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1.
The recent discoveries of deeply buried Cretaceous reservoir bodies in the Atlantic Ocean revealed that relationships between the distribution of spring carbonate deposits and faults are poorly understood. The well‐exposed Quaternary deposits at Obruktepe (Denizli Basin, Turkey) provide an opportunity to reconstruct the three‐dimensional sedimentary architecture of such a system. Integration of sedimentological, lithofacies and geochemical analyses reveals complexity in the lateral relationships between sedimentary environments, faults and geothermal spring carbonates. Five environmental systems are distinguished based on the lithofacies analysis: (i) vent; (ii) smooth slope; (iii) travertine‐terrace; (iv) tufa‐barrage; and (v) flood systems. Encrusting, baffling and settling sedimentary processes are reflected in data acquired at several scales, from lithofacies observations to the morphology and arrangement of geobodies, together with microfabrics and stable carbon and oxygen isotope data. Mean values of +4·9‰ δ13C and −8·74‰ δ18O Vienna PeeDee Belemnite reflect geothermal circulation of springwaters. The environmental distribution and lithofacies indicate a lateral continuum between travertine and tufa deposits within this hot spring system. This finding supports two depositional models in which water flow variation is the main control on both CaCO3 precipitation and the resulting formation of travertine and tufa. The proposed models address the factors responsible for the development of these complex mound‐shaped carbonate spring deposits, and how they are related to fluid circulation at depth and in association with faults.  相似文献   

2.
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3.
Iron‐bearing concretions are valuable records of oxidation states of subsurface waters, but the first concretions to form can be altered drastically during later diagenetic events. Distinctive concretions composed of heavy rinds of iron oxide that surround iron‐poor, mud‐rich cores are common along bases of fluvial cross‐bed sets of the Cretaceous Dakota Formation, Nebraska, USA. Concretion rinds thicken inward and cores contain 46 to 89% void space. Millimetre‐scale spherosiderites are abundant in palaeosols that developed in floodplain facies. Evolution of rinded concretions began when intraformational clasts were eroded from sideritic soils, transported, abraded and deposited in river channels. Alteration of siderite and formation of rinds occurred much later, perhaps in the Quaternary when sandstone pore waters became oxic. Dakota concretions are analogous to ‘rattlestones’ in Pleistocene fluvial channels of The Netherlands, and their rinded structure is analogous to that of iron‐rich concretions in the aeolian Navajo Sandstone of Utah. In all three deposits, rinded concretions formed when pre‐existing, siderite‐cemented concretions were oxidized within a sand matrix. Unlike fluvial examples, siderite in the Navajo Sandstone was autochthonous and of late diagenetic origin, having precipitated from carbon dioxide and methane‐enriched waters moving through folded and jointed strata. Iron‐rich rinds formed in all these strata because concretion interiors remained anaerobic, even as oxygen accumulated in the pore waters of their surrounding, permeable matrix. Iron oxide first precipitated at redox boundaries at concretion perimeters and formed an inward‐thickening rind. Acid generated by the oxidation reaction drove siderite dissolution to completion, creating the iron‐poor core. Iron‐oxide rinds are indicators of the former presence of siderite, a mineral that forms only under reducing conditions, during either early or late diagenesis. Siderite is vulnerable to complete oxidation upon exposure, so the distinctive rinded concretions are valuable clues that aid in deciphering diagenetic histories and for recognizing methanic floodplain palaeoenvironments and wet palaeoclimate.  相似文献   

4.
http://dx.doi.org/10.1016/j.gsf.2016.09.005   总被引：1，自引：1，他引：0  
We propose the nuclear geyser model to elucidate an optimal site to bear the first life.Our model overcomes the difficulties that previously proposed models have encountered.Nuclear geyser is a geyser driven by a natural nuclear reactor,which was likely common in the Hadean Earth,because of a much higher abundance of ~(235)U as nuclear fuel.The nuclear geyser supplies the following:(1)high-density ionizing radiation to promote chemical chain reactions that even tar can be used for intermediate material to restart chemical reactions,(2)a system to maintain the circulation of material and energy,which includes cyclic environmental conditions(warm/cool,dry/wet,etc.)to enable to produce complex organic compounds,(3)a lower temperature than 100℃ as not to break down macromolecular organic compounds,(4)a locally reductive environment depending on rock types exposed along the geyser wall,and(5)a container to confine and accumulate volatile chemicals.These five factors are the necessary conditions that the birth place of life must satisfy.Only the nuclear geyser can meet all five,in contrast to the previously proposed birth sites,such as tidal flat,submarine hydrothermal vent,and outer space.The nuclear reactor and associated geyser,which maintain the circulations of material and energy with its surrounding environment,are regarded as the nuclear geyser system that enables numerous kinds of chemical reactions to synthesize complex organic compounds,and where the most primitive metabolism could be generated.  相似文献   

