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1.
对6个大别山超高压榴辉岩中的粒间金红石进行了显微傅立叶变换红外光谱(Micro-FTIR)观察和电子探针(EMP)分析。结果显示所有金红石颗粒都在3280cm-1和3295cm-1出现强的吸收峰,少数颗粒在约3360cm-1出现较弱且宽的峰,这3组峰都是由金红石中的结构OH引起的。与高温高压合成实验结果比较发现,3280cm-1峰主要是由Ti3 H Ti4 取代引起的,3295cm-1峰可能是由Fe3 H Ti4 造成的,而约3360cm-1的峰与Mg2 取代Ti4 的电荷补偿有关。由目前认为较可靠的两个金红石红外吸收系数获得结构水的含量(质量分数)分别为:161×10-6~854×10-6和202×10-6~1075×10-6,不同的IR吸收系数导致计算的水含量相差4~5倍,因此,前人所得到的金红石高水含量可能需要重新评估。与共存的石榴石和绿辉石相似,不同样品间的金红石水含量也表现出不均一分布,指示着超高压过程中有限的流体活动和快速的板块俯冲-折返过程。  相似文献   

2.
大别山双河超高压榴辉岩中的水: 微区红外光谱分析   总被引:9,自引:2,他引:7  
大陆深俯冲板块到一定深度后(约90~110km), 几乎没有含水矿物存在, 超高压岩石中名义上无水矿物(NAMs) 成为俯冲板块中水的主要载体, 是示踪超高压变质流体的重要途径.对大别山双河地区超高压榴辉岩中的石榴石和绿辉石进行了详细的微区傅立叶变换红外光谱(MicroFTIR) 分析.FTIR结果显示所有石榴石和绿辉石颗粒都含有结构水, 以OH的形式存在, 其含量范围分别为(30~1860)×10-6和(360~620)×10-6.榴辉岩全岩水含量为(300~750)×10-6, 表明即使是在超高压变质作用的温压条件下, 榴辉岩也可以至少携带数百10-6的水进入深部地球.对石榴石颗粒内部的多点观察发现, 结构水含量的分布出现2种情况: (1) 颗粒内部的均一分布; (2) 核部水含量高而边部低.石榴石颗粒边部的低水含量可能是抬升过程中由于压力降低引起的H扩散所致, 扩散出来的H可能构成了早期退变质流体的重要来源.对于同一样品来说, 结构水含量在绿辉石和石榴石之间的比值为0.5~3.5.   相似文献   

3.
运用傅立叶变换红外光谱(FTIR)技术,对大别山碧溪岭和黄镇榴辉岩中的绿辉石进行了详细的结构水观察。绿辉石中普遍含有结构水,以OH~-的形式存在,含量可达~2000ppm(H_2O wt.)。碧溪岭绿辉石的水含量在露头尺度(-150km)上是不均一的,而黄镇绿辉石是均一的(至少在3km的尺度上)。碧溪岭绿辉石水含量的不均一分布和黄镇绿辉石水含量的均一分布都反映的是原岩特征,碧溪岭榴辉岩原岩经历的水-岩相互作用是“隧道式”的而黄镇是“弥散式”的碧溪岭榴辉岩的原岩可能是基性的侵入岩而黄镇榴辉岩的原岩可能是玄武岩。碧溪岭绿辉石的水含量(<1400ppm)明显低于黄镇绿辉石(~1850ppm),这是原岩水含量差异的体现,原岩性质的不同和经历的水-岩相互作用方式的不同造成了原岩水含量的差异。  相似文献   

4.
徐薇  刘祥文  金振民 《地球科学》2006,31(6):830-838
超高压变质岩中名义上无水矿物(NAMs) 在板块俯冲过程中可以携带一部分地表水进入上地幔, 这些水储存于地球深部并对地幔动力学有着重要的影响.对中国大陆科学钻探主孔榴辉岩中的绿辉石和石榴石进行了详细的显微傅立叶变换红外光谱(Micro-FTIR) 分析, 结果显示所有绿辉石和石榴石颗粒都含有结构水, 其水含量范围分别在68~29μg/g和20~75μg/g.榴辉岩全岩的水含量为150~300μg/g.绿辉石和石榴石结构水含量的分布出现2种情况: (1) 颗粒内部的均一分布; (2) 不均匀分布, 表现为水含量从核部到幔部到边部随之增加或水含量核部、边部低而幔部高.电子探针结果表明水含量分布不均与矿物化学成分无直接关系.位错分布不均匀可能导致了颗粒内部结构水分布的不均匀.   相似文献   

