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1.
伊犁盆地蒙其古尔铀矿床为典型的层间氧化带型铀矿床,虽然前人对该区铀矿的成矿流体进行了较为系统的研究,但对其成矿流体来源依然存在较大的分歧,尤其对该区成矿流体与蚀变特征、铀成矿的内在联系研究较少。本文为了研究蒙其古尔铀矿床成矿流体来源及其与成岩蚀变、铀成矿的内在联系,综合地应用了偏光显微镜、扫描电镜、电子探针等手段,对其含矿目的层砂岩成岩蚀变进行系统的分析,并对蚀变矿物高岭石H—O同位素、碳酸盐胶结物C—O同位素及黄铁矿S同位素进行了研究。研究表明：与砂岩型铀矿有关的成岩蚀变类型主要有黏土化、碳酸盐化、硅化及金属矿化;成矿流体中水δDH2O,V SMOW为-48.3‰～-93‰,
δ18OH2O,V SMOW为-10.3‰～-5.1‰,碳酸盐胶结物δ13CV PDB为-10.9‰～-7.2‰,δ18OV SMOW为176‰～249‰,黄铁矿δ34SV CDT为-17.3‰～12‰,上述特征揭示蒙其古尔铀矿床成矿流体是由大气降水性质的地表水（无机）和煤系地层有机质脱羟基及热降解作用产生的有机酸及CH4等还原性气体（煤层气）（有机）两部分组成;成岩蚀变和铀成矿效应皆是有机—无机流体及流体与周围砂岩相互作用的结果。 相似文献
2.
硅酸盐和金属氧化物矿物氧同位素组成的CO2激光氟化分析 总被引：9，自引：0，他引：9
我室采用MIR-10型CO2激光器,在一种富BrF5的氛围中使激光对硅酸盐和氧化物矿物样品加热形成O2,经多次纯化后用5A的分子筛吸收,再直接送至气体质谱仪进行氧同位素比值测定.这个实验流程与传统方法相比的改进不仅在使用激光加热技术及样品的放置上,而且在直接采用O2而不是CO2进行质谱测定.采用O2进行直接分析的优点不仅避免了向CO2转化过程中的潜在同位素分馏,而且能够得到样品的δ17O值,因此为宇宙样品分析提供了可能.CO2激光氟化技术的优点是所需样品量小(可低达1～2
mg),因此能够分析微小岩石区域或单矿物晶体内的氧同位素分布.同时,激光可以达到非常高的温度(＞4000K),因此能够对某些难熔矿物(如锆石、蓝晶石、橄榄石等)进行氧同位素分析. 相似文献
3.
硅酸盐和金属氧化物矿物氧同位素组成的CO_2激光氟化分析 总被引：3，自引：0，他引：3
我室采用MIR 10型CO2 激光器 ,在一种富BrF5的氛围中使激光对硅酸盐和氧化物矿物样品加热形成O2 ,经多次纯化后用 5 的分子筛吸收 ,再直接送至气体质谱仪进行氧同位素比值测定。这个实验流程与传统方法相比的改进不仅在使用激光加热技术及样品的放置上 ,而且在直接采用O2 而不是CO2 进行质谱测定。采用O2 进行直接分析的优点不仅避免了向CO2 转化过程中的潜在同位素分馏 ,而且能够得到样品的δ1 7O值 ,因此为宇宙样品分析提供了可能。CO2 激光氟化技术的优点是所需样品量小 (可低达 1～ 2mg) ,因此能够分析微小岩石区域或单矿物晶体内的氧同位素分布。同时 ,激光可以达到非常高的温度 (>40 0 0K) ,因此能够对某些难熔矿物 (如锆石、蓝晶石、橄榄石等 )进行氧同位素分析。 相似文献
4.
准噶尔盆地石炭-二叠系方解石脉的碳、氧、锶同位素组成与含油气流体运移 总被引：2，自引：1，他引：1
在准噶尔盆地当前油气勘探的重点目标区西北缘和腹部地区,油气主要源于深部石炭系—二叠系。通过对其中的典型水岩反应产物,即裂隙方解石脉进行碳、氧、锶同位素组成分析,尝试讨论了油源流体运移的基本特征。实验结果表明,25件方解石脉样品的δ13CPDB位于－21.5‰~ 5.2‰之间,δ18OPDB(δ18OSMOW)在－8.1‰～－22.3‰(22.6‰~ 6.9‰)之间;20个87Sr/86Sr比值分布在0.703 896～0.706 423之间。据此,结合样品地质产状和区域地质背景,提出本区含油气流体在运移过程中伴随着深部热流体的影响,它们在流经石炭—二叠系时,对火山岩层的溶蚀使得流体岩石相互作用产物,即方解石脉的同位素组成反映出火山岩地层的地球化学标记。该认识表明,在今后的区域储层成岩演化和油气运移研究工作中,应充分考虑这类深部热流体作用的影响。 相似文献
5.
