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1.
Review Section     
ABSTRACT

The petrology, geochronology, and geochemistry of the early Permian volcanic rocks from Houtoumiao area, south Xiwuqi County in central Inner Mongolia of China, are studied to elucidate the early Permian tectonic setting of the region. The volcanic rocks, which are interbedded with sandstone, feature both mafic and felsic compositions and show a bimodal nature. Zircon U–Pb dating reveals that the volcanic rocks formed at 274–278 Ma, similar to the ages of bimodal magmatism in neighbouring areas. The mafic rocks are composed of tholeiitic basalt, basaltic andesite, basaltic trachyandesite, and trachyandesite. They are rich in Th, U, and LILEs, depleted in HFSEs Nb, Ta, and Ti, and have positive εNd(t) values (+3.6 to +7.9). Geochemical analyses indicate that the mafic rocks originated from metasomatized lithospheric mantle. The felsic volcanic rocks are mainly rhyolite, with minor trachyte and dacite. They have different evolutionary tendencies of major elements, chondrite-normalized REE patterns, and isotopic compositions from the mafic volcanic rocks, which preclude formation by fractional crystallization of mafic melts. The εNd(t) values of the felsic rocks are similar to those of the Carboniferous Baolidao arc rocks in the region. It is suggested that Permian felsic melts originated from the partial melting of Carboniferous juvenile arc-related rocks. By comparison with typical Cenozoic bimodal volcanism associated with several tectonic settings, including rift, post-collisional setting, back-arc basin, and the Basin and Range, USA, the bimodal volcanic rocks in central Inner Mongolia display similar petrological and geochemical characteristics to the rocks from back-arc basin and the Basin and Range, USA. Based on the analysis of regional geological data, it is inferred that the early Permian bimodal volcanic rocks in the study area formed on an extensional continental margin of the Siberian palaeoplate after late Carboniferous subduction–accretion.  相似文献   

2.
通过岩石学、地球化学和同位素年代学研究, 从原划"布伦阔勒岩群"中识别出一套"双峰式"火山岩, 英安岩锆石LA-ICP-MS U-Pb年龄结果显示该套岩石形成年龄为521.3±3.3 Ma, 为早寒武世产物. 在岩石类型上, 玄武岩和英安岩属于低钾岩石系列, 玄武岩相对富集Rb、Ba、K、LREE, 而亏损Nb-Ta、Th, 源于受早期俯冲洋/陆壳流体交代的亏损地幔熔融源区. 英安岩表现出富集LILE、Th, 亏损Nb-Ta、Sr和Ti.两类岩石表现出不同的稀土元素配分模式和微量元素特征, 并缺乏分异演化的趋势, 反映二者的成因存在差别. 结合其地球化学特征和实验岩石学资料, 认为英安岩为玄武岩底侵提供热, 基性下地壳在相对低压条件下部分熔融形成的. 这套"双峰式"火山岩组合证实区域上早古生代存在一次大陆拉张环境下的构造-岩浆事件. 结合区域上研究资料, 古元古代布伦阔勒岩群至少包含以下3个组成部分: (1)古元古代布伦阔勒岩群; (2)印支期高压变质岩体; (3)早古生代火山-沉积岩组合.   相似文献   

3.
The Neoproterozoic Wadi Ranga metavolcanic rocks, South Eastern Desert of Egypt, constitute a slightly metamorphosed bimodal sequence of low-K submarine tholeiitic mafic and felsic volcanic rocks. The mafic volcanic rocks are represented by massive and pillow flows and agglomerates, composed of porphyritic and aphyric basalts and basaltic andesites that are mostly amygdaloidal. The felsic volcanic rocks embrace porphyritic dacites and rhyolites and tuffs, which overlie the mafic volcanic rocks. The geochemical characteristics of Wadi Ranga volcanic rocks, especially a strong Nb depletion, indicate that they were formed from subduction-related melts. The clinopyroxene phenocrysts of basalts are more akin to those crystallizing from island-arc tholeiitic magmas. The tholeiitic nature of the Wadi Ranga volcanics as well as their LREE-depleted or nearly flat REE patterns and their low K2O contents suggest that they were developed in an immature island arc setting. The subchondritic Nb/Ta ratios (with the lowest ratio reported for any arc rocks) and low Nb/Yb ratios indicate that the mantle source of the Wadi Ranga mafic volcanic rocks was more depleted than N-MORB-source mantle. Subduction signature was dominated by aqueous fluids derived from slab dehydration, whereas the role of subducted sediments in mantle-wedge metasomatization was subordinate, implying that the subduction system was sediment-starved and far from continental clastic input. The amount of slab-derived fluids was enough to produce hydrous magmas that follow the tholeiitic but not the calc-alkaline differentiation trend. With Mg# > 64, few samples of Wadi Ranga mafic volcanic rocks are similar to primitive arc magmas, whereas the other samples have clearly experienced considerable fractional crystallization.The low abundances of trace elements, together with low K2O contents of the felsic metavolcanic rocks indicate that they were erupted in a primitive island arc setting. The felsic volcanic rocks are characterized by lower K/Rb ratios compared to the mafic volcanic rocks, higher trace element abundances (~ 2 to ~ 9 times basalt) on primitive arc basalt-normalized pattern and nearly flat chondrite-normalized REE patterns, which display a negative Eu anomaly. These features are largely consistent with fractional crystallization model for the origin of the felsic volcanic rocks. Moreover, SiO2-REE variations for the Wadi Ranga volcanic rocks display steadily increasing LREE over the entire mafic to felsic range and enriched La abundances in the felsic lavas relative to the most mafic lavas, features which are consistent with production of the felsic volcanic rocks through fractional crystallization of basaltic melts. The relatively large volume of Wadi Ranga silicic volcanic rocks implies that significant volume of silicic magmas can be generated in immature island arcs by fractional crystallization and indicates the significant role of intra-oceanic arcs in the production of Neoproterozoic continental crust. We emphasize that the geochemical characteristics of these rocks such as their low LILE and nearly flat REE patterns can successfully discriminate them from other Egyptian Neoproterozoic felsic volcanic rocks, which have higher LILE, Zr and Nb and fractionated REE patterns.  相似文献   

