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1.
Discharge of heavy metals from metal processing industries is known to have adverse effects on the environment. Biosorption of heavy metals by metabolically inactive biomass of microbial organisms is an innovative and alternative technology for removal of these pollutants from aqueous solution. The search of marine actinobacteria with potential heavy metal biosorption ability resulted in the identification of a novel alkalophilic Streptomyces VITSVK5 species. The biosorption property of Streptomyces VITSVK5 spp. was investigated by absorbing heavy metals Cadmium (Cd) and Lead (Pb). Physiochemical characteristics and trace metal concentration analysis of the backwater showed the concentrations of different metals were lead 13±2.1 μg L−1, cadmium 3.1±0.3μg L−1, zinc 8.4±2.6μg L−1 and copper 0.3±0.1μg L−1, whereas mercury was well below the detection limit. The effect of pH and biomass dosage on removal efficiency of heavy metal ions was also investigated. The optimum pH for maximal biosorption was 4.0 for Cd (II) and 5.0 for Pb (II) with 41% and 84% biosorption respectively. The biosorbent dosage was optimized as 3 g L-1 for both the trace metals. Fourier transform infrared absorption spectrum results indicated the chemical interactions of hydrogen atoms in carboxyl (-COOH), hydroxyl (-CHOH) and amine (-NH2) groups of biomass with the metal ions. This could be mainly involved in the biosorption of Cd (II) and Pb (II) onto Streptomyces VITSVK5 spp. The results of our study revealed Streptomyces metabolites could be used to develop a biosorbent for adsorbing metal ions from aqueous environments.  相似文献   

2.
This study investigated the removal of heavy metal ions from cigarette mainstream smoke using chitosan. Chitosan of various deacetylation degrees and molecular weights were manually added to cigarette filters in different dosages. The mainstream smoke particulate matter was collected by a Cambridge filter pad, digested by a microwave digestor, and then analyzed for contents of heavy metal ions, including As(III/V), Pb(II), Cd(II), Cr(III/VI) and Ni(II), by graphite furnace atomic absorption spectrometry (GFAAS). The results showed that chitosan had a removal effect on Pb(II), Cd(II), Cr(III/VI) and Ni(II). Of these, the percent removal of Ni(II) was elevated with an increasing dosage of chitosan. Chitosan of a high deace tylation degree exhibited good binding performance toward Cd(II), Cr(III/VI) and Ni(II), though with poor efficiency for Pb(II). Except As(III/V), all the tested metal ions showed similar tendencies in the growing contents with an increasing chitosan molecular weight. Nonetheless, the percent removal of Cr(III/VI) peaked with a chitosan molecular weight of 200 kDa, followed by a dramatic decrease with an increasing chitosan molecular weight. Generally, chitosan had different removal effects on four out of five tested metal ions, and the percent removal of Cd(II), Pb(II), Cr(III/VI) and Ni(II) was approximately 55%, 45%, 50%, and 16%, respectively. In a word, chitosan used in cigarette filter can remove toxic heavy metal ions in the mainstream smoke, improve cigarette safety, and reduce the harm to smokers.  相似文献   

3.
Lead(Pb) and its compounds are common pollutants in industrial wastewaters.To develop appropriate Pb 2+ treatment technologies,aerobic granules(AG) and bacterial alginates(BA) were studied as alternative biosorbents to remove Pb 2+ from aqueous solutions.The biosorption mechanism of AG and BA were further analyzed to determine which functional groups in AG and BA are active in Pb 2+ biosorption.In this paper,the Pb 2+ biosorption behavior of AG and BA was respectively investigated in batch experiments from the perspectives of the initial pH,contact time,and initial Pb 2+ concentration.The results showed that biosorption of Pb 2+ by AG and BA occurred within 60min at the initial Pb 2+ concentrations(0 150 mg L-1).The actual saturated Pb 2+ biosorption capability of AG was 101.97 mg g-1(dry weight of aerobic granular biomass).When the initial pH was 5,the biosorption capability of AG and BA was highest at the initial Pb 2+ concentrations(0 20mg L-1).During the process of Pb 2+ biosorption,K +,Ca 2+,and Mg 2+ were released.The Ion Chromatography(IC) and Fourier Transform Infrared Spectroscopy(FTIR) further highlighted the main role of ion exchange between Ca 2+ and Pb 2+ and sequestration of Pb 2+ with carboxyl(-COO) of AG and BA.This analogical analysis verifies that BA is responsible for biosorption of Pb 2+ by AG.At the same optimal pH,AG cultivated with different carbon source has different Pb 2+ biosorption capacity.The Pb 2+ biosorption by AG with sodium acetate as the sole carbon source is higher than AG with glucose as carbon source.  相似文献   

