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1.
The Tethyan tectonic domain hosts numerous world-class mineral deposits. Among these, the Dewulu skarn copper deposit in Western Qinling, China belongs to the Paleotethys ore belt. The skarn and orebodies here occur as stratoids or lenses at the contact between the Triassic Dewulu intrusive complex and Permian marine clastic and carbonates. Alteration minerals include prograde skarns (garnet, diopside, wollastonite), plagioclase, hornblende, actinolite, tremolite, epidote, chlorite, calcite, quartz and sericite. The main ore types include early disseminated skarn-type replacement orebodies and late-stage quartz-sulfide veins. Chalcopyrite is the major ore mineral, along with pyrite, bornite and sphalerite. The Dewulu intrusive complex comprises quartz diorite, quartz diorite porphyry and dioritic mafic microgranular enclaves (MME). The MMEs are spheroidal in shape, and have igneous mineral assemblages, acicular apatites, complex oscillatory zoned plagioclase and quartz megacrysts surrounded by mafic minerals. The MMEs are metaluminous and calc-alkaline to high-K calc-alkaline, and possess relatively high Ni, Cr and MgO contents and Mg# values. They display sub-parallel patterns in trace element spider diagrams and rare earth element (REE) plots. They are also characterized by the enrichment of Rb, U and Th, depletion of Ba, Sr, Nb and Ta and negative Eu anomaly. Zircon LA-ICP-MS U–Pb dating of the dioritic MME yields an age of 247.0 ± 2.2 Ma, coeval with the host quartz diorite, quartz diorite porphyry and ore-related sericite 40Ar/39Ar plateau ages within analytical uncertainties. Oxygen fugacity estimated from trace element compositions of zircons from the dioritic MME shows FMQ ± 3.3. The zircons have negative εHf(t) values in a range of − 8.0 to − 3.3, corresponding to two-stage model ages ranging from 1.48 to 1.78 Ga. The integrated data from petrology, geochronology and bulk geochemistry suggest that the Early Triassic granitoids associated with Cu skarn mineralization at Dewulu were products of arc magmatism and involved magma mixing in an active continental margin setting. The magma was sourced through partial melting of enriched sub-continental lithospheric mantle that had been previously modified by slab-derived melt during the continuous northward subduction of the Paleotethys oceanic slab.  相似文献   

2.
Subduction erosion, which occurs at all convergent plate boundaries associated with magmatic arcs formed on crystalline forearc basement, is an important process for chemical recycling, responsible globally for the transport of ~1.7 Armstrong Units (1 AU = 1 km3/yr) of continental crust back into the mantle. Along the central Andean convergent plate margin, where there is very little terrigenous sediment being supplied to the trench as a result of the arid conditions, the occurrence of mantle-derived olivine basalts with distinctive crustal isotopic characteristics (87Sr/86Sr ≥ 0.7050; εNd ≤ −2; εHf ≤ +2) correlates spatially and/or temporally with regions and/or episodes of high rates of subduction erosion, and a strong case can be made for the formation of these basalts to be due to incorporation into the subarc mantle wedge of tectonically eroded and subducted forearc continental crust. In other convergent plate boundary magmatic arcs, such as the South Sandwich and Aleutian Islands intra-oceanic arcs and the Central American and Trans-Mexican continental margin volcanic arcs, similar correlations have been demonstrated between regions and/or episodes of relatively rapid subduction erosion and the genesis of mafic arc magmas containing enhanced proportions of tectonically eroded and subducted crustal components that are chemically distinct from pelagic and/or terrigenous trench sediments. It has also been suggested that larger amounts of melts derived from tectonically eroded and subducted continental crust, rising as diapirs of buoyant low density subduction mélanges, react with mantle peridotite to form pyroxenite metasomatites that than melt to form andesites. The process of subduction erosion and mantle source region contamination with crustal components, which is supported by both isotopic and U-Pb zircon age data implying a fast and efficient connectivity between subduction inputs and magmatic outputs, is a powerful alternative to intra-crustal assimilation in the generation of andesites, and it negates the need for large amounts of mafic cumulates to form within and then be delaminated from the lower crust, as required by the basalt-input model of continental crustal growth. However, overall, some significant amount of subducted crust and sediment is neither underplated below the forearc wedge nor incorporated into convergent plate boundary arc magmas, but instead transported deeper into the mantle where it plays a role in the formation of isotopically enriched mantle reservoirs. To ignore or underestimate the significance of the recycling of tectonically eroded and subducted continental crust in the genesis of convergent plate boundary arc magmas, including andesites, and for the evolution of both the continental crust and mantle, is to be on the wrong side of history in the understanding of these topics.  相似文献   