4.
The Xitieshan deposit (~ 64 Mt at 4.86% Zn, 4.16% Pb, 58 g/t Ag, and 0.68 g/t Au) is hosted by the Middle to Late Ordovician Tanjianshan Group of the North Qaidam tectonic metallogenic belt, NW China. This belt is characterized by island arc volcanic, ultra-high pressure (UHP) metamorphic and ophiolitic rocks. The Tanjianshan Group constitutes a succession of metamorphosed bimodal volcanic and sedimentary rocks, which are interpreted to have formed on the margin of a back-arc ocean basin between the Qaidam block and the Qilian block.Four stratigraphic units are identified within the Ordovician Tanjianshan Group. From northeast to southwest they are: 1) unit a, or the lower volcanic-sedimentary rocks, comprising bimodal volcanic rocks (unit a-1) and sedimentary rocks (unit a-2) ranging from carbonates to black carbonaceous schist; 2) unit b, or intermediate-mafic volcaniclastic rocks, characterized by intermediate to mafic volcaniclastic rocks intercalated with lamellar carbonaceous schist and minor marble lenses; 3) unit c, a purplish red sandy conglomerate that unconformably overlies unit b, representing the product of the foreland basin sedimentation during the Early Silurian; 4) unit d, or mafic volcanic rocks, from base to up, comprising the lower mafic volcaniclastic rocks (unit d-1), middle clastic sedimentary rocks (unit d-2), upper mafic volcaniclastic rocks (unit d-3), and uppermost mafic volcanic rocks (unit d-4). Unit a-2 hosts most of the massive sulfides whereas unit b contains subordinate amounts.The massive stratiform lenses constitute most of the Xitieshan deposit with significant amount of semi-massive and irregularly-shaped sulfides and minor amounts in stringer veins. Pyrite, galena and sphalerite are the dominant sulfide minerals, with subordinate pyrrhotite and chalcopyrite. Quartz is a dominant gangue mineral. Sericite, quartz, chlorite, and carbonate alteration of host rocks accompanies the mineralization.U-Pb zircon geochronology yields three ages of 454 Ma, 452 Ma and 451 Ma for the footwall felsic volcanic rocks in unit a-1, sedimentary host rocks in unit a-2 and hanging-wall unit b, respectively. The Xitieshan deposit is considered to be coeval with the sedimentation of unit a-2 and unit b of the Tanjianshan Group. The Xitieshan deposit has been intensely deformed during two phases (main ductile shear and minor ductile-brittle deformation). The main ductile shear deformation controls the general strike of the ore zones, whereas minor deformation controls the internal geometry of the ore bodies. 40Ar-39Ar age of muscovite from mylonitized granitic gneisses in the ductile shear zone is ~ 399 Ma, which is interpreted to date the Xitieshan ductile shear zone, suggesting that Early Devonian metamorphism and deformation post-dated the Tanjianshan Group.The Xitieshan deposit has many features similar to that of the Bathurst district of Canada, the Iberian Pyrite Belt of Spain, the Wolverine volcanogenic massive sulfide deposit in Canada. Based on its tectonic setting, host-rock types, local geologic setting, metal grades, geochronology, temperatures and salinities of mineralizing fluid and source of sulfur, the Xitieshan deposit has features similar to sedimentary exhalative (SEDEX) and VMS deposits and is similar to volcanic and sediment-hosted massive sulfide (VSHMS) deposits.  相似文献   

