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1.
长江口-杭州湾及其邻近海域不同粒级沉积有机碳分布特征 总被引：2，自引：0，他引：2
通过对长江口、杭州湾、舟山海域及东海陆架4个海区表层沉积物样品的粒度敏感组分分析,发现东海陆架与长江口具有相似的三级组分物质组成,杭州湾与舟山海域具有相似的两级组分物质组成.综合4个区域粒级组分分布特征,采用湿分法将4个海域表层沉积物样品分成6个粒级:＜0.004 mm,0.004～0.025 mm,0.025～0.063 mm,0.063～0.125 mm,0.125～0.250 mm和＞0.250 mm,分别提取各级组分和全样进行有机碳及同位素测试.定量分析各级组分有机碳含量、来源及物质组分,除杭州湾海域粗粒级外,基本上＜0.004 mm的粘土组分有机碳含量最高;富集在杭州湾海域粗颗粒中的有机质主要来源于陆源植物碎屑.沉积物颗粒大小、物质组成类型是不同粒级有机质富集的主要控制因素. 相似文献
2.
密云水库沉积物-水界面磷的地球化学作用 总被引：11，自引：4，他引：11
以密云水库为例，研究了水库沉积物中有机质的含量与有机磷的关系，表明表层沉积物中的总有机碳和有机磷的含量都明显高于底层，是由于一些以磷为营养素的富营养化指示藻类在水体中逐年增加，它们死亡后的残骸经分解-矿化后在底积物中累积的结果。沉积物和孔隙水中磷的剖面特征研究表明，表层沉积物和孔隙水中的磷都有明显上升的趋势，是由于沉积物的表层微生物和活性有机碎屑层比较丰富，有机质降解和含磷的有机化合物分解，使溶解性磷酸盐进入孔隙水。对沉积物磷形态、总有机碳及孔隙水中总磷对磷释放的影响进行了线性相关分析，结果表明上覆水中的磷主要来自沉积物的铁结合态磷、铝结合态磷、溶解态磷三种形态，孔隙水中总磷以及总有机碳含量对上覆水中总溶解磷浓度存在较大的影响，这些为研究水库沉积物作为水库内污染源对水质的影响提供了基础资料。 相似文献
3.
太湖沉积物重金属及营养盐污染研究 总被引：26，自引：1，他引：25
通过太湖MS沉积岩芯元素地球化学指标的分析,对太湖沉积物污染历史进行了系统的讨论。根据化学元素的聚类分析结果、变化趋势,并与太湖流域经济发展进程对比,认为太湖沉积物铅、锌、锰、镍污染开始于20世纪70年代末期,砷、汞污染分别开始于30年代和40年代,随着底泥重金属污染程度的加重,沉积物表层磁化率明显升高;总磷自40年代以来含量不断增加,总氮、总有机碳含量增加开始于70年代末期,表明湖泊富营养化程度不断加重。太湖沉积物重金属及营养盐污染历史与该区经济发展阶段相吻合。 相似文献
4.
利用2002年在崇明东滩采得的CDS、CDM和CDN三个典型区域沉积物剖面样品,测定了其中的有机碳、活性铁、总磷以及粒度等特征参数,分析了地球化学元素的分布变化特征并对其沉积环境的变化进行了探讨。结果表明崇明东滩沉积物中有机碳的含量较大(0．3％～1．07％),垂向分布上,表层／亚表层含量高且变化复杂,中下层有机碳含量逐渐变小。Fe3 在整个研究区域均是从表层向下逐渐递减的,Fe2 含量逐渐增加。从实验结果判断,所研究区域沉积环境上层以氧化环境为主,呈弱氧化型,中下层以还原环境为主。总磷含量呈现自上而下减少的变化,CDS表现为波浪形变化。分析发现潮滩沉积物各地球化学元素之间不仅相互作用,并且受到沉积物颗粒大小和水动力、物源输入、物理扰动等因素的影响。崇明东滩沉积物氧化还原界面与中、高潮滩划分界大致相当。 相似文献
5.
对南海表层沉积物与沉降颗粒物有机碳的δ13C进行了对比研究,从古环境再造方面探讨了陆源和海源对南海表层沉积物的贡献。南海表层沉积物有机碳的δ13C比沉降颗粒物中有机碳的δ13C偏重表明,Suess效应对南海现代过程的影响不可忽视,两者的δ13C差值反映了Suess效应对南海现代过程的影响程度。利用两者的δ13C差值,对现代陆源和海源有机碳的δ13C进行修正后,计算得到,在南海陆架周围表层沉积物的有机碳中,陆源的比例为48%,海源的比例为52%;在远离陆架的表层沉积物的有机碳中,陆源的比例为14%,海源的比例为86%。 相似文献
6.
