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1.
The composition and amount of colloidal and suspended participate matter transported during a small flood event in Magela Creek in tropical northern Australia was investigated. The flood studied constituted approximately 3 % of the total annual flow, most (90%) of which occurred between mid-January and mid-February of the study year. Three fractions were separated from water samples using a sequential method involving a continuous flow centrifuge to separate suspended particulate matter (SPM; nominally > 1 μm) followed by hollow fibre filtration, first using a 0.1 μm filter to separate course colloidal matter (CCM; nominal size 1–0.1 μm) and then a 0–015 μm filter to separate fine colloidal matter (FCM; nominal size 0.1–0.015 μm). The SPM was predominantly inorganic (organic matter 21 %), whereas the colloidal fractions were dominantly organic matter (CCM 60%; FCM 83%). Analysis of individual particles using electron microprobe and automated image analysis indicated that the mineral fractions in both the SPM and CCM were dominated by iron-enriched aluminosilicates (including kaolinite) (72–82%) and quartz (9–10%), indicative of a highly weathered and extensively laterized catchment. Surprisingly there was very little difference in the composition of the SPM or CCM fractions during the flood event studied, which may indicate either that sediment availability was restricted following the major run-off events in January and February, or that all the sediment sources within the catchment are geochemically similar. Approximately the same amounts of particulate (20 tonne), colloidal (21 tonne) and dissolved material (17 tonne) were transported during the 25 hour period of the main flood peak; over 90% of the colloidal matter was 0.1–1.0 μm in size. These data suggest that previous estimates of the amounts of particulate (and colloidal) matter transported by Magela Creek, which were based on suspended solids measurements, may have underestimated the particulate matter load by as much as 50%. It is possible that the relatively high proportion of colloidal matter is unique to Magela Creek because coagulation and aggregation of colloidal matter to particulate matter is slow due to the very low concentations of calcium and magnesium in these waters. However, if the result is more widespread, there are important implications for the global estimates of fluvially transported particulate and dissolved materials as many of the previous studies may have underestimated the particulate load and overestimated the dissolved load.  相似文献   

2.
《Marine pollution bulletin》2014,78(1-2):146-152
The interaction of dispersed oil droplets with large diameter suspended particulate materials (SPM) has been little studied. In the current study, particle size, oil characteristics and chemical dispersant significantly influence the adsorption of oil droplets to SPM in seawater. Sediments with a smaller particulate size (clay) approaching that of the oil droplets (2–20 μm) adsorbed more oil per gram than sediments with large particle size (sand). Heavier, more polar oils with a high asphaltene content adsorbed more efficiently to SPM than lighter, less polar oils. A decrease in the smaller, more water soluble oil components in the sediment adsorbed oil was observed for all oil types. Addition of chemical dispersant decreased the adsorption of oil droplets to suspended carbonate sand in an exponential-like manner. No change in the relative distribution of compounds adsorbed to the sediment was observed, indicating dispersants do not alter the dissolution of compounds from oil droplets.  相似文献   

3.
Multi-sensor tripod measurements in the high-turbidity area of the Belgian nearshore zone (southern North Sea) allowed investigating storm effects on near bed suspended particulate matter (SPM) concentrations. The data have shown that during or after a storm the SPM concentration increases significantly and that high concentrated mud suspensions (HCMS) are formed. Under these conditions, about 3 times more mass of SPM was observed in the water column, as compared to calm weather conditions. The following different sources of fine-grained sediments, influencing the SPM concentration signal, have been investigated: wind direction and the advection of water masses; the previous history and occurrence of fluffy layers; freshly deposited mud near the disposal grounds of dredged material, navigation channels and adjacent areas; and the erosion of medium-consolidated mud of Holocene age.  相似文献   