石笋能重建百年、十年的气候事件,为达到空间高分辨率,对微量碳酸盐的检测提出了更高要求,传统磷酸酸解法的样品用量大(约10 mg)已经无法满足微量样品的分析,而激光探针质谱分析方法需对检测结果进行校正。本文采用KielⅣ-IRMS双路在线分析技术对微量碳酸盐样品的碳、氧同位素进行检测研究其可行性,并以GBW 04405和NBS 19为例研究了不同样品量的碳酸盐标准样品在不同反应时间对同位素分馏的影响。结果表明,由于标准样品所需的反应时间不同,从而导致同位素分馏值的差异。对样品量为4~85μg的标准样品GBW 04405进行检测,δ13C、δ18O测量值分别为0.574‰±0.027‰、-8.519‰±0.065‰,与推荐值0.57‰±0.03‰、-8.49‰±0.14‰基本一致,表明该方法能够满足微量碳酸盐测试的要求。将KielⅣ-IRMS双路在线分析技术与GasbenchⅡ-IRMS检测方法进行对比,对于标准样品GBW 04405,KielⅣ-IRMS所用样品量约为50μg,δ13C、δ18O测量值分别为0.576‰±0.012‰、-8.501‰±0.050‰,GasbenchⅡ-IRMS所用样品量约为140μg,δ13C、δ18O测量值分别为0.569‰±0.034‰、-8.590‰±0.099‰。表明KielⅣ-IRMS方法相比于GasbenchⅡ-IRMS方法所需样品量少,精度高,结果重现性好,该方法在碳酸盐样品的应用上能达到空间高分辨率。 相似文献
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会昌早白垩世橄榄玄粗岩(shoshonite)成因的元素及Sr-O-Nd-Pb同位素地球化学证据 总被引：6，自引：0，他引：6
根据赣南会昌地区中基性火山岩高碱、富钾、低钛、贫铁,岩石中斜长石斑晶具钾长石环边,基质中存在大量钾长石微晶,以及富集轻稀土元素和大离子亲石元素等矿物岩石地球化学特征,确切厘定会昌地区的中基性火山岩为橄榄玄粗岩安粗岩组合,属典型的大陆板内橄榄玄粗岩系列火山岩。对会昌橄榄玄粗岩进行了RbSr同位素定年研究,确定其全岩RbSr等时线年龄为107.3±2.3Ma。 会昌橄榄玄粗岩系火山岩SrONdPb 同位素组成的特征为: 偏高的 ISr(0.7098~0.7115); 较低的δ18O值(5.3‰~7.0‰);中等的εNd(t)(-0.61~-3.60); 富放射性成因铅((206Pb/204Pb)i=17.32~18.29, (207Pb/204Pb)i=15.34~15.65, (208Pb/204Pb)i =37.51~38.60)。会昌橄榄玄粗岩的Δ7/4Pb值为-7.8~+16.8(平均值为+5.42), Δ8/4Pb值为27.3~97.3 (平均值为68.04), ΔSr值为96.2~114.1 (平均值为104.3),这表明存在典型的Dupal 同位素异常。根据SrO, SrNd, SrPb, NdPb, PbPb同位素相关特征, 判明会昌橄榄玄粗岩是由亏损地幔端元(DM)和岩石圈富集地幔端元(EM)在源区混合形成的。按SrNd双变量二元混合模型计算得出源区物质中亏损地幔端元和富集地幔端元所占份额各占50%左右。会昌早白垩世橄榄玄粗岩系火山岩带的形成反映了华南板块内部在燕山晚期发生的一起重要的伸展构造事件 相似文献
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华北克拉通北缘隆化地区蓝旗镇古元古代石榴石花岗岩的成因及地质意义 总被引：3，自引：0，他引：3
隆化地区蓝旗镇石榴石花岗岩位于华北克拉通北缘中部,与古元古代红旗营子杂岩密切共生。岩石主要由碱性长石、斜长石、石英、石榴石以及少量黑云母等矿物组成。锆石U Pb定年结果表明,石榴石花岗岩的形成时代为1894~1878Ma,属于古元古代中晚期。岩石的SiO2和K2O含量分别介于6409%~7080 %和364%~573 %之间,属于高钾钙碱性到钾玄岩过渡系列;岩石具有较高的Al2O3（1450%~1613%）和较低的CaO（125%~327%）和Na2O（180%~257%）含量,铝饱和指数（ACNK）介于107~134之间,表明该岩体属于S型花岗岩。岩石具有较高的CaO/Na2O比值（>03）,以及较低的Al2O3/Ti2O、Rb/Sr和Rb/Ba比值,指示岩浆源区为贫粘土、富斜长石的砂质岩。锆石Hf同位素分析进一步说明其物源可能是单塔子和红旗营子杂岩经风化作用的产物。蓝旗镇石榴石花岗岩具有与华北克拉通孔兹岩带内S型花岗岩相似的年代学和地球化学特征,结合区域变质岩和岩浆岩资料,本文认为孔兹岩带在空间上可能从内蒙古集宁地区向东延伸到了冀北地区。 相似文献
9.