3.
We present new zircon U–Pb–Hf and whole-rock geochemical data for volcanic rocks along the eastern margin of the Xing'an Massif of NE China in order to further our understanding of the history of subduction towards the SE and the spatial extent of the Mongol–Okhotsk tectonic regime. Zircon U–Pb dating indicates that the Triassic volcanism in the Xing'an Massif occurred in two stages during the Middle (ca. 242 Ma) and Late (ca. 223–228 Ma) Triassic. Middle Triassic basaltic andesites in the Heihe area have an affinity to arc-type volcanic rocks. The zircon εHf(t) values (+ 8.5 to + 12.7) suggest that the primary magma was generated by the partial melting of a relatively depleted mantle wedge that had been metasomatized by subduction-related fluids. The Late Triassic andesites in the Handaqi area exhibit geochemical affinities to high-Mg adakitic andesites. Their zircon εHf(t) values (+ 11.5 to + 14.5) and TDM2 ages (313–484 Ma) indicate that their primary magma was derived from the partial melting of a young subducted oceanic crust, followed by interaction with melts derived from mantle peridotite. The Late Triassic basaltic andesites, andesites, and dacites in the Zhalantun–Moguqi area have features similar to those of igneous rocks formed in subduction zones. Their zircon εHf(t) values (+ 8.4 to + 15.4) and TDM1 ages (260–542 Ma) indicate that their primary magma was derived from the partial melting of a depleted mantle wedge that had been metasomatized by subduction-related fluids. These data suggest that the Triassic volcanic rocks of the Xing'an Massif formed in an active continental margin setting associated with the southward subduction of the Mongol–Okhotsk oceanic plate towards the SE. We conclude that the Mongol–Okhotsk tectonic regime extended at least as far as the eastern margin of the Xing'an Massif, and that the tectonism spanned the period from the late Permian to early Early-Cretaceous.  相似文献   

4.
The Western Kunlun Orogen occupies a key tectonic position at the junction between the Tarim block and the Tethyan domain. However, the late Paleozoic to early Mesozoic, especially the middle to late Triassic tectonic evolution history of the Western Kunlun Orogen remains controversial. This study reports SHRIMP zircon U–Pb ages and geochemical as well as Sr–Nd–Hf isotopic data for middle to late Triassic Taer pluton in Western Kunlun Orogen, Northwest China. The Taer pluton shows a strong bimodal distribution of compositions, with the felsic rocks dominant and the mafic rocks subordinate. Zircon U–Pb dating reveals that the coexisting mafic and felsic rocks are coeval, both emplacing in a period between 234 and 225 Ma. Most of the studied rocks are potassium rich and can be classified into high-K calc-alkaline to shoshonitic series. They are also strongly enriched in LREE, LILE and depleted in HFSE with strong negative Ti and Nb anomalies, and characterized by enriched Sr–Nd–Hf isotopic signatures. Detailed geochemical and isotopic studies indicate that the Taer pluton was emplaced in a post-collisional extensional setting, with the mafic rocks derived from partial melting of the enriched continental lithospheric mantle in the spinel facies field, and the felsic rocks formed by anatexis of newly underplated basaltic rocks. The existence of middle to late Triassic post-collisional magmas in Western Kunlun region suggests that the final closure of Paleo-Tethys and the initial collision between the Western Kunlun and the Qiangtang terranes may have happened before ~234 Ma, most probably in late Permian, rather than in late Triassic or early Jurassic. In assistance with other geological evidences, such as the presence of early Triassic to late Triassic/early Jurassic S-type magmatism, terrestrial molasse depositions, regional unconformities, and strong deformation, we propose that the Western Kunlun Orogen may have undergone a long post-collisional intracontinental process from early Triassic to late Triassic/early Jurassic.  相似文献   

5.
The Pliocene–Pleistocene northern Taiwan volcanic zone (NTVZ) is located within a trench-arc–back-arc basin and oblique arc–continent collision zone. Consequently the origin and tectonic setting of the andesitic rocks within the NTVZ and their relation to other circum-Pacific volcanic island-arc systems is uncertain. Rocks collected from the Tatun volcanic group (TTVG) include basaltic to andesitic rocks. The basalt is compositionally similar to within-plate continental tholeiites whereas the basaltic andesite and andesite are calc-alkaline; however, all rocks show a distinct depletion of Nb-Ta in their normalized incompatible element diagrams. The Sr-Nd isotope compositions of the TTVG rocks are very similar and have a relatively restricted range (i.e. ISr = 0.70417–0.70488; εNd(T) = +2.2 to +3.1), suggesting that they are derived directly or indirectly from the same mantle source. The basalts are likely derived by mixing between melts from the asthenosphere and a subduction-modified subcontinental lithospheric mantle (SCLM) source, whereas the basaltic andesites may be derived by partial melting of pyroxenitic lenses within the SCLM and mixing with asthenospheric melts. MELTS modelling using a starting composition equal to the most primitive basaltic andesite, shallow-pressure (i.e. ≤1 kbar), oxidizing conditions (i.e. FMQ +1), and near water saturation will produce compositions similar to the andesites observed in this study. Petrological modelling and the Sr-Nd isotope results indicate that the volcanic rocks from TTVG, including the spatially and temporally associated Kuanyinshan volcanic rocks, are derived from the same mantle source and that the andesites are the product of fractional crystallization of a parental magma similar in composition to the basaltic andesites. Furthermore, our results indicate that, in some cases, calc-alkaline andesites may be generated by crystal fractionation of mafic magmas derived in an extensional back-arc setting rather than a subduction zone setting.  相似文献   