4.
During four surveys at spring and neap tides in July and November 2005, continuous observations were conducted at four stations adjacent to the Changjiang (Yangtze River) mouth. The observation times lasted for 26 h that covered two consecutive semidiurnal cycles. Resuspension events and subsequently enhancements of suspended particulate matter (SPM) were commonly observed within a tidal cycle. Although nutrients (SiO32−, NO3−, and PO43−) were primarily governed by salinity, their statistically significant correlations with SPM could always be extracted after partial correlation analysis. Three parameter (salinity, SPM, nutrients) regressions generally produced better results of simulating nutrient concentrations than two parameter (salinity and nutrients) regressions, although compared to the latter, the former R2 values were elevated by no more than 13%. The partial correlation between SPM and a specific nutrient could be either positive or negative in different surveys, suggesting SPM influenced the nutrients in different ways under various conditions. The minor (albeit statistically significant) impacts of highly dynamic SPM on nutrients might be ascribed to the short duration time of resuspension events and estuarine mixing process, together with the complex nature of circulation in the Changjiang plume seawater.  相似文献   

5.
Seasonal observations on the nature and concentration of suspended particulate matter (SPM) are presented for a cross-section of the English Channel, between the Isle of Wight (UK) and Cotentin peninsula (France) i.e. the western boundary of the eastern English Channel. The highest concentrations of suspended material are found adjacent to the English coastline, whereas the offshore waters are associated with low concentrations. Seasonal variations in the concentration and nature of suspended material are identified, with highest concentrations in winter. At this time, the suspended particles are characterised generally by peaked grain size spectra and an enrichment in coarse silt particles; in summer, the distributions are generally flat. The diatom communities found within the suspended matter indicate that material resuspended in the coastal zone and the estuarine environments is transported offshore. SPM fluxes (based upon the observed SPM concentrations and the output from a 2-D hydrodynamic model) from the western Channel through the Wight–Cotentin Section, ranged between 2 and 71×106 t a−1 with a mean of around 20×106 t a−1 over the period of the observations (1994–1995). These fluxes are comparable to the order of magnitude and mean value reported as output through the Dover Strait. Therefore, it is possible that the eastern English Channel may be characterised as an area of fine-grained sediment ‘bypass'. This interpretation is corroborated by: (a) the absence of fine-grained sediment deposits over the area; and (b) correlation between the potential resuspension time of the fine particles and the seabed sediment distribution.  相似文献   

6.
Measurements are presented of the properties of suspended particulate matter (SPM) in the estuarine turbidity maximum (ETM) of the upper Humber and Ouse estuaries during transient, relatively low freshwater inflow conditions of September 1995. Very high concentrations of near-bed SPM (more than 100 g l−1) were observed in the low-salinity (less than 1), upper reaches. SPM within the ETM consisted largely of fine sediment (silt and clay) that existed as microfloc and macrofloc aggregates and individual particles. Primary sediment particles were very fine grained, and typically, about 20–30% was clay-sized at high water. The clay mineralogy was dominated by chlorite and illite. There was a pronounced increase in particle size in the tidal river, up-estuary of the ETM. The mean specific surface area (SSA) of near-bed SPM within the ETM was 22 m2 g−1 on a spring tide and 24 m2 g−1 on a neap tide. A tidal cycle of measurements within a near-bed, high concentration SPM layer during a very small neap tide gave a mean SSA of 26 m2 g−1. The percentage of silt and clay in surficial bed sediments along the main channel of the estuary varied strongly. The relatively low silt and clay percentage of surficial bed sediments (about 10–35%) within the ETM’s region of highest near-bed SPM concentrations and their low SSA values were in marked contrast to the overlying SPM. The loss on ignition (LOI) of near-bed SPM in the turbid reaches of the estuary was about 10%, compared with about 12% for surface SPM and more than 40% in the very low turbidity waters up-estuary of the ETM. Settling velocities of Humber–Ouse SPM, sampled in situ and measured using a settling column, maximized at 1.5 mm s−1 and exhibited hindered settling at higher SPM concentrations.  相似文献   