5.
大陆深俯冲过程中的水:"名义上无水矿物(NAMs)"的信息   总被引:12,自引:1,他引:11  
对大别山典型产地榴辉岩中石榴子石和绿辉石的傅立叶变换红外光谱(FTIR)观察表明,石榴子石和绿辉石中都含育一定量的结构水,以OH-形式赋存。石榴子石中的水含量(H2O,wt)多为(200-1000)×10-6,可高达2200×10-6;绿辉石中的水含量相对高一些,多在500×10-6以上,最高可达3000×10-6;UHP榴辉岩的全岩水含量可高达10000×10-6。绿辉石的δD值为-67‰--110‰。矿物中的水含量和δD值都存在小尺度(同一样品不同颗粒间以及不同样品之间)的不均一性,这不仅表明超高压变质过程中自由流体的活动范围是有限的,而且说明板块的俯冲和折返都是十分快速的。"名义上无水矿物(NAMs)"的结构水含量和分布特征不仅可以示踪大陆深俯冲过程中流体的演化,还可以提供有意义的深俯冲过程的动力学信息。  相似文献   

6.
榴辉岩常用温压计在应用中应注意的问题   总被引:5,自引:6,他引:5  
陈意叶凯  吴春明 《岩石学报》2005,21(4):1067-1080
本文通过再现相平衡实验数据和检查热力学活度模型两种手段,对榴辉岩中几种常用的温压计进行了检验,发现榴辉岩中某些常用温压计存在以下问题:(1)在 Eliis and Green(1979)、Powell(1985)、Krogh(1988)和 Ravna(2000)四种石榴石-单斜辉石温度计中只有 Ravna(2000)的版本能较好的再现相平衡实验数据。(2)将石榴石-单斜辉石温度计应用于含 X_(Jd)>0.55绿辉石的榴辉岩中会出现很大的误差。(3)Green and Hellman(1982)的石榴石-多硅白云母温度计计算的高压含多硅白云母榴辉岩变质温度普遍偏高,但是计算超高压榴辉岩的结果能较好的与 Ravna(2000)的石榴石-单斜辉石温度计计算结果保持一致。(4)Waters and Martin(1993)的石榴石-单斜辉石-多硅白云母压力计、Ravna and Terry(2004)的石榴石-单斜辉石-多硅白云母-蓝晶石-柯石英/石英温压计的精度都受到了 Holland(1990)的单斜辉石活度模型的限制,它们不能适用于绿辉石 X_(Jd)>0.55的榴辉岩,而 Waters and Manin(1996)对 Waters and Martin(1993)的版本做了一个经验校正,弥补了单斜辉石活度模型的缺陷,因此可以适用于绿辉石 X_(Jd)>0.55的榴辉岩。(5)Nakamura and Banno(1997)的石榴石-绿辉石-蓝晶石-柯石英温压计因运用了不恰当的石榴石和铁钙辉石的活度模型,从而使得计算结果与岩相学观察结果不一致。因此,我们建议:对于绿辉石 X_(Jd)<0.55的多硅白云母榴辉岩,可以运用 Waters and Martin(1993)压力计和 Ravna(2000)的温度计联合求解温压;对于含高硬玉组分(X_(Jd)>0.55)绿辉石的超高压多硅白云母榴辉岩,可选用 Waters and Martin(1996)压力计和 Green andHellman(1982)的温度计联合求解温压;对于含有石榴石 绿辉石 蓝晶石 柯石英矿物组合的榴辉岩,在 X_(Jd)<0.55的情况下。可选用 Ravna and Terry(2004)的温压计求解温压。在应用这些温压计时,应注意各温压计的适用温压范围和成分范围,尤其是石榴石 X_(Jd)、Mg~#和绿辉石 X_(Jd)的范围。另外,由于矿物中 Fe~(3 )的含量对温度计算结果影响很大,所以还必须合理地校正所选矿物的 Fe~(3 )。  相似文献   