5.
Late Pleistocene travertines up to 40 m thick near Rapolano Terme in Tuscany, central Italy, were precipitated by hot water issuing from springs on hillsides and flowing into adjacent depressions to mix with rainwater. Proximal light-coloured slope and terrace travertines pass distally into darker reed mound and depression-fill travertines. Lithotypes include crystalline crust, shrub, pisoid, paper-thin raft, coated bubble, reed, and lithoclast-breccia. High precipitation rates resulted in rapid slope aggradation and progradation. Dilution by rainwater likely lowered precipitation rates in depressions, but deposition was augmented by allochthonous material eroded from upslope travertines. Slope Depositional Systems consist of Smooth and Terrace Slope facies characterized by white crystalline crusts, with diverse additional lithotypes in terrace pools. Depression Depositional Systems have mixed light and dark travertines with horizontal to gently concave stratification. Extensive light-coloured Shrub Flat travertine is dominant; darker Marsh-Pool Facies composed of fine lithoclast and reed travertine is localized. Reed Mounds composed of mixed light and dark travertines localized by abundant reed growth, formed where spring water emerged near the bases of low angle slopes. Distal reduction in accretion rate was the major influence on sequence development. Light-coloured slope travertines interdigitate with darker depression deposits. Vertical aggradation of slope deposits, mound progradation, and filling of topographic depressions is expressed by advance and retreat of facies. Evolution from depression to slope or mound sequences is termed ‘steepening up’. Up-sequence change from slope or mound to depression facies is termed ‘levelling up’. Exposure surfaces associated with palaeosols are common in all facies and often constitute sequence boundaries. They are more closely spaced in depression sequences, reflecting slower and possibly also more discontinuous accumulation at sites furthest from hot springs.  相似文献   

6.
Travertine deposits in western Turkey are very well‐exposed in the area of Kocaba?, in the eastern part of the Denizli Basin. The palaeoclimatic significance of these travertines is discussed using U/Th dates, stable isotope data and palynological evidence. The Kocaba? travertine occurrences are characterized by successions of depositional terraces associated with palaeosols and karstic features. The travertines have been classified into eight lithotypes and one erosional horizon, namely: laminated, coated bubble, reed, paper‐thin raft, intraclasts, micritic travertine with gastropods, extra‐formational pebbles and a palaeosol layer. The analysed travertines mostly formed between 181 ka and 80 ka (Middle to Late Pleistocene) during a series of climatic changes including glacial and interglacial intervals; their δ13C and δ18O values indicate that the depositional waters were mainly of basinal thermal origin, occasionally mixed with surficial meteoric water. Palynological results obtained from the palaeosols showed an abundance of non‐arboreal percentage and xerophytic plants (Oleaceae and Quercus evergreen type) indicating that a drought occurred. Marine Isotope Stage 6 is represented by grassland species but Marine Isotope Stage 5 is represented by Pinaceae–Pinus and Abies, Quercus and Oleaceae. Uranium/thorium analyses of the Kocaba? travertines show that deposition began in Marine Isotope Stage 6 (glacial) and continued to Marine Isotope Stage 4 (glacial), but mostly occurred in Marine Isotope Stage 5 (interglacial). The travertine deposition continued to ca 80 ka in the south‐west of the study area, in one particular depression depositional system. Palaeoenvironmental indicators suggest that the travertine depositional evolution was probably controlled by fault‐related movements that influenced groundwater flow. Good correlation of the stable isotope values and dates of deposition of the travertines and palynological data of palaeosols in the Kocaba? travertines serve as a starting point for further palaeoclimate studies in south‐west Turkey. Additionally, the study can be compared with other regional palaeoclimate archives.  相似文献   