7.
There is increasing interest in tidal wetlands as mechanisms for sustainable and long-term coastal defence. The complexities of the interaction between the deposition of suspended particulate matter (SPM) and submerged vegetation, however, is to a large extent poorly understood. Consequently, accurate parameterisation of cohesive sediment settling fluxes in these environments is a crucial requirement for the development of high-resolution numerical models of wetland morphodynamics. A novel laboratory experiment is described in which the turbulent flow structure within a canopy of the halophytic macrophyte Spartina anglica is examined, and floc characteristics quantified using a unique floc camera configuration able to measure directly the full spectral floc size (D) and settling velocity (Ws). We provide the first quantitative observations of floc characteristics from shallow (h<0.5 m), vegetated flows and investigate the potential influence that variations in vegetative density may have on flocculation, and thus depositional fluxes, in comparison to unvegetated flows.  相似文献   

8.
Large rivers have been previously shown to be vertically heterogeneous in terms of suspended particulate matter (SPM) concentration, as a result of sorting of suspended solids. Therefore, the spatial distribution of suspended sediments within the river section has to be known to assess the riverine sedimentary flux. Numerous studies have focused on the vertical distribution of SPM in a river channel from a theoretical or experimental perspective, but only a few were conducted so far on very large rivers. Moreover, a technique for the prediction of depth‐integrated suspended sediment fluxes in very large rivers based on sediment transport dynamics has not yet been proposed. We sampled river water along depth following several vertical profiles, at four locations on the Amazon River and its main tributaries and at two distinct water stages. Depending on the vertical profile, a one‐ to fivefold increase in SPM concentration is observed from river channel surface to bottom, which has a significant impact on the ‘depth‐averaged’ SPM concentration. For each cross section, a so‐called Rouse profile quantitatively accounts for the trend of SPM concentration increase with depth, and a representative Rouse number can be measured for each cross section. However, the prediction of this Rouse number would require the knowledge of the settling velocity of particles, which is dependent on the state of aggregation affecting particles within the river. We demonstrate that in the Amazon River, particle aggregation significantly influences the Rouse number and renders its determination impossible from grain‐size distribution data obtained in the lab. However, in each cross section, the Rouse profile obtained from the fit of the data can serve as a basis to model, at first order, the SPM concentration at any position in the river cross section. This approach, combined with acoustic Doppler current profiler (ADCP) water velocity transects, allows us to accurately estimate the depth‐integrated instantaneous sediment flux. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

9.
234Th:238U disequilibria have been used extensively as tracers of particle dynamics in marine environments. 234Th (t1/2=24.1 days) can be used as “proxy” for particle reactive pollutants, due to their similar rapid rate of scavenging onto particles and subsequent removal from the water column, to the sediments. Radioactive disequilibrium can be exploited to determine the rates and time-scales of processes occurring over days to months; in this instance the residence times of dissolved and particulate species with the benthic nepheloid layer (BNL).Three sampling cruises were undertaken in Thermaikos Gulf (NW Aegean Sea) during contrasting periods, to examine the impact of natural and anthropogenic activity on sediment resuspension. September and October 2001 represented background and trawling periods, respectively; January 2002 represented a mixed period, of trawling and storms.Dissolved 234Th is scavenged actively at the BNL, in the presence of suspended particulate material (SPM), with a mean residence time of 16 days. There is a weak inverse correlation between dissolved 234Th residence time and SPM concentration in the BNL, with the shortest residence times occurring during October 2001. No relationship was observed between particulate 234Th activities and SPM concentrations, indicating that particles are rapidly removed from the system, either by sinking or advection. The mean particulate 234Th residence time is 5 days.  相似文献   

10.
Suspended particulate matter (SPM) and colloidal matter (COM) in annual dry and wet deposition samples in urban Guangzhou were for the first time collected, and their trace metals were investigated by using inductively coupled plasma mass spectrometry (ICP-MS). The deposition flux of SPM and of metal elements varied largely among the investigated seasons, and reached the maximum in spring. The correlation analysis indicated that significant correlations existed among some of the metal elements in the deposition samples. The enrichment factors (EF) of metals in COM in the deposition ranging from 79.66 to 130,000 were much higher than those of SPM ranging from 1.65 to 286.48, indicating the important role of COM. The factor analysis showed that emissions from street dust, non-ferrous metal production, and heavy fuel oil were major sources of the trace metals. Positive matrix factorization (PMF) model was used to quantitatively estimate anthropogenic source.  相似文献   