6.
The Malayer–Boroujerd plutonic complex (MBPC) in western Iran, consists of a portion of a magmatic arc built by the northeast verging subduction of the Neo-Tethys plate beneath the Central Iranian Microcontinent (CIMC). Middle Jurassic-aged felsic magmatic activity in MBPC is manifested by I-type and S-type granites. The mafic rocks include gabbroic intrusions and dykes and intermediate rocks are dioritic dykes and minor intrusions, as well as mafic microgranular enclaves (MMEs). MBPC Jurassic-aged rocks exhibit arc-like geochemical signatures, as they are LILE- and LREE-enriched and HFSE- and HREE-depleted and display negative Nb–Ta anomalies. The gabbro dykes and intrusions originated from metasomatically enriched garnet-spinel lherzolite [Degree of melting (fmel) ~ 15%] and exhibit negative Nd and positive to slightly negative εHf(T) (+ 3.0 to ? 1.6). The data reveal that evolution of Middle Jurassic magmatism occurred in two stages: (1) deep mantle-crust interplay zone and (2) the shallow level upper crustal magma chamber. The geochemical and isotopic data, as well as trace element modeling, indicate the parent magma for the MBPC S-type granites are products of upper crustal greywacke (fmel: 0.2), while I-type granites formed by partial melting of amphibolitic lower crust (fmel: 0.25) and mixing with upper crustal greywacke melt in a shallow level magma chamber [Degree of mixing (fmix): 0.3]. Mixing between andesitic melt leaving behind a refractory dense cumulates during partial crystallization of mantle-derived magma and lower crustal partial melt most likely produced MMEs (fmix: 0.2). However, enriched and moderately variable εNd(T) (? 3.21 to ? 4.33) and high (87Sr/86Sr)i (0.7085–0.7092) in dioritic intrusions indicate that these magmas are likely experienced assimilation of upper crustal materials. The interpretations of magmatic activity in the MBPC is consistent with the role considered for mantle-derived magma as heat and mass supplier for initiation and evolution of magmatism in continental arc setting, elsewhere.  相似文献   

7.
Whole rock major and trace element geochemistry together with zircon U-Pb ages and Sr-Nd isotope compositions for the Middle Eocene intrusive rocks in the Haji Abad region are presented. The granitoid hosts, including granodiorite and diorite, yielded zircon U-Pb ages with a weighted mean value of 40.0 ± 0.7 Ma for the granodiorite phase. Mafic microgranular enclaves(MMEs) are common in these plutons, and have relatively low SiO_2 contents(53.04-57.08 wt.%) and high Mg#(42.6-60.1), probably reflecting a mantle-derived origin. The host rocks are metaluminous(A/CNK = 0.69-1.03), arc-related calc-alkaline, and I-type in composition, possessing higher SiO_2 contents(59.7-66.77 wt.%) and lower Mg#(38.6-52.2); they are considered a product of partial melting of the mafic lower crust. Chondritenormalized REE patterns of the MMEs and granitoid hosts are characterized by LREE enrichment and show slight negative Eu anomalies(Eu/Eu* = 0.60-0.93). The host granodiorite samples yield(87Sr/86Sr);ratios ranging from 0.70498 to 0.70591,positive eNd(t) values varying from +0.21 to +2.3, and TDM2 ranging from 760 to 909 Ma, which is consistent with that of associated mafic microgranular enclaves(87Sr/86Sr)i = 0.705111-0.705113, εNd(t)= +2.14 to +2.16, TDM2 = 697-785 Ma). Petrographic and geochemical characterization together with bulk rock Nd-Sr isotopic data suggest that host rocks and associated enclaves originated by interaction between basaltic lower crust-derived felsic and mantlederived mafic magmas in an active continental margin arc environment.  相似文献   

8.
The Parashi granitoid of northeasternmost Colombia intrudes the Upper Cretaceous to Lower Paleocene accretionary complex formed by the collision of the Caribbean arc and the continental margin of South America. This granitoid presently separated of the continental margin includes a major quartzdiorite body with andesite to dacite dikes and mafic enclaves. Zircon U–Pb LA-MC-ICP-MS and K–Ar geochronology on the quartzdiorite and the dikes suggest that crystallization extended from ca. 47 to 51 Ma. Major and trace elements are characterized by a medium-K, immature continental arc signature and high Al2O3, Na2O and Ba–Sr contents. Initial 87Sr/86Sr isotopic values range between 0.7050 and 0.7054, with 143Nd/144Nd = 0.51235–0.51253, εNd and εHf values from −0.81 to −4.40 and −4.4 and −5.2. Major and trace element ratios and isotopic modeling suggest that sedimentary and/or quartzofeldspathic crustal sources were mixed with a mafic melt input. The petrotectonic and geological constraints derived from this granitoid suggest that Parashi plutonism records an immature, oblique subduction-zone setting in which the presence of a high-temperature mantle realm and strong plate coupling associated to upper crust subduction caused the partial fusion of a previously tectonically underplated mafic crust and associated metasediments exposed in the continental margin. The limited temporal expression of this magmatism and the transition to a regional magmatic hiatus are related to a subsequent change to strongly and slow oblique tectonics in the Caribbean–South America plate interactions and the underflow of a relatively thick slab of Caribbean oceanic crust.  相似文献   

