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1.
The attenuation properties have been estimated in the Nubra-Siachen region situated in the highly mountainous region of Himalayan belt. Coda wave quality factor (Qc) has been determined for this virgin region by using the single backscattering method. A total of thirty earthquakes recorded in this region, which fall in the epicentral distance range of 3 to 115km have been used for the present work. A 30 sec window length of coda waves at different central frequencies 1.5, 3.0, 6.0, 9.0, 12.0, 18.0 and 24.0 Hz have been studied to determine Qc at different recording stations. The frequency dependent coda wave quality factor relationships of the form Qc(f) = Qofn, have been computed at each recording stations separately: BASE: Qc(f) = (137 ± 4.2) f(0.99 ± 0.12), CHALUNKA: Qc(f) = (116±3.8)f(1.0±0.05), PARTA: Qc(f) = (122±3.0)f(1.0±0.02), and SASOMA: Qc(f) = (111±4.1)f(1.0±0.03). A regional Qc relation has been developed for the Nubra-Siachen region by using the average value of Qc at different frequencies obtained at each recording station of the form Qc(f) = (121±7.2)f(1.0±0.04). The average Qc values vary from 183 at 1.5 Hz to 3684 at 24 Hz central frequencies. The present regional relation developed for Nubra-Siachen region indicates heterogeneous and tectonically active region.  相似文献   

2.
CodaQ (Q c) estimates for the Kumaun Himalaya region have been obtained in high frequency range. Local earthquakes, recorded by a digital seismic network in the region, which fall in the epicentral distances range of 10 to 80 km and with a local magnitude range of 1.4 to 2.8, have been used. The coda waves of 30 sec window length, filtered at seven frequency bands centered at 1.5, 3, 6, 9, 12, 18 and 24Hz, have been analysed using the single backscattering model. The values ofQ c estimates vary from 65 to 283 at 1.5 Hz to 2119 to 3279 at 24.0 Hz which showed thatQ c is frequency dependent and its value increases as frequency increases. A frequency-dependentQ c relationship,Q c = (92 ± 4.73)f(1.07±.023), is obtained for the region representing the average attenuation characteristics of seismic waves for Kumaun Himalaya region.  相似文献   

3.
The heat capacity of gadolinium orthophosphate (GdPO4) measured in the temperature range 11.15–344.11 K by adiabatic calorimetry and available literature data were used to calculate its thermodynamic functions at 0–1600 K. At 298.15 K, these functions are as follows: C p 0(298.15 K) = 101.85 ± 0.05 J K−1 mol−1, S 0(298.15 K) = 123.82 ± 0.18 J K−1 mol−1, H 0(298.15 K)–H 0(0) = 17.250 ± 0.012 kJ mol−1, and Φ 0(298.15 K) = 65.97 ± 0.18 J K−1 mol−1 The calculated Gibbs free energy of formation from the elements of GdPO4 is Δ f G 0 (298.15 K) = −1844.3 ± 4.7 kJ mol−1.  相似文献   

4.
The heat capacity of xenotime YPO4(c) was measured by adiabatic calorimetry at 4.78–348.07 K. Our experimental and literature data on H 0(T)-H 0(298.15 K) of Y orthophosphate were utilized to derive the C p 0(T) function of xenotime at 0–1600 K, which was then used to calculate the values of thermodynamic functions: entropy, enthalpy change, and reduced Gibbs energy. These functions assume the following values at 298.15 K: C p 0 (298.15 K) = 99.27 ± 0.02 J K−1 mol−1, S 0(298.15 K) = 93.86 ± 0.08 J K−1 mol−1, H 0(298.15 K) − H 0(0) = 15.944 ± 0.005 kJ mol−1, Φ0(298.15 K) = 40.38 ± 0.08 J K−1 mol−1. The value of the free energy of formation Δ f G 0(YPO4, 298.15 K) is −1867.9 ± 1.7 kJ mol−1.  相似文献   