11.
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12.
The chemical composition of suspended particulate material (SPM) in the Tamar Estuary and its response to tidal sediment resuspension at the turbidity maximum have been investigated. The results discriminate four regions: (1) the outer estuary where spatial changes in the composition of SPM reflect the dispersal of estuarine particles modified by in situ generation of organic particles, (2) the middle estuary where the composition of SPM is mainly determined by hydrodynamic mixing although there is some evidence of in situ chemical reactivity, (3) the upper estuary where sharply distinct and temporally variable SPM compositions are centred at the turbidity maximum; these are largely the result of particle-selective accumulation, sedimentation and resuspension processes rather than of local particle-water chemical exchanges, and (4) the fluvial estuary where the SPM composition reflects the influx of riverine particles.  相似文献   

13.
The impact of continuous disposal of fine-grained sediments from maintenance dredging works on the suspended particulate matter concentration in a shallow nearshore turbidity maximum was investigated during dredging experiment (port of Zeebrugge, southern North Sea). Before, during and after the experiment monitoring of SPM concentration using OBS and ADV altimetry was carried out at a location 5 km west of the disposal site. A statistical analysis, based on the concept of populations and sub-sampling, was applied to evaluate the effect. The data revealed that the SPM concentration near the bed was on average more than two times higher during the dredging experiment. The disposed material was mainly transported in the benthic layer and resulted in a long-term increase of SPM concentration and formation of fluid mud layers. The study shows that SPM concentration can be used as an indicator of environmental changes if representative time series are available.  相似文献   

14.
Polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) were measured in the dissolved and suspended particulate phase in the sea-surface microlayer (SML) and subsurface water (SSW) collected from Hong Kong's coastal environment. The concentration ranges (pg/L) for summation sigmaHCHs, summation sigmaDDTs and summation sigmaPCBs in the SSW dissolved phase (DP i.e. sum of truly dissolved and colloidal phase) were 409-940 (mean 602), 774-5583 (mean 1908) and 266-433 (mean 278), respectively. The concentration ranges (pg/L) for summation sigmaHCHs, summation sigmaDDTs and summation sigmaPCBs in SSW suspended particulate matter (SPM) were <5-85 (mean 59), 358-1369 (mean 787) and 85.6-273 (mean 172), respectively. The enrichment factor of PCBs and OCPs in the SML varied between 1.1 and 4.5 for the DP, and 0.4-8.2 for the SPM. The distribution of contaminants between DP and SPM in both the SML and SSW indicates that particulate matter plays an important role in the distribution and fate of DDTs and PCBs, but not for HCH isomers. The Pearl River Estuary is likely to be a major source of contaminants transported to Hong Kong.  相似文献   

15.
Aggregation processes of fine sediments have rarely been integrated in numerical simulations of cohesive sediment transport in riverine systems. These processes, however, can significantly alter the hydrodynamic characteristics of suspended particulate matter (SPM), modifying the particle settling velocity, which is one of the most important parameters in modelling suspended sediment dynamics. The present paper presents data from field measurements and an approach to integrate particle aggregation in a hydrodynamic sediment transport model. The aggregation term used represents the interaction of multiple sediment classes (fractions) with corresponding multiple deposition behaviour. The k–ε–turbulence model was used to calculate the coefficient of vertical turbulent mixing needed for the two‐dimensional vertical‐plane simulations. The model has been applied to transport and deposition of tracer particles and natural SPM in a lake‐outlet lowland river (Spree River, Germany). The results of simulations were evaluated by comparison with field data obtained for two levels of river discharge. Experimental data for both discharge levels showed that under the prevailing uniform hydraulic conditions along the river reach, the settling velocity distribution did not change significantly downstream, whereas the amount of SPM declined. It was also shown that higher flow velocities (higher fluid shear) resulted in higher proportions of fast settling SPM fractions. We conclude that in accordance with the respective prevailing turbulence structures, typical aggregation mechanisms occur that continuously generate similar distribution patterns, including particles that settle toward the river bed and thus mainly contribute to the observed decline in the total SPM concentration. In order to determine time‐scales of aggregation and related mass fluxes between the settling velocity fractions, results of model simulations were fitted to experimental data for total SPM concentration and of settling velocity frequency distributions. The comparison with simulations for the case of non‐interacting fractions clearly demonstrated the practical significance of particle interaction for a more realistic modelling of cohesive sediment and contaminant transport. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

