共查询到20条相似文献，搜索用时 15 毫秒
1.
Stable C and O isotope records were obtained from carbonate rocks spanning the Hauterivian to Cenomanian interval collected in several sections from the carbonate platform of Pădurea Craiului (Apuseni Mountains, Romania). In the absence of some key biostratigraphic marker species, stable isotopes were applied as a tool for stratigraphic correlation and dating. The composite δ13C and δ18O curves for the Early Cretaceous shows variable conditions with large positive and negative excursions and provide information on past environmental changes. The Hauterivian and the Barremian limestones (Blid Formation) display lower δ13C values (−2.8‰ to +2.9‰) relative to the Aptian–Albian deposits (−2.6‰ to +5.4‰) (Ecleja, Valea Măgurii and Vârciorog Formations). The red detrital formation (Albian–Cenomanian) is characterized by a highly variable distribution of the δ13C values (−3.5‰ to +3.9‰). Based on the similarities between the C-isotope curve established in Pădurea Craiului and from other sections in the Tethyan and the Pacific regions, two major oceanic anoxic events characterized by δ13C positive excursions were clearly recognized. The first is the OAE1a event (Early Aptian) in the upper part of the Ecleja Formation and the Valea Măgurii Formation. The second is the OAE1b event (Late Aptian–Albian) in the upper part of the Vârciorog Formation and in the Subpiatră Member. The position of the Aptian/Albian boundary is estimated to be at the upper part of the Vârciorog Formation, immediately after the beginning of the δ13C positive excursion. The δ13C data show major negative excursions during the Barremian (Blid Formation), Early Aptian (Ecleja Formation), and Late Aptian (Vârciorog Formation). The O isotope variation pattern (−10.2‰ to −2.1‰) is consistent with progressively warming temperatures during the Early Barremian followed by a cooling period. A subsequent warming period culminated in the Early Aptian. A significant cooling phase corresponds to the Late Aptian and Early Albian and the climate cooled again during the Late Albian and into the Early Cenomanian stage. The data provide a better understanding of the Early Cretaceous sedimentation cycles in Pădurea Craiului and create a more reliable framework for regional correlations. 相似文献
2.
《Chemie der Erde / Geochemistry》2015,75(1):65-72
This study was conducted on recent desert samples—including (1) soils, (2) plants, (3) the shell, and (4) organic matter from modern specimens of the land snail Eremina desertorum—which were collected at several altitudes (316–360 m above sea level) from a site in the New Cairo Petrified Forest. The soils and shellE. desertorum were analyzed for carbonate composition and isotopic composition (δ18O, δ13C). The plants and organic matterE. desertorum were analyzed for organic carbon content and δ13C. The soil carbonate, consisting of calcite plus minor dolomite, has δ18O values from −3.19 to −1.78‰ and δ13C values −1.79 to −0.27‰; covariance between the two values accords with arid climatic conditions. The local plants include C3 and C4 types, with the latter being dominant. Each type has distinctive bulk organic carbon δ13C values: −26.51 to −25.36‰ for C3-type, and −13.74 to −12.43‰ for C4-type plants.The carbonate of the shellE. desertorum is composed of aragonite plus minor calcite, with relatively homogenous isotopic compositions (δ18Omean = −0.28 ± 0.22‰; δ13Cmean = −4.46 ± 0.58‰). Most of the δ18O values (based on a model for oxygen isotope fractionation in an aragonite-water system) are consistent with evaporated water signatures. The organic matterE. desertorum varies only slightly in bulk organic carbon δ13C values (−21.78 ± 1.20‰) and these values suggest that the snail consumed more of C3-type than C4-type plants. The overall offset in δ13C values (−17.32‰) observed between shellE. desertorum carbonate and organic matterE. desertorum exceeds the value expected for vegetation input, and implies that 30% of carbon in the shellE. desertorum carbonate comes from the consumption of limestone material. 相似文献
3.
The clay fractions of sedimentary kaolin deposits representing different ages (Carboniferous and Cretaceous), types (pisolitic flint and plastic), and localities (Sinai and Aswan) from Egypt were analyzed for their H and O isotopic compositions to examine the paleoclimate conditions during their formation. The δD values of the Carboniferous deposits in Sinai range between −67‰ and −88‰, while the values for the Cretaceous deposits in Sinai range between −59‰ and −75‰. The δ18O values of the Carboniferous deposits range from 17.9‰ to 19.4‰ and the values for the Cretaceous deposits range between 19.2‰ and 20.4‰. The relatively low δD and δ18O values of the Carboniferous deposit at the Abu Natash area (−67‰ and 17.9‰, respectively) compared to other Carboniferous deposits (averages of −83.3‰, and 18.8‰ for δD and δ18O, respectively) could be due to isotopic exchange between this deposit and the adjacent dolomite and/or the enclosed hydrothermally-formed Mn ores of the Carboniferous Um Bogma Formation. The δD and δ18O values of the Cretaceous pisolitic flint kaolin deposit from Aswan (averages of −65‰ and 20.3‰, respectively) and plastic kaolin from the same area (averages of −66‰ and 19.5‰, respectively) are almost identical. The differences in the δ18O values between the clay fractions of the pisolitic flint kaolin (20.3‰) and the previously analyzed bulk kaolin of the same deposit (average of 17.5‰) suggest a significant effect of non-clay minerals on the isotopic compositions of the kaolin deposits.The H and O isotopic compositions plot close to the kaolinite line that marks the isotopic composition of kaolinite in equilibrium with meteoric water at 20 °C. This indicates that the kaolinite from both the Carboniferous and Cretaceous deposits in Egypt formed by meteoric water weathering of the source rock(s). The δD and δ18O values also suggest that kaolinite of these deposits formed under warm-temperate to tropical conditions. The slight deviations of some samples from the kaolinite line suggest post-depositional modifications of the isotopic compositions of studied deposits probably due to the interaction between earlier-formed kaolinite and downward percolating meteoric water.The δD and δ18O values of the Cretaceous and Carboniferous deposits from all localities suggest that both deposits formed under similar climatic conditions due to the location of Egypt at almost the same distance from the equator either to the south during the Carboniferous or to the north during the Cretaceous. 相似文献
4.
