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粘土矿物在气候环境变化研究中的应用进展 总被引：1，自引：0，他引：1
在古环境和古气候的重建中,粘土矿物和碳-氧同位素、孢粉、树轮、冰芯等代用指标一样具有同等重要的地位。在没有地质构造运动影响时,气候是影响粘土矿物形成的主要因素,沉积物中的粘土矿物可用来分析古气候和古环境。粘土矿物及其组合可以独立或作为主要指标反映气候和环境变化,并已应用于高分辨率的晚第四纪地层的气候环境研究中。粘土矿物在很短的时间内也会发生明显地变化,不仅可以反映千年-百年尺度的气候环境变化,而且也可以反映几十年尺度的古气候环境变化过程。粘土矿物与其它指标对同一气候环境响应的相位差有待深入研究。不同的半定量分析方法测量出的同一剖面中粘土矿物的含量变化趋势和特征具有一致性。 相似文献
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云南兰坪—思茅盆地江城勐野井钾盐矿床SHK4孔含盐系粘土矿物特征及其成钾环境指示意义 总被引：3，自引：0，他引：3
SHK4孔揭示了晚白垩世含盐系勐野井组(K2me)地层, 根据岩性特征将该孔划分为三个粘土矿物单元, 依次反映了从淡化期到成盐期再到淡化期的转换过程。单元Ⅰ粘土矿物主要为伊利石(70.6%)和高岭石(26.7%), 以及极少量的绿泥石(2.7%)。处于高盐度环境下的单元Ⅱ沉积物粘土矿物主要为伊利石(53.6%)和绿泥石(46.4%)。而这一时期物源区面积的急剧减小在一定程度上改变了粘土矿物的输入类型。单元Ⅲ的粘土矿物主要为伊利石(44.5%)、绿泥石(41.8%)和高岭石(10.7%)。另外粘土矿物组合与沉积过程中的卤水演化程度有着良好的对应关系, 表明富K、Mg的高盐度环境对粘土矿物的形成转化应具有一定的制约作用。考虑到含盐系地层发育时研究区的地质构造背景, 以及SHK4孔伊利石结晶度(平均0.35°Δ2θ)与化学指数(>0.5)的特征, 认为埋藏成岩作用对SHK4孔粘土矿物的形成也具有一定程度的影响。 相似文献
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含油气区岩相古地理学的几个问题 总被引：12，自引：3，他引：12
近 2 0年来 ,在含油气区工作的沉积地质学家似乎更多关注地层学 (地震地层学、层序地层学以及高分辨率层序地层学等 )的发展 ,对岩相古地理环境研究的理论创新及方法研究关注甚少。实际上 ,对岩石地层记录中古地理信息及其它们的驱动力来源和驱动机制的研究有非常丰富的内容 ,信息提取和环境重塑的新方法新技术也不断出现 ,岩相古地理学的发展仍然面临许多重大的理论和技术问题。本文对构造过程与沉积岩相分布样式的耦合关系及其敏感度 ;岩相古地理重塑的时间尺度和分辨率 ;岩相和环境单元的精细描述与刻画 ;岩相单元分布的预测 ;岩相古地理重塑的信息来源及其对称性以及数字化的岩相古地理制图等含油气区岩相古地理学中的几个问题给予了阐明。 相似文献
