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1.
Variability in soil respiration at various spatial and temporal scales has been the focus of much research over the last decade aimed to improve our understanding and parameterization of physical and environmental controls on this flux. However, few studies have assessed the control of landscape position and groundwater table dynamics on the spatiotemporal variability of soil respiration. We investigated growing season soil respiration in a ～393 ha subalpine watershed in Montana across eight riparian–hillslope transitions that differed in slope, upslope accumulated area (UAA), aspect, and groundwater table dynamics. We collected daily‐to‐weekly measurements of soil water content (SWC), soil temperature, soil CO2 concentrations, surface CO2 efflux, and groundwater table depth, as well as soil C and N concentrations at 32 locations from June to August 2005. Instantaneous soil surface CO2 efflux was not significantly different within or among riparian and hillslope zones at monthly timescales. However, cumulative integration of CO2 efflux during the 83‐day growing season showed that efflux in the wetter riparian zones was ～25% greater than in the adjacent drier hillslopes. Furthermore, greater cumulative growing season efflux occurred in areas with high UAA and gentle slopes, where groundwater tables were higher and more persistent. Our findings reveal the influence of landscape position and groundwater table dynamics on riparian versus hillslope soil CO2 efflux and the importance of time integration for assessment of soil CO2 dynamics, which is critical for landscape‐scale simulation and modelling of soil CO2 efflux in complex landscapes. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

2.
We present a system of ordinary differential equations (ODEs) capable of reproducing simultaneously the aggregated behavior of changes in water storage in the hillslope surface, the unsaturated and the saturated soil layers and the channel that drains the hillslope. The system of equations can be viewed as a two-state integral-balance model for soil moisture and groundwater dynamics. Development of the model was motivated by the need for landscape representation through hillslopes and channels organized following stream drainage network topology. Such a representation, with the basic discretization unit of a hillslope, allows ODEs-based simulation of the water transport in a basin. This, in turn, admits the use of highly efficient numerical solvers that enable space–time scaling studies. The goal of this paper is to investigate whether a nonlinear ODE system can effectively replicate observations of water storage in the unsaturated and saturated layers of the soil. Our first finding is that a previously proposed ODE hillslope model, based on readily available data, is capable of reproducing streamflow fluctuations but fails to reproduce the interactions between the surface and subsurface components at the hillslope scale. However, the more complex ODE model that we present in this paper achieves this goal. In our model, fluxes in the soil are described using a Taylor expansion of the underlying storage flux relationship. We tested the model using data collected in the Shale Hills watershed, a 7.9-ha forested site in central Pennsylvania, during an artificial drainage experiment in August 1974 where soil moisture in the unsaturated zone, groundwater dynamics and surface runoff were monitored. The ODE model can be used as an alternative to spatially explicit hillslope models, based on systems of partial differential equations, which require more computational power to resolve fluxes at the hillslope scale. Therefore, it is appropriate to be coupled to runoff routing models to investigate the effect of runoff and its uncertainty propagation across scales. However, this improved performance comes at the expense of introducing two additional parameters that have no obvious physical interpretation. We discuss the implications of this for hydrologic studies across scales.  相似文献   

3.
Topography and landscape characteristics affect the storage and release of water and, thus, groundwater dynamics and chemistry. Quantification of catchment scale variability in groundwater chemistry and groundwater dynamics may therefore help to delineate different groundwater types and improve our understanding of which parts of the catchment contribute to streamflow. We sampled shallow groundwater from 34 to 47 wells and streamflow at seven locations in a 20‐ha steep mountainous catchment in the Swiss pre‐Alps, during nine baseflow snapshot campaigns. The spatial variability in electrical conductivity, stable water isotopic composition, and major and trace ion concentrations was large and for almost all parameters larger than the temporal variability. Concentrations of copper, zinc, and lead were highest at sites that were relatively dry, whereas concentrations of manganese and iron were highest at sites that had persistent shallow groundwater levels. The major cation and anion concentrations were only weakly correlated to individual topographic or hydrodynamic characteristics. However, we could distinguish four shallow groundwater types based on differences from the catchment average concentrations: riparian zone‐like groundwater, hillslopes and areas with small upslope contributing areas, deeper groundwater, and sites characterized by high magnesium and sulfate concentrations that likely reflect different bedrock material. Baseflow was not an equal mixture of the different groundwater types. For the majority of the campaigns, baseflow chemistry most strongly resembled riparian‐like groundwater for all but one subcatchment. However, the similarity to the hillslope‐type groundwater was larger shortly after snowmelt, reflecting differences in hydrologic connectivity. We expect that similar groundwater types can be found in other catchments with steep hillslopes and wet areas with shallow groundwater levels and recommend sampling of groundwater from all landscape elements to understand groundwater chemistry and groundwater contributions to streamflow.  相似文献   