The Zhibula Cu skarn deposit contains 0.32 Mt. Cu metal with an average grade of 1.64% and is located in the Gangdese porphyry copper belt in southern Tibet. The deposit is a typical metasomatic skarn that is related to the interaction of magmatic–hydrothermal fluids and calcareous host rock. Stratiform skarn orebodies occur at the contact between tuff and marble in the Lower Jurassic Yeba Formation. Alteration zones generally grade from a fresh tuff to a garnet-bearing tuff, a garnet pyroxene skarn, and finally to a wollastonite marble. Minor endoskarn alteration zonations are also observed in the causative intrusion, which grade from a fresh granodiorite to a weakly chlorite-altered granodiorite, a green diopside-bearing granodiorite, and to a dark red-brown garnet-bearing granodiorite. Prograde minerals, which were identified by electron probe microanalysis include andradite–grossularite of various colors (e.g., red, green, and yellow) and green diopside. Retrograde metamorphic minerals overprint the prograde skarn, and are mainly composed of epidote, quartz, and chlorite. The ore minerals consist of chalcopyrite and bornite, followed by magnetite, molybdenite, pyrite, pyrrhotite, galena, and sphalerite. Three types of fluid inclusions are recognized in the Zhibula deposit, including liquid-rich two-phase inclusions (type L), vapor-rich two-phase inclusions (type V), and daughter mineral-bearing three-phase inclusions (type S). As the skarn formation evolved from prograde (stage I) to early retrograde (stage II) and later retrograde (stage III), the ore-forming fluids correspondingly evolved from high temperature (405–667 °C), high salinity (up to 44.0 wt.% NaCl equiv.), and high pressure (500–600 bar) to low-moderate temperature (194–420 °C), moderate-high salinity (10.1–18.3 and 30.0–44.2 wt.% NaCl equiv.), and low-moderate pressure (250–350 bar). Isotopic data of δ34S (− 0.1‰ to − 6.8‰, estimated δ34Sfluids = − 0.7‰), δDH2O (− 91‰ to − 159‰), and δ18OH2O (1.5‰ to 9.2‰) suggest that the ore-forming fluid and material came from magmatic–hydrothermal fluids that were associated with Miocene Zhibula intrusions. Fluid immiscibility likely occurred at the stage I and stage II during the formation of the skarn and mineralization. Fluid boiling occurred during the stage III, which is the most important Cu deposition mechanism for the Zhibula deposit. 相似文献
5.
Zhaxikang is one large Sb–Pb–Zn–Ag deposit located in the North Himalaya of southern Tibet. To date, the genesis of this deposit still remains controversial. Here, we present new pyrite Fe and sphalerite Zn isotopic data for the first three stages of mineralization, Fe–Zn isotopic data for Mn–Fe carbonate that formed during the first two stages of mineralization, and Zn isotopic data for the slate wall rocks of the Jurassic Ridang Formation to discuss the genesis of the Zhaxikang deposit. The overall δ56Fe and δ66Zn values range from −0.80‰ to 0.43‰ and from −0.03‰ to 0.38‰, respectively. The δ56Fe values of Mn–Fe carbonates are lighter than those of associated pyrite in six mineral pairs, indicating that the iron carbonates are preferentially enriched in light Fe isotopes relative to pyrite. The sphalerite has lighter δ66Zn values than associated Mn–Fe carbonates in three mineral pairs.The δ56Fe values of pyrite that formed during the first three stages of mineralization gradually increase from stage 1 (−0.33‰ to −0.09‰) through stage 2 (−0.30‰ to 0.19‰) to stage 3 (0.16‰–0.43‰). In comparison, the sphalerite that formed during these stages has δ66Zn values that gradually decrease from stage 1 (0.16‰–0.35‰) through stage 2 (0.09‰–0.23‰) to stage 3 (−0.03‰ to 0.22‰). These data, in conjunction with the observations of hand specimens and thin sections, suggest that the deposit was overprinted by a second pulse of mineralization. This overprint would account for these Fe–Zn isotopic variations as well as the kinetic Rayleigh fractionation that occurred during mineralization. The temporally increasing δ56Fe and decreasing δ66Zn values recorded in the deposit are also coincident with an increase in alteration, again supporting the existence of two pulses of mineralization. The δ56Fe values of the first pulse of ore-forming fluid were calculated using theoretical equations, yielding values of −0.54‰ to −0.34‰ that overlap with those of submarine hydrothermal solutions (−1‰ to 0‰). However, the δ56Fe values of the stage 3 pyrite are heavier than those of typical submarine hydrothermal solutions, which suggests that the second pulse of mineralization was probably derived from a magmatic hydrothermal fluid. In addition, the second pulse of ore-forming fluid has brought some Fe and taken away parts of Zn, which results the lighter δ66Zn values of sphalerite and heavier δ56Fe values of pyrite from the second pulse of mineralization. Overall, the Zhaxikang deposit records two pulses of mineralization, and the overprint by the second pulse of mineralization causes the lighter δ66Zn values and heavier δ56Fe values of modified samples. 相似文献
6.
