundwater. This phenomenon was observed in the Jerba Island which is located in southeast Tunisia. Jerba??s unconfined aquifer shows high values of groundwater salinity reaching, locally, 17?g/l and a strong contrast between some zones of the aquifer. High pumping rates and weak recharge disturb the natural equilibrium between fresh and saline water causing water salinization in most areas of the island. This study aims at establishing the salinity map of the aquifer and identifying the origin of groundwater salinization. The salinity map shows that zones characterized by low groundwater salinity are located in the center of the study area. High groundwater salinities are observed near the coast and in some parts having low topographic and piezometric levels. Groundwater geochemical characterization, and Br/Cl and Na/Cl ratios suggest that the origin of abnormal salinity is seawater intrusion. Considering groundwater salinity values and Br concentrations, a seawater intrusion map is established. It shows that many areas of the unconfined aquifer are contaminated by mixed groundwater and seawater. The statistical analysis demonstrates that high mineralization of the groundwater is due to gypsum and carbonate dissolution coupled with the mixed groundwater and seawater in many areas.  相似文献   

9.
Transient Electromagnetic (TEM), known also as Time Domain Electromagnetic (TDEM) and Magnetic Resonance Sounding (MRS) methods were applied jointly to investigate variations in lithology and groundwater salinity in the Nahal Hever South area (Dead Sea coast of Israel). The subsurface in this area is highly heterogeneous and composed of intercalated sand and clay layers over a salt formation, which is partly karstified. Groundwater is very saline, with a chloride concentration of 100–225 g/l. TEM is known as an efficient tool for investigating electrically conductive targets like saline water, but it is sensitive to both the salinity of groundwater and the porosity of rocks. MRS, however, is sensitive primarily to groundwater volume, but it also allows delineating of lithological variations in water-saturated formations. MRS is much less sensitive to variations in groundwater salinity in comparison with TEM. We show that MRS enables us to resolve the fundamental uncertainty in TEM interpretation caused by the equivalence between groundwater resistivity and lithology. Combining TEM and MRS, we found that the sandy Dead Sea aquifer filled with Dead Sea brine is characterized by a bulk resistivity of ρx > 0.4 Ωm, whereas zones with silt and clay in the subsurface are characterized by a bulk resistivity of ρx < 0.4 Ωm. These observations are confirmed by calibration of the TEM method performed near 18 boreholes.  相似文献   

10.
A model has been established on the origin and extent of fresh groundwater, salty paleowaters and saltwater from recent seawater intrusions in the Red River flood plain in Vietnam. This was done with geological observations, geophysical borehole logging and transient electromagnetic methods. Salt paleowater is present up to 50–75?km from the coastline, with occurrence controlled by the Holocene transgression. A density-driven leaching of salty porewater has occurred from high-permeability Holocene sediments into underlying Pleistocene deposits, whereas diffusion has dominated in low-permeability layers. In the Pleistocene aquifer, the highest content of dissolved solids is found below two intrinsic valleys with Holocene marine sediments and along the coastline. Recent intrusion of saltwater from the South China Sea is observed in shallow groundwater 35?km inland, probably a result of transport of salty water inland in rivers or leaching of paleowaters from very young near-coast marine sediments. The observed inverted salinity profile, with high saline water overlying fresher groundwater, has been formed due to the global eustatic sea-level changes during the last 8,000–9,000?years. The proposed model may therefore be applicable to other coastal aquifers, with a proper incorporation of the local geological environments.  相似文献   