5.
月照-琵琶寺地区的变质火山岩出露于甘肃武都县境内,夹在泥盆系和前震旦碧口群地层之间.按地球化学分类,火山岩可划分为双峰式和碱性两个系列.双峰式火山岩系由低K富Na拉斑玄武岩和酸性英安岩、流纹岩组成.该玄武岩具有类似MORB的微量元素特征,平坦的稀土配分模式,但富Th贫Nb显示其受到陆壳混染的影响.该套火山岩总体特征指示其为大陆裂谷向成熟洋盆转化阶段的产物,从而推测本区火山岩可能为勉略古洋盆西延的分支产物.  相似文献   

6.
刘军锋  孙勇  高明  杨磊 《地质学报》2008,82(7):998-2008-01-30
月照琵琶寺地区的变质火山岩出露于甘肃武都县境内,夹在泥盆系和前震旦碧口群地层之间。按地球化学分类,火山岩可划分为双峰式和碱性两个系列。双峰式火山岩系由低K富Na拉斑玄武岩和酸性英安岩、流纹岩组成。该玄武岩具有类似MORB的微量元素特征,平坦的稀土配分模式,但富Th贫Nb显示其受到陆壳混染的影响。该套火山岩总体特征指示其为大陆裂谷向成熟洋盆转化阶段的产物,从而推测本区火山岩可能为勉略古洋盆西延的分支产物。  相似文献   

7.
The Canatuan and Malusok massive sulfide deposits are located near Siocon, Zamboanga del Norte, in southwestern Mindanao, Philippines. The Canatuan–Malusok area is underlain by the Jurassic–Cretaceous Tungauan schists, which form much of the Zamboanga Peninsula. The volcanic strata at Canatuan and Malusok can be traced for >7 km along strike and is host to at least three discrete massive sulfide bodies: Canatuan, Malusok and SE Malusok. Basal basaltic andesite volcanic rocks are generally chemically uniform and show only moderate alteration. The massive sulfide deposits occur in overlying rhyolitic to rhyodacitic volcanic rocks that are altered to a schistose assemblage of quartz, sericite, chlorite and pyrite. The alteration is texturally destructive but graded clastic beds are locally observed. Despite tropical saprolitic weathering, four lithogeochemical subunits of the felsic package are identified. Stratigraphic interleaving, however, has made correlation of these units over any significant distance difficult. The sulfide lenses are overlain by a few metres of felsic schists which locally contain manganese-bearing silicates and oxides that serve as a stratigraphic marker. Hangingwall andesitic volcaniclastic rocks are discontinuously preserved, although where present, they consist of regularly bedded mafic volcanic sandstones. The lateral continuity of a manganese-bearing marker and flanking felsic volcaniclastic intervals indicate that locally the volcanic strata form a homoclinal sequence. The Canatuan Au–Ag–Cu–Zn deposit consists of a gossan overlying a massive sulfide lens. The sulfides and gossan are flat lying and hosted within felsic volcanic rocks. The gossan is gold–silver-rich, and was formed by a combination of oxidation and volume collapse of the original sulfide lens. The sulfide minerals present below the current water table, are auriferous massive pyrite with base metal sulfides, with some supergene chalcocite. The transition from gossan to sulfides is very sharp, occurring at the water table. Massive sulfide deposits at Malusok are hosted in the same felsic sequence as Canatuan and they have similar base and precious metal contents. Only limited gossan has been found at Malusok. The bimodal nature of the volcanic rocks at Canatuan, together with their low HFSE contents, near-flat REE patterns and tholeiitic affinities, suggest that they formed in an intra-oceanic arc setting above a depleted mantle source. Mafic and felsic volcanic rocks of similar composition have been recovered from the Tonga-Kermadec and Izu-Bonin-Marianas island-arc systems in the western Pacific. Mafic rocks at Canatuan show no evidence for LILE enrichment that characterizes melts derived from metasomatized mantle under more mature arcs, suggesting that they are the product of a nascent, rather than a mature arc. There is no evidence from the REE, or other incompatible trace elements, that continental crust or evolved arc crust was involved in the generation of the Canatuan-Malusok volcanic rocks. Although it has been proposed that the Zamboanga metamorphic complex comprises microcontinental fragments of Eurasian affinity, our data do not support an evolved crustal setting for the Canatuan-Malusok volcanic rocks, which we suggest were derived from an intra-oceanic arc and subsequently accreted to the eastern Mindanao terrane.Electronic Supplementary Material Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s00126-003-0350-7Editorial handling: R.R. Large  相似文献   