The Hadamengou-Liubagou Au-Mo deposit is the largest gold deposit in Inner Mongolia of North China. It is hosted by amphibolite to granulite facies metamorphic rocks of the Archean Wulashan Group. To the west and north of the deposit, there occur three alkaline intrusions, including the Devonian-Carboniferous Dahuabei granitoid batholith, the Triassic Shadegai granite and the Xishadegai porphyritic granite with molybdenum mineralization. Over one hundred subparallel, sheet-like ore veins are confined to the nearly EW-trending faults in the deposit. They typically dip 40° to 80° to the south, with strike lengths from hundreds to thousands of meters. Wall rock alterations include potassic, phyllic, and propylitic alteration. Four distinct mineralization stages were identified at the deposit, including K-feldspar-quartz-molybdenite stage (I), quartz-pyrite-epidote/chlorite stage (II), quartz-polymetallic sulfide-gold stage (III), and carbonate-sulfate-quartz stage (IV). Gold precipitated mainly during stage III, while Mo mineralization occurred predominantly in stage I. The δDH2O and δ18OH2O values of the ore-forming fluids range from −125‰ to −62‰ and from 1.4‰ to 7.5‰, respectively, indicating that the fluids were dominated by magmatic water with a minor contribution of meteoric water. The δ13CPDB and δ18OSMOW values of hydrothermal carbonate minerals vary from −10.3‰ to −3.2‰ and from 3.7‰ to 15.3‰, respectively, suggesting a magmatic carbon origin. The δ34SCDT values of sulfides from the ores vary from −21.7‰ to 5.4‰ and are typically negative (mostly −20‰ to 0‰). The wide variation of the δ34SCDT values, the relatively uniform δ13C values of carbonates (typically −5.5‰ to −3.2‰), as well as the common association of barite with sulfides suggest that the minerals were precipitated under relatively high fo2 conditions, probably in a magmatic fluid with δ34SƩS ≈ 0‰. The Re-Os isotopic dating on molybdenite from Hadamengou yielded a weighted average age of 381.6 ± 4.3 Ma, indicating that the Mo mineralization occurred in Late Devonian. Collectively, previous 40Ar-39Ar and Re-Os isotopic dates roughly outlined two ranges of mineralizing events of 382–323 Ma and 240–218 Ma that correspond to the Variscan and the Indosinian epochs, respectively. The Variscan event is approximately consistent with the Mo mineralization at Hadamengou-Liubagou and the emplacement of the Dahuabei Batholith, whereas the Indosinian event roughly corresponds to the possible peak Au mineralization of the Hadamengou-Liubagou deposit, as well as the magmatic activity and associated Mo mineralization at Xishadegai and Shadegai. Geologic, petrographic and isotopic evidence presented in this study suggest that both gold and molybdenum mineralization at Hadamengou-Liubagou is of magmatic hydrothermal origin. The molybdenum mineralization is suggested to be associated with the magmatic activity during the southward subduction of the Paleo-Asian Ocean beneath the North China Craton (NCC) in Late Devonian. The gold mineralization is most probably related to the magma-derived hydrothermal fluids during the post-collisional extension in Triassic, after the final suturing between the Siberian and NCC in Late Permian. 相似文献
7.
The several-hundred-m-thick Miocene Upper Red Formation in northwestern Iran hosts stratiform and fault-controlled copper mineralization. Copper enrichment in the percent range occurs in dm-thick carbonaceous sandstone and shale units within the clastic redbed sequence and consists of fine-grained disseminated copper sulfides (chalcopyrite, bornite, chalcocite) and supergene alteration minerals (covellite, malachite and azurite). The copper mineralization formed after calcite cementation of the primary rock permeability. Copper sulfides occur mainly as replacement of diagenetic pyrite, which, in turn, replaced organic matter. Electron microprobe analysis on bornite, chalcocite and covellite identifies elevated silver contents in these minerals (up to 0.12, 0.72 and 1.21 wt%, respectively), whereas chalcopyrite and pyrite have only trace amounts of silver (<0.26 and 0.06 wt%, respectively). Microthermometric data on fluid inclusions in authigenic quartz and calcite indicate that the Cu mineralization is related to a diagenetic fluid of moderate-to low temperature (Th = 96–160 °C) but high salinity (25–38 wt% CaCl2 equiv.). The range of δ34S in pyrite is −41.9 to −16.4‰ (average −31.4‰), where framboidal pyrite shows the most negative values between −41.9 and −31.8‰, and fine-grained pyrite has relatively heavier δ34S values (−29.2 to −16.4‰), consistent with a bacteriogenic derivation of the sulfur. The Cu-sulfides (chalcopyrite, bornite and chalcocite) show slightly heavier values from −14.6 to −9.0‰, and their sulfur sources may be both the precursor pyrite-S and the bacterial reduction of sulfate-bearing basinal brines. Carbonates related to the ore stage show isotopically light values of δ13CV-PDB from −8.2 to −5.1‰ and δ18OV-PDB from −10.3 to −7.2‰, indicating a mixed source of oxidation of organic carbon (ca. −20‰) and HCO3− from seawater/porewater (ca. 0‰). The copper mineralization is mainly controlled by organic matter content and paleopermeability (intragranular space to large fracture patterns), enhanced by feldspar and calcite dissolution. The Cheshmeh-Konan deposit can be classified as a redbed-type sediment-hosted stratiform copper (SSC) deposit. 相似文献
8.