11.
The alluvial aquifer is the primary source of groundwater along the eastern Dead Sea shoreline, Jordan. Over the last 20 years, salinity has risen in some existing wells and several new wells have encountered brackish water in areas thought to contain fresh water. A good linear correlation exists between the water resistivity and the chloride concentration of groundwater and shows that the salinity is the most important factor controlling resistivity. Two-dimensional electrical tomography (ET) integrated with geoelectrical soundings were employed to delineate different water-bearing formations and the configuration of the interface between them. The present hydrological system and the related brines and interfaces are controlled by the Dead Sea base level, presently at 410 m b.s.l. Resistivity measurements show a dominant trend of decreasing resistivity (thus increasing salinity) with depth and westward towards the Dead Sea. Accordingly, three zones with different resistivity values were detected, corresponding to three different water-bearing formations: (1) strata saturated with fresh to slightly brackish groundwater; (2) a transition zone of brine mixed with fresh to brackish groundwater; (3) a water-bearing formation containing Dead Sea brine. In addition, a low resistivity unit containing brine was detected above the 1955 Dead Sea base level, which was interpreted as having remained unflushed by infiltrating rain.  相似文献   

12.
The aim of this article is to assess the main factors influencing salinity of groundwater in the coastal area between El Dabaa and Sidi Barani, Egypt. The types and ages of the main aquifers in this area are the fractured limestone of Middle Miocene, the calcareous sandstone of Pliocene and the Oolitic Limestone of Pleistocene age. The aquifers in the area are recharged by seasonal rainfall of the order of 150 mm/year. The relationship of groundwater salinity against the absolute water level, the well drilling depth, and the ability of aquifer to recharge has been discussed in the present work. The ability of aquifer to locally recharge by direct rainfall is a measure of the vertical permeability due to lithological and structural factors that control groundwater salinity in the investigated aquifers. On the other hand, the fracturing system as well as the attitude of the surface water divide has a prime role in changing both the mode of occurrence and the salinity of groundwater in the area. Directly to the west of Matrouh, where the coastal plain is the narrowest, and east of Barrani, where the coastal plain is the widest, are good examples of this concept, where the water salinity attains its maximum and minimum limits respectively. Accordingly, well drilling in the Miocene aquifer, in the area between El Negila and Barrani to get groundwater of salinities less than 5000 mg/l is recommended in this area, at flow rate less than 10 m3/hr/well. In other words, one can expect that the brackish water is probably found where the surface water divide is far from the shore line, where the Wadi fill deposits dominate (Quaternary aquifer), acting as a possible water salinity by direct rainfall and runoff.  相似文献   

13.
This study is an attempt to quantify the geochemical processes and the timescale of seawater intrusion into a coastal aquifer from changes in the major ionic composition of the water and the natural distribution of the cosmogenic isotopes 14C and 3H. For that purpose, we sampled saline and brackish groundwaters from the Israeli coastal aquifer. A multilayer sampler (MLS) was used to obtain very high resolution (10 cm) profiles across the fresh-saline water interface (FSI).The chemical and stable isotope data revealed three distinct water types (end members) that are located in different zones on the route to the coastal aquifer: (1) slightly modified Mediterranean seawater (SWS); (2) slightly diluted (with up to 20% fresh groundwater) saline groundwater (SDS); and (3) fresh groundwater (FGW).The SWS samples generally show an excess of total alkalinity and total dissolved inorganic carbon (DIC), and a depletion of 13CDIC and 14CDIC with respect to normal seawater indicating that anaerobic oxidation of organic matter is the first diagenetic reaction that affects seawater during its penetration into the bottom sediments. SDS waters appear when SWS is slightly diluted, gain Ca2+ and Sr2+, and is depleted in K+, suggesting that the main processes that transform SWS into SDS are slight dilution with fresh groundwater and cation exchange. At the fresh-saline water interface, SDS generally shows conservative mixing with FGW.Inspection of chemical data from coastal aquifers around the world indicates that intensive ion exchange in slightly diluted saline groundwater is a globally important phenomenon of seawater intrusion. Most of our saline groundwater samples contain substantial amounts of 3H suggesting that penetration of Mediterranean seawater and its inland travel to a distance of 50-100 m onshore occurred 15-30 yr ago. This is supported by the 14CDIC mass balance that explains the relatively low 14CDIC activities in the SDS as influenced by diagenesis and not by simple radioactive decay.  相似文献   

