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1.
Triassic pisolites from the Calcare Rosso, Lombardy, Italy, were formed in a hypersaline vadose environment and now show alternating dolomite and calcite laminae. The calcite consists either of microsparite laminae with a brick-like fabric, or of a mass of mosaic crystals with the external form of square-ended rays.These features suggest that the original laminae and rays were aragonitic, like those of the Holocene supratidal pisolites of the Persian Gulf, which consist of alternating laminae of unoriented nannomicrite with Mg-rich mucilaginous material, and aragonitic fibers with radial orientation separated by mucilaginous films. It is suggested that the transformation to brick-like and ray textures passed through the following diagenetic path: (1) original formation of fibrous aragonite laminae; (2) local aggrading recrystallization of aragonite fibers to large square-ended rays during hypersaline phases; (3) dolomitization of Mg-rich mucilaginous nannomicrite laminae during hyposaline phases; (4) inversion of the aragonite fibers and rays to calcite on a piece-by piece basis that preserved the original textural details, when the pH or Mg/Ca ratio dropped.The brick-like and ray fabrics have not been found in laminae of continental freshwater pisolites because these were deposited as equant and stable crystals of low-Mg calcite. These textures consequently make it possible to establish the chemistry of the depositional and early diagenetic milieu for some ancient pisolitic rocks.  相似文献   

2.
Holocene stromatolites are described from Lake Walyungup, a coastal hyposaline lake in south-western Australia. At summer low water, this groundwater-fed depression comprises two permanent shallow water bodies and an ephemeral southern pool, set within an areally extensive littoral zone of variably cemented carbonate crust. Up to 5 m of organic-rich carbonate mud has been deposited within each of these basins in less than 7000 years. Stromatolites rim the water bodies with individual columns up to 2 m tall. Stromatolite-capped tepee structures in subparallel alignment are widespread in the littoral crust, suggesting a linkage between stromatolite growth and zones of groundwater discharge. Lake Walyungup stromatolites, regardless of external morphology and setting, are coarsely laminated and have aragonitic mesoclot microfabrics. These microfabrics are similar to those from lithified portions of active thrombolitic microbialites from nearby Lake Clifton. Hydromagnesite is a minor to subdominant phase (up to 47 wt%) of the carbonate mineral assemblage in Lake Walyungup. It occurs mainly in the littoral zone as a diagenetic replacement of precursor aragonite, particularly within the mesoclot fabric of stromatolites, but also in sediments (strandline and dune sand, crusts) derived mainly from erosion of stromatolites. In contrast with nonreplaced and impermeable inorganic aragonitic cements, stromatolite mesoclots are microper- meable. Micropermeability is inferred to facilitate hydromagnesite diagenesis. Dolomite is also present in minor amounts as a pore fill in stromatolites, and as a subdominant to dominant (up to 100 wt%) phase in thin, mudcracked micrite layers within the crust package. The layered dolomite may be precipitated directly from the lake water. Major element abundance of the lake water is: Na+ > Mg2+ » K+ > Ca2+ for cations, and Cl? » SO42? ≈ HCO3? > CO32? for anions. Compared to other nearby coastal lakes, Lake Walyungup has a high pH (> 9·0), and an extremely high molar Mg/Ca ratio of > 90. Groundwater in the area has a Mg/Ca ratio generally less than 1. The unusual Mg/Ca ratio in Lake Walyungup is partially a result of in-lake processes with additional minor contribution of Mg2+ sourced from basal marine sand because no Mg-rich bedrock source has been found in the region.  相似文献   