《Quaternary Science Reviews》2004,23(3-4):245-260
In Arctic and sub Arctic seas, shell growth and/or secondary calcite overgrowth of Neogloboquadrina pachyderma (left coiled)—Npl—occur along the pycnocline, and their δ13C and δ18O-values are size and weight dependent. However, whereas the Npl 18O data from the NW Atlantic indicate near-equilibrium conditions with ambient waters and a positive relationship between shell weight and 18O-content, assemblages from box-cored sediments of the Chukchi Sea (western Arctic) are depleted by ∼2‰ with respect to equilibrium values with modern conditions, and depict a negative relationship between shell weight and its δ18O-value (−0.15±0.03‰/μg on VPDB scale). A similar feature is also depicted by the dextral form of N. pachyderma (Npd). We associate the reverse shell-size or weight vs. δ18O relationship to the reverse temperature gradient observed along the thermocline between the surface cold and dilute water layer, and the underlying near 3°C-warmer saline North Atlantic water mass. The analysis of two late to post-glacial sedimentary sequences from the Chukchi Sea indicates that such a water mass stratification with a reverse thermocline persisted throughout the Holocene, thus reflecting an early onset of the modern-like linkage between the Arctic Ocean and the North Atlantic. Moreover, lower δ18O-values in both Npl and Npd together with larger δ18O-gradients between the different shell sizes at ca 9–7 ka BP suggest ∼3°C higher temperatures in the upper North Atlantic water mass, in comparison with the present (approximately +1°C, at the study site), thus likely a higher inflow rate of this water mass during the early Holocene. 相似文献
9.
The Yindongpo gold deposit is located in the Weishancheng Au–Ag-dominated polymetallic ore belt in Tongbai Mountains, central China. The ore bodies are stratabound within carbonaceous quartz–sericite schists of the Neoproterozoic Waitoushan Group. The ore-forming process can be divided into three stages, represented by early barren quartz veins, middle polymetallic sulfide veinlets and late quartz–carbonate stockworks, with most ore minerals, such as pyrite, galena, native gold and electrum being formed in the middle stage. The average δ18Owater values changed from 9.7‰ in the early stage, through 4.9‰ in the middle stage, to − 5.9‰ in the late stage, with the δD values ranging between − 65‰ and − 84‰. The δ13CCO2 values of ore fluids are between − 3.7‰ and + 6.7‰, with an average of 1.1‰. The H–O–C isotope systematics indicate that the ore fluids forming the Yindongpo gold deposit were probably initially sourced from a process of metamorphic devolatilization, and with time gradually mixed with meteoric water. The δ34S values range from − 0.3‰ to + 5.2‰, with peaks ranging from + 1‰ to + 4‰. Fourteen sulfide samples yield 206Pb/204Pb values of 16.990–17.216, 207Pb/204Pb of 15.419–15.612 and208Pb/204Pb of 38.251–38.861. Both S and Pb isotope ratios are similar to those of the main lithologies of the Waitoushan Group, but differ from other lithologic units and granitic batholiths in the Tongbai area, which suggest that the ore metals and fluids originated from the Waitoushan Group. The available K–Ar and 40Ar/39Ar ages indicate that the ore-forming process mainly took place in the period of 176–140 Ma, during the transition from collisional compression to extension and after the closure of the oceanic seaway in the Qinling Orogen. The Yindongpo gold deposit is interpreted as a stratabound orogenic-style gold system formed during the transition phase from collisional compression to extension.The ore metals in the Waitoushan Group were extracted, transported and then accumulated in the carbonaceous sericite schist layer. The carbonaceous sericite schist layer, especially at the junction of collapsed anticline axis and fault structures, became the most favorable locus for the ore bodies. 相似文献
10.