14.
Managing environmental problems in Cuban karstic aquifers   总被引：1，自引：0，他引：1  
The study area is located along the Dead Sea Rift, the climate is considered arid in its southern margin near the Dead Sea, which is the lowest water reservoir found on the globe (412 m BSL), to semiarid in its northern part. During the last few decades, the water resources became depleted limiting the natural development of the agricultural settlements, which are the most common type of communities in the region. Previous studies suggested that a large amount of freshwater is lost as the result of salinization processes, which occur when fresh groundwater from the mountain aquifers, flow into the saline clastic Neogene aquifer complex. In order to comprehend this complex system, a detailed outlining of the regional hydrogeological system is essential. Since there are no boreholes, which penetrate the aquiferous rock sequences within the Rift, it was necessary to interpolate a large variety of data from several fields of geosciences. The methods applied included geological mapping, geophysical modeling based on interpretation of seismic profiles and geochemical modeling based on chemical and isotopic analysis of runoff, sediments and groundwater. The combined modeling based on results from the different types of analyses implied to several conclusions relevant to the regional water management policy: (1) groundwater becomes saline as it flows from the margins of the Rift to its center. Therefore, it is recommended to exploit it along the foothills of the rift escarpment. (2) Geophysical modeling indicated that the foothills and the Karstic mountain aquifer extend into the subsurface of the valley and can be farther exploited (up to 15 mm3 per annum) by relatively shallow wells. (3) Several mechanisms of groundwater salinization were deciphered: (a) the dense vertical faulting systems act as potential conduits for saline water, which flow-up from deep-seated sources and penetrate into the fresh aquifers. (b) Fresh groundwater in the clastic aquifer complex is rare, furthermore, two evaporates bodies were encountered (Auja and Zaharat el Qurein), also acting as sources for fresh water salinization. (c) Although the quantity of runoff recharge to the Jordan Valley aquifer complex is negligible, the increase in its salt-content (TDS) turns this negligible freshwater recharge to a significant contributor of salts.  相似文献   

15.
上海市地下水位大幅抬升条件下土层变形特征分析   总被引：1，自引：0，他引：1       下载免费PDF全文
过去对地下水位持续下降条件的地面沉降研究较多,但对水位大幅持续抬升过程中的地面沉降研究较少。本文根据 上海大量地面沉降、水位观测和钻孔资料,系统分析上海市90年代末以来地下水位大幅抬升条件下各土层的变形特征。自 1998年以来,上海市通过大幅压缩开采量、回灌地下水等措施使第二、三、四和五承压含水层水位分别平均抬升2.1 m, 3.6 m, 12.4 m, 12.7 m。水位的抬升使上海市地面沉降平均速率由1998年的12.2 mm/a减小到2011年的1.83 mm/a,减少85%。 通过对27组分层标数据分析发现：现阶段主要压缩层位在第一、二软土层,年沉降速率为2~4 mm/a;而第二含水层以下土 层已经有少量回弹。在水位持续大幅抬升过程中,本文总结了两种变形特征：1） 变形和水位变化基本同步,残余变形量非 常小,变形可概化为线弹性变形,这种变形主要发生在第一、二、三和五承压含水层、第五和六弱透水层;2） 压缩速率逐 渐减小,无明显持续回弹趋势,有较大残余压缩量且存在变形滞后现象,变形可概化为弹塑性变形,这种变形主要发生在 地第二、三和四弱透水层。第四承压含水层变形较复杂,两种变形特征都有。其中较大残余变形量主要由塑性贮水率比弹 性贮水率大2个数量级引起;变形滞后主要由弱透水层中超孔隙水压力消散较慢引起。本文研究成果对于掌握水位抬升过 程中土层变形方式、发生发展机理、预测未来地面沉降及地下水科学管理和资源评价具有重要意义。  相似文献   