3.
中国豫西寒武系馒头组叠层石的沉积特征及其古环境意义   总被引：1，自引：0，他引：1  
中国豫西寒武系馒头组一、二段共出露9层叠层石,占寒武纪18层叠层石中的50%,且其特征明显、形态多样,可分为圆柱状、波状、半球状和围绕竹叶状砾屑灰岩生长的叠层石等4大类8小类。本文在逐层分析豫西寒武系馒头组一、二段叠层石相序特征的基础上,通过对不同类型叠层石的宏观、中观形态特征及伴生的其它沉积特征进行详细描述,并以巴哈马Highborne Cays现代海相叠层石的生长环境和前寒武纪叠层石的沉积环境等为佐证,建立了豫西寒武系馒头组8小类11种不同叠层石的沉积环境分布模式,其中潮上带以近水平状叠层石为主,少量为缓波状、小柱状和含水平状薄泥层的叠层石;潮间带上部以缓波状、小柱状和含水平状薄泥层的叠层石为主,少量锥柱状叠层石;潮间带中部以圆柱状叠层石为主,含扁平状核形石和竹叶状砾屑,少量为锥柱状和围绕竹叶状砾屑生长的叠层石;潮间带下部至潮下带以含圆形核形石的圆柱状和半球状叠层石为主,少量含核形石的倒锥状叠层石。海平面的变化即水动力条件是叠层石生长类型变化的决定因素。  相似文献   

4.
Laminated cryptalgal carbonates occur in the Precambrian Copper Harbor Conglomerate of northern Michigan, which was deposited in the Keweenawan Trough, an aborted proto-oceanic rift. This unit is composed of three major facies deposited by braided streams on a large alluvial-fan complex. Coarse clastics were deposited in braided channels, predominantly as longitudinal bars, whereas cross-bedded sandstones were deposited by migrating dunes or linguoid bars. Fine-grained overbank deposits accumulated in abandoned channels. Gypsum moulds and carbonate-filled cracks suggest an arid climate during deposition. Stromatolites interstratified with these clastic facies occur as laterally linked drapes over cobbles, as laterally linked contorted beds in mudstone, as oncolites, and as poorly developed mats in coarse sandstones. Stromatolites also are interbedded with oolitic beds and intraclastic conglomerates. Stromatolitic microstructure consists of alternating detrital and carbonate laminae, and open-space structures. Radial-fibrous calcite fans are superimposed on the laminae. The laminae are interpreted as algal in origin, whereas the origin of the radial fibrous calcite is problematic. The stromatolites are inferred to have grown in lakes which occupied abandoned channels on the fan surface. Standing water on a permeable alluvial fan in an arid climate requires a high water table maintained by high precipitation, or local elevation of the water table, possibly due to the close proximity of a lake. Occurrence of stromatolites in the upper part of the Copper Harbor Conglomerate near the base of the lacustrine Nonesuch Shale suggests that these depositional sites may have been near the Nonesuch Lake.  相似文献   

5.
Manganese-rich encrustations along the modern shoreline of the Dead Sea are of three kinds: (a) Black laminae, ranging in thickness from 0.1 mm to 4 mm, alternating with aragonite layers which form continous hard crusts on pebbles and boulders (b) Thin black laminae in laminated muds found in very shallow waters. (c) Thin black laminae, alternating with aragonite and gypsum, surrounding partially submerged tree trunks.

No identifiable X-ray diffraction pattern was obtained in the black layers. SEM studies revealed discrete, shapeless manganese-rich aggregates embedded in an aragonitic matrix. The black laminae consist of approximately 75% aragonite, 15% insoluble residue (mostly quartz), and about 10% manganese-rich fraction. Chemical analyses of the isolated manganese-rich fraction gave up to 50% manganese, and less than 1% iron.

Profiles of dissolved manganese in interstitial water show a two-fold enrichment of manganese as compared with the overlying water, with a particularly high concentration (18 mg/l) at the sediment—water interface. This is interpreted to be due to release of manganese from solid phases in the reduced sediments, and upward migration of dissolved manganese in interstitial water, and oxidation to insoluble tetravalent manganese at the interface with the oxygen-containing water.