8.
祁漫塔格地区十字沟蛇绿岩地质特征   总被引:7,自引:1,他引:6  
十字沟蛇绿岩产出于东昆仑西段祁漫塔格结合带东部,主要由蛇纹岩、辉长岩、辉绿岩、基性火山岩及硅质岩等组成。其中,从超基性岩—基性岩—基性火山岩,具稀土总量逐渐增加,轻稀土弱亏损型特征,基性火山岩为洋脊玄武岩,总体岩石化学成分与大洋中脊低钾拉斑玄武岩相当,三者的配分型式基本一致,说明其继承了源区地幔的特征,微量元素显示基性火山岩具弧后盆地玄武岩特点。Nεd(t)比值表明玄武岩来自亏损地幔源区,总体地球化学特征显示以N-M ORB型为主,兼具有E-M ORB型的特征,形成于与俯冲作用有关的弧后盆地环境,形成时代为晚奥陶世。后期至少经历了3期以上构造变形变质作用的叠加改造,于早志留世运移至地表。  相似文献   

9.
The Rainy Lake area in northern Minnesota and southwestern, Ontario is a Late Archean (2.7 Ga) granite-greenstone belt within the Wabigoon subprovince of the Canadian Shield. In Minnesota the rocks include mafic and felsic volcanic rocks, volcaniclastic, chemical sedimentary rocks, and graywacke that are intrucded by coeval gabbro, tonalite, and granodiorite. New data presented here focus on the geochemistry and petrology of the Minnesota part of the Rainy Lake area. Igneous rocks in the area are bimodal. The mafic rocks are made up of three distinct suites: (1) low-TiO2 tholeiite and gabbro that have slightly evolved Mg-numbers (63–49) and relatively flat rare-earth element (REE) patterns that range from 20–8 x chondrites (Ce/YbN=0.8–1.5); (2) high-TiO2 tholeiite with evolved Mg-numbers (46–29) and high total REE abundances that range from 70–40 x chondrites (Ce/YbN=1.8–3.3), and (3) calc-alkaline basaltic andesite and geochemically similar monzodiorite and lamprophyre with primitive Mg-numbers (79–63), enriched light rare-earth elements (LREE) and depleted heavy rare-earth elements (HREE). These three suites are not related by partial melting of a similar source or by fractional crystallization of a common parental magma; they resulted from melting of heterogeneous Archean mantle. The felsic rocks are made up of two distinct suites: (1)low-Al2O3 tholeiitic rhyolite, and (2) high-Al2O3 calc-alkaline dacite and rhyolite and consanguineous tonalite. The tholeiitic felsic rocks are high in Y, Zr, Nb, and total REE that are unfractionated and have pronounced negative Eu anomalies. The calcalkaline felsic rocks are depleted in Y, Zr, and Nb, and the REE that are highly fractionated with high LREE and depleted HREE, and display moderate negative Eu anomalies. Both suites of felsic rocks were generated by partial melting of crustal material. The most reasonable modern analog for the paleotectonic setting is an immature island arc. The bimodal volcanic rocks are intercalated with sedimentary rocks and have been intruded by pre- and syntectonic granitoid rocks. However, the geochemistry of the mafic rocks does not correlate fully with that of mafic rocks in modern are evvironments. The low-TiO2 tholeiite is similar to both N-type mid-ocean-ridge basalt (MORB) and low-K tholeiite from immature marginal basins. The calc-alkaline basaltic andesite is like that of low-K calc-alkaline mafic volcanic rocks from oceanic volcanic arcs; however, the high-TiO2 tholeiite is most similar to modern E-type MORB, which occurs in oceanic rifts. The conundrum may be explained by: (1) rifting of a pre-existing immature arc system to produce the bimodal volcanic rocks and high-TiO2 tholeiite; (2) variable enrichment of a previously depleted Archean mantle, to produce both the low- and high-TiO2 tholeiite and the calc-alkaline basaltic andesite, and/or (3) enrichment of the parental rocks of the high-TiO2 tholeiite by crustal contamination.  相似文献   

10.
Late Miocene–Pliocene to Quaternary calc-alkaline lava flows and domes are exposed in southeast of Isfahan in the Urumieh Dokhtar magmatic belt in the Central Iran structural zone. These volcanic rocks have compositions ranging from basaltic andesites, andesites to dacites. Geochemical studies show these rocks are a medium to high K calc-alkaline suite and meta-aluminous. Major element variations are typical for calc-alkaline rocks. The volcanic rocks have SiO2 contents ranging between 53.8% and 65.3%. Harker diagrams clearly show that the dacitic rocks did not form from the basaltic andesites by normal differentiation processes. They show large ion lithophile elements- and light rare earth elements (LREE)-enriched normalized multielement patterns and negative Nb, Ti, Ta, and P. Condrite-normalized REE patterns display a steep decrease from LREE to light rare earth elements without any Eu anomaly. These characteristics are consistent with ratios obtained from subduction-related volcanic rocks and in collision setting. The melting of a heterogeneous source is possible mechanism for their magma genesis, which was enriched in incompatible elements situated at the upper continental lithospheric mantle or lower crust. The geochemical characteristics of these volcanic rocks suggested that these volcanic rocks evolved by contamination of a parental magma derived from metasomatized upper lithospheric mantle and crustal melts.  相似文献   