5.
Origin and evolutionary history of the Cuddapah Basin in SE India has remained a subject of considerable speculation whether it was evolved through vertical tectonic movements, extentional stretching or even cometary impact. Based on detailed seismic and other geophysical studies (Gravity, magnetotelluric and heat flow), we have delineated signatures of a possible deep seated mantle plume below southwestern part of the Cuddapah Basin, which may have been responsible for the 1.1 Ga kimberlitic magmatism in the eastern part of the Dharwar craton (EDC). The thermal anomaly associated with this mantle plume appears to have resulted into 15–20 km thick magmatic underplating (Vp: 7.10–7.30 km/s; density 3.07–3.16 g/cm3) below the Parnapalle region of the southwestern Cuddapah Basin, which also coincides with the high gravity and high conductivity anomaly. The massive underplating led to thickening of the crust to about 40–44 km below southwestern part of the Cuddapah Basin, compared to about 34± 2 km in the surrounding regions of EDC, indicating thermal restructuring of the crust / mantle boundary. This plume, which was apparently active in an area of about 500 km radius, may have also affected the Closepet granitic region, which is ∼100 km west of Cuddapah Basin.  相似文献   

6.
The Indian Shield is cross-cut by a number of distinct Paleoproterozoic mafic dyke swarms. The density of dykes in the Dharwar and Bastar Cratons is amongst the highest on Earth. Globally, boninitic dyke swarms are rare compared to tholeiitic dyke swarms and yet they are common within the Southern Indian Shield. Geochronology and geochemistry are used to constrain the petrogenesis and relationship of the boninitic dykes (SiO2 = 51.5 to 55.7 wt%, MgO = 5.8 to 18.7 wt%, and TiO2 = 0.30 wt% to 0.77 wt%) from the central Bastar Craton (Bhanupratappur) and the NE Dharwar Craton (Karimnagar). A single U-Pb baddeleyite age from a boninitic dyke near Bhanupratappur yielded a weighted-mean 207Pb/206Pb age of 2365.6 ± 0.9 Ma that is within error of boninitic dykes from the Dharwar Craton near Karimnagar (2368.5 ± 2.6 Ma) and farther south near Bangalore (2365.4 ± 1.0 Ma to 2368.6 ± 1.3 Ma). Rhyolite-MELTS modeling indicates that fractional crystallization is the likely cause of major element variability of the boninitic dykes from Bhanupratappur whereas trace element modeling indicates that the primary melt may be derived from a pyroxenite mantle source near the spinel-garnet transition zone. The Nd isotopes (εNd(t) = −6.4 to +4.5) of the Bhanupratappur dykes are more variable than the Karimnagar dykes (εNd(t) = −0.7 to +0.6) but they overlap. The variability of Sr-Nd isotopes may be related to crustal contamination during emplacement or is indicative of an isotopically heterogeneous mantle source. The chemical and temporal similarities of the Bhanupratappur dykes with the dykes of the Dharwar Craton (Karimnagar, Penukonda, Chennekottapalle) indicate they are members of the same giant radiating dyke swarm. Moreover, our results suggest that the Bastar and Dharwar Cratons were adjacent but likely had a different configuration at 2.37 Ga than the present day. It is possible that the 2.37Ga dyke swarm was related to a mantle plume that assisted in the break-up of an unknown or poorly constrained supercontinent.  相似文献   

7.
The heat capacity of synthetic pretulite ScPO4(c) was measured by adiabatic calorimetry within a temperature range of 12.13–345.31 K, and the temperature dependence of the pretulite heat capacity at 0–1600 K was derived from experimental and literature data on H 0(T)-H 0(298.15 K) for Sc orthophosphate. This dependence was used to calculate the values of the following thermodynamic functions: entropy, enthalpy change, and reduced Gibbs energy. They have the following values at 298.15 K: C p 0 (298.15 K) = 97.45 ± 0.06 J K−1 mol−1, S 0(298.15 K) = 84.82 ± 0.18 J K−1 mol−1, H 0(298.15 K)-H 0(0) = 14.934 ± 0.016 kJ mol−1, and Φ 0(298.15 K) = 34.73 ± 0.19 J K−1mol−1. The enthalpy of formation Δ f H 0(ScPO4, 298.15 K) = − 1893.6 ± 8.4 kJ mol−1.  相似文献   