The manganese-rich crusts were formed below the water table and were deposited no later than 350 years and possibly sooner.  相似文献   


6.
Carbonate-dominant sediments are currently forming and accumulating over the extensive marine shelf of the passive margin of southern Australia. A dearth of continental detritus results from both a very low relief and a predominantly arid climate. The wide continental shelf is bathed by cold upwelling ocean waters that support luxuriant growths of bryozoans and coralline algae, together with sponges, molluscs, asteroids, benthic and some planktonic foraminifera. The open ocean coast is battered by a persistent southwest swell, resulting in erosion of calcrete-encrusted Pleistocene eolianites. Much sediment is reworked and overall shelf sedimentation rates are low. High-energy microtidal beach/dune systems occur between headlands and along the very long ocean beach in the Coorong region. The northern, more arid coastal areas also contain saline lakes that precipitate gypsum from infiltrated sea water, and display marginal facies of aragonite boxwork to fenestral carbonate crusts, with stromatolites and tepee structures. In contrast, the southern, seasonally humid Coorong region, has a predominantly continental groundwater regime where sulphate is rare, and the high summer evaporation precipitates dolomite, magnesite and aragonite muds. Fenestral crusts, breccias, tepees and some stromatolites are also present.

St. Vincent and Spencer gulfs both afford some protection from ocean swell, but tidal amplitude and currents increase, and a depth and inundation-related zonation of plants and animals is established. Muddy carbonate sand accumulates on the sea floor below 30 m, where filter-feeding bryozoans, bivalves and sponges dominate. In shallower regions, seagrass meadows contain a rich fauna that results in rapid accumulation of an unsorted muddy bioclastic sand. Mangrove woodlands backed by saline marsh with cyanobacterial mats are common, and accumulate mud-rich and gastropod-bearing sediment. As tidal amplitude and desiccation increase northward into both gulfs, a supratidal zone bare of vegetation (sabkha) becomes the site for deposition of gypsum-rich and fenestral calcitic mud.  相似文献   


7.
一、引言自从Ginsburg(1955)及Logan等(1961,1964)研究了巴哈马、佛罗里达和西澳大利亚的现代藻叠层石以来,已经建立了用藻叠层石的形态和构造来解释现代或古代海洋沉积环境的基础。在我国,报道前寒武纪叠层石的文章较多,上古生代则不多见。作者自1980年以来对广东泥盆纪碳酸盐沉积中的藻叠层石做了一些研究,现根据所得资料进行报道。  相似文献   

8.
The Middle Jurassic Todilto Member of the Wanakah Formation is a carbonate and gypsum unit inset into the underlying aeolian Entrada Sandstone in the San Juan Basin. Field and thin section study of the uppermost Entrada and Todilto at Ghost Ranch, New Mexico, identified Todilto facies and their relationship to remnant Entrada dune topography. Results support the previous interpretation that the Entrada dunes, housed in a basin below sea level, were rapidly flooded by marine waters. Mass wasting of the dunes gave rise to sediment‐gravity flows that largely buried remnant dune topography, leaving ca 12 m of relief that defined the antecedent condition for Todilto deposition. Previously interpreted as seasonal varves deposited in a stratified water body, the Todilto is reinterpreted as a microbial biolaminite. Most diagnostic are organic‐rich laminae with structures characteristic of filamentous microbes and containing trapped aeolian silt, and clotted‐texture laminae with a fabric associated with calcification of extracellular polymeric substances. The spatial arrangement of Todilto facies is controlled by the dune palaeotopography. A continuous basal laminated mudstone thickens over the dune crest, reflecting the optimum conditions for microbial mat development, and is interpreted to have been deposited when marine waters submerged the topography. Subsequent drying caused emergence of the crestal area, and formation of tepee structures and a dissolution breccia. Gypsiferous mudflats and periodic ponds occupied the dune flanks and interdune area, with gypsum concentrated within the interdune area. Entrada sands remained unstable during Todilto deposition with common injection structures into the Todilto, and a remnant slope caused the downslope movement and folding of Todilto strata on the upper lee face. Although some expansion of the gypsum occurred in the subsurface, facies architecture fostered development of a dissolution front adjacent to the interdune gypsum body with section collapse of gypsiferous limestone on the dune flanks.  相似文献   