4.
There are rising concerns about the hazardous effects of heavy metals on the environment. In this study, comet assay and DNA alkaline unwinding assay were conducted on the tissues (gills, hepatopancreas, and hemocytes) of Charybdis japonica in order to illustrate genotoxicity of three heavy metal ions (Cu2+, Pb2+, and Cd2+) on the marine crabs C. japonica. The crabs were exposed to Cu2+ (10, 50, and 100 ?g.L?1), Pb2+ (50, 250, and 500 ?g L?1) and Cd2+ (5, 25, and 50 ?g L?1), and the tissues were sampled at days 0.5, 1, 3, 6, 9, and 15. DNA alkaline unwinding assay was used for testing the DNA single strand break in gills and hepatopancreas and comet assay was employed for testing the DNA damage in hemocytes. The results showed that the DNA damage (F-value) of gills in the crabs exposed to the three heavy metals was decreased gradually during the exposure periods and there was a dose-time response relationship in certain time, suggesting that the levels of DNA single strand break in all the experimental groups increased significantly compared to the controls. Changes of F-value in hepatopancreas of the crabs exposed to the three heavy metals were similar to those in gills except that the peak values were found in the 500 ?g L?1 Pb2+ treatment group at day 3 and the 50 ?g L?1 Cd2+ treatment group at day 9. The ranks of DNA damage in gills and hepatopancreas induced by the three heavy metal ions (50 ?g L?1, day 15) were Cd2+ >Pb2+ >Cu2+ and Pb2+ >Cu2+ >Cd2+. The levels of DNA damage in gills were higher than those in hepatopancreas in the same experimental group. It can be concluded that indices of DNA damage can be used as the potential biomarkers of heavy metal pollution in marine environment.  相似文献   

5.
Historical records of metal inputs were studied by using a sediment core collected from a sand-rich mudflat in the Qinjiang River estuary, China. 210Pb chronology was used to reconstruct the fluxes of Hg, Cu, Pb, Zn, Cd, Cr and As to the core site during the last 86 years. Based on the constant initial concentration model, the sedimentation rates are 1.18 cm year-1 in the top 30 cm sandy layer and 0.92 cm year-1 in the muddy bottom layer. To compensate for grain-size and mineralogy effects on metal concentra-tions, aluminum was used as the normalizing element. The enrichment factors (EF) indicate that the natural inputs had prevailed up to the early 1980s. After this period, the intensity of human activities has resulted in continual increasing trend of metals towards the surface. Recent sediment samples from the Qinjiang River estuary are found moderately enriched by Cd (EF>1.5) and slightly enriched by other metals (EF<1.5). Considering that the drainage area of the Qinjiang River is mostly agricultural land, the increased Cd may be due to the usage of fertilizers and pesticides in agricultural activities and the combustion of fossil fuels.  相似文献   

6.
Rainwater samples were collected in series in Qianliyan Island (southern Yellow Sea) and Shengsi Archipelago (East China Sea) between May 2000 and May 2002, chemical analysis for pH values,concentrations of heavy metals (Cu, Pb, Zn and Cd) and nutrients (NH4^-, NO3^-, PO43^-, SiO32^-) were performed.Results indicate that concentrations of most of the heavy metals and nutrients in rainwater show clear seasonal variation, i.e. high level in winter and low level in summer. Regionally, concentrations are higher in the southern Yellow Sea than in the East China Sea, but the annual input of heavy metals into oceans by wet deposition is similar in both stations. However, the input of nutrients by wet deposition in the East China Sea is 2-3 times higher than that in the southern Yellow Sea. In individual, Pb and PO4^3- are input to the sea mainly by dry deposition; whereas Cu, Zn, Cd and N compounds are input dominantly by wet deposition, the N/P ratios in the rainwater from two stations are much higher than those in seawater, showing a significant impact of atmospheric wet deposition on marine production and biogeochemical circulation of nutrients in these sea regions.  相似文献   