16.
A significant component of domestic demand for water of urban areas located in the Gangetic plains is met by heavy pumping of groundwater. The present study is focused on the Patna municipal area, inhabited by 17 million people and spanning over 134 km2, where entire urban water demand is catered from pumping by wells of various capacities and designs. The present study examines the nature of the aquifer system within the urban area, the temporal changes in the water/piezometric level and the recharge mechanism of the deeper aquifers. The aquifer system is made up of medium-to-coarse unconsolidated sand, lying under a ~40-m-thick predominantly argillaceous unit holding 8- to 13-m-thick localised sand layers and continues up to 220 m below ground. Groundwater occurs under semi-confined condition, with transmissivity of aquifers in 5,500–9,200 m2 day?1 range. Hydraulic head of the deeper aquifer remains in 9–19 m range below ground, in contrast to 1–9 m range of that of the upper aquitard zone. The estimated annual groundwater extraction from the deeper aquifer is ~212.0 million m3, which has created a decline of 3.9 m in the piezometric level of the deeper aquifer during the past 30 years. Unregulated construction of deep tube wells with mushrooming of apartment culture may further exacerbate the problem. The sand layers within the aquitard zone are experiencing an annual extraction of 14.5 million m3 and have exhibited stable water level trend for past one and half decades. This unit is recharged from monsoon rainfall, besides contribution from water supply pipe line leakage and seepage from unlined storm water drains.  相似文献   

17.
The current study introduces the geological subsurface cross-sections in the southern part of the Gaza Strip to show the structure of the aquifer in the area. The cross-sections give evidence of four subaquifers of the coastal aquifer in the southern part of the Gaza Strip. These cross-sections give the natural reasons for the deterioration of the groundwater in the study area. The results show presence of clay lenses that prevent the replenishment processes of the aquifer of fresh water from the rainfall and returns flow from agricultural activities. Lithological formation was evident as one of the natural causes which accelerate destroying process of the coastal aquifer. The results also show that the structure of the aquifer causes the increase of the groundwater salinity in the Gaza Strip. The cross-sections had shown the shortage of storage capacity of high quantities of fresh water in the coastal aquifer in these areas. The role of lithological formation was evident as one of the natural causes to accelerate the process of destroying the coastal aquifer.  相似文献   

18.
Evaporite karst has intensively developed recently along the Dead Sea (DS) coastal area in Israel and Jordan. It takes place in very saline groundwater dissolving buried salt layers, causing collapse of the surface. In this paper, groundwater salinity throughout the DS coastal area is investigated using the Transient Electromagnetic (TEM) method. Twenty-eight TEM soundings along the DS coastal area were carried out close to observation boreholes to calibrate resistivity–salinity relationships. Groundwater electrical conductivity was measured in these boreholes, and its salinity was analyzed at the laboratory by the Geological Survey of Israel (GSI). Quantitative relationships between bulk resistivity (ρx), water resistivity (ρw) and chloride concentration (Ccl) were derived in the resistivity range less than 1.0 Ω·m that enabled to evaluate the salinity of the aquifer in in situ conditions. Average values of the effective porosity of sandy sediments, φe = 0.32, and of silty ones, φe = 0.44, were used to generate the corresponding Archie equations. The study has shown that a DS aquifer with bulk resistivity in the range of 0.55–1.0 Ω·m contains in pores brine with 50–110 gchloride/l of (22–50% of that in saturated conditions, respectively), i.e. it keeps the potential to dissolve up to 114–174 g/l of salt.  相似文献   