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粘土矿物在安宁盆地含盐系中分布很广。其矿物学、结晶学及地球化学特征与成盐环境和成盐作用密切相关。石盐层序中主要含伊利石;硫酸盐层序中,除伊利石外尚有绿泥石及绿/蒙混层矿物。这是由于不同盐类沉积阶段,卤水浓度、成分及pH值不同所致。在结构上,粘土矿物以三八面体型组合为特征（伊利石除外）,反映了成盐盆地中相对富Mg2+的特点。此外,粘土矿物中硼和钾的含量远高于非盐系地层,因为这些元素在盐盆地中均得到了蒸发浓集。显然,粘土矿物的上述特征,很好地反映了蒸发环境的具体特点,具有良好的指相意义。 相似文献
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陆相深水沉积层序和体系域边界识别方法初探——以东营凹陷牛38井为例 总被引：2，自引：2，他引：2
浅水环境中 ,在水体由深变浅或者由浅变深变化过程中 ,沉积岩的特性会发生明显的变化。但在深水环境中 ,沉积岩的特征对水体深度的小范围变动的反应并不明显。如何进行偏深水陆相沉积地层的沉积旋回划分 ,是层序地层学研究中一个薄弱的环节。以位于东营凹陷牛庄洼陷内资料较为齐全的牛 38井为研究对象 ,选用对水深变化较敏感的指标 ,如总有机碳含量、稀土元素、声波时差等 ,并结合Fischer曲线法 ,对深水沉积地层的层序地层单元划分进行了初步探讨 ,取得了较好的对应效果。研究结果表明 ,在层序和体系域边界上 ,总有机碳含量较低 ,声波时差曲线的斜率会发生明显的变化 ,稀土元素的相对含量较低 ,Fischer曲线的斜率也会发生变化 相似文献
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基准面旋回结构与叠加样式的沉积动力学分析 总被引：190，自引：27，他引：163
以地层过程-响应沉积动力学为理论基础,以中期基准面旋回为周期,以短期基准面旋回为成因地层单元,较为详细地讨论了层序结构、层序叠加样式与可容纳空间 /沉积物补给通量比值 (A/S比值 )变化、基准面升降幅度及沉积动力学条件的相互关系,描述了不同结构和叠加样式的短期基准面旋回在中期基准面旋回中的分布规律,最终提出以中期基准面旋回为单元的标准层序模式。有意义的是,上述理论分析结果与四川、鄂尔多斯和辽河等盆地中的中、新生代陆相地层高分辨率层序地层分析结果完全一致,说明高分辨率层序地层学理论及其技术方法非常适合于中国广泛分布的中、新生代陆相含油气盆地的层序地层学研究。 相似文献
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全风化花岗岩三大矿物组分——石英、长石和粘土矿物含量变化情况怎样?粘土矿物含量变化幅度多大?以香港九龙3个探坑中采到的18箱(边长30cm的立方体)样品为例, 将1箱样品的不同区分别取样后的XRD鉴定结果(包括全岩3种主要矿物成分变化、粘粒中高岭石和伊利石变化范围值)进行对比, 结果发现它们中矿物成分含量变化范围一般为10%~20%.高岭石相对含量变化幅度大于伊利石, 粗粒结构样品变化值大于细粒样品值.对同一样品不同分析人员得出的结果差别很大.分析后认为样品自身的非均质性和分析人员经验不同, 都可造成粘土矿物含量的明显差别.为进一步分析XRD鉴定样品间矿物成分差异值的可靠性, 还将XRD结果同薄片统计结果进行了对比.结果发现来自石硖尾样品中的石英含量普遍较高, 长石含量普遍较低, 而粘土矿物含量在石硖尾和观塘都有高有低.从两者差值看, 矿物含量相差0%~35%.这项研究说明全风化花岗岩一定范围内的非均质性程度同风化物中矿物是原矿物还是粘土矿物的认定一起对最终结果产生很大影响. 相似文献
9.