8.
Diffusion couples made from homogeneous gem quality natural pyrope and almandine garnets were annealed within graphite capsules under anhydrous conditions at 22–40 kbar, 1057–1400 °C in a piston-cylinder apparatus. The concentration profiles that developed in each couple were modeled to retrieve the self diffusion coefficients [D(I)] of the divalent cations Fe, Mg, Mn and Ca. Because of their usually low concentrations and lack of sufficient compositional change across the interface of the diffusion couples, only a few reliable data can be obtained for D(Ca) and D(Mn) from these experiments. However, nine sets of D(Fe) and D(Mg) data were retrieved in the above P-T range, and cast in the form of Arrhenian relation, D=D 0exp{−[Q(1 bar)+PΔV +]/RT}. The values of the activation energy (Q) and activation volume (ΔV +) depend on whether f O2 is constrained by graphite in the system C-O or held constant. For the first case, we have for Fe:Q(1 bar)=65,532±10,111 cal/mol, D 0=3.50 (±2.30)×10−5 cm2/s, ΔV +=5.6(±2.9) cm3/mol, and for Mg:Q(1 bar)=60,760±8,257 cal/mol, D 0=4.66 (±2.48)×10−5 cm2/s, ΔV +=5.3(±3.0) cm3/mol. Here the ΔV + values have been taken from Chakraborty and Ganguly (1992). For the condition of constant f O2, the Q values are ∼9 kcal lower and ΔV + values are ∼4.9 cm3/mol larger than the above values. Lower temperature extrapolation of the Arrhenian relation for D(Mg) is in good agreement with the Mg tracer diffusion data (D * Mg) of Chakraborty and Rubie (1996) and Cygan and Lasaga (1985) at 1 bar, 750–900 °C, when all data are normalized to the same pressure and to f O2 defined by graphite in the system C-O. The D * Mg data of Schwandt et al. (1995), on the other hand, are lower by more than an order of magnitude than the low temperature extrapolation of the present data, when all data are normalized to the same pressure and to f O2 defined by the graphite buffer. Comparison of the D(Fe), D(Mg) and D(Mn) data in the pyrope-almandine diffusion couple with those in the spessartine-almandine diffusion couple of Chakraborty and Ganguly (1992) shows that the self diffusion of Fe and Mn are significantly enhanced with the increase in Mn/Mg ratio; the enhancement effect on D(Mg) is, however, relatively small. Proper application of the self diffusion data to calculate interdiffusion coefficient or D matrix elements for the purpose of modeling of diffusion processes in natural garnets must take into account these compositional effects on D(I) along with the effects of thermodynamic nonideality, f O2, and pressure. Received: 8 May 1997 / Accepted: 2 October 1997  相似文献   

9.
New geochemical data of the crater-facies Tokapal kimberlite system sandwiched between the lower and upper stratigraphic horizons of the Mesoproterozoic lndravati Basin a：：e presented. The kimberlite has been subjected to extensive and pervasive low-temperature alteration. Spinel is the only primary phase identifiable, while olivine macrocrysts and juvenile lapilli are largely pseudomorphed （talc-serpentine- carbonate alteration）. However, with the exception of the alkalies, major element oxides display systematic fractionation trends; likewise, HFSE patterns are well correlated and allow petrogenetic interpretation. Various crustal contamination indices such as （SiO2 ＋ AI：：O3 ~ Na20）]（MgO ~ K20） and Si] Mg are close to those of uncontaminated kimberlites. Similar La]Yb （＇79-109） of the Tokapal samples with those from the kimberlites of Wajrakarur （73-145） and Narayanpet （72-156）, Eastern Dharwar craton, southern India implies a similarity in their genesis. In the discriminant plots involving HFSE the Tokapal samples display strong affinities to Group 1I kimberlites from southern Africa and central India as well as to ＇transitional kimberlites＇ from the Eastern Dharwar craton, southern India, and those from the Prieska and Kuruman provinces of southern Africa. There is a striking ~;imilarity in the depleted-mantle （TOM） Nd model ages of the Tokapal kimberlite system, Bastar craton, th~ kimberlites from NKF and WKE Eastern Dharwar craton, and the Majhgawan diatreme, Bundelkhand craton, with the emplacement age of some of the lamproites from within and around the Palaeo~Mesoproterozoic Cuddapah basin, southern India. These similar ages imply a major tectonomagmatic event, possibly related to the break- up of the supercontinent of Columbia, at 1.3-1.5 Ga across the l：hree cratons. The ＇transitional＇ geochemical features displayed by many of the Mesoproterozoic po~：assic-ultrapotassic rocks, across these Indian cratons are inferred to be memories of the metasomatisi  相似文献   