9.
ABSTRACT A number of non‐marine evaporite units composed of primary gypsum were deposited in saline lakes that developed in the southern Teruel Basin (NE Spain) during the Miocene. In the basin depocentre, a continuum of lacustrine evaporite lithofacies influenced by the activity of organisms is displayed. The Libros Gypsum was deposited in a deep lake, in which water stratification became unstable with progressive shoaling. Rhythmites, composed of laminae of pelletal gypsum and laminae of very fine lenticular gypsum crystals mixed with siliceous microorganisms, formed in addition to gypsum turbidites, intraformational gypsum breccias and slump structures. The pelletal laminae originated from the faecal activity of animals (crustaceans?) ingesting gypsum crystallites in the lake water during episodes of maximum evaporation, whereas the laminae of very fine lenticular gypsum mixed with microorganisms accumulated during episodes of relative dilution. In the wide marginal zones of the basin, the Libros Gypsum unit consists of massive to thin‐bedded bioturbated gypsum and thin‐bedded clotted gypsum, which formed in intermediate to very shallow (palustrine) water depths. The bioturbated gypsum lithofacies were produced by the action of diverse organisms, presumably worms and coleopterans, and chironomid larvae to a lesser extent; the massive lithofacies precipitated in very shallow water; and the thin‐bedded lithofacies formed in shallow to deeper settings. The thin‐bedded clotted gypsum is a relatively deep facies that may have diverse origins (e.g. bioturbation, compaction, disruption of soft sediments and early diagenesis). There is a well‐developed metre‐scale cyclicity in the marginal lake sequences, which is not observed in the inner lake deposits. This suggests a depth control in the various lacustrine subenvironments to record cyclic evaporitic processes. The isotopic composition of the gypsum indicates early sulphate‐reducing bacterial activity in the bottom of the lake and suggests that the sulphate was derived from the chemical recycling of Triassic evaporites of the country rocks.  相似文献   

10.
ABSTRACT The Tripoli Formation (Lower Messinian) in Sicily includes diatomites irregularly alternating with marl and carbonate beds and lies, stratigraphically, between the Tortonian pelagic marls and the evaporitic Calcare di base. The relationships between mineralogy, textural features and oxygen-carbon isotopic compositions of carbonate components point to a wide variability of depositional conditions and suggest that Tripoli sedimentation occurred in small basins characterized by periodic and marked restriction from the open sea.
The isotopic values of calcite and dolomite in the diatomites suggest an evolution from normal marine towards more restricted environments. Evaporating conditions are also indicated by the occurrence of anhydrite, length-slow chalcedonic quartz and moulds of gypsum. In a more advanced stage, the precipitation of heavy δ180 dolomite in the interstitial pores of fossil-poor diatomites denotes an environment with highly evaporated water. Mixing of meteoric and marine waters, on the other hand, might have favoured the precipitation of a dolomite characterized by relatively low δ180 and δ13C values.
The deposition of marl and carbonate beds alternating with or overlying the diatomites took place in an environment with highly evaporated marine waters on the basis of δl18O values of dolomite (up to + 9.10‰) and aragonite (up to + 5.83‰), occurrence of evaporitic minerals and lack of fossils. The presence at these levels of calcite with extremely negative δ13C values (down to - 38.40‰), filling gypsum moulds, suggests activity of sulphate-reducing bacteria. Some aragonitic marls, however, bear evidence of deposition in relatively normal marine conditions.  相似文献   