9.
We constrain the origin and tectonic setting of the giant Duolong porphyry–epithermal Cu–Au deposit in the South Qiangtang Terrane of northern Tibet, based on new zircon U–Pb ages and Hf isotopic data, as well as whole-rock major and trace element data from poorly studied ore-associated intrusions in the Duolong area. The LA–ICP–MS zircon U–Pb dating indicates that the ore-associated rocks formed between 121 and 126 Ma. These ore-associated rocks are geochemically similar to low-K tholeiitic M-type granitoids and to mid- to high-K, calc-alkaline I-type granitoids. They have variable and predominantly positive zircon εHf(t) values (− 1.4 to + 15.6) and variable crustal model ages (TCDM(Hf); 176–1122 Ma). Taking into account previous data and the regional geology of the study area, we propose that the ore-associated rocks originated from fractional crystallization of mantle-derived mafic melts and magma mixing of mantle-derived mafic and hybrid lower crust-derived felsic melts, and the hybrid lower crust included a mix of juvenile and older continental material. The Duolong porphyry–epithermal Cu–Au deposit formed within an ‘ensialic forearc’ of an active continental margin as a result of the northwards subduction of the Bangong–Nujiang Ocean crust beneath the South Qiangtang Terrane.  相似文献   

10.
The Sri Lankan fragment of Gondwana preserves the records of Neoproterozoic tectonothermal events associated with the final assembly of the supercontinent. Here we investigate a suite of magmatic rocks from the Wanni, Kadugannawa and Highland Complexes through geological, petrological, geochemical and zircon U–Pb and Lu–Hf isotopic techniques. The hornblende biotite gneiss, charnockites, metagabbro and metadiorites investigated in this study show geochemical features consistent with calc-alkaline affinity and subduction-related signature including LILE enrichment relative to HFSE coupled with distinct Nb–Ta depletion and weak negative Zr–Hf anomalies. The felsic suite falls in the volcanic arc granites (VAGs) field and the mafic suite shows island arc basalt affinity in tectonic discrimination plots, suggesting that the protoliths of the rocks were derived from arc-related magmas in a convergent margin setting. LA-ICPMS zircon U–Pb analyses show crystallization of charnockite and dioritic mafic magmatic enclave from the Highland Complex during ca. 565 and 576 Ma corresponding to bimodal magmatism. The diorite also contains metamorphic zircons of ca. 525 Ma. Hornblende–biotite gneiss from the Kadugannawa Complex shows protolith emplacement age at 973–980 Ma, followed by new zircon growth during repeated thermal events through late Neoproterozoic. The dioritic enclaves in these rocks are much younger, and form part of a deformed and metamorphosed dyke suite with emplacement ages of 559 Ma, broadly coeval with the bimodal magmatism in the Highland Complex at that time. The youngest group of zircons in this rock shows ages of 508 Ma, corresponding to the latest thermal event. A charnockite from this locality shows oldest group of zircons at 962 Ma, corresponding to emplacement age similar to that of the magmatic protolith of the hornblende biotite gneiss. This rock also shows zircon growth during repeated thermal events at 832 Ma, 780 Ma, 721 Ma and 661–605 Ma. The lower intercept age of 543 Ma marks the timing of collisional metamorphism. Charnockite from the Wanni Complex shows emplacement age at 1000 Ma, followed by thermal event at 570 Ma, the latter correlating with the bimodal magmatic event in the Highland Complex. The dioritic enclave within this charnockite shows an age of ca. 980 Ma, suggesting intrusion of mafic magma into the felsic magma chamber. Zircons in the diorite also record multiple zircon events during 950 to 750 Ma. Zircons in the Highland Complex charnockite possess negative εHf(t) values in the range − 6.7 to − 12.6 with TDMC of 2039–2306 Ma suggesting magma derivation through melting of Paleoproterozoic source. In contrast, the εHf(t) range of − 11.1 to 1.6 suggests a mixed source of both of older crustal and juvenile material. The εHf(t) values of − 4.5 to 4.5 and TDMC of 1546–1962 Ma for the hornblende biotite gneiss also shows magma derivation from mixed sources that included Paleoproterozoic components. The younger dioritic intrusive, however, has a more juvenile magma source as indicated by the mean εHf(t) value of 1.3. The associated charnockite shows a tight positive cluster of εHf(t) from 0.6 to 5.1, suggesting juvenile input. Charnockite from the Wanni Complex shows clearly positive εHf(t) values of up to 13.1, and TDMC in the range 937–1458 Ma suggesting much younger and depleted mantle source. The diorite enclave also has positive εHf(t) values with an average value of 8.5 and TDMC in the range of 709–1443 Ma clearly suggesting younger juvenile sources. The early and late Neoproterozoic bimodal suites are correlated to convergent margin magmatism associated with the assembly of Sri Lanka within the Gondwana supercontinent.  相似文献   