7.
A cruise was undertaken from 3rd to 8th November 2004 in Changjiang （Yangtze） River Estuary and its adjacent waters to investigate the spatial biomass distribution and size composition of phytoplankton. Chlorophyll-a （Chl-a） concentration ranged 0.42-1.17 μg L^-1 and 0.41-10.43 μg L^-1 inside and outside the river mouth, with the mean value 0.73 μg L^-1 and 1.86 μg L^-1, respectively. Compared with the Chl-a concentration in summer of 2004, the mean value was much lower inside, and a little higher outside the river mouth. The maximal Chl-a was 10.43 μg L^-1 at station 18 （122.67°E, 31.25°N）, and the region of high Chl-a concentration was observed in the central survey area between 122.5°E and 123.0°E. In the stations located east of 122.5°E, Chl-a concentration was generally high in the upper layers above 5 m due to water stratification. In the survey area, the average Chl-a in sizes of 〉20 μm and 〈20 μm was 0.28 μg L^-1 and 1.40 μg L^-1, respectively. High Chl-a concentration of 〈20 μm size-fraction indicated that the nanophytoplankton and picophytoplankton contributed the most to the biomass of phytoplankton. Skeletonema costatum, Prorocentrum micans and Scrippsiella trochoidea were the dominant species in surface water. The spatial distribution of cell abundance of phytoplankton was patchy and did not agree well with that of Chl-a, as the cell abundance could not distinguish the differences in shape and size of phytoplankton cells. Nitrate and silicate behaved conservatively, but the former could probably be the limitation factor to algal biomass at offshore stations. The distribution of phosphate scattered considerably, and its relation to the phytoplankton biomass was complicated.  相似文献   

8.
根据2011年7月浙江舟山西蟹峙海洋倾倒区及邻近海域表层沉积物重金属的监测结果,采用单因子指数法和Hakanson生态危害指数法分析表层沉积物重金属的污染特征,并评价其潜在生态风险。结果表明:沉积物重金属元素Cu、Zn、Pb、Cd、Cr、Hg、As含量均符合国家海洋沉积物质量一类标准;重金属元素污染程度由高到低依次为Zn、Cr、Pb、Cu、As、Cd、Hg,其中Cu、Pb、Cd、Hg和As 5种重金属元素为低污染水平,Zn和Cr 2种重金属元素为中等污染程度水平;7种重金属元素单个和综合潜在生态危害程度均为低风险水平,由高到低依次为Cd、Hg、As、Pb、Cu、Cr、Zn。  相似文献   

9.
A new kinetic spectrophotometric method has been developed for the determination of trace Ni (II) in natural water.The method is based on the catalytic effect of Ni (II) on the oxidation of weak acid brilliant blue dye (RAWL) by KIO4 in acid medium.The concentration of nickel (II) can be determined spectrophotometrically by measuring the decrease of absorbance of RAWL at λ= 626 nm using the fix-time method.The influencing factors are investigated by the orthogonal experimental design.The obtained optimum analytical conditions are:pH=2.00,c RAWL=5.00×10-5 mol L-1,cKIO 4= 2.00×10-5 mol L-1,the reaction time t=10 min and the temperature T=25℃..Under the optimum conditions,the developed method allows the measurement of Ni (II) in a range of 0-40.0 ng mL-1.The standard deviation of eleven independent measurements of blank reaction is S=3.08×10-3 and the limit of detection is 2.20 ng mL-1.The relative standard deviations (RSDs) in six replicate determinations of 5 ng mL-1 and 8 ng mL-1 Ni (II) are 2.87% and 1.11%,respectively.Moreover,the experiments show few cations and anions can interfere with the measurement of Ni (II).The recovery efficiencies of this method are in a range of 97.0%-102.5% in freshwater samples.But there is a decreasing effect,which is about 0.2 times the added Ni (II) in seawater medium.After reasonable calibration this processing method is used for the determination of Ni (II) in seawater samples successfully.The results show this developed method has high accuracy and precision,high sensitivity,large range of linearity and high speed.The method can,therefore,be employed at room temperature.  相似文献   