19.
The El Minia governorate lies within the Nile Valley, surrounded by calcareous plateaus to the east and west. The present study focuses on the hydrogeochemistry of the Eocene limestone aquifer at some wadis in the east El Minia governorate, Eastern Desert, Egypt. Hydrogeologically, two main aquifers are encountered in the study area, namely the Maghagha marly limestone and the Samalut chalky limestone aquifers. The Maghagha aquifer is composed of alternating layers of marly limestone and shale with thicknesses ranging from 3.49 m to 177.05 m and a groundwater depth ranging from 8.5 m to 59.27 m which reflects low groundwater potentiality. The groundwater salinity representing this aquifer ranges from 603.5 mg/L to 978.5 mg/L, reflecting fresh water type. Samalut aquifer is made up of chalky, cavernous and fractured limestone with thickness ranging from 30 m to 205 m and groundwater depth ranging from 9 m to 86.77 m, which indicates good groundwater potential. The groundwater salinity of the concerned aquifer ranges from 349.7 mg/L to 2043.9 mg/L, reflecting fresh to possibly brackish water types. Groundwater in the study area is of meteoric water origin; recent recharge is mainly controlled through the presence of fractures and their densities. The majority of groundwater samples in the study area are suitable for drinking and irrigation purposes.  相似文献   

20.
In this study a typical coastal karst aquifer, developed in lower Cretaceous limestones, on the western Mediterranean seashore (La Clape massif, southern France) was investigated. A combination of geochemical and isotopic approaches was used to investigate the origin of salinity in the aquifer. Water samples were collected between 2009 and 2011. Three groundwater groups (A, B and C) were identified based on the hydrogeological setting and on the Cl− concentrations. Average and maximum Cl− concentrations in the recharge waters were calculated (ClRef. and ClRef.Max) to be 0.51 and 2.85 mmol/L, respectively). Group A includes spring waters with Cl− concentrations that are within the same order of magnitude as the ClRef concentration. Group B includes groundwater with Cl− concentrations that range between the ClRef and ClRef.Max concentrations. Group C includes brackish groundwater with Cl− concentrations that are significantly greater than the ClRef.Max concentration. Overall, the chemistry of the La Clape groundwater evolves from dominantly Ca–HCO3 to NaCl type. On binary diagrams of the major ions vs. Cl, most of the La Clape waters plot along mixing lines. The mixing end-members include spring waters and a saline component (current seawater or fossil saline water). Based on the Br/Clmolar ratio, the hypothesis of halite dissolution from Triassic evaporites is rejected to explain the origin of salinity in the brackish groundwater.Groundwaters display 87Sr/86Sr ratios intermediate between those of the limestone aquifer matrix and current Mediterranean seawater. On a Sr mixing diagram, most of the La Clape waters plot on a mixing line. The end-members include the La Clape spring waters and saline waters, which are similar to the deep geothermal waters that were identified at the nearby Balaruc site. The 36Cl/Cl ratios of a few groundwater samples from group C are in agreement with the mixing hypothesis of local recharge water with deep saline water at secular equilibrium within a carbonate matrix. Finally, PHREEQC modelling was run based on calcite dissolution in an open system prior to mixing with the Balaruc type saline waters. Modelled data are consistent with the observed data that were obtained from the group C groundwater. Based on several tracers (i.e. concentrations and isotopic compositions of Cl and Sr), calculated ratios of deep saline water in the mixture are coherent and range from 3% to 16% and 0% to 3% for groundwater of groups C and B, respectively.With regard to the La Clape karst aquifer, the extension of a lithospheric fault in the study area may favour the rise of deep saline water. Such rises occur at the nearby geothermal Balaruc site along another lithospheric fault. At the regional scale, several coastal karst aquifers are located along the Gulf of Lion and occur in Mezosoic limestones of similar ages. The 87Sr/86Sr ratios of these aquifers tend toward values of 0.708557, which suggests a general mixing process of shallow karst waters with deep saline fossil waters. The occurrence of these fossil saline waters may be related to the introduction of seawater during and after the Flandrian transgression, when the highly karstified massifs invaded by seawater, formed islands and peninsulas along the Mediterranean coast.  相似文献   

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