The Yangla Cu deposit is the largest Cu skarn deposit in the Jinshajiang tectonic belt. Based on the detailed observation of crosscutting relationships, three mineralization stages (i.e., pre-ore, ore and supergene) have been identified in the Yangla deposit. The pre-ore stage is dominated by prograde skarn. The ore stage is characterized by the precipitation of hydrous silicate minerals, Fe-oxides, Fe-Cu-Mo-sulfides, quartz and calcite, whose mineral assemblages were formed in the early and late sub-ore stages. The early sub-ore stage is marked by retrograde alteration with the deposition of hydrous silicate minerals (e.g., actinolite, epidote and chlorite), Fe-oxides, abundant Fe-Cu-Mo-sulfides, quartz and minor calcite. Whilst, the late sub-ore stage, associated with silicic and carbonate alteration, is represented by widespread thick quartz or calcite veins with disseminated pyrite, chalcopyrite, galena and sphalerite. We present new carbon-oxygen (C-O) isotopic compositions of the ore-hosting marble and hydrothermal calcite of this deposit. The hydrothermal calcite in the Yangla deposit was precipitated from both the early and late sub-ore stages. Calcite I from the early sub-ore stage is anhedral, and occurs as spot in the skarn or locally replaces the skarn minerals. Calcite II from the late sub-ore stage is distinguished by being coarse-grained, subhedral to euhedral and its occurrence in thick veins. Calcite I contains lower δ13CPDB (−7.0‰ to −5.0‰) and δ18OSMOW (7.2‰ to 12.7‰) than Calcite II (δ13CPDB = −4.5‰ to −2.3‰; δ18OSMOW = 10.7‰ to 19.4‰). In the δ13CPDB vs. δ18OSMOW diagram, the Calcite I and Calcite II data fall close to the igneous carbonatite field and between the fields of igneous carbonatite and marine carbonates, respectively. This suggests a dominantly magmatic origin for the early sub-ore fluids, and there might have been increasing carbonate wall rock involvement towards the late sub-ore stage. The ore-hosting marble (δ13CPDB = −4.8‰ to −0.3‰; δ18OSMOW = 10.2‰ to 23.9‰) also shows a positive δ13CPDB vs. δ18OSMOW correlation, which is interpreted to reflect the decreasing alteration intensity during the interactions between the hydrothermal fluids and ore-hosting carbonates. Simulated calculation suggests that both the Calcite I and Calcite II precipitated at 350 °C to 250 °C and 250 °C to 150 °C, respectively. We proposed that CO2 degassing and water/rock interactions were likely the two major processes that precipitated the calcite and led to the observed C-O isotopic features of the Yangla Cu deposit. 相似文献
11.
《Applied Geochemistry》2003,18(7):997-1009
The δ18O and δD values in the deep confined aquifer beneath the North China Plain which is located at 112°30′E–119°30′E and 34°46′N–40°25′N, reflect differences in paleoclimatic conditions between the Holocene and the late Pleistocene. Groundwater samples whose 14C ages are between 12 and 25 ka B.P have ranges of −9.4 to −11.7‰ for δ18O and −76‰ to −85‰ for δD values. These very negative δ18O and δD values reflect the cold and arid climate in the last glacial period. The temperature estimated in this period is 6–9 °C cooler than that of the present. The entire ranges of δ18O and δD values for samples with 14C dating from 7 ka B.P to present are −7.7‰ to −10.2‰ and −63‰ to −73‰, respectively. The greater δ18O and δD enrichments of these samples indicate a period of relatively humid and warm climate in the Holocene. However, the wide ranges of δ18O (−9.0‰ to −11.1‰) and δD (−66‰ to −80‰) values for samples with 14C age ranging from 12 to 7 ka B.P. imply an unstable climatic condition of rapidly increasing temperature, which marks the transition from the Pleistocene to the Holocene. 相似文献
12.
《Chemical Geology》2006,225(1-2):137-155
Carbon stable isotopes from carbonate minerals (mainly dolomite) from six wells from the Lower Triassic Sherwood Sandstones of the Corrib Gas Field, Slyne Basin, west of Ireland, allow stratigraphic correlation. The results also provide information on palaeoenvironmental change during the deposition of these continental redbed sedimentary rocks. The Triassic reservoir rocks have been buried to > 4000 m and heated to > 165 °C and now contain methane-rich gas. Although the oxygen isotopic signal has been at least partially reset during burial and heating, a primary carbon isotopic signal appears to have survived diagenesis. The carbon isotope ratio varies from − 3.2‰ to + 2.1‰. All six wells show similar stratigraphic changes when all the carbon isotope data are plotted relative to a major playa horizon. δ13C increases from about − 3‰ at the base of the Sherwood to about + 2‰ 170 m above the base. δ13C then decreases to about − 2‰ for the next 70 m and remains steady for the following 50 m. The top 20 m of the Sherwood contains carbonate with a δ13C values decreasing to about − 3‰. The occurrence of a stratigraphically-correlatable carbon isotope pattern implies that the primary evolution signal has been preserved. The change in δ13C correlates with indicators of aridity and biological stress such that the highest δ13C values are in sedimentary rocks deposited in a playa lake (arid times); these rocks contain the greatest quantity of dolomite cement. Conversely, the lowest δ13C values correspond to sedimentary rocks deposited from well-developed rivers (relatively humid times) from the lowest quantity of dolomite cement. The same carbon isotope evolution has been found in another well in the Slyne basin and in Belgium, suggesting that the palaeoenvironmental isotope signal in the Triassic sedimentary rocks of the Corrib Field may have a regional significance. 相似文献
13.