11.
塔什库尔干大型铁矿成矿带位于昆仑造山带西段,原岩恢复表明该区含铁岩系主要为一套双峰式火山岩碎屑岩碳酸盐岩建造组合,岩石普遍遭受绿片岩相变质和多期构造变形。本文报道了在老并一带变安山岩中获得的LA ICP MS锆石U Pb同位素年龄值(603±10)Ma,并结合前人年龄数据,将原划古元古界布伦阔勒岩群的含铁岩系厘定为震旦系寒武系纽芬兰统马尔洋岩组(Z 1m),其内发育典型的双峰式火山岩组合,证实了区内震旦纪早寒武世仍处于拉张伸展背景,变质火山沉积组合特征表明其形成于大陆边缘裂谷构造环境。含铁岩系典型的膏(钡)铁建造很可能为新元古代晚期“Marinoan雪球”冰期后地球系统变化的火山沉积响应。  相似文献   

12.
In the Dharwar Craton, southern India, gold deposits are found mostly along the six arcuate shear zones passing through late Archaean greenstone belts (2.7 Ga). One such shear zone complex extends for about 400 km within and along the Ramagiri–Hungund schist belt. The Penakacherla sector of this shear zone is excellently exposed, enabling a detailed investigation of synorogenic gold mineralisation and its relationship to associated hydrothermal alteration.Metamorphism and deformation under NE–SW compression associated with Archaean subduction processes converted mafic volcanic rocks into amphibolites and intermediate to felsic volcanic rocks into quartz mica schists. Continued compression generated a 50–100-m-wide shear zone complex consisting of mafic phyllonites. Advection of hydrothermal fluids through this shear zone and reaction between fluids and the mafic phyllonites resulted in a silicified, K-metasomatic assemblage mainly consisting of chlorite, amphibole, K-mica, plagioclase, ankerite, quartz, Fe-oxides, pyrite, chalcopyrite and arsenopyrite. Networks of quartz and carbonate veinlets, a few millimeters to a few centimeters thick, formed along the foliation planes giving rise to microscopic alteration envelope, in which individual veinlet systems are merged into one another to form a composite alteration system. Gold is found within these quartz veinlets, mafic phyllonites and at their mutual contacts.Hydrothermal fluids have modified the primary major, minor, trace and LREE compositions of host rocks such that their mutual behaviour became non-systematic. Some HFSE and HREE also show minor mobility but the overall REE pattern generally resembles that of the precursor mafic volcanic rocks. Mass and volume loss/gain by Si and Ca has made significant impact on Al, Ti and Zr abundances, which are generally immobile during hydrothermal alteration. However, element pairs such as Zr–Hf, V–Sc and Nb–Ta maintain primary inter-element ratios, although their absolute abundances are drastically diluted. Similarly, ΣREE in highly silicified and carbonatised samples are reduced, but patterns remain similar to those of relatively least altered mafic phyllonites with (LaN/Yb)N between 1 and 3. In some samples, LREE enrichment is observed elevating in (LaN/Yb)N from 3 to 11. Pathfinder elements and base metals such as As, Cd, Cu, Pb, Zn and Sb have been added along with the Au and Ag.δ13C of carbon varies from −16‰ to −21‰ suggesting a biogenic origin, whereas coexisting pyrite δ34S ranges from 1‰ to 3‰, pointing towards the involvement of magmatic or average crustal sulphur. Overall concentrations of K, Rb, Sr, Ba, Nb, Ta, Ti, Cs, Cr, Co, V, Y and Sc and many of the ratios such as K/Rb, La/Sc, La/Yb indicate that metamorphism, devolatilisation and dehydration of an oceanic subducting slab might have partially contributed the mineralising fluids and generated the alteration assemblage observed in the host rocks. Fluid sources were mantle and greenstone belt dehydration and devolatilisation generating observed compositional and alteration diversity.  相似文献   