10.
Whole-rock Sm-Nd isochron ages are reported for two stratiform meta-anorthosite complexes emplaced into the Archean supracrustal-gneiss association in the amphibolite facies terrain around Holenarsipur, in the Dharwar craton, South India. While these metaperidotite-pyroxenite-gabbro-anorthosite complexes are petrologically and geochemically similar, they differ in the intensity of tectonic fabric developed during the late Archean (c. 2.5 Ga) deformation. They also differ in their whole-rock Sm-Nd isochron ages and initial Nd isotopic compositions: 3.285 ± 0.17 Ga,ɛNd0.82 ± 0.78 for the Honnavalli metaanorthosite complex from a supracrustal enclave in the low-strain zone, and 2.495 ± 0.033 Ga, ɛNd = -2.2 ± 0.3 for the Dodkadnur meta-anorthosites from the high-strain southern arm of the Holenarsipur Supracrustal Belt (HSB). We interpret these results as indicating that the magmatic protoliths of both meta-anorthosite complexes were derived from a marginally depleted mantle at c. 3.29 Ga but only the Dodkadnur rocks were isotopically reequilibrated on a cm-scale about 800 Ma later presumably due to the development of strong penetrative fabrics in them during Late Archean thermotectonic event around 2.5 Ga. Our results set a younger age limit at c. 3.29 Ga for the supracrustal rocks of the HSB in the Dharwar craton.  相似文献   

11.
Diffusion coefficients of Cr and Al in chromite spinel have been determined at pressures ranging from 3 to 7 GPa and temperatures ranging from 1,400 to 1,700°C by using the diffusion couple of natural single crystals of MgAl2O4 spinel and chromite. The interdiffusion coefficient of Cr–Al as a function of Cr# (=Cr/(Cr + Al)) was determined as D Cr–Al = D 0 exp {−(Q′ + PV*)/RT}, where D 0 = exp{(10.3 ± 0.08) × Cr#0.54±0.02} + (1170 ± 31.2) cm2/s, Q′ = 520 ± 81 kJ/mol at 3 GPa, and V* = 1.36 ± 0.25 cm3/mol at 1,600°C, which is applicable up to Cr# = 0.8. The estimation of the self-diffusion coefficients of Cr and Al from Cr–Al interdiffusion shows that the diffusivity of Cr is more than one order of magnitude smaller than that of Al. These results are in agreement with patterns of multipolar Cr–Al zoning observed in natural chromite spinel samples deformed by diffusion creep.  相似文献   

12.
Stromatolites associated with cherty dolomites of the Vanivilaspura Formation of the Archaean Dharwar Supergroup show a morphology indicative of the deposition of the latter in a intertidal to subtidal environment. The cherts are moderately high in their Al/Al + Fe ratios but depleted in Fe2C3 and also most trace elements. Unlike most other Archaean cherts, the Vanivilaspur cherts exhibit significant negative Ce anomaly, which is interpreted to have resulted from contemporary manganese deposition. The Rb/Sr ratios in the cherts show a sufficient spread to define a linear correlation line in the Rb-Sr evolution diagram corresponding to an age of 2512 ± 159 Ma and initial Sr ratio of 0.7128 ± 0.0012 (2σ). While this age is strikingly close to that of regional metamorphism in the Dharwar craton, the initial ratio is distinctly higher than that of the associated volcanics. Acid leaching experiments on the cherts suggest that they may have been isotopically equilibrated on a mm to cm scale about 500 Ma later than the time of regional metamorphism.  相似文献   

13.
Gulf of Suez consists mainly of three tectonic provinces that are separated by two accommodation zones. The southern edge of the gulf is bordered by N–S faults which mark the transition between the shallow water, Suez Basin and the deep northern Red Sea Basin. The sensitivity of coda Q measurements with respect to geological differences in the crust is demonstrated in three regions with a large variety of tectonic and geologic properties. The estimation of coda Q (Qc) is performed for 370 local earthquakes recorded at 12 digital seismic stations during the period from 2000 to 2007. The magnitudes of the earthquakes between 1.5 and ~4.5 have been used at central frequencies 1.5, 3, 6, 9, 12, 15, 18, and 24 Hz through three lapse time windows 10, 20, 30 s starting at once and twice the time of the primary S wave from the origin time. The time domain coda decay method of the single isotropic scattering model is employed to calculate frequency-dependent values of coda Q. The Qc values are frequency dependent in the range 1–25 Hz, and are approximated by a least squares fit to the power law [Qc(f) = Qo(f/fo)η]. The observed coda Q indicates that the area is seismically and tectonically active with high heterogeneities. The variation of the quality factor Qc has been estimated at different regions to observe the effect of different tectonic province. The average frequency-dependent estimated relations of Qc vary from 65f1.1 to 96f0.9 at 10 to 30 s window length, respectively. The decreasing value of the frequency parameter with increasing lapse time shows that the crust acquires homogeneity with depth. The variation of Qc with the variations in the geologic and tectonic properties of the crust was investigated. The frequency exponent η might be larger in active tectonic areas and smaller in more stable regions. In the northern region of the Gulf of Suez, the obtained value of η?=?0.8?±?0.011, which might indicate a low level of tectonic activity compared with η?=?1.1?±?0.005 and 1.3?±?0.009 for the central and southern regions of the gulf.  相似文献   