日本大沼湖沉积物碳氮比值、有机碳同位素特征及其近400年的古气候环境意义 总被引：1，自引：0，他引：1
通过对日本大沼湖沉积物样品总有机碳含量(TOC)及其稳定同位素、总氮含量(TN)和C/N值的测定,结合沉积岩芯火山灰和1℃年代,分析了大沼湖沉积物中有机质的来源,探讨了沉积物有机碳同位素的主要影响因素.结果表明:大沼湖沉积物中有机质主要来源于自生藻类,受陆源输入的影响较小;沉积物δ13C值指示了夏季温度的变化.过去400年来,大沼湖地区存在1660～ 1730年和1780～ 1860年两个明显的冷期,与邻近地区冰芯、树轮和湖泊沉积物记录的冷期基本一致,分别对应于Maunder和Dalton太阳黑子极小期. 相似文献
7.
8.
我国海洋沉积物的研究近几年发展较快,但是缺少有定值的氮、有机碳标准物质。本文针对及其匮乏的氮、有机碳国家二级标准物质进行了我国近海沉积物总氮(TN)、总碳(TC)、总有机碳(TOC)含量的分析标准参考物质的研制。研究样品采自"我国近海海洋综合调查与评价"专项提供的表层沉积物,经过冷冻干燥、研磨至74μm,使用元素分析仪和氧化热解-气相色谱法分析总氮和总碳的含量;使用元素分析仪和氧化热解-电位法分析总有机碳的含量,制备了一系列16个有定值的总氮、总碳、总有机碳含量的近海沉积物标准物质。样品在均匀性检验中,F的实测值小于临界值,相对偏差较小,样品的均匀性较好。在稳定性检验方面,两年内多次测定的分析结果无方向性变化,统计计算结果显示稳定性良好。本文研制的这16个近海沉积物标准物质在3家实验室进行了联合定值,按照ISO导则35和国家一级标准物质研制规范,给出了该系列标准物质总氮、总碳、总有机碳含量的标准值和不确定度。这批标准物质分为不同海区,不同海区的标准物质又分为不同的沉积物类型,研制的不同海区不同沉积物类型的标准物质对现有的海洋沉积物标准物质进行了有效的补充。 相似文献
9.
在莱州湾海岸带采集了62个表层沉积物样品,对黑碳(BC)的含量及其空间分布特征进行了研究,同时探讨了BC与持久性有机污染物(POPs)的关系。结果表明:(1)莱州湾海岸带表层沉积物中BC的含量范围为0.02~9.35 mg/g,平均为0.98 mg/g,低于欧美和我国其他海岸带区域;(2)河流沉积物中的BC含量呈现出明显的空间差异,主要是受点源排放、河流本身的特征和沉积物粒度等因素的影响;海洋沉积物中的BC分布不仅受到沉积物粒度的影响,河流输入和沉积速率也是其重要的影响因素;(3)由于POPs的来源和理化性质差异,POPs与BC和总有机碳(TOC)的相关性也存在一定程度的差异,其中六氯苯(HCB)与BC、TOC的相关性最好。就河流和海洋分区而言,海洋沉积物中POPs与BC、TOC的相关性明显好于河流沉积物,但都没有表现出POPs与BC的相关性优于POPs与TOC的相关性的现象。 相似文献
10.
对南海表层沉积物与沉降颗粒物有机碳的δ13C进行了对比研究,从古环境再造方面探讨了陆源和海源对南海表层沉积物的贡献。南海表层沉积物有机碳的δ13C比沉降颗粒物中有机碳的δ13C偏重表明,Suess效应对南海现代过程的影响不可忽视,两者的δ13C差值反映了Suess效应对南海现代过程的影响程度。利用两者的δ13C差值,对现代陆源和海源有机碳的δ13C进行修正后,计算得到,在南海陆架周围表层沉积物的有机碳中,陆源的比例为48%,海源的比例为52%;在远离陆架的表层沉积物的有机碳中,陆源的比例为14%,海源的比例为86%。 相似文献
11.
Particulate organic carbon (POC) of 161 water samples collected from 8 depths (surface to 1000 m) at 21 stations was measured. The POC concentrations ranged from 154 to 554 ¼g per litre at the surface and decreased in the upper 300 m water column. At greater depths (> 300 m), POC concentrations increased and were similar (145 to 542 ¼g1?1) to those observed at surface. Deep water POC maximum was embedded within the oxygen minimum layer and was also associated with high phosphate-phosphorus. The POC contents increased, whereas oxygen decreased as the distance away from the shore increased. Phytoplankton biomass was a major source of POC. The observed pattern of POC is discussed with respect to some physicochemical and biological factors. 相似文献
12.
