共查询到20条相似文献，搜索用时 546 毫秒
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电感耦合等离子体发射光谱法同时测定铅锌矿中银铜铅锌 总被引：4，自引：3，他引：1
采用盐酸-硝酸-硫酸混合酸分解样品,全谱直读电感耦合等离子体发射光谱法同时测定铅锌矿石中的银、铜、铅和锌。基于改善和提高测定结果准确度和精密度的要求,分析了溶液稀释因子和酸度等实验条件对测定结果的影响。结果表明,当溶液的稀释因子为1000,盐酸的体积分数在5%～10%时,测定结果最佳。采用内标法,通过加入钴内标测量分析谱线的相对强度,抵消了由于实验条件的波动引起的影响。方法检出限银为1.96μg/g,铜为6.00μg/g,铅为9.00μg/g,锌为3.00μg/g,精密度(RSD,n=10)为1.41%～7.50%。方法经国家标准物质分析验证,测定值与标准值相符,结果准确可靠。 相似文献
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为寻找合适的湿度调节材料,本文对海泡石及海泡石复合样品进行了吸湿能力和放湿能力测试。与坡缕石比较,10g200目海泡石样品可以将10L密闭容器的湿度从70%降至4%,吸湿能力强于同样条件下的坡缕石。海泡石(10g)的吸、放湿能力经过3次吸、放湿实验后有所减弱,最后一次吸湿量达0.4g,放湿量达0.15g。实验还发现,30g海泡石和白水泥复合样品可以使10L容器内部的湿度稳定在40%～50%,因此,海泡石可以用作室内湿度调节的建筑材料。 相似文献
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研究了石墨炉原子吸收法测定地质样品中微量Ag的方法,探索了以NH4IrCl6做基体改进剂的最佳仪器工作条件.在取样0.2000g,定容25mL的情况下,方法检出限为0.010μg/g,用国家标准物质验证,其准确度(RE%)小于10%,10次测定的精密度(RSD%)小于10%. 相似文献
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超强吸水性蒙脱石/聚丙烯酸钠复合材料的研究 总被引：8，自引：2，他引：6
以蒙脱石和丙烯酸为原料,采用溶液聚合法合成了超强吸水性蒙脱石／聚丙烯酸钠复合材料,优化了该复合材料吸自来水性能的配方,即蒙脱石添加量为30％,单体的中和度为70％．交联剂用量为0．10％,引发剂用量为0．15％,在此配方下制备的复合材料吸蒸馏水倍率为420g／g,吸自来水倍率为220g／g,吸生理盐水倍率为55g／g,凝胶强度215g／cm^2。同时,该复合材料具有聚合反应便于控制且不粘容器、吸水倍率高、抗盐性能好、凝胶强度大、成本大幅度降低的优点,可广泛应用于农林园艺、生态环境治理等领域作保水剂。 相似文献
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化学发光法测定岩矿中痕量铊 总被引：4，自引：0，他引：4
本文研究了鲁米诺-KI-Tl(Ⅲ)体系的化学发光反应条件以及用泡沫塑料吸附分离干扰元素,化学发光分析岩矿中痕量Tl的方法。对Tl的检出限为2×10~(-10)g/ml,线性范围为2×10~(-10)—10~(-8)g/ml。 相似文献
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兰坪金顶铅锌矿区土壤重金属Zn、Cd分布特征研究 总被引：6，自引：0，他引：6
通过连续提取法测定兰坪金顶铅锌区土壤中Zn、Cd的形态含量,笔者等分析了污染物的分布、化学形态的变化。结果表明,金顶矿区土壤中Zn、Cd总量大范围超标,Zn的水溶态含量为n·100μg/g,离子交换态为n·10μg/g,残渣态、活性铁锰态、碳酸盐态和有机结合态含量为n·102μg/g,Cd的水溶态含量为n·10-2μg/g,其他各态基本在同一数量级为n·100μg/g,部分地区Zn离子交换态含量超过国家土壤环境质量标准（Ⅲ级）中总量标准1倍以上,而Cd离子交换态含量平均是Ⅲ级总量标准的5倍,Cd污染要更加严重。污染及形态分布受矿体展布、地形、矿业活动、地表径流等的影响。Zn、Cd的环境有效态（水溶态、离子交换态与碳酸盐态之和）含量比较高,对兰坪矿区及沘江流域具有潜在的危害。 相似文献
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电感耦合等离子体光谱／质谱法测定环境样品中的硼 总被引：7，自引：3，他引：7
采用HF-HNO3-H3PO4-HClO4密封溶样处理样品,电感耦合等离子体光谱/质谱法(ICP-AES/MS)测定农作物、膳食和粪便中的硼。所拟定的方法在测硼的同时,还可测定Cr、Cu、Li、V、Co、Zn、Sr、Cd、Ba、K、Na、Fe、Mn、Zn元素,可以为农作物和饮食中痕量元素研究提供参考。ICP-AES测定硼的方法检出限(3σ)为0.0063μg/mL,测定限(10σ,DF=100)为2.10μg/g;ICP-MS测定硼方法检出限(3σ)为0.0228ng/mL,测定限(10σ,DF=1000)为0.092μg/g。方法经植物国家一级标准物质GBW07602～07605验证,测定值与标准值接近,样品10次测定的RSD<10%。 相似文献
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采用微波消解对样品进行前处理,建立了氢化物发生-双道原子荧光光谱同时测定化肥中砷和汞的方法。以20 g/L KBH4为还原剂,8%的盐酸为载液,测定砷和汞的负高压均为270 V,砷的灯电流为60 mA,汞的灯电流为20 mA。讨论了常见元素对测定的干扰,40 g/L的主量元素N、P、K,10倍于砷、汞浓度的杂质元素Te、Ca、Zn、Cu、Cr、Mn、Ni、Sb、Sn、Pb对砷和汞测定的影响满足分析要求。方法测定砷和汞的线性范围As为0.68～100μg/L,Hg为0.12～10μg/L;检出限As为0.68μg/L,Hg为0.12μg/L;方法精密度(RSD,n=5)低于8%。该方法具有前处理简便快速、易于操作、灵敏度高等特点,能满足化肥中砷和汞同时测定的要求。 相似文献