11.
Accumulation of microbial mats and stromatolites dominate in the crystallization ponds of solar salt works west of Alexandria, Egypt. These microbial mats are laminar in the permanent submerged part of the ponds. The microbial mats commonly form sites for growth of gypsum crystals during periods having higher salinity. In the dominant submerged part of the pond, domal stromatolites are common around groundwater seepage holes. In the shallow, intermittent margin of the ponds, the laminated microbial structure forms laterally close-linked hemispheroidal stromatolite type, with unidirectional and multidirectional ripple mark-like morphology on their surface. The microbial laminite and stromatolite types in the modern solar salt works are similar to the organic-rich Miocene gypsum beds of El-Barqan (west Alexandria, Egypt) and Rabigh (north Jeddah, Saudi Arabia). The Miocene organic-rich beds consist of interlayered dark-colored microbial laminae and light-colored gypsum laminae. These beds may have three different variations: regular even lamination, laterally closed-linked hemispheroidal stromatolites, and/or discrete hemispheroidal stromatolites. Petrographic examination of the microbial laminites and stromatolites in the solar salt works and the Miocene gypsum beds indicate that the dark-colored, organic-rich laminae are composed of micritized microbial laminae and/or brown organic filaments. In El-Barqan area, the light-colored gypsum-rich laminae are composed of either gypsum crystal fragments, or lenticular and prismatic gypsum. These gypsum crystals are either entrapped within the microbial filaments or are nucleated at the surface of the microbial laminae to form a radial pattern, whereas in Rabigh area, the light-colored gypsum-rich laminae are composed of secondary porphyrotopic, poikilotopic, or granular gypsum crystals. By comparison of the microbial structure in the Miocene gypsum beds with the recent occurrence of the microbial laminites and stromatolites in the solar salt works, it is demonstrated that the organic-rich Miocene gypsum beds were formed in a very shallow salina with slightly fluctuating brine levels.  相似文献   

12.
This paper focuses on a borehole, Xichen-1 well, drilled on the Chenhang Island, Xisha Islands in the South China Sea. Mineralogical, petrographic, stable isotopic and minor-element data from the Holocene to Pleistocene interval (0–179 m ) in the Xichen-1 well are discussed in detail. The 400-m-long core is divisible into four mineralogical facies: a high-Mg calcitic aragonite facies (0–16.91 m, Holocene), an aragonitic low- Mg calcite facies (16.91–30.60 m, Late Pleistocene), a low- Mg calcitic facies (30.60–179 m, Middle-Early Pleistocene) and a low- Mg calcitic and dolomitic facies (179–400 m, Early Pleistocene–Late Miocene). The Holocene section has much higher whole-rock δ18O and δ13C values and Mg and Sr content than the non-dolomitized Pleistocene limestones (16.91–179 m). The 16.91–165 m interval is characterized by a relatively invariant oxygen isotopic composition and very heterogeneous carbon isotopic composition. Between 165 and 179 m, there is a positively correlated increase of whole-rock δ18O and δ18C with depth, and Mg content also shows a gradual increase with depth. Petrographic data demonstrate that the Pleistocene reef sequence has been extensively affected by meteoric waters. We conclude that the Late Pleistocene section (16.91–30.60 m) and the Middle-Early Pleistocene section (30.60–165 m) have suffered incomplete and complete meteoric diagenesis, respectively, and that the Early Pleistocene interval (165–179 m) was diagenetically altered in a meteoric–marine mixing environment.  相似文献   