间带不同性质的底质中 ,介形虫动物群的特征和生态分布各不相同。在岩石滩和沙滩中介形虫较丰富、多样 ,前者具有 Xestoleberishanaii,Cythere lutea lutea,Loxoconcha hattorii,Aurila cymba等 ,而后者有 Sinocytheridea impressa,Pistocythereis bradyformis,Bicornucytherebisanensis,Cushmanidea subjaponica等。泥质滩中介形虫通常很少 ,有 Loxoconcha binhaiensis和L.ocellata等。受高潮和中潮影响的河口区 ,通常介形虫丰度和多样性的分布较低 ,都是适应环境变化很强的属种 ,并具有海、陆相介形虫分布的混合区段。朝向海洋方向 ,非海相介形虫的百分含量呈逐渐降低变化 ,而海相介形虫正好相反。 相似文献
13.
认识沉积环境有机碳留存状况是阐述油气形成过程中有机碳早期成岩的关键内容。以南海珠江口盆地及其邻近海域为背景,通过研究表层沉积物中脂类化合物的形态组成,认识脂类有机碳的来源和留存状态,阐述特征脂类分子的早期成岩特征。结果表明,研究区域表层沉积物有机碳含量为0.22%～0.66%,有机碳稳定同位素分布在-20.88‰～-22.93‰之间,表现为显著的海源特征。沉积物中共检测出21种脂肪酸、6种脂肪醇、8种甾醇和植醇;总脂肪酸、脂肪醇、甾醇和植醇含量分别为12.57～40.27μg/g、5.35～8.98μg/g、0.15～3.75μg/g和0.01～3.99μg/g干重,总体表现为靠近珠江口和台湾海峡略高。脂类化合物的存在形态以游离态(FR)和碱性水解态(BH)为主,酸性水解态(AH)贡献较低;其中植醇和甾醇呈现显著的BH优势,植醇中未检出AH组分的贡献。脂类化合物主要来自于海洋现场生产,海洋微藻和细菌的相对贡献率分别为21.18%～33.78%和11.02%～15.64%,陆源高等植物贡献低于5%。来源于硫酸盐还原菌的支链脂肪酸在靠近珠江口海域高达1.79～2.62μg/g,占总脂肪酸的5.14%～6.50%,并与硫酸盐还原过程相关的古菌分布相一致。 相似文献
14.
S. W. A. Naqvi 《Journal of Earth System Science》1994,103(2):279-300
Recent information on some consequences of the acute mid-water oxygen deficiency in the Arabian Sea, especially on carbon-nitrogen
cycling, is reviewed. An evaluation of published estimates of water column denitrification rate suggests an overall rate in
the vicinity of 30Tg Ny-1, but the extent of benthic contribution remains unknown. A decoupling of denitrification from primary production, unique
to the Arabian Sea, is revealed by nitrite, electron transport system (ETS) activity and bacterial production data. Results
of both enzymatic and microbiological investigations strongly point to a major role of organic carbon other than that sinking
from surface layers in supporting denitrification. Although denitrification is associated with an intermediate nepheloid layer,
it seems unlikely that the excess carbon comes with particles re-suspended along the continental margins and transported quasi-horizontally
into the ocean interior; instead, the particle maximum may directly reflect a higher bacterial abundance. It is proposed that
denitrification may be predominantly fuelled by the dissolved organic matter. 相似文献
15.
Two vibrocores from the inner shelf off Hong Kong are investigated to compare the contents of organic and inorganic carbon
in postglacial sediments. The compositions of organic elements and carbonate are highly variable in the core sediments, but
overall drop within the compositional ranges of modern seabed sediments in the Zhujiang estuarine and its shelf area. The
Holocene sediments in the inner shelf have never been subject to subaerial exposure and the organic matter and carbonate can
be preserved well. The burial of carbon in river-dominated shelf environments is highly dependent on the river flux with time.
Nevertheless, it is difficult to establish a simple relationship between carbon burial in sediments in relation to climatic
changes of basin-wide scale due to complex controls of production, transport and deposition of organic matter and carbonate.
Our study suggests that the organic carbon to nitrogen ratio can not reliably identify the sources of depositional organic
matters because of selective decomposition of organic matter components during humification and sedimentation. Caution is
therefore needed in using organic elemental compositions as indicators of organic matter sources and paleoenvironmental changes
in the East Asian continental shelves where intense river-sea interaction and variable carbon flux in geologic record occur. 相似文献
16.