4.
Streamflow generation in mountain watersheds is strongly influenced by snow accumulation and melt as well as groundwater connectivity. In mountainous regions with limestone and dolomite geology, bedrock formations can host karst aquifers, which play a significant role in snowmelt–discharge dynamics. However, mapping complex karst features and the resulting surface-groundwater exchanges at large scales remains infeasible. In this study, timeseries analysis of continuous discharge and specific conductance measurements were combined with gridded snowmelt predictions to characterize seasonal streamflow response and evaluate dominant watershed controls across 12 monitoring sites in a karstified 554 km2 watershed in northern Utah, USA. Immense surface water hydrologic variability across subcatchments, years and seasons was linked to geologic controls on groundwater dynamics. Unlike many mountain watersheds, the variability between subcatchments could not be well described by typical watershed properties, including elevation or surficial geology. To fill this gap, a conceptual framework was proposed to characterize subsurface controls on snowmelt–discharge dynamics in karst mountain watersheds in terms of conduit flow direction, aquifer storage capacity and connectivity. This framework requires only readily measured surface water and climatic data from nested monitoring sites and was applied to the study watershed to demonstrate its applicability for evaluating dominant controls and climate sensitivity.  相似文献   

5.
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6.
Results from hydrometric and isotopic investigations of unsaturated flow during snowmelt are presented for a hillslope underlain by well-sorted sands. Passage of melt and rainwater through the vadose zone was detected from temporal changes in soil water 2H concentrations obtained from sequential soil cores. Bypassing flow was indicated during the initial snowmelt phase, but was confined to the near-surface zone. Recharge below this zone was via translatory flow, as meltwater inputs displaced premelt soil water. Estimates of premelt water fluxes indicate that up to 19 per cent of the premelt soil water may have been immobile. Average water particle velocities during snowmelt ranged from 6.2 × 10?7 to 1.1 × 10?6 ms?1, suggesting that direct groundwater recharge by meltwater during snowmelt was confined to areas where the premelt water table was within 1 m of the ground surface. Soil water 2H signatures showed a rapid response to isotopically-heavy rain-on-snow inputs late in the melt. In addition, spatial variations in soil moisture content at a given depth induced a pronounced lateral component to the predominantly vertical transport of water. Both factors may complicate isotopic profiles in the vadose zone, and should be considered when employing environmental isotopes to infer recharge processes during snowmelt.  相似文献   

7.
This paper reviews work related to interbasin groundwater flow (naturally occurring groundwater flow beneath watershed topographic divides) into lowland rainforest watersheds at La Selva Biological Station in Costa Rica. Chemical mixing calculations (based on dissolved chloride) have shown that up to half the water in some streams and up to 84% of the water in some riparian seeps and wells is due to high-solute interbasin groundwater flow (IGF). The contribution is even greater for major ions; IGF accounts for well over 90% of the major ions at these sites. Proportions are highly variable both among watersheds and with elevation within the same watershed (there is greater influence of IGF at lower elevations). The large proportion of IGF found in water in some riparian wetlands suggests that IGF is largely responsible for maintaining these wetlands. δ18O data support the conclusions from the major ion data. Annual water and major ion budgets for two adjacent watersheds, one affected by IGF and the other not, showed that IGF accounted for two-thirds of the water input and 92–99% of the major ion input (depending on the major ion in question) to the former watershed. The large (in some cases, dominating) influence of IGF on watershed surface water quantity and quality has important implications for stream ecology and watershed management in this lowland rainforest. Because of its high phosphorus content, IGF increases a variety of ecological variables (algal growth rates, leaf decay rate, fungal biomass, invertebrate biomass, microbial respiration rates on leaves) in streams at La Selva. The significant rates of IGF at La Selva also suggest the importance of regional (as opposed to small-scale local) water resource planning that links lowland watersheds with regional groundwater. IGF is a relatively unexplored and potentially critical factor in the conservation of lowland rainforest.  相似文献   

8.
Riparian wetlands as typical aquatic-terrestrial interfaces control, in a very specific way, nonpoint water and related chemical fluxes exchanging between catchment areas to their respective water systems (streams, lakes). The existing groundwater and soilwater flow models reveal gaps in dealing with the complex behaviour of processes and the considerable spatial and temporal heterogeneity of riparian wetlands. Based on long-term experience gained through field observations and the interpretation of model produced data, a multi-box aggregation of processes which determines lateral as well as vertical flows and, as a whole, water balance, is used to discretise a generic riparian wetland transect situated between an upland aquifer and a receiving water body.