13.
A sloping travertine mound, approximately 85 m across and a few metres thick is actively forming from cool temperature waters issuing out of Crystal Geyser, east‐central Utah, USA. Older travertine deposits exist at the site, the waters having used the Little Grand Wash Fault system as conduits. In contrast, the present Crystal Geyser travertine mound forms from 18°C waters which have been erupting for the last 80 years from an abandoned oil well. The present Crystal Geyser travertine accumulation forms from a ‘man‐made’ cool temperature geyser system; nevertheless, the constituents are an analogue for ancient geyser‐fed carbonate deposits. The travertine primary fabric is composed of couplets of highly porous, thin micritic laminae intercalated with thicker iron oxide rich laminae. Low Mg‐calcite is the dominant mineralogy; however, aragonite is a major constituent in deposits proximal to the vent and decreases in abundance distally. Cements exhibit a variety of fabrics, isopachous being common. Constituents include micro‐stromatolites, clasts, pisoids and the common occurrence of Frutexites‐like iron oxide precipitates. Leptothrix, a common iron‐oxidizing bacterium, is believed to be responsible for the production of the dense iron‐rich laminae. Pisoids litter the ground around the vent and rapidly decrease distally in abundance and size.  相似文献   

14.
The Trooper Creek Formation is a mineralised submarine volcano‐sedimentary sequence in the Cambro‐Ordovician Seventy Mile Range Group, Queensland. Most of the Trooper Creek Formation accumulated in a below‐storm‐wave‐base setting. However, microbialites and fossiliferous quartz‐hematite ± magnetite lenses provide evidence for local shoaling to above fairweather wave‐base (typically 5–15 m). The microbialites comprise biogenic (oncolites, stromatolites) and volcanogenic (pumice, shards, crystal fragments) components. Microstructural elements of the bioherms and biostromes include upwardly branching stromatolites, which suggest that photosynthetic microorganisms were important in constructing the microbialites. Because the microbialites are restricted to a thin stratigraphic interval in the Trooper Creek area, shallow‐water environments are interpreted to have been spatially and temporarily restricted. The circumstances that led to local shoaling are recorded by the enclosing volcanic and sedimentary lithofacies. The microbialites are hosted by felsic syneruptive pumiceous turbidites and water‐settled fall deposits generated by explosive eruptions. The microbialite host rocks overlie a thick association (≤?300 m) of andesitic lithofacies that includes four main facies: coherent andesite and associated autoclastic breccia and peperite; graded andesitic scoria breccia (scoriaceous sediment gravity‐flow deposits); fluidal clast‐rich andesitic breccia (water‐settled fall and sediment gravity‐flow deposits); and cross‐stratified andesitic sandstone and breccia (traction‐current deposits). The latter three facies consist of poorly vesicular blocky fragments, scoriaceous clasts (10–90%), and up to 10% fluidally shaped clasts. The fluidal clasts are interpreted as volcanic bombs. Clast shapes and textures in the andesitic volcaniclastic facies association imply that fragmentation occurred through a combination of fire fountaining and Strombolian activity, and a large proportion of the pyroclasts disintegrated due to quenching and impacts. Rapid syneruptive, near‐vent aggradation of bombs, scoria, and quench‐fragmented clasts probably led to temporary shoaling, so that subsequent felsic volcaniclastic facies and microbialites were deposited in shallow water. When subsidence outpaced aggradation, the depositional setting at Trooper Creek returned to being relatively deep marine.  相似文献   

15.
Lilypad stromatolites, up to 3 m long and 1·5 m wide, were found to be actively growing in the shallow marginal waters of Frying Pan Lake and its outflow channel. These stromatolites, composed of Phormidium (> 90%), Fischerella, and a variety of other microbes, develop through a series of distinct growth stages. Dark green microbial mats cover the floor of the outflow channel and give rise to columns of various sizes and shapes in the shallower marginal waters. Once the columns reach the water level, the mats spread laterally to form a lilypad stromatolite. The lilypads are characterized by a raised, dark green rim, 4–5 mm high, that encircles a flat interior covered with a distinctive orange-red mat. The microbes forming the columns and lilypad plate are being actively silicified. The stromatolites are formed of: (i) flat-lying Phormidium filaments (P-laminae), (ii) upright filaments of Phormidium that are commonly associated with Fischerella (U-laminae), and (iii) mucus, diatoms and pyrite framboids (M-laminae). P-laminae dominate most of the columns, with tripartite cycles of P-, U-, to M-laminae being found mostly in the upper parts of the stromatolites. The transition from the P- to U-laminae is marked by a change in the growth pattern of the Phormidium and branching of Fischerella, which was probably triggered by a change in environmental conditions. In the Frying Pan Lake outflow channel, this change may be related to fluctuations in water level and flow rates that are caused by periods of heavy rain, seasonal changes, long-term variations in rainfall, and/or the unique 40-day hydrological cycle that exists between Frying Pan Lake and Inferno Crater, which is a nearby hydrothermal crater lake.  相似文献   