11.
The Duolong porphyry Cu–Au deposit (5.4 Mt at 0.72% Cu, 41 t at 0.23 g/t Au) was recently discovered in the southern Qiangtang terrane, central Tibet. Here, new whole‐rock elemental and Sr–Nd–Pb isotope and zircon Hf isotopic data of syn‐ and post‐ore volcanic rocks and barren and ore‐bearing granodiorite porphyries are presented for a reconstruction of magmas associated with Cu–Au mineralization. LA–ICP–MS zircon U–Pb dating yields mean ages of 117.0 ± 2.0 and 120.9 ± 1.7 Ma for ore‐bearing granodiorite porphyry and 105.2 ± 1.3 Ma for post‐ore basaltic andesite. All the samples show high‐K calc‐alkaline compositions, with enrichment of light rare earth elements (LREE) and large ion lithophile elements (LILE: Cs and Rb) and depletion of high field strength elements (HFSE: Nb and Ti), consistent with the geochemical characteristics of arc‐type magmas. Syn‐ and post‐ore volcanic rocks show initial Sr ratios of 0.7045–0.7055, εNd(t) values of −0.8 to 3.6, (206Pb/204Pb)t ratios of 18.408–18.642, (207Pb/204Pb)t of 15.584–15.672 and positive zircon εHf(t) values of 1.3–10.5, likely suggesting they dominantly were derived from metasomatized mantle wedge and contaminated by southern Qiangtang crust. Compared to mafic volcanic rocks, barren and ore‐bearing granodiorite porphyries have relatively high initial Sr isotopic ratios (0.7054–0.7072), low εNd(t) values (−1.7 to −4.0), similar Pb and enriched zircon Hf isotopic compositions [εHf(t) of 1.5–9.7], possibly suggesting more contribution from southern Qiangtang crust. Duolong volcanic rocks and granodiorite porphyries likely formed in a continental arc setting during northward subduction of the Bangong–Nujiang ocean and evolved at the base of the lower crust by MASH (melting, assimilation, storage and homogenization) processes. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

12.
The Late Paleozoic volcanic and sedimentary rocks are widespread in the North Tianshan along the north margin of the Yili block. They consist of basalt, basaltic andesite, andesite, trachyandesite, dacite, rhyolite, tuff, and tuffaceous sandstone. According to zircon sensitive high-resolution ion microprobe (SHRIMP) dating, the age of the Late Paleozoic volcanic rocks in Tulasu basin in western part of North Tianshan is constrained to be Early Devonian to Early Carboniferous (417–356 Ma), rather than Early Carboniferous as accepted previously. Geochemical characteristics of the Early Devonian to Early Carboniferous volcanic rocks are similar to those of arc volcanic rocks, which suggest that these volcanic rocks could be the major constituents of a continental arc formed by the southward subduction of North Tianshan Oceanic lithosphere. Geochemical studies indicate that the magma source of the volcanic rocks might be the mantle wedge mixed with subduction fluid, which is geochemically enriched than primitive mantle but depleted than E-MORB. The calculation shows that the basalt could be formed by ∼10% partial melting of subduction fluid modified mantle wedge. Andesites with high initial 87Sr/86Sr (0.7094–0.7104) and negative εNd(t) (−4.45 to −4.79) values reveal the contribution of continental crust to its source. The calculation of assimilation–fractional crystallization (AFC) shows that the fractional crystallization process of the basaltic magma, which was accompanied with assimilation by different degree of continental crust, produced andesite (7–9%), dacite (∼12%) and rhyolite (>20%).  相似文献   

13.
The transition from oceanic subduction to continental collision is a key stage in the evolution of ancient orogens. We present new data for Early Cretaceous diorite and granite porphyry from north–central Tibet to constrain the evolution of the Bangong–Nujiang Tethyan Ocean (BNTO). The diorites have moderate SiO2 and high MgO contents, similar to high-Mg andesites. Zircon grains yield U–Pb ages of 128–124 Ma and positive εHf(t) values between +13.2 and + 16.3, corresponding to Hf depleted-mantle model ages (TDM) of 281–131 Ma. The high-Mg diorite was probably formed by partial melting of hydrous mantle wedge fluxed by slab-derived fluids in an oceanic subduction setting. The granite porphyries yield zircon U–Pb ages of 117–115 Ma and zircon εHf(t) values ranging from +0.1 to +4.5. Most samples have high SiO2 and Fe2O3T contents, variable FeOT/MgO and Ga/Al ratios, and are depleted in Ba, Sr, P, and Ti, similar to I- and A-type granites. The granite porphyries were most likely derived from partial melting of juvenile dioritic or granodioritic crust due to break-off of the BNTO lithosphere following collision between the Lhasa and Qiangtang blocks. The Early Cretaceous high-Mg diorite and A-type granite porphyry thus record the Early Cretaceous transition from oceanic subduction to continental collision along the Bangong–Nujiang suture zone (BNSZ).  相似文献   