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Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
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Gilles Serge Odin 《Comptes Rendus Geoscience》2002,334(6):409-414
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414. 相似文献
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The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引：4，自引：0，他引：4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
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Muriel Rocher Stéphane Baize Stéphane Jaillet Edward Marc Cushing Yannick Lozac&#x;h Francis Lemeille 《Comptes Rendus Geoscience》2003,335(8):701-708
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003). 相似文献
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正20141520 Bo Ying(Key Laboratory of Metallogeny and Mineral Assessment,MLR,Beijing 100037,China);Liu Chenglin Saline Spring Hydrochemical Characteristics and Indicators for Potassium Exploration in Southwestern and Northern Tarim Basin,Xinjiang(Acta Geoscientica Sinica,ISSN1006-3021,CN11-3474/P,34(5),2013,p.594-602,5 illus.,3 tables,28 refs.) 相似文献
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正20141243Chen Ge(Hangzhou Research Institute of Petroleum Geology,PetroChina,Hangzhou 310023,China);Si Chunsong Study on Sedimentary Numerical Simulation Method of Fan Delta Sand Body(Journal of Geology, 相似文献
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正20142599Chen Sanming(Guangxi Key Laboratory of Concealed Deposits Exploration,Guilin University of Technology,Guilin541004,China);He Yuzhou Block Model and Reserves Estimation of Panzhihua Iron Deposit Based on 3D Geological Modeling(Journal of Guilin University of Technology,ISSN1674-9057,CN45-1375/N,33(4),2013,p.610-615,9illus.,1table,15refs.) 相似文献
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正20140594 Bai Daoyuan(Hunan Institute of Geology Survey,Changsha 410016,China);Zhong Xiang Faults in the Jingzhou Basin and Their Tectonic Settings(Geotectonica et Metallogenia,ISSN1001-1552,CN44-1595/P,37(2),2013,p.173-183,6illus.,59refs.)Key words:basin evolution,tectonic setting,South China In the Upper Paleozoic and Jurassic se- 相似文献
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正20141912Cao Hui(State Key Laboratory for Continental Tectonics and Dynamics,Institute of Geology,Chinese Academy of Geological Sciences,Beijing 100037,China)Gravitational Collapse and Folding during Orogenesis:A Comparative Study of FIA Trends and Fold Axial Plane Traces(Geology in China,ISSN1000-3657,CN11-1167/P,40(6),2013,p.1818-1828,9illus.,35refs.,with 相似文献