10.
SYNTHESIS AND PROPERTIES OF SULFHYDRYL CHITOSAN   总被引：1，自引：0，他引：1  
A new adsorbent for heavy metal ions, sulfhydryl chitosan (S-chitosan), was produced by treatment of chitosan with sulhydryl acetic acid in the presence of sulfuric acid as a catalyst. Its structure was confrrmed by elemental analysis and FI‘-IR spectra analysis. The adsorption properties of sulthydryl chitosan for Cu(Ⅱ ), Cd(Ⅱ ), Pb(Ⅱ), Cr(Ⅲ) and Ni(Ⅱ) were investigated, and the effect of pH value on adsorption, adsorption kinetics, and selective adsorption was examined. It was shown that S-chitosan has good adsorption for Pb(Ⅱ), Cu(Ⅱ) and Cd(Ⅱ) like chitosan, is also insoluble in acid solution; has good adsorption kinetic properties for heavy metal ions; and can be used in acid solution. The adsorption capacities of S-chitosan can be affected by media acidity. The adsorbed Cu(Ⅱ) Cd(Ⅱ) and Pb(Ⅱ) could be eluted by diluted chlorhydric acid.  相似文献   

11.
Heavy metal is a main pollutant in the marine ecosystem, so study on the effect of heavy metal on phytoplankton is important. Algae (Chaetoceros sp.,Dunaliella sp.,Dicrateria zhanjiangenis Hu. var. sp.) were laboratory cultured to observe the effect of heavy metals on their growth. The effect of different metal ion concentration, the detoxication effect of complexation agents and the growth of algae in different media and different nutrition levels were studied to evaluate the effect of metal speciation. It is proved that trace amount of heavy metals can stimulate the growth of algae cells but that high concentration is lethal. The sequence of toxicity is Cd2+>Zn2+>Pb2+. In ordinary nutrition conditions, the detoxication sequence of complexation agents toChaetoceros sp. is EDTA >sodium salicylate>sodium oxalate >sodium citrate>sulfanilic acid>O-phenanthroline. This is in good conformity with the stability constant sequence of these agents with copper and good evidence that toxicity of metal ion is related to its activity and not to its total concentration. Project supported by the Fund of Excellent Young Teachers of State Educational Commission of China.  相似文献   

12.
Twenty-nine samples of surface sediments from tidal flats in the Northern Shandong Province were collected for grain size, heavy metal(Hg, Cu, Pb, Zn, Cd, and Cr), and oil pollution analyses. The geoaccumulation index(Igeo) and factor analysis were introduced to evaluate sediment quality and source of contaminants. The mean concentrations of Hg, Cu, Pb, Zn, Cd, Cr, and oil in the surface sediments in the study area are 0.033, 17.756, 19.121, 55.700, 0.291, 59.563, and 14.213 μg g-1, respectively. The heavy metal contamination in the old delta lobe is slightly higher than that in the abandoned delta lobe; however, the opposite was observed for oil pollution. The Igeo results revealed that the overall quality of the surface sediments in the study area is in good condition. The heavy metal pollution levels show a descending order: Cd Hg Cr Cu Zn Pb, Cd being the main pollutant. The contamination level for in the study area is relatively lower than those for China's other tidal flats. Heavy metals are mainly derived from natural sources of rock weathering and erosion, partly influenced by industrial and agricultural discharge. However, oil pollution is mainly from runoff input, motorized fishing boat sewage, and oil exploitation.  相似文献   

13.
Accumulation and distributions of aliphatic and polyaromatic hydrocarbons (PAHs) and heavy metals were measured in tissues of the clam Ruditapes philippinarum collected from 5 sites in Jiaozhou Bay, Qingdao, China. The concentrations of total aliphatic hydrocarbon and PAHs ranged from 570 to 2 574 ng/gdw (gram dry weight) and from 276 to 939 ng/gdw, in the most and least polluted sites, respectively. The bio-accumulation of hydrocarbons and PAHs in the clams appeared to be selective. Aliphatic hydrocarbons were predominantly represented by short chain (<nC23) n-alkanes, suggesting that petroleum hydrocarbons were likely the major contamination source. The selective uptake of 3 and 4 ring PAHs, such as naphthalene, fluorene, phenanthrene, fluoranthene and pyrene, by the clams was probably related to the physiological and bio-kinetic processes that were energetically favorable for uptake of compounds with fewer rings. Accumulation of the metals Cd, Cu, Zn, Pb, Cr, Hg, and As in the clam tissues also showed high variability, ranging from 0.043 to 87 μg/gdw. Among the 7 detected metals, Zn, Cd, Cu, and As had a particularly high potential of accumulation in R. philippinarum. In general, a positive correlation was found between the tissue concentrations and sediment concentrations of hydrocarbons and of some metals. Our study suggests that moderate contamination with polyaromatic hydrocarbons, and low to moderate contamination with metals, currently exists for clam R. philippinarum in Jiaozhou Bay, in comparison with other regional studies. A long-term monitoring program is certainly needed for assessment of the potential ecological influence and toxicity of these contaminants of R. philippinarum in Jiaozhou Bay.  相似文献   