14.
We present elemental and Sr–Nd–Pb isotopic data for the magmatic suite (~79 Ma) of the Harşit pluton, from the Eastern Pontides (NE Turkey), with the aim of determining its magma source and geodynamic evolution. The pluton comprises granite, granodiorite, tonalite and minor diorite (SiO2 = 59.43–76.95 wt%), with only minor gabbroic diorite mafic microgranular enclaves in composition (SiO2 = 54.95–56.32 wt%), and exhibits low Mg# (<46). All samples show a high-K calc-alkaline differentiation trend and I-type features. The chondrite-normalized REE patterns are fractionated [(La/Yb) n  = 2.40–12.44] and display weak Eu anomalies (Eu/Eu* = 0.30–0.76). The rocks are characterized by enrichment of LILE and depletion of HFSE. The Harşit host rocks have weak concave-upward REE patterns, suggesting that amphibole and garnet played a significant role in their generation during magma segregation. The host rocks and their enclaves are isotopically indistinguishable. Sr–Nd isotopic data for all of the samples display I Sr = 0.70676–0.70708, ε Nd(79 Ma) = −4.4 to −3.3, with T DM = 1.09–1.36 Ga. The lead isotopic ratios are (206Pb/204Pb) = 18.79–18.87, (207Pb/204Pb) = 15.59–15.61 and (208Pb/204Pb) = 38.71–38.83. These geochemical data rule out pure crustal-derived magma genesis in a post-collision extensional stage and suggest mixed-origin magma generation in a subduction setting. The melting that generated these high-K granitoidic rocks may have resulted from the upper Cretaceous subduction of the Izmir–Ankara–Erzincan oceanic slab beneath the Eurasian block in the region. The back-arc extensional events would have caused melting of the enriched subcontinental lithospheric mantle and formed mafic magma. The underplating of the lower crust by mafic magmas would have played a significant role in the generation of high-K magma. Thus, a thermal anomaly induced by underplated basic magma into a hot crust would have caused partial melting in the lower part of the crust. In this scenario, the lithospheric mantle-derived basaltic melt first mixed with granitic magma of crustal origin at depth. Then, the melts, which subsequently underwent a fractional crystallization and crustal assimilation processes, could ascend to shallower crustal levels to generate a variety of rock types ranging from diorite to granite. Sr–Nd isotope modeling shows that the generation of these magmas involved ~65–75% of the lower crustal-derived melt and ~25–35% of subcontinental lithospheric mantle. Further, geochemical data and the Ar–Ar plateau age on hornblende, combined with regional studies, imply that the Harşit pluton formed in a subduction setting and that the back-arc extensional period started by least ~79 Ma in the Eastern Pontides.  相似文献   

15.
《Gondwana Research》2014,26(4):1445-1468
The continental crust of the North China Craton (NCC) is a major reservoir of mineral resources with imprints of secular changes in tectonics and metallogeny. The Jiaodong Peninsula, located in the eastern margin of the North China Craton (NCC), is currently one of the largest gold producers over the globe, and preserves the records of multiple magmatic and metamorphic events. Here we characterize the timing and tectonics of the major Mesozoic magmatism and the associated gold metallogeny in this region through a comprehensive U–Pb geochronological and Hf isotope investigation of zircons in a suite of granitoids, mafic magmatic enclaves, melanocratic dikes and melted basement rocks.The Linglong granite, hosting one of the major gold deposits in Jiaodong, shows emplacement ages between 150 and 160 Ma, and the dominantly negative εHf (t) values (− 34.0 to − 23.8) of zircons from this intrusion suggest magma derivation from recycled components in the Archean basement. The Guojialing granodiorite and its mafic magmatic enclaves show similar ages between 123 and 127 Ma, with negative εHf (t) values (− 19.3 to − 16.8), corresponding to crustal magma source. The melanocratic dikes, belonging to pre- and syn-mineralization stages, with U–Pb age range of 126 to 166 Ma display large variation in their zircon εHf (t) values (− 25.7 and 2.3) suggesting the involvement of both recycled crustal and juvenile mantle components. Zircons in the melted basement rocks with ages in the range of ca. 127–132 Ma also display both positive and negative εHf (t) values (− 44.6 and 9.8) indicating a mixture of recycled ancient crust and juvenile magmas. Our study shows that although the peak of gold metallogeny coincided with the tectonics associated with Pacific plate subduction which mobilized and concentrated the ores, the source materials of gold mineralization and magmatism had multiple origins including from the Precambrian basement rocks, Mesozoic granitoids and mantle-derived mafic magmas with extensive mixing of crustal, lithosphere mantle and asthenospheric components. A combination of delamination, mantle upwelling, subduction-related metasomatic enrichment and recycling of ancient components facilitated the gold metallogeny in this region. Our study provides a typical case of juvenile and recycled components in the formation and evolution of continental crust and associated mineral resources.  相似文献   

16.
The Kuh-e Dom Pluton is located along the central northeastern margin of the Urumieh–Dokhtar Magmatic Arc, spanning a wide range of compositions from felsic rocks, including granite, granodiorite, and quartz monzonite, through to intermediate-mafic rocks comprising monzonite, monzodiorite, diorite, monzogabbro, and gabbro. The Urumieh–Dokhtar Magmatic Arc forms a distinct linear magmatic complex that is aligned parallel with the orogenic suture of the Zagros fold-thrust belt. Most samples display characteristics of metaluminous, high-K calc-alkaline, I-type granitoids. The initial isotopic signatures range from εNd (47 Ma) = −4.77 to −5.89 and 87Sr/86Sr(i) = 0.7069 to 0.7074 for felsic rocks and εNd (47 Ma) = −3.04 to −4.06 and 87Sr/86Sr(i) = 0.7063 to 0.7067 for intermediate to mafic rocks. This geochemical and isotopic evidence support a mixed origin for the Kuh-e Dom hybrid granitoid with a range of contributions of both the crust and mantle, most probably by the interaction between lower crust- and mantle-derived magmas. It is seem, the felsic rocks incorporate about 56–74% lower crust-derived magma and about 26–44% of the enriched mantle-derived mafic magma. In contrast, 66–84% of the enriched mantle-derived mafic magma incorporates 16–34% of lower crust-derived magma to generate the intermediate-mafic rocks. According to the differences in chemical composition, the felsic rocks contain a higher proportion of crustal material than the intermediate to mafic ones. Enrichment in LILEs and depletion in HFSEs with marked negative Nb, Ba, and Ti anomalies are consistent with subduction-related magmatism in an active continental margin arc environment. This suggestion is consistent with the interpretation of the Urumieh–Dokhtar Magmatic Arc as an active continental margin during subduction of the Neotethys oceanic crust beneath the Central Iranian microcontinent.  相似文献   