The resulting mathematical model, FEUWAnet, endowed also with an original methodology to adapt parameters, has been applied to a riparian alder wetland adjacent to Lake Belau (northern Germany). Results of simulations illustrate a good fit between calculated water levels and observed values and an accordance of calculated water balance to previous independent evaluations. This confirms that the sound simplifications of real situations performed by the FEUWAnet mathematical model are a promising way to deal with hydrological complexity of riparian zones. Moreover, FEUWAnet permits, to a certain extent, one to unravel the spatial heterogeneity and temporal variation of lateral (from catchment area to water systems) and vertical (from canopy to groundwater zone) water fluxes typical of riparian ecosystems: this is the necessary step to undertake when developing integrated models capable of assessing the effectiveness of riparian systems in controlling the fluxes of nonpoint pollution discharging in the open water bodies.  相似文献   


9.
High‐frequency water discharge and suspended sediment concentration (SSC) databases were collected for 3 years on four contrasted watersheds: the Asse and the Bléone (two Mediterranean rainfall regime watersheds) and the Romanche and the Ferrand (two rainfall–snowmelt regime watersheds). SSCs were calculated from turbidity recordings (1‐h time step), converted into SSC values. The rating curve was calculated by means of simultaneous SSC measurement taken by water sampling and turbidity recording. Violent storms during springtime and autumn were responsible for suspended sediment transport on the Asse and the Bléone rivers. On the Ferrand and the Romanche, a large share of suspended sediment transport was also caused by local storms, but 30% of annual fluxes results from snowmelt or icemelt which occurred from April to October. On each watershed, SSC up to 50 g l?1 were observed. Annual specific fluxes ranged from 450 to 800 t km?2 year?1 and 40–80% of annual suspended sediment fluxes occurred within 2% of the time. These general indicators clearly demonstrate the intensity of suspended sediment transport on these types of watersheds. Suspended sediment fluxes proved to be highly variable at the annual scale (inter‐annual variability of specific fluxes) as well as at the event scale (through a hysteresis loop in the SSC/Q relationship) on these watersheds. In both cases, water discharge and precipitations were the main processes involved in suspended sediment production and transport. The temporal and spatial variability of hydro‐meteorological processes on the watershed provides a better understanding of suspended sediment dynamics. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

10.
The potential for increased loads of dissolved organic carbon (DOC) in streams and rivers is a concern for regulating the water quality in water supply watersheds. With increasing hydroclimatic variability related to global warming and shifts in forest ecosystem community and structure, understanding and predicting the magnitude and variability of watershed supply and transport of DOC over multiple time scales have become important research and management goals. In this study, we use a distributed process‐based ecohydrological model (Regional Hydro‐Ecological Simulation System [RHESSys]) to explore controls and predict streamflow DOC loads in Biscuit Brook. Biscuit Brook is a forested headwater catchment of the Neversink Reservoir, part of the New York City water supply system in the Catskill Mountains. Three different model structures of RHESSys were proposed to explore and evaluate hypotheses addressing how vegetation phenology and hydrologic connectivity between deep groundwater and riparian zones influence streamflow and DOC loads. Model results showed that incorporating dynamic phenology improved model agreement with measured streamflow in spring, summer, and fall and fall DOC concentration, compared with a static phenology. Additionally, the connectivity of deep groundwater flux through riparian zones with dynamic phenology improved streamflow and DOC flux in low flow conditions. Therefore, this study suggests the importance of inter‐annual vegetation phenology and the connectivity of deep groundwater drainage through riparian zones in the hydrology and stream DOC loading in this forested watershed and the ability of process‐based ecohydrological models to simulate these dynamics. The advantage of a process‐based modelling approach is specifically seen in the sensitivity to forest ecosystem dynamics and the interactions of hydroclimate variability with ecosystem processes controlling the supply and distribution of DOC. These models will be useful to evaluate different forest management approaches toward mitigating water quality concerns.  相似文献   