14.
Scales of the Lake Anchovy in Taihu Lake are used as a basis for its age determination. Annual variation of scale edge growth rate (α) indicates that the annulus forms once a year, mainly in April–June. The relationship formula for body length and scale diameter is L=18.658+118.06R, that for body length and weight isW♀=7.588×10−6 L 2.8301;W♂=5.584×10−6 L 2.8781. The fish before age II have a higher relative growth rate in body length and weight and a higher growth index. Growth is consistent with the growth equation by Von Bertalanffy. The turning point of the body weight growth curve is located between age II and III; the exact position is atW=0.292W ∞. Variation specificity of the growth course can be reflected by the growth rate and its acceleration curves. Time for capture of the fish should preferably be after age II, when they have reached a body length of 170 mm. That is one of the key measures to increase Lake Anchovy production in Taihu Lake.  相似文献   

15.
A new kinetic-spectrophotometric method is proposed for the determination of copper （ Ⅱ ）. The method is based on the catalytic effect of copper （ Ⅱ ） on the oxidation of weak acid brilliant blue dye （RAWL） by hydrogen peroxide. The copper （ Ⅱ ） can be determined spectrophotometrically by measuring the decrease of absorbance of RAWL at λ = 626 nm using the fix-time method. The optimum reaction conditions are as follows： pH 7.20, buffer solution NaOH-KH2PO4, RAWL （200 mgL-1） 5.00 mL, H2O2 （30%） 0.50 mL, reaction temperature 80 ？？ and reaction time 20 min. The linear range of this method is between 0 μg L^-1 and 12 μg L^-1 and the limit of detection is 0.011 μg L-1, the relative standard deviation （RSD） in five replicate determinations for 2 and 8 μg L-1 copper （ Ⅱ ） are 3.2% and 2.3%, respectively. Twenty ions do not interfere in the determination of copper （ Ⅱ ）. The method has been applied satisfactorily to the determination of copper （ Ⅱ ） in freshwater samples （tap water and Yellow River water from Lijin, Shandong, China） and seawater samples （from the South China Sea）, the recovery rates are 98.0%, 102.5% and 96.0%, respectively.  相似文献   

16.
In this study, the ability of macroalgae Gracilaria sp. of removing eutrophication factors and toxic heavy metals Al, Cr, and Zn in a closed cultivation system is reported. The results show that the concentration of the three heavy metals decreased significantly during the experimental period in an algal biomass dependent manner. The biofiltration capacity of the alga for Al, Cr, and Zn is 10.1%–72.6%, 52.5%–83.4% and 36.5%–91.7%, respectively. Using more materials resulted in stronger heavy metal removal. Additionally, the concentration of chl-a, TN, TP and DIN of water samples from aquariums involving large, medium, and small algal biomass cultivation increased first and then decreased during the experiment. COD value of all three groups decreased with time and displayed algal biomass dependency: more algae resulting in a greater COD value than those of less biomass. Furthermore, changes in COD reflect an obvious organic particles deprivation process of algae. This is the first report on heavy metal removal effect by Gracilaria species. The results suggest that macroalgae can be used as a biofilter for the treatment of nutrient-enriched or heavy-metal polluted water, to which an appropriate time range should be carefully determined.  相似文献   

17.
以山东省济南市章丘区北部表层土壤中As等8种重金属元素为研究对象,利用多元统计进行重金属来源分析,采用污染负荷指数法及潜在生态危害指数法进行污染评价,结果表明:研究区表层土壤重金属元素含量低于济南市土壤背景值,Cd和Hg元素含量为强度变异,在表层土壤产生一定的富集;不同土地利用类型下重金属元素含量具有差异性。土壤中Cr,Cu,Ni和Zn来源于土壤母质,Cd和Pb元素来源于人类活动,As元素来源复杂。土壤综合污染以轻度污染为主,重金属元素污染程度大小为AsNiPbZnCrCuCdHg。综合潜在生态风险以轻微和中度为主,潜在生态风险强弱程度为HgCdAsCuPbNiCrZn,建议防范Hg和Cd元素污染及生态风险。  相似文献   