16.
The distribution of organic carbon (OC) and of some metals (Cu, Mn) amongst the particulate (>0·2 μm), colloidal (10 kDa–0·2 μm) and the truly dissolved (<10 kDa) fractions of the River Marne was investigated during the phytoplankton spring bloom. A tangential ultrafiltration (UF) device was utilized to separate the colloidal fraction. On average, 22% of the OC, 31% of the Cu and 53% of the Mn, usually assigned to the so‐called dissolved fraction, were found in the colloidal fraction. The colloidal fraction exhibited a behaviour different from that of the particulate and truly dissolved fractions. Autochthonous production led to enrichment in the colloidal and particulate OC pools: up to 47% of the total dissolved OC was in the colloidal fraction. An increase in the colloidal metal fraction, concomitant with a fall in the truly dissolved fraction, coincided with peaks in phytoplankton during the bloom. These phenomena might be related either to an increase in pH associated with photosynthetic activity, resulting in the precipitation of truly dissolved forms into the colloidal fraction, or to scavenging of the truly dissolved metals by the algal species of colloidal size. The interaction between the colloidal and the truly dissolved phases was very important. The partition coefficients of the Cu and Mn between the colloidal and truly dissolved fractions were higher than between the particulate and the truly dissolved fractions. This pattern is consistent with a greater specific surface area of colloids than macroparticles. Consequently, the adsorption and complexation capacities are enhanced in the colloidal fraction of the particulate matter. The extraction of hydrophobic complexes with Cu using C18 Sep‐Pak columns, showed that the Cu occurring in colloidal, total dissolved or truly dissolved forms was significantly complexed by the organic matter. The truly dissolved fraction might be complexed up to 100% during a phytoplankton bloom. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

17.
J. Pfannkuche  A. Schmidt 《水文研究》2003,17(10):1951-1963
Measurements of suspended particulate matter concentration and turbidity point towards the possibility of a site‐specific algorithm (SPM), relating SPM to nephelometric turbidity units (NTU). In this paper regression models are presented that account for changes in the relationship of SPM and NTU as a result of changes in particle properties. The models have been developed by the use of daily measurements of SPM concentration and a continuous record of turbidity for the period from June 1996 to February 2001 in the River Elbe, a major river in the eastern part of Germany. The effect of changes in the particle properties with increasing water discharge was taken into account by varying the slope of a linear regression equation according to a logistic function. Water discharge, Q, was defined to be the only variable of this function—as an adequate substitute of the parameter bottom shear stress, which cannot be measured directly. Measurements of flow velocity in the River Elbe show that bottom shear stress is related almost linearly to water discharge up to bankful discharges. Regression models with slopes varying continuously with hydraulic parameters may account for the effects resulting from changes of particle characteristics and thus may have some advantages compared with models with a constant slope or models calibrated for different seasons. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

18.
The effect of hydro-meteorological forcings (tidal and wind-induced flows) on the transport of suspended particulate matter (SPM), on the formation of high-concentrated mud suspensions and on the occurrence of sand–mud suspensions has been studied using long-term multi-parametric observations. Data have been collected in a coastal turbidity maximum area (southern North Sea) where a mixture of sandy and muddy sediments prevails. Data have been classified according to variations in subtidal alongshore currents, with the direction of subtidal flow depending on wind direction. This influences the position of the turbidity maximum; as such also the origin of SPM. Winds blowing from the NE will increase SPM concentration, whilst SW winds will induce a decrease. The latter is related to advection of less turbid English Channel water, inducing a shift of the turbidity maximum towards the NE and the Westerschelde estuary. Under these conditions, marine mud will be imported and buffered in the estuary. Under persistent NE winds, high-concentrated mud suspensions are formed and remain present during several tidal cycles. Data show that SPM consists of a mixture of flocs and locally eroded sand grains during high currents. This has implications towards used instrumentation: SPM concentration estimates from optical backscatter sensors will only be reliable when SPM consists of cohesive sediments only; with mixtures of cohesive and non-cohesive sediments, a combination of both optical and acoustic sensors are needed to get an accurate estimate of the total SPM concentration.  相似文献   