为深入研究准噶尔盆地南缘新生界古气候演化过程,采用X射线衍射(XRD)和扫描电镜(SEM)等手段对准噶尔盆地南缘(准南)新生界地层泥岩、砂岩中粘土矿物成分、坡缕石矿物学特征进行了系统分析。分析结果表明,新生界泥岩中粘土矿物组成主要有蒙脱石、伊利石、坡缕石和绿泥石等;坡缕石是指示干旱-半干旱气候条件的特征矿物,呈纤维状、束状等形态,其形态及与周围矿物的接触关系说明坡缕石为典型自生成因,坡缕石、伊利石、绿泥石构成的粘土矿物组合所反映的干旱气候与地层颜色变化相吻合。 相似文献
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文章通过对泥质岩的黏土质矿物组分、成岩作用中黏土质矿物变化综合研究,认为泥质岩中存在大量黏土矿物,且泥质沉积物由松散到固结成岩实质上是黏土矿物组成的变化。泥质岩中主要黏土矿物包括高岭石、蒙皂石、绿泥石、伊利石以及其组成的混层型矿物伊利石/蒙皂石、绿泥石/蒙皂石,其成岩过程可划分为成岩早期的压实阶段、成岩晚期的黏土矿物转化阶段。压实阶段的泥质沉积物中黏土矿物具有物源的继承性、沉积水体古环境指示意义;受压实作用孔隙水、层间水被排出,原生絮凝团被压破,使片状质点趋于平行排列,黏土矿物与孔隙水发生反应,亦形成少量的新生作用矿物,因而黏土矿物具继承源和新生作用源特性。成岩晚期阶段发生层间水释放及层间阳离子交换,从而使得矿物晶体结构与成分发生变化,主要表现为一元黏土矿物向二元混层型转化,最后再到一元型黏土矿物的转化,最终形成转变源黏土矿物。 相似文献
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Arieh Singer 《Earth》1980,15(4):303-326
The interpretation of paleoclays for paleoclimatic purposes is based on five major assumptions: (1) clay mineral formation is directly related to climatic parameters; (2) once formed in the weathering milieu, clay minerals are stable and do not change any more as long as the climate remains stable (pre-burial stability); (3) clay mineral assemblages are uniform throughout the weathering profile; (4) once formed or deposited and buried, clay minerals are stable (post-burial stability); (5) the sensitivity of clay minerals towards environmental factors is uniform. All these assumptions have only a limited validity. Clay mineral formation is in few cases directly related to climatic parameters, nor do clay minerals always represent the stable end products in equilibrium with environmental factors. The vertical distribution pattern of authigenically formed clay minerals is seldom monomineralic. Post-depositional changes are not infrequent. The sensitivity of clay minerals to environmental factors is variable. The use of paleoclays occurring in paleosols and weathering profiles is reviewed. Paleoclays occurring in paleosols or weathering profiles are, in well-defined situations, suitable for paleoclimatic interpretation. At our present state of knowledge, references as to the nature of climates of the past that are based solely on the interpretation of paleoclays are warranted only in exceptional cases. Authigenic occurrences of clay minerals with limited stability fields that can be used as ‘marker minerals’ and the isotopic composition of paleoclay minerals promise, with future research, to increase the value of paleoclays as paleoclimatic indicators. 相似文献
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湖相白云岩是渤海湾盆地北塘凹陷古近系沙河街组三段发现的一种特殊油气储层类型。根据钻井岩心、古生物、薄
片、扫描电镜及电子探针等分析,确定了该套白云岩的主要岩石类型及矿物特征,并通过地球化学特征分析,对白云岩的
形成环境进行了探讨。北塘凹陷白云岩常与泥岩和方沸石岩呈互层状产出,其次为均匀块状;矿物成分主要有白云石、方
沸石、粘土矿物等。通过X射线衍射、主微量元素地球化学分析,对白云岩形成时的古盐度、古温度、水深、氧化还原条
件等进行了研究,认为研究区白云岩沉积于高盐度、较高水体温度和较高PH值的半咸水湖湾还原环境。海水的侵入使湖水
的含盐度增大,提供了有利的物理化学条件,促进了白云岩的形成。 相似文献
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湖相白云岩是渤海湾盆地北塘凹陷古近系沙河街组三段发现的一种特殊油气储层类型。根据钻井岩心、古生物、薄
片、扫描电镜及电子探针等分析，确定了该套白云岩的主要岩石类型及矿物特征，并通过地球化学特征分析，对白云岩的
形成环境进行了探讨。北塘凹陷白云岩常与泥岩和方沸石岩呈互层状产出，其次为均匀块状；矿物成分主要有白云石、方
沸石、粘土矿物等。通过X射线衍射、主微量元素地球化学分析，对白云岩形成时的古盐度、古温度、水深、氧化还原条
件等进行了研究，认为研究区白云岩沉积于高盐度、较高水体温度和较高PH值的半咸水湖湾还原环境。海水的侵入使湖水
的含盐度增大，提供了有利的物理化学条件，促进了白云岩的形成。 相似文献