The Qianfanling Mo deposit, located in Songxian County, western Henan province, China, is one of the newly discovered quartz-vein type Mo deposits in the East Qinling–Dabie orogenic belt. The deposit consists of molybdenite in quartz veins and disseminated molybdenite in the wall rocks. The alteration types of the wall rocks include silicification, K-feldspar alteration, pyritization, carbonatization, sericitization, epidotization and chloritization. On the basis of field evidence and petrographic analysis, three stages of hydrothermal mineralization could be distinguished: (1) pyrite–barite–quartz stage; (2) molybdenite–quartz stage; (3) quartz–calcite stage.Two types of fluid inclusions, including CO2-bearing fluid inclusions and water-rich fluid inclusions, have been recognized in quartz. Homogenization temperatures of fluid inclusions vary from 133 °C to 397 °C. Salinity ranges from 1.57 to 31.61 wt.% NaCl eq. There are a large number of daughter mineral-CO2-bearing inclusions, which is the result of fluid immiscibility. The ore-forming fluids are medium–high temperature, low to moderate salinity H2O–NaCl–CO2 system. The δ34S values of pyrite, molybdenite, and barite range from − 9.3‰ to − 7.3‰, − 9.7‰ to − 7.3‰ and 5.9‰ to 6.8‰, respectively. The δ18O values of quartz range from 9.8‰ to 11.1‰, with corresponding δ18Ofluid values of 1.3‰ to 4.3‰, and δ18D values of fluid inclusions of between − 81‰ and − 64‰. The δ13CV-PDB values of fluid inclusions in quartz and calcite have ranges of − 6.7‰ to − 2.9‰ and − 5.7‰ to − 1.8‰, respectively. Sulfur, hydrogen, oxygen and carbon isotope compositions show that the sulfur and ore-forming fluids derived from a deep-seated igneous source. During the peak collisional period between the North China Craton and the Yangtze Craton, the ore-forming fluids that derived from a deep igneous source extracted base and precious metals and flowed upwards through the channels that formed during tectonism. Fluid immiscibility and volatile exsolution led to the crystallization of molybdenite and other minerals, and the formation of economic orebodies in the Qianfanling Mo deposit. 相似文献
14.
Stable chlorine isotopes are useful geochemical tracers in processes involving the formation and evolution of evaporitic halite. Halite and dissolved chloride in groundwater that has interacted with halite in arid non-marine basins has a δ37Cl range of 0 ± 3‰, far greater than the range for marine evaporites. Basins characterized by high positive (+1 to +3‰), near-0‰, and negative (−0.3 to −2.6‰) are documented. Halite in weathered crusts of sedimentary rocks has δ37Cl values as high as +5.6‰. Salt-excluding halophyte plants excrete salt with a δ37Cl range of −2.1 to −0.8‰. Differentiated rock chloride sources exist, e.g. in granitoid micas, but cannot provide sufficient chloride to account for the observed data. Single-pass application of known fractionating mechanisms, equilibrium salt-crystal interaction and disequilibrium diffusive transport, cannot account for the large ranges of δ37Cl. Cumulative fractionation as a result of multiple wetting-drying cycles in vadose playas that produce halite crusts can produce observed positive δ37Cl values in hundreds to thousands of cycles. Diffusive isotope fractionation as a result of multiple wetting-drying cycles operating at a spatial scale of 1–10 cm can produce high δ37Cl values in residual halite. Chloride in rainwater is subject to complex fractionation, but develops negative δ37Cl values in certain situations; such may explain halite deposits with bulk negative δ37Cl values. Future field studies will benefit from a better understanding of hydrology and rainwater chemistry, and systematic collection of data for both Cl and Br. 相似文献
15.
Carbon (δ13CPDB) and oxygen (δ18OSMOW) isotopic compositions of auriferous quartz-carbonate veins (QCVs) of gold deposits from Sangli, Kabuliyatkatti, Nagavi, Nabapur and Mysore mining areas developed on the Central Lode system of the Gadag Gold Field (GGF) in the Neoarchaean Gadag schist belt of the Dharwar Craton, southern India have been examined for the first time to understand the origin of the mineralising fluids. In majority of the samples (46 out of 49), δ13Cpdb of carbonates of the QCVs fall in the range from − 2.2‰ to − 9.7‰ and the δ18O values range from 12.0‰ to 30.5‰ SMOW. The calculated fluid δ13C∑ C compositions for these deposits range from − 2.1‰ to − 9.6‰ and δ18OH2O from 6.8‰ to 25.9‰, respectively. Carbonate δ13C and fluid δ13C∑ C compositions of the carbonates of the QCVs of the GGF are not only distinct from the carbon isotope range of marine carbonates or meta-sedimentary carbonates of the Chitradurga schist belt, but are consistent with C-isotope values of magmatic (− 5 ± 3‰, Burrows et al., 1986) and/or mantle (− 6 ± 2‰, Ohmoto, 1986) carbonates. As dissolution/decarbonation reactions during metamorphism of pre-existing carbonate/carbonated rocks produce CO2 with δ13C values similar to or more enriched than parent rock, the carbonate or fluid δ13C ratios of the QCVs (which fall in the compositional range of mantle/magmatic derived CO2 or carbonates) obtained in this work cannot be the result of metamorphism. The present study corroborates our previous reports from Ajjanahalli and G.R. Halli gold deposits (Sarangi et al., 2012) occurring in the vicinity of the southern extension of the same crustal scale shear zone on which all the GGF deposits are located.The age of gold mineralisation in this area has been reported to be 2522 ± 6 Ma by Sarma et al., 2011. Chardon et al. (2011) have proposed large-scale remobilization of the older gneissic basement, as well as, emplacement of juvenile granites between 2559 Ma and 2507 Ma, close to the crustal scale shear zone along the eastern margin of the Chitradurga schist belt. Based on these observations and our isotope studies, it is proposed that gold mineralising fluids were derived from mantle/juvenile magmatic melts and were channelled through crustal scale shear zones to give rise to the gold deposits in the GGF. 相似文献
16.