19.
Suspended particulate matter (SPM) fluxes and dynamics are investigated in the East Frisian Wadden Sea using a coupled modeling system based on a hydrodynamical model [the General Estuarine Transport Model (GETM)], a third-generation wave model [Simulating Waves Nearshore (SWAN)], and a SPM module attached to GETM. Sedimentological observations document that, over longer time periods, finer sediment fractions disappear from the Wadden Sea Region. In order to understand this phenomenon, a series of numerical scenarios were formulated to discriminate possible influences such as tidal currents, wind-enhanced currents, and wind-generated surface waves. Starting with a simple tidal forcing, the considered scenarios are designed to increase the realism step by step to include moderate and strong winds and waves and, finally, to encompass the full effects of one of the strongest storm surges affecting the region in the last hundred years (Storm Britta in November 2006). The results presented here indicate that moderate weather conditions with wind speeds up to 7.5 m/s and small waves lead to a net import of SPM into the East Frisian Wadden Sea. Waves play only a negligible role during these conditions. However, for stronger wind conditions with speeds above 13 m/s, wind-generated surface waves have a significant impact on SPM dynamics. Under storm conditions, the numerical results demonstrate that sediments are eroded in front of the barrier islands by enhanced wave action and are transported into the back-barrier basins by the currents. Furthermore, sediment erosion due to waves is significantly enhanced on the tidal flats. Finally, fine sediments are flushed out of the tidal basins due to the combined effect of strong erosion by wind-generated waves and a longer residence time in the water column because of their smaller settling velocities compared to coarser sediments.
Karsten A. LettmannEmail:
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20.
Data on riverine fluxes are essential for calculating element cycles (carbon, nutrients, pollutants) and erosion rates from regional to global scales. At most water‐quality stations throughout the world, riverine fluxes are calculated from continuous flow data (q) and discrete concentration data (C), the latter being the main cause of sometimes large uncertainties. This article offers a comprehensive approach for predicting the magnitude of these uncertainties for water‐quality stations in medium to large basins (drainage basin area > 1000 km²) based on the commonly used discharge‐weighted method. Uncertainty levels – biases and imprecisions – for sampling intervals of 3 to 60 days are correlated first through a nomograph with a flux variability indicator, the quantity of riverine material discharged in 2% of time (M2%). In turn, M2% is estimated from the combination of a hydrological reactivity index, W2% (the cumulative flow volume discharged during the upper 2% of highest daily flow) and the truncated b50sup exponent, quantifying the concentration versus discharge relationship for the upper half of flow values (C = a q b50sup, for q > q50, where q50 is the median flow): M2% = W2% + 27.6b50sup. W2% can be calculated from continuous flow measurements, and the b50sup indicator can be calculated from infrequent sampling, which makes it possible to predict a priori the level of uncertainty at any station, for any type of riverine material either concentrated (b50sup > 0) or diluted (b50sup > 0) with flow. A large data base of daily surveys, 125 station variables of suspended particulate matter (SPM), total dissolved solids (TDS) and dissolved and particulate nutrients, was used to determine uncertainties from simulated discrete surveys and to establish relationships between indicators. Results show, for example, that for the same relatively reactive basin (W2% > 25%), calculated fluxes from monthly sampling would yield uncertainties approaching ±100% for SPM (b50sup > 1.4) fluxes and ±10% for TDS (b50sup = ?0.2). The application to the nitrate survey of the river Seine shows significant trends for the 1972–2009 records. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

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