11.
Allan Rodhe  Jan Seibert 《水文研究》2011,25(12):1899-1909
Knowledge of groundwater dynamics is important for the understanding of hydrological controls on chemical processes along the water flow pathways. To increase our knowledge of groundwater dynamics in areas with shallow groundwater, the groundwater dynamics along a hillslope were studied in a boreal catchment in Southern Sweden. The forested hillslope had a 1‐ to 2‐m deep layer of sandy till above bedrock. The groundwater flow direction and slope were calculated under the assumption that the flow followed the slope of the groundwater table, which was computed for different triangles, each defined by three groundwater wells. The flow direction showed considerable variations over time, with a maximum variation of 75°. During periods of high groundwater levels the flow was almost perpendicular to the stream, but as the groundwater level fell, the flow direction became gradually more parallel to the stream, directed in the downstream direction. These findings are of importance for the interpretation of results from hillslope transects, where the flow direction usually is assumed to be invariable and always in the direction of the hillslope. The variations in the groundwater flow direction may also cause an apparent dispersion for groundwater‐based transport. In contrast to findings in several other studies, the groundwater level was most responsive to rainfall and snowmelt in the upper part of the hillslope, while the lower parts of the slope reached their highest groundwater level up to 40 h after the upper parts. This can be explained by the topography with a wetter hollow area in the upper part. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

12.
The seasonal snowmelt period is a critical component of the hydrologic cycle for many mountainous areas. Changes in the timing and rate of snowmelt as a result of physical hydrologic flow paths, such as longitudinal intra-snowpack flow paths, can have strong implications on the partitioning of meltwater amongst streamflow, groundwater recharge, and soil moisture storage. However, intra-snowpack flow paths are highly spatially and temporally variable and thus difficult to observe. This study utilizes new methods to non-destructively observe spatio-temporal changes in the liquid water content of snow in combination with plot experiments to address the research question: What is the scale of influence that intra-snowpack flow paths have on the downslope movement of liquid water during snowmelt across an elevational gradient? This research took place in northern Colorado with study plots spanning from the rain-snow transition zone up to the high alpine. Results indicate an increasing scale of influence from intra-snowpack flow paths with elevation, showing higher hillslope connectivity producing larger intra-snowpack contributing areas for meltwater accumulation, quantified as the upslope contributing area required to produce observed changes in liquid water content from melt rate estimates. The total effective intra-snowpack contributing area of accumulating liquid water was found to be 17, 6, and 0 m2 for the above tree line, near tree line, and below tree line plots, respectively. Dye tracer experiments show capillary and permeability barriers result in increased number and thickness of intra-snowpack flow paths at higher elevations. We additionally utilized aerial photogrammetry in combination with ground penetrating radar surveys to investigate the role of this hydrologic process at the small watershed scale. Results here indicate that intra-snowpack flow paths have influence beyond the plot scale, impacting the storage and transmission of liquid water within the snowpack at the small watershed scale.  相似文献   

13.
Major inorganic ions and stable carbon and oxygen isotopes in stream water, groundwater, groundwater seeps and springs were measured in the Corral Canyon meadow complex and watershed in the Toquima Mountains of central Nevada, USA. The purpose of the study was to determine whether stream water or groundwater was the source of water that supports vegetation in the meadow complex. Water samples from the watershed and meadow complex were mixed cation–HCO3 type. Stream water sampled at different locations in the meadow complex showed variations in temperature, pH and specific conductance. The cation–anion proportions for stream water were similar to groundwater, groundwater seeps and runoff from the meadow complex. Stable oxygen isotope ratios for stream water (?17·1 to ?17·6‰ versus VSMOW) and groundwater and groundwater seeps in the meadow site (?17·0 to ?17·7‰ versus VSMOW) were similar, and consistent with a local meteoric origin. Dissolved inorganic carbon (DIC) and the δ 13CDIC for stream water (?12·1 to ?15·0‰ versus VPDB) were different from that of groundwater from the meadow complex (?15·3 to ?19·9‰ versus VPDB), suggesting different carbon evolution pathways. However, a simple model based on cation–δ 13CDIC suggests that stream water was being recharged by shallow groundwater, groundwater seeps and runoff from the meadow complex. This leads to the conclusion that the source of water that supports vegetation in the meadow complex was primarily groundwater. The results of this study suggest that multiple chemical and stable carbon isotope tracers are useful in determining the source of water that supports vegetation in meadow complexes in small alpine watersheds. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