The Xiaguan Ag–Pb–Zn orefield (Neixiang County, Henan Province), hosting the Yindonggou, Zhouzhuang, Yinhulugou and Laozhuang fault-controlled lode deposits, is situated in the Erlangping Terrane, eastern Qinling Orogen. The quartz-sulfide vein mineralization is dominated by main alteration styles of silicic-, sericite-, carbonate-, chlorite- and sulfide alteration. Major Ag-bearing minerals are freibergite, argentite and native Ag. The deposits were formed by a CO2-rich, mesothermal (ca. 250–320 °C), low-density and low salinity (< 11 wt.% NaCl equiv.), Na+–Cl−-type fluid system. Trapping pressures of the carbonic-type fluid inclusions (FIs) decreased from ca. 280–320 MPa in the early mineralization stage to ca. 90–92 MPa in the late mineralization stage, indicating that the ore-forming depths had become progressively shallower. This further suggests that the metallogenesis may have occurred in a tectonic transition from compression to extension. Geological- and ore fluid characteristics suggest that the Xiaguan Ag–Pb–Zn orefield belongs to orogenic-type systems.The δ18OH2O values change from the Early (E)-stage (7.8–10.8 ‰), through Middle (M)-stage (6.0–9.4 ‰) to Late (L)-stage (− 1.5–3.3 ‰), with δD values changing from E-stage − 95 to − 46 ‰, through M-stage − 82 to − 70 ‰ to L-stage − 95 to − 82 ‰. δ13CCO2 values of the ore fluids in the E- and M-stage quartz vary between 0.1 ‰ and 0.9 ‰ (average: 0.3 ‰); δ13CCO2 values of L-stage FIs are − 0.2–0.1 ‰ in quartz and − 6.8 ‰ to − 3.5 ‰ in calcite. The H–O–C isotopic data indicate that the initial ore fluids were sourced from the underthrusted Qinling Group marine carbonates, and were then interacted with the ore-hosting Erlangping Group metasedimentary rocks. Inflow of circulated meteoric water may have dominated the L-stage fluid evolution.Sulfur (δ34S = 1.9–8.1 ‰) and lead isotopic compositions (206Pb/204Pb = 18.202–18.446, 207Pb/204Pb = 15.567–15.773 and 208Pb/204Pb = 38.491–39.089) of sulfides suggest that the ore-forming materials were mainly sourced from the ore-hosting metasedimentary strata. The stepped heating sericite 40Ar/39Ar detection suggests that the mineralization occurred in the Middle Jurassic to Early Cretaceous (ca. 187 − 124 Ma). Considering the regional tectonic evolution of the Erlangping Terrane, we propose that the Xiaguan Ag–Pb–Zn orefield was formed in a continent–continent collisional tectonic regime, in accordance with the tectonic model for continental collision, metallogeny and fluid flow (CMF). 相似文献
17.
The Chalukou giant porphyry Mo deposit, located in the northern Great Xing'an Range, is the largest Mo deposit in the Xing'an–Mongolia orogenic belt. This deposit's ore bodies are mainly hosted in an intermediate–felsic complex and Jurassic volcanic sedimentary rocks, of which Late Jurassic granite porphyry, quartz porphyry and fine grained granite are closely associated with the Mo mineralization. Three types of fluid inclusions (FIs) are present in the quartz associated with oxide and sulphide minerals, i.e., liquid-rich two-phase, gas-rich two-phase and daughter mineral-bearing multiphase FIs. The FIs in the quartz phenocrysts of the granite porphyry contain liquid-rich two-phase, gas-rich two-phase and daughter mineral-bearing multiphase FIs. The homogenization temperatures vary from 230 °C to 440 °C and 470 °C to 510 °C, and their salinities vary from 0.7% to 53.7% NaCl eq. and 6.2% to 61.3% NaCl eq., respectively. The FIs of K-feldspar–quartz–magnetite veins of the early stage are composed of liquid-rich two-phase, gas-rich two-phase and daughter mineral-bearing multiphase FIs with homogenization temperatures and salinities of 320 °C to 440 °C and 4.2% to 52.3% NaCl eq., respectively. The FIs of quartz–molybdenite veins and breccia of the middle stage are composed of liquid-rich two-phase, gas-rich two-phase and daughter mineral-bearing multiphase FIs with homogenization temperatures and salinities of 260 °C to 410 °C and 0.4% to 52.3% NaCl eq., respectively. FIs of quartz–fluorite–galena–sphalerite veins of the late stage are liquid-rich two-phase FIs with homogenization temperatures and salinities of 170 °C to 320 °C and 0.5% to 11.1% NaCl eq., respectively. The ore-forming fluids of the Chalukou deposit are characterised by high temperature, high salinity and high oxygen fugacity, belonging to an F-rich H2O–NaCl ± CO2 system. The δ18OW values vary from − 4.5‰ to 3.2‰, and the δDW values vary from − 138‰ to − 122‰, indicating that the ore-forming fluids were a mixture of magmatic and meteoric water. The δ34S values range from − 1.9‰ to + 3.6‰ with an average of + 1.6‰. The 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb values of the metallic minerals are in the ranges of 18.269–18.501, 15.524–15.567 and 38.079–38.264, respectively. Both the S and Pb isotopic systems indicate that the ore metals and fluids came primarily from a deep-seated magma source from the juvenile lower crust. The Mo mineralization in the Chalukou deposit occurred at a depth of 0.5 to 1.3 km, and multiple stages of phase separation or immiscibility of ore-forming fluid was critical for the formation of the Chalukou deposit. 相似文献
18.