17.
Whole rock major and trace element and Sr-, Nd- and Hf-isotope data, together with zircon U-Pb, Hf- and O-isotope data, are reported for the Nb-Ta ore bearing granites from the Lingshan pluton in the Southeastern China, in order to trace their petrogenesis and related Nb-Ta mineralization. The Lingshan pluton contains hornblende-bearing biotite granite in the core and biotite granite, albite granite and pegmatite at the rim. In addition, numerous mafic microgranular enclaves occur in the Lingshan granites. Zircon SIMS U-Pb dating gives consistent crystallization ages of ca. 132 Ma for the Lingshan granitoids and enclaves, consistent with the Nb-Ta mineralization age of ∼132 Ma, indicating that mafic and felsic magmatism and Nb-Ta mineralization are coeval. The biotite granites contain hornblende, and are metaluminous to weakly peraluminous, with high initial 87Sr/86Sr ratios of 0.7071–0.7219, negative εNd(t) value of −5.9 to −0.3, εHf(t) values of −3.63 to −0.32 for whole rocks, high δ18O values and negative εHf(t) values for zircons, and ancient Hf and Nd model ages of 1.41–0.95 Ga and 1.23–1.04 Ga, indicating that they are I-type granites and were derived from partial melting of ancient lower crustal materials. They have variable mineral components and geochemical features, corresponding extensive fractionation of hornblende, biotite and feldspar, with minor fractionation of apatite. Existence of mafic microgranular enclaves in the biotite granites suggests a magma mixing/mingling process for the origin of the Lingshan granitoids, and mantle-derived mafic magmas provided the heat for felsic magma generation. In contrast, the Nb-Ta mineralized albite granites and pegmatites have distinct mineral components and geochemical features, which show that they are highly-fractionated granites with extensive melt and F-rich fluid interaction in the generation of these rocks. The fluoride-rich fluids induce the enrichment in Nb and Ta in the highly evolved melts. Therefore, we conclude that the Nb-Ta mineralization is the result of hydrothermal process rather than crystal fractionation in the Lingshan pluton, which provides a case to identify magmatic and hydrothermal processes and evaluate their relative importance as ore-forming processes.  相似文献   

18.
Bima Formation volcanic rocks, which record the history of Neo-Tethyan subduction, are found within the central and eastern segments of the southern Lhasa subterrane, Tibetan Plateau. Zircon UPb dating, whole-rock major and trace element analysis, and Sr–Nd–Pb–Hf isotopic compositions of Bima Formation volcanic rocks from the central segment of the southern Lhasa subterrane were used to constrain the magmatic and tectonic evolution of the Lhasa terrane during the early Mesozoic. Zircon UPb dating of five samples yielded consistent ages of 184.3 ± 2.4 to 176.8 ± 3.5 Ma. The dominant volcanic rock types within the Bima Formation are basalts, basaltic andesites, andesites, and dacites, which are enriched in the large-ion lithophile elements (e.g., Rb, Sr, and Ba) and depleted in high-field-strength elements (e.g., Nb, Ta, and Ti). (87Sr/86Sr)t ratios are low (0.702900–0.704146), εNd(t) and εHf(t) values are high and positive (+4.4 to +6.9 and + 9.6 to +15.7, respectively), and Pb isotope ratios are homogeneous (initial 206Pb/204Pb = 18.28–18.40; 207Pb/204Pb = 15.53–15.56; 208Pb/204Pb = 38.21–38.38). Combining the new data with those from a previous study of Bima Formation volcanic rocks from the eastern segment of the southern Lhasa subterrane indicates that the Bima Formation formed between the Middle Triassic and Early Jurassic. It suggests that more widespread early Mesozoic volcanic rocks in the southern margin of the Lhasa terrane. The basaltic rocks of the Bima Formation were generated by partial melting of a depleted mantle wedge metasomatized by slab-derived fluids, and subsequently experienced fractional crystallization without significant crustal contamination. The andesitic and dacitic rocks were formed by fractional crystallization of the basaltic magma. Our study indicates that the Bima Formation volcanic rocks were generated within a continental island arc setting related to northward subduction of the Neo-Tethyan oceanic slab during the early Mesozoic.  相似文献   