14.
Global warming has leaded to permafrost degradation, with potential impacts on the runoff generation processes of permafrost influenced alpine meadow hillslope. Stable isotopes have the potential to trace the complex runoff generation processes. In this study, precipitation, hillslope surface and subsurface runoff, stream water, and mobile soil water (MSW) at different hillslope positions and depths were collected during the summer rainfall period to analyse the major flow pathway based on stable isotopic signatures. The results indicated that (a) compared with precipitation, the δ2H values of MSW showed little temporal variation but strong heterogeneity with enriched isotopic ratios at lower hillslope positions and in deeper soil layers. (b) The δ2H values of middle-slope surface runoff and shallow subsurface flow were similar to those of precipitation and MSW of the same soil layer, respectively. (c) Middle-slope shallow subsurface flow was the major flow pathway of the permafrost influenced alpine meadow hillslope, which turned into surface runoff at the riparian zone before contributing to the streamflow. (d) The slight variation of δ2H values in stream water was shown to be related to mixing processes of new water (precipitation, 2%) and old water (middle-slope shallow subsurface flow, 98%) in the highly transmissive shallow thawed soil layers. It was inferred that supra-permafrost water levels would be lowered to a less conductive, deeper soil layer under further warming and thawing permafrost, which would result in a declined streamflow and delayed runoff peak. This study explained the “rapid mobilization of old water” paradox in permafrost influenced alpine meadow hillslope and improved our understanding of permafrost hillslope hydrology in alpine regions.  相似文献   

15.
This study documented the spatial and temporal variability of outflow from a forested hillslope segment during snowmelt at a small mountain catchment in south coastal British Columbia, Canada. A pit 5 m wide was established just upslope from the stream channel. Outflow from the organic horizon was intercepted and measured by a single trough, and outflow from the mineral horizons was measured separately for three adjacent sections. Throughflow exhibited non‐steady‐state behaviour involving shifting allocations of flow amongst different sections of the outflow pit, as well as threshold effects and hysteresis in the relationship between pit outflow and water table elevation. Most of the pit outflow originated from the mineral horizons, indicating that throughflow was the dominant pathway by which water was delivered to the stream channel. Direct precipitation and snowmelt onto near‐stream saturated areas can account for less than 20% of the total outflow from the hillslope segment. Throughflow from the mineral sections consistently peaked either at the same time as or earlier than stream flow from the 150‐ha catchment during diurnal snowmelt cycles, indicating that throughflow appears to respond rapidly enough to contribute to snowmelt‐induced peak stream flow. Pit outflow cannot be extrapolated reliably to the catchment scale on the basis of simple length‐ or area‐based ratios. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

16.
Nonpoint sources of nitrogen (N) and other nutrients are a major source of water pollution within the Chesapeake Bay watershed and other basins around the world. Human activities associated with agricultural practices can account for a large percentage of N loadings delivered to streams and rivers. This work aims to improve understanding of N transport from groundwater to surface waters, quantifying the principal hydrological processes driving water and N fluxes into and out of a headwater agricultural stream reach. The study site is a 175-m stream reach in a heavily cultivated 40-ha watershed in east-central Pennsylvania. This subwatershed is underlain by fractured shale bedrock, and receives most of its baseflow from groundwater, either by diffuse matrix discharge through the streambed or by localized discharge through riparian seeps. Samples of stream, seep, and shallow groundwater were collected approximately monthly under steady hydrologic conditions in 2017. Calculated matrix flow from hydraulic head and conductivity measurements paired with differential stream gauging was used to solve for the riparian seep flux using a mass balance approach. Riparian seep fluxes ranged from 45 to 217 m3/d, transporting 0.6–4.2 kg N d−1 of nitrate-N from the fractured bedrock aquifer to the stream. Hydrochemical data suggest that the stream is mainly disconnected from the underlying aquifer and that seeps supply essentially all water and N to the system. Seeps are likely sourced with N in nearby agricultural fields and accelerated through the system with shorter residence times than shallow groundwater. Water isotope data reinforced this notion. This study underscores the importance of agriculture as a source of N to ground and surface waters. Identifying source areas that are causing groundwater enrichment of N and seep areas where N discharges to streams is beneficial for developing N pollution mitigation strategies and implementing management practices that aim to reduce nutrient loads to the Chesapeake Bay.  相似文献   