甘肃北山火石山哈尔根头口布花岗岩年代学、地球化学及其地质意义 总被引：11，自引：0，他引：11
首次利用锆石LAICPMS UPb法测得甘肃火石山东北部侵位于长城系、蓟县系以及志留系中的哈尔根头口布花岗岩形成于中泥盆世早期（同位素年龄为387.6±8.2Ma）,同时发现该花岗岩体内存在晚蓟县世产物（继承性锆石年龄1172±7Ma）。哈尔根头口布花岗岩体主要由钾长花岗岩、二长花岗岩、花岗岩组成,岩石具有高硅（SiO2含量为70.28％~79.4%）、富碱（Na2O＋K2O为6.52%~9.11%）、低铝（Al2O3含量为8.82%~14.05%）、低Sr（含量为40~150×10-6,平均为101.5×10-6）的特征、岩石的δ<3.3、A/CNK值为0.8~1.1,为钙碱性准铝质到弱过铝质岩石;稀土元素具有明显的LREE富集(LREE/HREE=2.89~16.4, LaN/YbN= 1.82~25.18)和Eu亏损,相对富集Rb、Th、Ce和Sm,而亏损Ta、Nb、Zr、Hf。综合分析认为该花岗岩为A型花岗岩,产于构造挤压向构造伸展转换的地质背景之中。 相似文献
10.
高温裂解在线测试高氯酸盐氧同位素方法研究 总被引：1，自引：0，他引：1
高温裂解在线测试高氯酸盐氧同位素的方法与技术,能够为环境介质中高氯酸盐来源的识别、迁移转化过程的示踪及其污染的防治提供重要的分析工具。采用单因子试验系统研究了方法的裂解温度、样品质量和样品类型对高氯酸盐氧同位素测试精度的影响,并采用阴离子交换树脂法进行高氯酸盐环境样品的预处理,探讨测试方法的应用。实验结果表明,反应温度对方法测试精度的影响显著,反应温度必须严格控制在1325℃;样品质量对测试精度不产生显著影响,但最小样品量不低于0.25μmol ClO-4;测试方法适用于不同类型的高氯酸盐,测试精度均优于0.5‰。测试结果不同的校正方法表明,采用多种氧同位素标准的线性校正优于采用单一高氯酸盐氧同位素标准的校正,特别是在样品与标准的氧同位素组成差别较大时,单一标准的校正会产生较大的误差。基于A530E型双官能团阴离子交换树脂的富集与提取ClO-4的预处理方法,可实现高氯酸盐环境样品的氧同位素测定,测试精度优于0.3‰。 相似文献
11.
Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
12.
Gilles Serge Odin 《Comptes Rendus Geoscience》2002,334(6):409-414
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414. 相似文献
13.
The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引：4，自引：0，他引：4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
14.
Muriel Rocher Stéphane Baize Stéphane Jaillet Edward Marc Cushing Yannick Lozac&#x;h Francis Lemeille 《Comptes Rendus Geoscience》2003,335(8):701-708
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003). 相似文献
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正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level 相似文献
16.
正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7), 相似文献
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正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci- 相似文献
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正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli- 相似文献
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正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.) 相似文献