东海陆架泥质区沉积有机质的物源分析 总被引：28，自引：3，他引：28
色谱和色谱／质谱分析表明，济州鸟西南泥质区正构烷烃、姥鲛烷、植烷、藿烷和甾烷等生物标志物的特征与现代长江口、老黄河口和新黄河口的河流沉积物均区别很大，该泥质区的沉积有机质主要来源于海洋低等生物（如细菌和藻类等）以及陆源高等植物的输入，表现为不同来源和成熟度的生物标志物的混合，同时该泥质区沉积有机质与矿物碎屑沉积物来源不尽相同。长江口泥质区正构烷烃高相对分子质量部分与长江口沉积物相似，正构烷烃和藿烷所反映的有机质成熟度高于现代长江和老黄河口沉积物，甾烷的成熟度与长江相仿而明显高于老黄河口沉积物。长江口泥质区的沉积有机质主要来源于长江输入的陆源高等植物碎片和海洋源的低等生物。东海陆架近岸与远端泥质区沉积有机质的物源很不相同。 相似文献
17.
南海北部古俯冲带的位置及其对南海扩张的控制 总被引：3，自引：0，他引：3
为了确定南海北部古俯冲带的具体位置,作者利用美国LCT综合反演软件对收集到的重磁数据进行处理解释,结果显示在南海北部从台湾西南部到一统暗沙隆起,即沿南海海盆北部陆坡为一条布格重力异常水平梯度峰值带,指示了古俯冲带的具体位置;其北部的高磁异常代表了与之对应的古火山弧。深反射地震资料也验证了南海北部陆坡位置存在古俯冲带,钻井资料显示俯冲带存在的时代为晚侏罗世到早白垩世。据此绘制了南海地区晚中生代到现今的构造古地理演化图,指出南海的扩张应与晚中生代俯冲带这个先存的软弱带有关,南海海盆正是从古俯冲带的位置开始扩张。 相似文献
18.
Farooq Azam Grieg F. Steward David C. Smith Hugh W. Ducklow 《Journal of Earth System Science》1994,103(2):341-351
In the Arabian Sea, temporal contiguity of highly oligotrophic and eutrophic periods, along with high water temperatures,
may result in unique features of bacteriaorganic matter coupling, nutrient cycling and sedimentation, which are unlike those
in the classical oligotrophic and eutrophic waters. Bacteria-phytoplankton interactions are suggested to influence phytoplankton
aggregation and its timing. It is also hypothesized that, within aggregates, hydrolytic ectoenzyme activity, together with
condensation reactions between the hydrolysis products, produce molecular species which are not readily degraded by pelagic
bacteria. Accumulation of a reservoir of such slow-to-degrade dissolved organic carbon (DOC) is proposed to be a carbon flux
and energy buffer, which moderates the response of bacteria to the dramatic variations in primary production in the Arabian
Sea. Use of the slow-to-degrade DOC pool during the intermonsoon could temporarily render the Arabian Sea net-heterotrophic
and a source of CO2 to the atmosphere. Stored DOC is also suggested to balance the observed deficit between mesopelagic carbon demand and the
sinking particulate organic carbon supply. Knowledge of the significance of bacteria in carbon storage and cycling in the
Arabian Sea is needed to understand the response of the ocean’s biogeochemical state to strong physical forcing and climate
change. 相似文献
19.
Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters 相似文献
20.
In order to investigate how monsoons influence biogeochemical fluxes in the ocean, twelve time-series sediment traps were
deployed at six locations in the northern Indian Ocean. In this paper we present particle flux data collected during May 1986
to November 1991 and November 1987 to November 1992 in the Arabian Sea and Bay of Bengal respectively. Particle fluxes were
high during both the SW and NE monsoons in the Arabian Sea as well as in the Bay of Bengal. The mechanisms of particle production
and transport, however, differ in both the regions.
In the Arabian Sea, average annual fluxes are over 50gm-2y-1 in the western Arabian Sea and less than 27gm-2 y-1 in the central part. Biogenic matter is dominant at sites located near upwelling centers, and is less degraded during peak
flux periods. High particle fluxes in the offshore areas of the Arabian Sea are caused by injection of nutrients into the
euphotic zone due to wind-induced mixed layer deepening. In the Bay of Bengal, average annual fluxes are highest in the central
Bay of Bengal (over
50gm-2y-1) and are least in the southern part of the Bay (37gm-2y-1). Particle flux patterns coincide with freshwater discharge patterns of the Ganges-Brahmaputra river system. Opal/carbonate
and organic carbon/carbonate carbon ratios increase during the SW monsoon due to variations in salinity and productivity patterns
in the surface waters as a result of increased freshwater and nutrient input from rivers.
Comparison of S years data show that fluxes of biogenic and lithogenic particulate matter are higher in the Bay of Bengal
even though the Arabian Sea is considered to be more productive. Our results indicate that in the northern Indian Ocean interannual
variability in organic carbon flux is directly related to the strength and intensity of the SW monsoon while its transfer
from the upper layers to the deep sea is partly controlled by input of lithogenic matter from adjacent continents. 相似文献