14.
The heat capacity of eskolaite Cr2O3(c) was determined by adiabatic vacuum calorimetry at 11.99–355.83 K and by differential calorimetry at 320–480 K. Experimental data of the authors and data compiled from the literature were applied to calculate the heat capacity, entropy, and the enthalpy change of Cr2O3 within the temperature range of 0–1800 K. These functions have the following values at 298.15 K: C p 0 (298.15) = 121.5 ± 0.2 J K−1mol−1, S 0(298.15) = 80.95 ± 0.14 J K−1mol−1, and H 0(298.15)-H 0(0) = 15.30±0.02 kJ mol−1. Data were obtained on the transitions from the antiferromagnetic to paramagnetic states at 228–457 K; it was determined that this transition has the following parameters: Neel temperature T N = 307 K, Δ tr S = 6.11 ± 0.12 J K−1mol−1 and δ tr H = 1.87 ± 0.04 kJ mol−1.  相似文献   

15.
The Peninsular Gneiss around Gorur in the Dharwar craton, reported to be one of the oldest gneisses, shows nealy E-W striking gneissosity parallel to the axial planes of a set of isoclinal folds (DhF1). These have been over printed by near-coaxial open folding (DhF12) and non-coaxial upright folding on almost N-S trend (DhF2). This structural sequence is remarkably similar to that in the Holenarasipur schist belt bordering the gneisses as well as in the surpracrustal enclaves within the gneisses, suggesting that the Peninsular Gneiss has evolved by migmatization synkinematically with DhF1 deformation. The Gorur gneisses are high silica, low alumina trondhjemites enriched in REE (up to 100 times chondrite), with less fractionated REE patterns (CeN/YbN < 7) and consistently negative Eu anomalies (Eu/Eu* = 0.5 to 0.7). A whole rock Rb-Sr isochron of eight trondhjemitic gneisses sampled from two adjacent quarries yields an age of 3204 ± 30 Ma with Sr i of 0.7011 ± 6 (2σ). These are marginally different from the results of Beckinsale and coworkers (3315 ± 54 Ma, Sr i = 0.7006 ± 3) based on a much wider sampling. Our results indicate that the precursors of Gorur gneisses had a short crustal residence history of less than a 100 Ma.  相似文献   

16.
Summary Mineral chemistry and petrological data of chromites from chromitite bands in the N–S trending schist belt of Nuggihalli (southern Karnataka, India), belonging to the Dharwar craton of South India, are presented in this paper. Crystal chemical data indicate a komatiitic affinity of the chromitite. P–T calculations of the chromite-hosting peridotites yielded a pressure range of 13 to 28 kbar and temperatures ranging from 775 to 1080 °C; the oxygen fugacity (log fO2) varies from +0.5 to +1.6 above the QFM buffer. The P, T and fO2 data indicate that Nuggihalli chromitites crystallized in an environment akin to the upper mantle. The studied samples also show partial resetting; the lower temperatures ranging from 515 to 680 °C are ascribed to subsequent metamorphism of the area.  相似文献   

17.
The hydrolysis of the Pd2+ ion in HClO4 solutions was examined at 25–70°C, and the thermodynamic constants of equilibrium K (1)0 and K (2)0were determined for the reactions Pd2+ + H2O = PdOH+ + H+ and Pd2+ + 2H2O = Pd(OH)20 + 2H+, respectively. The values of log K (1)0 = −1.66 ± 0.5 (25°C) and −0.65 ± 0.25 (50°C) and log K (2)0 = −4.34 ± 0.3 (25°C) and −3.80 ± 0.3 (50°C) were derived using the solubility technique at 0.95 confidence level. The values of log K (1)0 = −1.9 ± 0.6 (25°C), −1.0 ± 0.4 (50°C), and −0.5 ± 0.3 (70°C) were obtained by spectrophotometric techniques. The palladium ion is significantly hydrolyzed at elevated temperatures (50–70°C) even in strongly acidic solutions (pH 1–1.5), and its hydrolysis is enhanced with increasing temperature.  相似文献   