18.
The southern sea area of the Huludao City, Liaoning Province might be polluted by heavy metals because it is close to the Jinzhou Bay, one of the heaviest sea area polluted by heavy metals in China. The undisturbed modern sediment core can be used to analyze the accumulation and source of the pollutants using 137 Cs and 210 Pb ex . Thirty-five samples of surface sediment and two core sediments were collected from the southern sea area of Huludao City. The concentrations of copper (Cu), lead (Pb), chrome (Cr), zinc (Zn), arsenic (As) and mercury (Hg) in the surface sediments as well as Cu, Pb, Zn, Cr, 137 Cs and 210 Pb ex in the core sediments were determined to research the spatial distribution and accumulation characteristics, and to analyze the sources and the potential risks of heavy metals. The results show that the pollution levels of Zn and Hg are serious, and 26 stations are at moderate or heavy ecological risks. The concentrations of the heavy metals increase from east to west, as well as from open sea to offshore marine area. The concentrations of heavy metals are not high in the sediments adjacent to the Jinzhou Bay, and the influence caused by the seawater exchange with the Jinzhou Bay is little. The concentrations of the heavy metals in the core sediments show low-high-low characteristic, and it coincides with the pollution history of Huludao City. The atmospheric deposition of heavy metals from the Huludao Zinc Plant is likely to be the main source of pollution without direct discharge of wastewater. The high concentrations of heavy metals appear on the upper sediment of 20 cm. The shallow sediment with high heavy metal contents might be exposed to surface when it was disturbed by the ocean engineering and big storm surge, then cause risk to the safety of aquaculture and human healthy.  相似文献   

19.
The sea fluxes of trace metals, POC, and settled material were studied in anoxic seawater, Saanich Inlet, B. C., Canada with sediment traps. This paper discusses the change of mass fluxes of sediment, trace metals and POC for various seasons and depths. The annual mean of settled material is 1.56 g.m−2.a−1, 84.6 mg. m−2.a−1 for POC, 60.0 mg. m−2.a−1 for Cu, 16.5 mg.m−2.a−1 for Pb, 189 mg.m−2.a−1 for Zn, 2.20 mg.m−2.a−1 for Cd, 699 mg.m−2.a−1 for Fe, 38.8 mg.m−2.a−1 for Co, and 84.6 mg.m−2.a−1 for Ni. The relations between the average fluxes of trace metals and POC, the fluxes of trace metals and settled matter, and the sea fluxes of trace metals and Fe are in linear progression. The resident times of elements as calculated from sea flux, are 1.1 a. for Cu, 0.014 a. for Pb, 0.50 a. for Zn, 3.8 a. for Cd, 0.16 a. for Fe, 0.39 a. for Co, and 1.14 a. for Ni. The order of resident times is as follows: Pb−Fe−Co−Zn−Cu−Ni−Cd. The metal resident times in Saanich Inlet are shorter than the values estimated for the open ocean. It illustrates that the biochemical processes in shallow Saanich Inlet are faster than those in the open ocean, and that debries of plankton and fecal pellets of zooplankton play an important role in vertical transport of organic carbons. Contribution No. 1650 from the Institute of Oceanology, Academia Sinica.  相似文献   

20.
农用地土壤中7种重金属可提取态的测定   总被引：1，自引：0，他引：1       下载免费PDF全文
该文以氯化钙溶液进行提取,采用电感耦合等离子体质谱法和原子荧光光谱法,测定农用地土壤中Cd,As,Pb,Cr,Cu,Zn,Ni等7种重金属可提取态,检出限在0.003~0.06 mg/kg之间。该方法用于4个可提取态质控样品的测定,测定值与推荐值基本相符,测定的相对标准偏差(n=8)在3.3%~9.1%之间。基于800余件农用地土壤样品的测定数据,对7种重金属可提取态与土壤pH值及重金属总量之间的关系进行了初步考察。结果表明,7个重金属可提取态和总量关系无明显相关性,仅在土壤酸性条件下可提取态Cd与总量Cd呈正相关性。7种重金属提取率大小顺序为Cd>Zn>Ni>Cu,As>Pb>Cr,其中Cd,Zn,Ni,Cu,Pb的提取率随土壤pH值的增大而迅速下降,而As,Cr在土壤碱性条件下的提取率略高于中酸性条件下的提取率。  相似文献   

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