16.
Modern cemented intervals (beachrock, firmgrounds to hardgrounds and concretionary layers) form in the lagoon and intertidal sabkha of Abu Dhabi. Seafloor lithification actively occurs in open, current-swept channels in low-lying areas between ooid shoals, in the intertidal zone of the middle lagoon, some centimetres beneath the inner lagoonal seafloor (i.e. within the sediment column) and at the sediment surface the intertidal sabkha. The concept of ‘concretionary sub-hardgrounds’, i.e. laminar cementation of sediments formed within the sediment column beneath the shallow redox boundary, is introduced and discussed. Based on calibrated radiocarbon ages, seafloor lithification commenced during the Middle to Late Holocene (ca 9000 cal yr bp ), and proceeds to the present-day. Lithification occurs in the context of the actualistic relative sea-level rise shifting the coastline landward across the extremely low-angle carbonate ramp. The cemented intervals are interpreted as parasequence boundaries in the sense of ‘marine flooding surfaces’, but in most cases the sedimentary cover overlying the transgressive surface has not yet been deposited. Aragonite, (micritic) calcite and, less commonly, gypsum cements lithify the firmground/hardground intervals. Cements are described and placed into context with their depositional and marine diagenetic environments and characterized by means of scanning electron microscope petrography, cathodoluminescence microscopy and Raman spectroscopy. The morphology of aragonitic cements changes from needle-shaped forms in lithified decapod burrows of the outer lagoon ooidal shoals to complex columnar, lath and platy crystals in the inner lagoon. Precipitation experiments provide first tentative evidence for the parameters that induce changes in aragonite cement morphology. Data shown here shed light on ancient, formerly aragonite-cemented seafloors, now altered to diagenetic calcites, but also document the complexity of highly dynamic near coastal depositional environments.  相似文献   

17.
Ancient carbonate buildups may contain extraordinarily large amounts of early diagenetic precipitates. In some, host rock lamination may be traced into inclusion bands within the 'cement' crystals, suggesting that the crystals are replacive. By analogy with a Pleistocene speleothem from the Sorrento Peninsula, however, these relationships can be explained differently. In the speleothem, large, repeatedly split and dendritic calcite crystals occur within a laminated carbonate. Lamination consists of sub-mm alternations of micrite and microspar. Micritic laminae pass laterally into inclusion-rich growth bands in the dendritic calcite crystals, and have replaced an aragonitic cement, whereas the microspar laminae were primary calcite cements. Three types of inclusion-rich bands occur in the dendrite crystals: (1) with aragonite relicts, (2) 'ribbon calcite' and (3) with oriented micropores. When aragonite precipitated, the calcite dendrite branches were unable to keep growing as single crystals and split into crystallites (separated by micropores, some forming ribbon calcite), whereas during episodes of calcite lamina precipitation, the larger crystals were regenerated by crystallite coalescence. Calcite crystals are primary: they did not replace a micritic precursor. By analogy with the Italian speleothem, some ancient reefal sparry carbonates may not be replacements of earlier laminated sediments, but may have grown concurrently with them. It is also probable that some ancient laminated sediments were instead sea-floor precipitates, and that stromatolites containing cross-cutting crystal fabrics, and the alternating micrite-microspar laminae typical of Archaeolithoporella , could be largely abiotic crystal growths.  相似文献   