13.
Extensional-tectonic processes have generated extensive magmatic activity that produced volcanic/plutonic rocks along an E-W-trending belt across north-western Turkey; this belt includes granites and coeval volcanic rocks of the Ala?amdağ volcano-plutonic complex. The petrogenesis of the Early Miocene Ala?amdağ granitic and volcanic rocks are here investigated by means of whole-rock Sr–Nd isotopic data along with field, petrographic and whole-rock geochemical studies. Geological and geochemical data indicate two distinct granite facies having similar mineral assemblages, their major distinguishing characteristic being the presence or absence of porphyritic texture as defined by K-feldspar megacrysts. I-type Ala?amdağ granitic stocks have monzogranitic-granodioritic compositions and contain a number of mafic microgranular enclaves of monzonitic, monzodioritic/monzogabbroic composition. Volcanic rocks occur as intrusions, domes, lava flows, dykes and volcanogenic sedimentary rocks having (first episode) andesitic and dacitic-trachyandesitic, and (second episode) dacitic, rhyolitic and trachytic-trachydacitic compositions. These granitic and volcanic rocks are metaluminous, high-K, and calc-alkaline in character. Chondrite-normalised rare earth element patterns vary only slightly such that all of the igneous rocks of the Ala?amdağ have similar REE patterns. Primitive-mantle-normalised multi-element diagrams show that these granitic and volcanic rocks are strongly enriched in LILE and LREE pattern, high (87Sr/86Sr)i and low ε Nd(t) ratios suggesting Ala?amdağ volcano-plutonic rocks to have been derived from hybrid magma that originated mixing of co-eval lower crustal-derived more felsic magma and enriched subcontinental lithospheric mantle-derived more mafic magmas during extensional processes, and the crustal material was more dominant than the mantle contribution. The Ala?amdağ volcano-plutonic complex rocks may form by retreat of the Hellenic/Aegean subduction zone, coinciding with the early stages of back-arc extension that led to extensive metamorphic core-complex formation.  相似文献   

14.
Throughout Earth??s history, all volcanogenic massive sulfide (VMS)-hosting environments are associated with specific assemblages of mafic and felsic rocks with distinct petrochemistry (petrochemical assemblages) indicative of formation at anomalously high temperatures within extensional geodynamic environments. In mafic-dominated (juvenile/ophiolitic) VMS environments, there is a preferential association with mafic rocks with boninite and low-Ti tholeiite, mid-ocean ridge basalt (MORB), and/or back-arc basin basalt affinities representing forearc rifting or back-arc initiation, mid-ocean ridges or back-arc basin spreading, or back-arc basins, respectively. Felsic rocks in juvenile oceanic arc environments in Archean terrains are high field strength element (HFSE) and rare earth element (REE) enriched. In post-Archean juvenile oceanic arc terrains, felsic rocks are commonly HFSE and REE depleted and have boninite like to tholeiitic signatures. In VMS environments that are associated with continental crust (i.e., continental arc and back-arc) and dominated by felsic volcanic and/or sedimentary rocks (evolved environments), felsic rocks are the dominant hosts to mineralization and are generally HFSE and REE enriched with calc-alkalic, A-type, and/or peralkalic affinities, representing continental arc rifts, continental back-arcs, and continental back-arcs to continental rifts, respectively. Coeval mafic rocks in evolved environments have alkalic (within-plate/ocean island basalt like) and MORB signatures that represent arc to back-arc rift versus back-arc spreading, respectively. The high-temperature magmatic activity in VMS environments is directly related to the upwelling of mafic magma beneath rifts in extensional geodynamic environments (e.g., mid-ocean ridges, back-arc basins, and intra-arc rifts). Underplated basaltic magma provides the heat required to drive hydrothermal circulation. Extensional geodynamic activity also provides accommodation space at the base of the lithosphere that allows for the underplated basalt to drive hydrothermal circulation and induce crustal melting, the latter leading to the formation of VMS-associated rhyolites in felsic-dominated and bimodal VMS environments. Rifts also provide extensional faults and the permeability and porosity required for recharge and discharge of VMS-related hydrothermal fluids. Rifts are also critical in creating environments conducive to preservation of VMS mineralization, either through shielding massive sulfides from seafloor weathering and mass wasting or by creating environments conducive to the precipitation of subseafloor replacement-style mineralization in sedimented rifts. Subvolcanic intrusions are also products of the elevated heat flow regime common to VMS-forming environments. Shallow-level intrusive complexes (i.e., within 1?C3?km of the seafloor) may not be the main drivers of VMS-related hydrothermal circulation, but are likely the manifestation of deeper-seated mantle-derived heat (i.e., ~3?C10?km depth) that drives hydrothermal circulation. These shallower intrusive complexes are commonly long-lived (i.e., millions of years), and reflect a sustained thermally anomalous geodynamic environment. Such a thermally anomalous environment has the potential to drive significant hydrothermal circulation, and, therefore multi-phase, long-lived subvolcanic intrusive complexes are excellent indicators of a potentially fertile VMS environment. The absence of intrusive complexes, however, does not indicate an area of low potential, as they may have been moved or removed due to post-VMS tectonic activity. In some cases, shallow-level intrusive systems contribute metals to the VMS-hydrothermal system.  相似文献   