7.
Abstract Siliceous sinter precipitation within hot spring systems has been attributed to a variety of mechanisms: evaporative concentration, cooling, changes in pH and cation effects. Repetitive in situ (T, pH, alkalinity, etc.) and laboratory (major, minor and trace elemental, stable isotopic) analyses of the waters plus observations of silica precipitation on natural (e.g. twigs, pine cones) as well as artificial substrates (glass slides and copper plates) in the waters substantiate that subaqueous precipitation is occurring throughout the vent to distal end of flow in both Cistern Spring (Norris Geyser Basin) and Deerbone Spring (Lower Geyser Basin), Yellowstone National Park, Wyoming, USA. Quartz and sodium–potassium geothermometers indicate that Cistern Spring is fed by a subsurface reservoir that is between 232 and 272 °C. Calculated reservoir temperatures are significantly lower at Deerbone Spring (182–197 °C). Based on a suite of measured and theoretical saturation indices, downflow changes in the system resulting from evaporative concentration (e.g. Cl increases 10%), changes in pH (e.g. 5·6–7·1) and cation effects (Al and Fe) are of negligible importance in the subaqueous precipitation of hot spring opal‐A. Similarly, at the macroenvironmental scale, potential biotic effects on opal‐A precipitation appear to be minimal. Modelling of the two active siliceous sinter precipitating systems indicates that cooling (e.g. 80–17 °C) is the predominant process governing subaqueous mineral precipitation.  相似文献   

8.
The abundance of As and Sb in aqueous, mineral and biological reservoirs was examined at El Tatio Geyser Field, a unique hydrothermal basin located in the Atacama Desert region of Chile. Here the concentration of total As and Sb in hydrothermal springs and discharge streams are the highest reported for a natural surface water, and the geyser basin represents a significant source of toxic elements for downstream users across Region II, Chile. The geyser waters are near neutral Na:Cl type with ∼0.45 and 0.021 mmol L−1 total As and Sb, respectively, primarily in the reduced (III) redox state at the discharge with progressive oxidation downstream. The ferric oxyhydroxides associated with the microbial mats and some mineral precipitates accumulate substantial As that was identified as arsenate by XAS analysis (>10 wt% in the mats). This As is easily mobilized by anion exchange or mild dissolution of the HFO, and the ubiquitous microbial mats represent a significant reservoir of As in this system. Antimony, in contrast, is not associated with the mineral ferric oxides or the biomats, but is substantially enriched in the silica matrix of the geyserite precipitates, up to 2 wt% as Sb2O3. Understanding the mobility and partitioning behavior of these metalloids is critical for understanding their eventual impact on regional water management.  相似文献   

9.
《Sedimentology》2018,65(4):1331-1353
The Faxe Quarry in south‐east Denmark offers excellent exposures of Early Palaeocene, Danian deep‐water intercalated coral and bryozoan mounds that form complexes at least 40 m thick and a few kilometres wide along and over submarine highs. The coexisting coral and bryozoan mounds represent two different biogenic carbonate factories with a highly dynamic interplay during growth. The sedimentary facies, mound geometries and the density, diversity and palaeoecology of the associated benthic invertebrates and nannofossils allow recognition of six successive growth units. Unit 1 represents an outer shelf bryozoan mound belt characterized by an oligotrophic cool‐water nannofossil assemblage. Unit 2 comprises a mixed faunal assemblage of bryozoans and octocorals with an initial sparse colonization of hexacorals. The nannofossil assemblage records a decrease in diversity and an increase in warm water forms. Unit 3 marks the onset of dense colonization of the scleractinian coral Dendrophyllia candelabrum with associated low‐diversity macrofauna and nannofossil assemblages. Unit 4 represents the main coral build‐up phase with frame‐building hexacorals of Dendrophyllia and Faxephyllia associated with a high‐diversity invertebrate fauna, and relatively low‐diversity nannofossil assemblages. Unit 5 represents the late coral mound phase showing extensive lateral distribution and finally death and erosion of the coral mounds. This event was contemporaneous with a warming trend in the pelagic environment. The succeeding Unit 6 marks the burial and overgrowth of the coral mound complex by bryozoan‐rich sediments. The coral mound complex in the Faxe Quarry initiated and terminated in global nannofossil zone NP 3 and regional nannofossil zones NNT p2G–3 suggesting a mound growth duration of ca 300 kyr and a mean vertical accretion of the coral mound of 13 cm kyr−1. The mound complex probably serves as the best‐exposed analogue to modern deep and cold‐water coral mounds in the North Atlantic.  相似文献   