7.
对大别山石马和英山超高压榴辉岩中的“名义上无水矿物”(NAM s)石榴石和绿辉石的Fourier变换红外光谱(FT IR)观察表明,它们都含有以OH-或者H2O形式存在的氢,而且发现NAM s从不同地区到同一样品不同颗粒、再到同一颗粒的不同部位的水含量并不均匀。研究结果表明:石马和英山地区绿辉石中结构水的含量范围分别为90×10-6~1 670×1-0 6,110×10-6~710×10-6;石榴石中结构水的含量分别为510×10-6~830×1-0 6,0~180×1-0 6。同时结合地球物理化学等因素对NAM s中结构水在促进榴辉岩变形方面的效应及其与流体包裹体之间的关系进行了初步探讨。  相似文献   

8.
近期在市场上出现一种绿松石仿制品,外观与天然绿松石极为相似,极具迷惑性.采用常规宝石学测试方法、红外吸收光谱、显微红外吸收光谱、紫外可见吸收光谱、X荧光能谱对其宝石学性质、光谱特征进行了系统研究分析.结果 表明:这种绿松石仿制品具有粒状结构,可见角砾状颗粒,颜色分布均匀,具有典型的再造宝石特征.该绿松石仿制品折射率为1.56,与绿松石一致,相对密度为2.34,略低于绿松石.无损显微红外吸收光谱显示该绿松石仿制品主要由顽火辉石与石英组成,并含有胶结物质.顽火辉石的红外吸收峰为1083 cm-1,1009 cm-1,938 cm-1,855 cm-1,721 cm-1,647 cm-1,505 cm-1,478 cm-1,424 cm-1.石英的红外光谱吸收峰为1182 c m-1,1112 cm-1,800 cm-1,692 cm-1.有机胶结物的红外吸收峰为2978 cm-1,2937 cm-1,2878 cm-1,3055 cm-1,3035 cm-1,1612 cm-1,1512 cm-1,1385 cm-1,1458 cm-1.X荧光光谱分析显示主要含有Ba,Ti,Sr,Fe,Ni,Zn元素,与绿松石的成分不相符.紫外可见光谱分析显示在680 nm、630 nm处具有吸收带,应是样品呈现蓝绿色的原因.本次研究旨在利用无损检验方法确定样品为仿绿松石,并确定有环氧树脂胶结物的存在.  相似文献   

9.
采用IR光谱和质谱技术分析了海南福基田幔源巨晶和包体中辉石的结构羟基红外光谱和氢氧同位素。测试的所有巨晶普通辉石和包体中透辉石及顽火辉石均含结构OH,对比印证了国内外同类矿物的红外光谱特征。结构水质量分数分别是:普通辉石87×10-6~389×10-6;透辉石127×10-6~273×10-6;顽火辉石69×10-6~207×10-6。包体中结构水质量分数为1 811×10-6~5 377×10-6,平均为3 133×10-6。包体中辉石的氢氧同位素特征如下:透辉石的δ(D)为-123.17‰,顽火辉石的δ(D)为-132.04‰;透辉石的δ(18O)为5.96‰,顽火辉石的δ(18O)为5.60‰。实验和对比表明,辉石是海南福基田上地幔重要的"水储库",包体未受地壳成分污染,继承和保持了上地幔"富水贫氘"的特征。上述结果为该地区上地幔研究提供了结构水和氢氧同位素的基础资料。  相似文献   

10.
福建龙海牛头山新生代玄武岩橄榄岩包体的水   总被引:1,自引:0,他引:1  
王蓉  张保民 《地球科学》2011,36(4):635-642
对福建龙海牛头山新生代玄武岩中橄榄岩包体进行了傅利叶变换红外光谱(FTIR)分析,结果显示,二辉橄榄岩中的辉石包体含有结构水,均以OH的形式存在,结构水含量分别如下: 单斜辉石为(151~845)×10-6,斜方辉石为(40~710)×10-6,全岩为(25~90)×10-6.无论是辉石中的水含量还是全岩中的水含量,福建牛头山地区均高于华北克拉通的安徽女山、河北汉诺坝和苏北盆地,而与同是华北克拉通的河北阳原地区水含量相当.实验证明辉石是牛头山地区上地幔重要的水储库.初步推断福建牛头山经历了洋壳俯冲作用及底侵作用.   相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.  相似文献   

15.
PALEONTOLOGY     
正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)  相似文献   

16.
正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)  相似文献   

17.
正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)  相似文献   

18.
PETROLOGY     
正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,  相似文献   

19.
正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an  相似文献   

20.
正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of  相似文献   

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