19.
Described half a century ago, the Galiléia tonalite represents a milestone in the discovery of plate margin magmatic arcs in the Araçuaí-Ribeira orogenic system (southeastern Brazil). In the 1990's, analytical studies on the Galiléia tonalite finally revealed the existence of a Late Neoproterozoic calc-alkaline magmatic arc in the Araçuaí orogen. Meanwhile, the name Rio Doce magmatic arc was applied to calc-alkaline plutons found in the Araçuaí-Ribeira boundary. After those pioneer studies, the calc-alkaline plutons showing a pre-collisional volcanic arc signature and age between 630 Ma and 585 Ma have been grouped in the G1 supersuite, corresponding to the Rio Doce arc infrastructure. Here, we revisit the Rio Doce arc with our solid field knowledge of the region and a robust analytical database (277 lithochemical analyses, and 47 U–Pb, 53 Sm–Nd, 25 87Sr/86Sr and 7 Lu–Hf datasets). The G1 supersuite consists of regionally deformed, tonalitic to granodioritic batholiths and stocks, generally rich in melanocratic to mesocratic enclaves and minor gabbroic to dioritic plutons. Gabbroic to dioritic enclaves show evidence of magma mixing processes. The lithochemical and isotopic signatures clearly reveal a volcanic arc formed on a continental margin setting. Melts from a Rhyacian basement form the bulk of the magma produced, whilst gabbroic plutons and enclaves record involvement of mantle magmas in the arc development. Tonalitic stocks (U–Pb age: 618–575 Ma, εNd(t): −5.7 to −7.8, Nd TDM ages: 1.28–1.68 Ga, 87Sr/86Sr(t): 0.7059–0.7118, and εHf(t): −5.2 to −11.7) form the northernmost segment of the Rio Doce arc, which dies out in the ensialic sector of the Araçuaí orogen. At arc eastern and central zones, several batholiths (e.g., Alto Capim, Baixo Guandu, Galiléia, Muniz Freire, São Vítor) record a long-lasting magmatic history (632–580 Ma; εNd(t): −5.6 to −13.3; Nd TDM age: 1.35–1.80 Ga; 87Sr/86Sr(t): 0.7091–0.7123). At arc western border, the magmatic evolution started with gabbro-dioritic and tonalitic plutons (e.g., Chaves pluton, U–Pb age: 599 ± 15 Ma, εNd(t): −4.8 to −6.8, Nd TDM ages: 1.48–1.68 Ga, 87Sr/86Sr(t): 0.7062–0.7068, and εHf(t): −4.3 to −9.7; and Brasilândia pluton, U–Pb age: 581 ± 11 Ma, εNd(t): −8.2 to −10.2, Nd TDM ages: 1.63–1.68 Ga, 87Sr/86Sr(t): 0.7088–0.7112, εHf(t): −12.3 to −14.9), followed by late granodioritic intrusions (e.g., Guarataia pluton, U–Pb age: 576 ± 9 Ma, εNd(t): −12.52 to −13.11, Nd TDM age: 1.74–2.06 Ga, 87Sr/86Sr(t): 0.7104–0.7110, εHf(t): −12.9 to −21.6). The Muriaé batholith (U–Pb age: 620–592 Ma, εNd(t): −8.2 to −13.6, Nd TDM age: 1.41–1.88 Ga) and the Conceição da Boa Vista (586 ± 7 Ma) and Serra do Valentim (605 ± 8 Ma) stocks represent a segment of the Rio Doce arc correlated to the Serra da Bolívia and Marceleza complexes, making the link between the Araçuaí and Ribeira orogenic domains. We suggest three phases of arc development: i) eastward migration of arc front (632–605 Ma), ii) widespread magma production in the whole arc (605–585 Ma), and iii) late plutonism in the western arc region (585–575 Ma). Usual processes of volcanic arc development, like subduction of oceanic lithosphere under a continental margin, followed by asthenosphere ascent related to slab retreating and break-off may explain the Rio Doce arc evolution.  相似文献   

20.
Zircon U–Pb ages, geochemical and Sr–Nd isotopic data are presented for the late Carboniferous Baoligaomiao Formation (BG Fm.) and Delewula Formation (DW Fm.) volcanic rocks, widely distributed in northern Inner Mongolia, in the northern part of the Xing'an–Mongolia Orogenic Belt (XMOB). The BG Fm. rocks mainly consist of basaltic andesites and andesites while the DW Fm. rocks include dacites, trachytes, rhyolites, pyroclastic rocks and minor andesites. New LA-ICPMS zircon U–Pb analyses constrain their eruption to late Carboniferous (317–322 Ma and 300–310 Ma, respectively). The BG Fm. volcanic rocks are characterized by enriched large ion lithophile elements (LILE) and depleted high field strength elements (HFSE), with initial 87Sr/86Sr ratios of 0.70854–0.70869 and negative εNd(t) (− 2.1 to − 2.4) values. They have low La/Ba (0.03–0.05), high La/Nb (2.05–3.70) ratios and variable Ba/Th (59.5–211) ratios. Such features suggest that they are derived from melting of heterogeneous sources including a metasomatized mantle wedge and Precambrian crustal material. The DW Fm. volcanic rocks are more depleted in HFSE with significant Nb, Ta, P, Ti anomalies. They have high initial 87Sr/86Sr ratios (0.72037–0.72234) and strong negative εNd(t) (− 11 to − 11.6) values which indicate those igneous rocks were mainly derived from reworking of the Paleoproterozoic crust. The late Carboniferous volcanic rocks have geochemical characteristics similar to those of the continental arc rocks which indicate the northward subduction of the Paleo Asian Ocean may have continued to the late Carboniferous. The volcanic association of this study together with the early Permian post-collisional magmatic rocks suggests that a tectonic transition from subduction-related continental margin arc volcanism to post-collisional magmatism occurred in the northern XMOB between the late Carboniferous and the early Permian.  相似文献   

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