15.
The Dir-Utror volcanic series forms a NE–SW trending belt within the northwestern portion of the Kohistan island arc terrane in the western Himalayas of northern Pakistan. The Kohistan arc terrane comprises a diverse suite of volcanic, plutonic, and subordinate sedimentary rocks of late Mesozoic to Tertiary age, developed prior to and after suturing of the Indo-Pakistan and Asiatic continental blocks. The Dir-Utror volcanic series near Dir is dominated by basaltic-andesite and andesite, with subordinate basalt, high-MgO basalt, dacite, and rhyolite. Porphyritic textures are dominant, with less common aphyric and seriate textures. Plagioclase is the dominant phenocryst in mafic to intermediate rocks, K-feldspar and quartz phenocrysts predominate in the dacites and rhyolites. Chlorite, epidote, albite, and actinolite are the most common metamorphic phases; blue-green amphibole, andesine, muscovite, biotite, kaolinite, sericite, carbonate, and opaques are widespread but less abundant. Phase assemblages and chemistry suggest predominant greenschist facies metamorphism with epidote-amphibolite facies conditions attained locally.Whole rock major element compositions define a calc-alkaline trend: CaO, FeO, MgO, TiO2, Al2O3, V, Cr, Ni, and Sc all decrease with increasing silica, whereas alkalis, Rb, Ba, and Y increase. MORB-normalized trace element concentrations show enrichment of the low-field strength incompatible elements (Ce, La, Ba, Rb, K) and deep negative Nb, P, and Ti anomalies—patterns typical of subduction related magmas. Mafic volcanic rocks plot in fields for calc-alkaline volcanics on trace element discrimination diagrams, showing that pre-existing oceanic crust is not preserved here. All rocks are LREE-enriched, with La=16–112×chondrite, La/Lu=2.6–9.8×chondrite, and Eu/Eu*=0.5–0.9. Dacites and rhyolites have the lowest La/Lu and Eu/Eu* ratios, reflecting the dominant role of plagioclase fractionation in their formation. Some andesites have La/Lu ratios which are too high to result from fractionation of the more mafic lavas; chondrite-normalized REE patterns for these andesites cross those of the basaltic andesites, indicating that these lavas cannot be related to a common parent.The high proportion of mafic lavas rules out older continental crust as the main source of the volcanic rocks. The scarcity of more evolved felsic volcanics (dacite, rhyolite) can be explained by the nature of the underlying crust, which consists of accreted intra-oceanic arc volcanic and plutonic rocks, and is mafic relative to normal continental margins. Andesites with high La, La/Lu, K2O, and Rb may be crustal melts; we suggest that garnet-rich high-pressure granulites similar to those exposed in the Jijal complex may be restites formed during partial melting of the crust.  相似文献   

16.
内蒙朝克山蛇绿岩地球化学: 洋内弧后盆地的产物?   总被引:8,自引:6,他引:2  
王树庆  许继峰  刘希军  侯青叶 《岩石学报》2008,24(12):2869-2879
朝克山蛇绿岩是内蒙贺根山地区出露最好的蛇绿岩之一,可能形成于中晚石炭世。朝克山蛇绿岩中的基性岩具有LREE亏损、类似N-MORB的稀土配分模式,而相对N-MORB富集大离子亲石元素,亏损Nb、Ta等高场强元素又类似岛弧火山岩的成分特征,因此,我们认为朝克山蛇绿岩应形成于弧后盆地。将朝克山蛇绿岩的基性岩与现代Mariana洋内弧后盆地和Okinawa陆缘弧后盆地的玄武岩及同属中亚造山带的、形成于洋内弧后盆地的新疆库尔提蛇绿岩对比,朝克山蛇绿岩更类似于Mariana玄武岩和库尔提蛇绿岩,因此其很可能形成于洋内弧后盆地而不是大陆边缘弧后盆地环境。  相似文献   

17.
Major and trace element data on the Archean metavolcanic rocks of the Prince Albert Group (PAG), Northwest Territories. Canada, are reported. The following major groups were found, based on combined field and geochemical evidence: ultramafic flows; basaltic rocks, predominantly tholeiites; andesites; heavy REE depleted dacites; and rhyolites.The ultramafic and basaltic rocks are relatively normal Archean volcanics except for the downward bowed REE patterns of the tholeiitic basalts. The andesites, dacites and rhyolites, however, are not typical of Archean terrains. Comparisons between the andesites of the PAG and other Archean and more recent ones show that those of the PAG are most similar chemically to modern high-K andesites. REE patterns in these rocks suggest that partial melting of assemblages with significant garnet are an unlikely source but it is not possible to ascribe their origin to any simple process. Partial melting of a garnet-poor mafic granulite is an acceptable source for the heavy REE depleted dacites. The geochemical characteristics of the rhyolites cannot be explained by partial melting of a mafic source or by fractional crystallization from the daeites. It is suggested that these rocks originated by partial melting of pre-existing sialic crust.  相似文献   