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Inorganic minerals in mudstone are composed of clay minerals,carbonate and detrital minerals.Detrital minerals(such as quartz and feldspar)are mainly original deposit.However,clay minerals(kaolinite,illite,and chlorite)and carbonate(calcite and dolomite)are mostly diagenetic minerals.Furthermore,conversion of the four kinds of clay minerals are common.The formation of clay minerals and carbonate is controlled by temperature,pressure,p H,Eh and type of cations during diagenesis.Therefore mineral assemblage can indicate the characteristics and change of diagenetic environment.In addition to inorganic minerals,there are also organic matter of different sources and chemical properties in mudstone.Traditionally,it is considered that evolution of organic matter is controlled by thermal effect.Now studies show that inorganic and organic matter can interact with each other and form clay-organic complexes.This suggest that attention should be paid to the influence of diagenetic mineral assemblage and diagenetic environment on the evolution of organic matter* Samples of mudstone from 1500-4500m of the Palaeogene in the Dongying Depression,China,were collected to investigate the changes of mudstone diagenetic environment.XRD,thin section and SEM were used to detect diagenetic minerals and assemblage characteristics.Results showed that content of detrital minerals,which are floating in mud matrix or preserved as silt laminae,is basically unchanged from shallow to deep strata.Clay minerals which are gathered as argillaceous matrix or preserved as argillaceous laminae have growth and decline relation to carbonate which mainly appear as micropoikilitic ferriferous calcite and ferriferous dolomite.All these characteristics indicate that detrital minerals are exogenetic,whereas carbonate is diagenetic minerals.Based on the SEM analysis of the clay minerals,it was found that smectite present honeycomb and reticulate structure,while illite present filiform and schistose structure and there are growth and decline relationship between them.Nevertheless,hexagonal tabular and stratified kaolinite has the highest content from 2400m to3300m.Rosette and stratified chlorite shows increase trend when the burial depth is deeper than 3300m.These characteristics indicated that clay minerals are diagenetic minerals and there are conversions among the four types.Therefore form shallow to deep,three diagenetic mineral assemblage zones can be divided based on the characteristics of carbonate and clay minerals in mudstone.Namely,smectite+illite/smectite zone in the depth of 2000-2500m;kaolinite+illite/smectite zone in the depth of 2500-3300m and illite+chlorite+carbonate zone below 3300m.Previous studies showed that kaolinite is stable under acidic conditions,while other clay minerals and carbonate are stable under alkaline conditions.Hence according to mineral assemblages feature,it was inferred that diagenetic environment of mudstonehasundergonethechangeof alkaline-acid-alkaline.For the organic matter with different chemical properties in mudstone,the hydrocarbon generation will be different in the acidic and alkaline diagenetic environment even if the conditions of temperature and pressure are the same.Therefore,for hydrocarbon generation we should not only focus on thermal effect,but also pay more attention to the differences of diagenetic environment which have great significance for the understanding of hydrocarbon generation,hydrocarbon expulsion and reservoir formation in mudstone. 相似文献
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青藏高原是我国盐湖分布的主要地区之一。对该地区盐湖沉积物中的粘土矿物,前人未进行过系统研究。近年来,作者对柴达木盆地盐湖中的粘土矿物做过一些工作。本文报道了该区49个湖区约200个样品的粘土有关资料,其中包括藏北某些半咸水湖和盐湖周围的某些土壤和泥样的有关资料。文中对含粘土矿物的碎屑沉积物的岩性、粘土矿物类型、粘土化学组分以及粘土资料在盐湖形成演化过程中的地质意义等方面进行了初步讨论和总结。 相似文献
18.