《Chemie der Erde / Geochemistry》2016,76(1):63-75
Geothermal resources are very rich in Yunnan, China. However, source of dissolved solutes in geothermal water and chemical evolution processes remain unclear. Geochemical and isotopic studies on geothermal springs and river waters were conducted in different petrological-tectonic units of western Yunnan, China. Geothermal waters contain Ca–HCO3, Na–HCO3, and Na (Ca)–SO4 type, and demonstrate strong rock-related trace elemental distributions. Enhanced water–rock interaction increases the concentration of major and trace elements of geothermal waters. The chemical compositions of geothermal waters in the Rehai geothermal field are very complicated and different because of the magma chamber developed at the shallow depth in this area. In this geothermal field, neutral-alkaline geothermal waters with high Cl, B, Li, Rb Cs, As, Sb, and Tl contents and acid–sulfate waters with high Al, Mn, Fe, and Pb contents are both controlled by magma degassing and water–rock interaction. Geothermal waters from metamorphic, granite, and sedimentary regions (except in the Rehai area) exhibit varying B contents ranging from 3.31 mg/L to 4.49 mg/L, 0.23 mg/L to 1.24 mg/L, and <0.07 mg/L, respectively, and their corresponding δ11B values range from −4.95‰ to −9.45‰, −2.57‰ to −8.85‰, and −4.02‰ to +0.06‰. The B contents of these geothermal waters are mainly controlled by leaching host rocks in the reservoir, and their δ11B values usually decrease and achieve further equilibrium with its surrounding rocks, which can also be proven by the positive δ18O-shift. In addition to fluid–rock reactions, the geothermal waters from Rehai hot springs exhibit higher δ11B values (−3.43‰ to +1.54‰) than those yielded from other areas because mixing with the magmatic fluids from the shallow magma. The highest δ11B of steam–heated waters (pH 3.25) from the Zhenzhu spring in Rehai is caused by the fractionation induced by pH and the phase separation of coexisting steam and fluids. Given the strong water–rock interaction, some geothermal springs in western Yunnan show reservoir temperatures higher than 180 °C, which demonstrate potential for electricity generation and direct-use applications. The most potential geothermal field in western Yunnan is located in the Rehai area because of the heat transfer from the shallow magma chamber. 相似文献
19.
This study examined the distributions and stable carbon isotopic compositions of saturated fatty acids (SaFAs) in one 300 cm long sedimentary profile, which was named as Site4B in Shenhu, northern South China Sea. The concentrations of total SaFAs in sediments ranged from 1.80 to 10.16 μg/g (μg FA/g dry sediment) and showed an even-over-odd predominance in the carbon chain of C12 to C32, mostly with n-C16 and n-C18 being the two major components. The short-chain fatty acids (ScFAs; n-C12 to n-C18) mainly from marine microorganisms had average δ13C values of −26.7‰ to −28.2‰, whereas some terrigenous-sourced long-chain fatty acids (LcFAs; n-C21 to n-C32) had average δ13C values of −29.6‰ to −34.1‰. The other LcFAs (n-C24 & n-C26 ∼ n-C28; average δ13C values are −26.1‰ to −28.0‰) as well as n-C19 and n-C20 SaFAs (average δ13C values are −29.1‰ and −29.3‰, respectively) showed a mixed signal of carbon isotope compositions.The relative bioproductivity calculation (marine vs. terrigenous) demonstrated that most of organic carbon accumulation throughout the sedimentary profile was contributed by marine organism. The high marine productivity in Shenhu, South China Sea may be related to the hydrocarbon seepage which evidenced by diapiric structures. Interestingly, there is a sever fluctuation of terrigenous inputs around the depth of 97 cm below the seafloor (bsf), probably resulting from the influence of the Dansgaard–Oeschger events and the Younger Dryas event as revealed by 14C age measurements. 相似文献
20.
《Organic Geochemistry》1999,30(8):881-889
The 13C/12C isotopic ratios for coal-derived polycyclic aromatic hydrocarbons (PAHs) from a number of processes encompassing low and high temperature carbonisation, gasification and combustion have been determined using gas chromatography–isotope ratio mass spectrometry (δ13C GC–IRMS). The results, in conjunction with those for PAHs released under controlled laboratory pyrolysis conditions, indicate that the primary control on the isotopic values of coal-derived PAHs is likely to be the extent of ring growth required to form PAHs during processing. Thus, for relatively mild conversion processes such as low temperature carbonisation where the major aromatics are alkyl substituted 2–3 ring PAHs, the isotopic signatures are similar to those of the parent coals (−24 to −25‰ for UK bituminous coals). However, the δ13C values for the PAHs become lighter in going to high temperature carbonisation (−25 to −27‰), gasification (−27 to −29‰ for old Town gas plants in the UK) and combustion (−29 to −31‰) as the extent of ring condensation increases and confirming that the PAHs are not released as primary volatiles. To demonstrate the potential of applying these differences to source apportion environmental PAHs where major inputs from coals can be expected, soil and vegetation samples taken close to a low temperature carbonisation plant (Bolsover, North Derbyshire) have been analysed. In addition to low temperature coal tar, significant inputs of PAHs from transport fuels, high temperature carbonisation and possibly combustion (coal/biomass) have been inferred from the isotopic ratios, taken in conjunction with the differences in alkyl substitution patterns. 相似文献