17.
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18.
To evaluate the influence of hydrological processes on dissolved organic carbon (DOC) dynamics in a forested headwater catchment, DOC concentration was observed along the flow path from rainfall to stream water via throughfall, soil water, groundwater, and spring water for 4 years, and DOC flux through the catchment was calculated. The spatial and temporal variations in DOC concentration and flux were compared with physical hydrological observations and the mean residence time of water. In the upslope soil layer, DOC concentrations were not significantly correlated with water fluxes, suggesting that DOC concentrations were not strictly controlled by water fluxes. In the upslope perennial groundwater, DOC concentration was affected by the change in the amount of microbial degradation of DOC produced by changes in the mean residence time of water. In stream water, the temporal variation in DOC concentration was usually affected by changes in DOC concentration of the inflow component via vertical infiltration from above the perennial groundwater. During dry periods, however, the component from inflow via vertical infiltration was negligible and DOC in the upslope perennial groundwater became the major component of stream water DOC. The temporal variation in stream water DOC concentration during baseflow was affected by rainfall patterns over several preceding months. Therefore, records of rainfall over several preceding months are one of the most important factors for predicting changes in DOC concentration on a catchment scale. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

19.
M. Rahman  M. Sulis  S. J. Kollet 《水文研究》2016,30(10):1563-1573
Subsurface and land surface processes (e.g. groundwater flow, evapotranspiration) of the hydrological cycle are connected via complex feedback mechanisms, which are difficult to analyze and quantify. In this study, the dual‐boundary forcing concept that reveals space–time coherence between groundwater dynamics and land surface processes is evaluated. The underlying hypothesis is that a simplified representation of groundwater dynamics may alter the variability of land surface processes, which may eventually affect the prognostic capability of a numerical model. A coupled subsurface–land surface model ParFlow.CLM is applied over the Rur catchment, Germany, and the mass and energy fluxes of the coupled water and energy cycles are simulated over three consecutive years considering three different lower boundary conditions (dynamic, constant, and free‐drainage) based on groundwater dynamics to substantiate the aforementioned hypothesis. Continuous wavelet transform technique is applied to analyze scale‐dependent variability of the simulated mass and energy fluxes. The results show clear differences in temporal variability of latent heat flux simulated by the model configurations with different lower boundary conditions at monthly to multi‐month time scales (~32–91 days) especially under soil moisture limited conditions. The results also suggest that temporal variability of latent heat flux is affected at even smaller time scales (~1–3 days) if a simple gravity drainage lower boundary condition is considered in the coupled model. This study demonstrates the importance of a physically consistent representation of groundwater dynamics in a numerical model, which may be important to consider in local weather prediction models and water resources assessments, e.g. drought prediction. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

20.
The hydrochemical behaviour of catchments is often investigated by inferring stream chemistry through identification of source areas involved in hydrograph separation analysis, yet its dynamic evolution of hydrologic pathways has received little attention. Intensive hydrometric and hydrochemical measurements were performed during two different storms on March 29, 2001 and August 21–22, 2001 to define hydrochemical evolution under the dynamic of flow pathways in a 5·2 ha first‐order drainage of the Kawakami experimental basin (KEB), Central Japan, a forested headwater catchment with various soil depths (1·8 to 5 m) overlying late Neogene of volcanic bedrocks. The hydraulic potential distribution and flow lines data showed that the change in flow direction, which was controlled by rainfall amount and antecedent wetness of the soil profile, agreed well with the hydrochemical change across the slope segment during the storm. Hydrograph separation predicted by end‐member mixing analysis (EMMA) using Ca2+ and SiO2 showed that near surface riparian, hillslope soil water and deep riparian groundwater were important in stream flow generation. The evidence of decrease in solutes concentration at a depth of 1 m in the hillslope and 0·6 m in the near surface riparian during peak storm suggested a flushing of high solutes concentration. Most of the solutes accumulated in the deep riparian groundwater zone, which was due to prominent downward flow and agreed well with the residence time. The distinct flow pathways and chemistry between the near surface riparian and deep riparian groundwater zones and the linkage hillslope aquifer and near surface riparian reservoir, which controls rapid flow and solutes flushing during the storm event, are in conflict with the typical assumption that the whole riparian zone resets flow pathways and chemical signature of hillslope soil water, as has been reported in a previous study. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

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