Jeremy H. Wei David B. Finkelstein Julie Brigham‐Grette Isla S. Castañeda Norbert Nowaczyk 《Sedimentology》2014,61(6):1793-1811
Marine Isotope Stage 11 has been proposed as an analogue for the present interglacial interval; yet, terrestrial climate records from both this region and time interval are rare. The sediments deposited at Lake El'gygytgyn (67°30′N, 172°5′E) in Far East Russia contain a 3·56 Ma record of climate variability. This study presents a high‐resolution record of sediment colour change from Marine Isotope Stage 8 to 12 (ca 275 to 475 ka) and demonstrates the link between lake catchment processes and climate variability. The hue colour parameter, calculated from data collected via colour reflectance spectroscopy in the visible spectrum (380 to 720 nm), exhibits correspondence with global climate records. Determining the source of sediment colour changes was achieved through detailed mineralogical and sedimentological methods, and linked to colour changes through a series of colour sensitivity tests. Mineralogical data, measured by X‐ray diffraction, reveal fluctuations in concentrations of clay minerals corresponding to colour changes. Further analyses of the clay mineral assemblages show no change in relative clay mineral abundances, yet demonstrate a lake catchment dominated by physical weathering processes. Using measured mineral abundances, reconstructions of sediment colour based on colour reflectance mineral standards link mineral and clay mineral content to overall sediment colour. Colour sensitivity tests demonstrate the ability of iron oxide minerals to stain sediments red. Additionally, colour sensitivity to organic matter content was tested, suggesting that organic content drives variability in the red portion of the spectrum and darkens the overall colour signal. Sediment colour is then ultimately linked to physical weathering of bedrock minerals, with small amounts of chemical weathering producing iron oxides during wet intervals. Fluctuations in the sediment colour reveal a high‐resolution record of wet/dry cycles, and provide new information about wet periods for the Russian Arctic region not yet understood from other lake proxy records. 相似文献
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E.C. Gaucher C. Tournassat F.J. Pearson C. Crouzet S. Altmann 《Geochimica et cosmochimica acta》2009,73(21):6470-6487
The chemistry of pore water is an important property of clayrocks being considered as host rocks for long-term storage of radioactive waste. It may be difficult, if not impossible, to obtain water samples for chemical analysis from such rocks because of their low hydraulic conductivity. This paper presents an approach for calculating the pore-water compositions of clayrocks from laboratory-measured properties of core samples, including their leachable Cl and SO4 concentrations and analysed exchangeable cations, and from mineral and cation exchange equilibria based on the formation mineralogy. New core sampling and analysis procedures are presented that reduce or quantify side reactions such as sample oxidation (e.g. pyrite) and soluble mineral dissolution (celestite, SrSO4) that affect measured SO4 concentrations and exchangeable cation distributions. The model considers phase equilibria only with minerals that are observed in the formation including the principal clay phases. The model has been used to calculate the composition of mobile pore water in the Callovo-Oxfordian clayrock and validated against measurements of water chemistry made in an underground research laboratory in that formation. The model reproduces the measured, in situ pore-water composition without any estimated parameters. All required parameters can be obtained from core sample analysis. We highlight the need to consider only those mineral phases which can be shown to be in equilibrium with contacting pore water. The consequence of this is that some conceptual models available in the literature appear not to be appropriate for modelling clayrocks, particularly those considering high temperature and/or high pressure detrital phases as chemical buffers of pore water. The robustness of our model with respect to uncertainties in the log K values of clay phases is also demonstrated. Large uncertainties in log K values for clay minerals have relatively small effects on modelled pore-water compositions. 相似文献
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民和盆地上侏罗统湿型冲积扇沉积 总被引：2，自引：0，他引：2
本文通过岩相特征、粘土矿物分布、早期成岩矿物组合、微量元素等特征的综合分析，认为民和盆地上侏罗统下部为一较典型的湿型冲积扇沉积。冲积扇扇中发育河道冲刷充填和漫流沉积，而泥石流不发育。沉积层序与现代湿型冲积扇可对比。扇体中粘土岩及早期成岩矿物组合中富含高岭石，应与扇体发育时的潮湿气候和弱酸性流体的较强的淋滤有关。由粘土岩中微量元素因子分析进一步表明，该地层中富硼、钒的特征与相邻非扇相地层明显不同 相似文献