18.
The sulfide deposits of Chizeuil (Saone et Loire) occur in a Late Devonian volcano-sedimentary sequence within an acid volcanic unit and close to a Carboniferous granite batholith. Sulfide bodies, mainly pyrite, are enclosed in andalusite-bearing siliceous rocks lacking primary textures and recrystallized by the granitic thermal metamorphism.Several genetic interpretations were proposed for these siliceous rocks and the associated mineralization, i.e., as either being related to the granite intrusion or of volcanogenic derivation. Detailed studies led to their identification as hydrothermal alterites.A petrographic study of these siliceous alterites reveals that the main mineral phases are only constituted of silica and alumina: quartz, andalusite, kaolinite and minor contents of muscovite, diaspore and corundum. Neither K-feldspar or biotite are present with andalusite. This implies that thermal metamorphism occurred on an already alkali-, calcium- and magnesium-depleted rock.These siliceous alterites show less mobile-element (Al, Ti, V, Zr, Nb) concentration ranges similar to those of acid volcanic host rocks. A metasomatic model is computed from chemical data on surrounding soda dacites, assuming that acid hydrolysis was the only phenomenon involved, and that Al was stable in this process.Although altered rock types grading to soda dacites do not crop out, their existence may be deduced from surficial bedrock multielement geochemical data. The zoned distribution of elements agrees with that deduced from reactions and experimental phase diagrams.The pyrite bodies are surrounded by two distinct concentric alteration zones; the inner one is advanced argillic and the outer one is sericitic. Such a pattern is unusual for volcanogenic sulfide deposits but commonly associated with porphyry deposits. It may be related to the strong acidity (pH3) of hydrothermal solutions.These siliceous rocks were produced by an in-situ alteration of brecciated dacitic lavas, inside which a stockwork-type pyritic mineralization was deposited.  相似文献   

19.
Mount St. Helens has explosively erupted dacitic magma discontinuously over the last 40,000 years, and detailed stratigraphic data are available for the past 4,000 years. During this last time period the major-element composition of the dacites has ranged from mafic (62–64 wt% SiO2) to felsic (65–67 wt% SiO2), temperature has varied by about 150°C (770°–920°C), and crystallinity has ranged between 20% and 55%. Water content of these dacites has also fluctuated greatly. Although the source for the dacitic magmas is probably partial melting of lower crustal rocks, there is strong physical evidence, such as banded pumices, thermal heterogeneities in single pumices, phenocryst disequilibrium, contrasts between compositions of glass inclusions and host matrix glass, and amphibole reaction rims, that suggests that magma mixing has been prominent in the dacitic reservoir. Indeed, we suggest that the variations in major- and trace-element abundances in Mount St. Helens dacites indicate that magma mixing between felsic dacite and mafic magma has controlled the petrologic diversity of the dacitic magmas. Magma mixing has also controlled the composition of andesites erupted at Mount St. Helens, and thus it appears that the continuum of magmatic composition erupted at the volcano is controlled by mixing between felsic dacite, or possibly rhyodacite, and basalt. The flux of the felsic endmember to the reservior appears to have been relatively constant, whereas the flux of basalt may have increased in the past 4,000 years, as suggested by the apparently increased abundance of mafic dacite and andesite erupted in this period.  相似文献   

20.
新地沟和卯独庆金矿赋存于新太古界色尔腾山群柳树沟岩组中,是典型的与韧性一脆韧性剪切变形有关的绿岩型金矿。构造-蚀变岩石的主要类型有千糜岩化石英绢云片岩、千糜岩化绿泥绢云片岩、糜棱岩化绿泥石英片岩、绢云绿泥长英质糜棱片岩、长英质碎裂岩、黄铁绢英岩质构造片岩等。构造一蚀变岩石的岩石地球化学特征与中基性火山岩类似.其稀土元素总量∑REE(44.9×10^-6~155.4×10^-6)、LREE/HREE比值(7.0~26.1)、δEu(0.6~1.2)也显示了中基性火山原岩的特点。构造一蚀变一成矿流体的特征为富CO2的低盐度的较高密度的流体,具有造山型金矿的特点。前寒武纪绿岩带建造变质镁铁质火山岩分布的地区构造一蚀变作用强烈的地段是重要的找矿有利地区。  相似文献   

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