18.
Based on the expert review of literature data on the thermodynamic properties of species in the Cl-Pd system, stepwise and overall stability constants are recommended for species of the composition [PdCl n ]2 ? n , and the standard electrode potential of the half-cell PdCl 4 2? /Pd(c) is evaluated at E 298,15° = 0.646 ± 0.007 V, which corresponds to Δ f G 298.15° = ?400.4 ± 1.4 kJ/mol for the ion PdCl 4 2? (aq). Derived from calorimetric data, Δ f H 298.15° PdCl 4 2? (aq) = ?524.6 ± 1.6 kJ/mol and Δ f H 298.15° Pd2+(aq) = 189.7 ± 2.6 kJ/mol. The assumed values of the overall stability constant of the PdCl 4 2? ion and the standard electrode potential of the PdCl 4 2? /Pd(c) half-cell correspond to Δ f G 298.15° = 190.1 ± 1.4 kJ/mol and S 298.15° = ?94.2 ± 10 J/(mol K) for the Pd2+(aq) ion.  相似文献   

19.
The thermochemical study of a natural basic copper phosphate, pseudomalachite Cu5(PO4)2(OH)4 (Virneberg deposit, Germany), was carried out using high-temperature melt solution calorimetry method with a Tian–Calvet microcalorimeter. The enthalpy of formation of the mineral from elements was obtained to be Δ f Hel(298.15 K) =–3214 ± 13 kJ/mol. The value of the Gibbs energy of pseudomalachite formation calculated using literature data on its standard entropy is Δ f Hel°(298.15 K) =–2812 ± 13 kJ/mol.  相似文献   

20.
A natural Ca-poor pigeonite (Wo6En76Fs18) from the ureilite meteorite sample PCA82506-3, free of exsolved augite, was studied by in situ high-temperature single-crystal X-ray diffraction. The sample, monoclinic P21/c, was annealed up to 1,093°C to induce a phase transition from P21/c to C2/c symmetry. The variation with increasing temperature of the lattice parameters and of the intensity of the b-type reflections (h + k = 2n + 1, present only in the P21/c phase) showed a displacive phase transition P21/c to C2/c at a transition temperature T Tr = 944°C, first order in character. The Fe–Mg exchange kinetics was studied by ex situ single-crystal X-ray diffraction in a range of temperatures between the closure temperature of the Fe–Mg exchange reaction and the transition temperature. Isothermal disordering annealing experiments, using the IW buffer, were performed on three crystals at 790, 840 and 865°C. Linear regression of ln k D versus 1/T yielded the following equation: ln k\textD = - 3717( ±416)/T(K) + 1.290( ±0.378);    (R2 = 0.988) \ln \,k_{\text{D}} = - 3717( \pm 416)/T(K) + 1.290( \pm 0.378);\quad (R^{2} = 0.988) . The closure temperature (T c) calculated using this equation was ∼740(±30)°C. Analysis of the kinetic data carried out taking into account the e.s.d.'s of the atomic fractions used to define the Fe–Mg degree of order, performed according to Mueller’s model, allowed us to retrieve the disordering rate constants C 0 K dis+ for all three temperatures yielding the following Arrhenius relation: ln( C0 K\textdis + ) = ln K0 - Q/(RT) = 20.99( ±3.74) - 26406( ±4165)/T(K);    (R2 = 0.988) \ln \left( {C_{0} K_{\text{dis}}^{ + } } \right) = \ln \,K_{0} - Q/(RT) = 20.99( \pm 3.74) - 26406( \pm 4165)/T(K);\quad (R^{2} = 0.988) . An activation energy of 52.5(±4) kcal/mol for the Fe–Mg exchange process was obtained. The above relation was used to calculate the following Arrhenius relation modified as a function of X Fe (in the range of X Fe = 0.20–0.50): ln( C0 K\textdis + ) = (21.185 - 1.47X\textFe ) - \frac(27267 - 4170X\textFe )T(K) \ln \left( {C_{0} K_{\text{dis}}^{ + } } \right) = (21.185 - 1.47X_{\text{Fe}} ) - {\frac{{(27267 - 4170X_{\text{Fe}} )}}{T(K)}} . The cooling time constant, η = 6 × 10−1 K−1 year−1 calculated on the PCA82506-3 sample, provided a cooling rate of the order of 1°C/min consistent with the extremely fast late cooling history of the ureilite parent body after impact excavation.  相似文献   

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