18.
Onondaga Lake is a moderately saline, eutrophic lake characterized by waters rich in calcium, sodium, chloride and bicarbonate. Large quantities of CaCO3 that are precipitated in the lake result from excess calcium supplied as calcium chloride wastes produced by soda-ash manufacturing to lake waters that are at or near saturation with respect to CaCO3 from solution of carbonate rocks in the drainage basin. Beaches along the leeward (northeastern) shore of the lake are composed almost entirely of oncolites ranging from a few millimeters to several centimeters in maximum dimension. Offshore, in 1–2 m of water, the oncolites are biscuit-shaped concretions as much as 15 cm in diameter. The oncolites consist mainly of low-magnesium calcite, but dissolution of the carbonate with dilute acid results in a mass of blue-green algal filaments of the same approximate size and shape as the original oncolite. Most oncolites have an obvious nucleus; the most common nucleus is the hollow stem and cortication tubules of charophytes. Charophytes do not occur in Onondaga Lake today although they are common in other limestone-bedrock lakes in central New York State. Charophytes probably were eliminated by the marked increases in salinity of the lake that resulted from the introduction of soda-ash manufacturing on the lake shores around 1880 which means that growth of the oncolites began at least 100 years ago.  相似文献   

19.
山东乳山海滩岩及其重要科学意义   总被引：2，自引：0，他引：2  
毕福志  袁又申 《现代地质》1991,5(2):201-207,T002
乳山海滩岩,经过室内对微体化石、大化石和沉积岩石学研究,查明该岩体具有典型的海滩岩特征:含有两种文石胶结物、滨海相微体古生物和热带大化石。该岩体形成在全新世最佳气侯期,至少有3次成岩期,对研究古环境变化规律具有重要的科学意义。  相似文献   

20.
Earlier interpretations of textural alteration affecting Great Salt Lake ooids have greatly influenced concepts of ooid diagenesis. Scanning electron microscope study shows, however, that the coarse radial aragonite rays are depositional, that no recrystallization of pellet cores has occurred, and that Great Salt Lake ooids have not suffered noticeable diagenesis. As suggested by Kahle (1974), radial texture in ancient calcitic ooids is probably mainly original, not diagenetic. Retention of such fine textures has been attributed to organic matter (since found to be equivalent in modern skeletal and non-skeletal grains) or to paramorphic replacement (proposed for non-skeletal grains whose original aragonite mineralogy was only inferred from modern analogs). Pleistocene ooids known to have been aragonite alter like aragonite shells to coarse neomorphic calcite, often with aragonite relics. The striking uniformity of that coarse texture in neomorphic calcite replacing known skeletal aragonites throughout the geologic record has been noted for over 100 years. In contrast, Mississippian ooids retain fine texture as do calcite layers of coexisting gastropods, but unlike the strongly altered aragonite layers of these same gastropods. Therefore, inferences of original aragonitic mineralogy of ancient non-skeletal carbonate grains (including muds) which are now calcite but retain fine texture appear unwarranted, as do assumptions of differential diagenetic behaviour of ancient aragonitic skeletal and non-skeletal grains. Accordingly, modern depositional environments of marine ooids and carbonate muds must be rejected as chemically unrepresentative of comparable ancient environments. It is inferred that ancient non-skeletal carbonates were originally predominantly or exclusively calcite because of an earlier lower oceanic Mg/Ca ratio (<2/1) which altered progressively to values favouring aragonite (modern Mg/Ca value = 5/1). Major influencing factors are: selective removal of calcium by planktonic foraminifers and coccolithophorids since Jurassic-Cretaceous time and by abundant younger, Mg-poor aragonite skeletons and an erratic trend toward decreasing dolomite formation (decreasing removal of oceanic Mg). The change to aragonite dominance over calcite for non-skeletal carbonates was probably during early to middle Cenozoic time.  相似文献   

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