10.
Sulphate mineralization precipitated around a geyser located above the village of Pinchollo, Chivay district and below Hualca Hualca volcano (6025 m a.s.l.) in the Western Cordillera of southern Peru is described. The geyser is one of many manifestations of thermal activity in the Arequipa department. Its age is estimated to be Upper Pleistocene–Holocene, as the discharge point lies at the intersection of a fault system with latitudinal dip-slip fault cutting a volcanic-debris avalanche of probably Pleistocene age. Thermal waters present in the Chivay district are mainly chloride-rich with a neutral pH. They are rich in Li, Sr, and B. The water erupting in the geyser boils at about 85 °C, as it lies at some 4353 m a.s.l.The minerals examined, of various habits and various yellow, orange and white colours were precipitated on the soil and on plants close to the geyser (location 1), on the walls of a 1 m diameter pothole filled with boiling water (location 1a) and at a distance of some 100 m to the west of the geyser (location 2). All are sulphates. Their chemical composition is fairly simple, consisting of Al, Fe, K, Mg, Ca, S, NH4 and O, and all display chemical zoning. But the phase composition is more complex. In all locations, alunogene, copiapite, coquimbite, tschermigite and gypsum are present. Close to the geyser (location 1) magnesium-containing sulphates, namely, boussingaultite and pickeringite also occur. Iron sulphates such as mohrite and rozenite precipitate on the walls of the pothole (location 1a). Sulphates containing potassium such as jarosite, alunite and voltaite–voltaite (Mg) dominate among the efflorescences in location 2, where hematite was also noted. Any quartz and kaolinite or illite/mica admixture identified in some samples derives from adjacent soil.The present geothermal system does not involve the deposition of precious-metal deposits such as those associated with an earlier deep-going epithermal system that scavenged a large volume of rock. Most likely, as the present-day thermal waters do not involve a juvenile-water component, the geyser waters derive from a shallower source.  相似文献   

11.
Calcite dendrite crystals are important but poorly understood components of calcite travertine that forms around many hot springs. The Lýsuhóll hot-spring deposits, located in western Iceland, are formed primarily of siliceous sinters that were precipitated around numerous springs that are now inactive. Calcite travertine formed around the vent and on the discharge apron of one of the springs at the northern edge of the area. The travertine is formed largely of two types (I and II) of complex calcite dendrite crystals, up to 1 cm high, that grew through the gradual addition of trilete sub-crystals. The morphology of the dendrite crystals was controlled by flow direction and the competition for growth space with neighbouring crystals. Densely crowded dendrites with limited branching characterize the rimstone dams whereas widely spaced dendrites with open branching are found in the pools. Many dendrite bushes in the pools nucleated around plant stems. Growth of the dendrite crystals was seasonal and incremental. Calcite precipitation was driven by rapid CO2 degassing of CO2-rich spring waters during the spring and summer. During winter, when snow covered the ground and temperatures were low, opal-A precipitated on the exposed surfaces of the dendrites. Segmentation of dendrite branches by discontinuities coated with opal-A and overgrowth development around sub-crystals resulted from this seasonal growth cycle. The calcite dendrite crystals in the Lýsuhóll travertine differ in morphology from those at other hot springs, such as those at Lake Bogoria, Kenya, and Waikite in New Zealand. Comparison with the calcite dendrite crystals found at those sites shows that dendrite morphology is site-specific and probably controlled by carbonate saturation levels that, in turn, are controlled by the rate of CO2 degassing and location in the spring outflow system.  相似文献   

12.
在地表环境下,钙华沉积常常是物理化学和生物沉积过程共同作用的结果。藻类因其在钙华沉积环境中具有较大的生物量及其自身拥有多样的代谢方式,对钙华沉积过程和形态具有重要影响。本研究以四川黄龙钙华为例,通过对典型沉积点的水化学、藻类群落组成和现代钙华微岩相结构进行综合分析,来揭示藻类在钙华沉积中的作用。研究发现,黄龙钙华沉积环境中分布的藻类主要包括蓝藻、绿藻和硅藻等。这些藻类代谢活动会在一定程度上改变沉积水体水化学环境,但在快速流动的水体中,其影响有限。不同藻类群落常常形成几百微米至1~2 mm厚的微生物席或生物膜层,作为碳酸钙沉积发生的重要场所,即钙华沉积活动层。在该活动层内,藻体及其分泌的胞外聚合物（EPS）能够为碳酸钙晶体生长提供大量成核位点和生长模板,从而极大地促进钙华沉积。同时,EPS可以控制或影响碳酸钙结晶形态及钙华微岩相结构。准确认识和量化藻类在钙华沉积中的作用还需要继续开展更多微观尺度方面的研究,以便更好地理解钙华沉积机制,并为准确解译古老钙华岩相结构和地球化学特征奠定基础,同时为预测钙华景观演化和保育提供更多科学依据。   相似文献   

13.
Abstract: The gold content in siliceous deposits formed from geothermal waters at the Hatchobaru geothermal power station in central Kyushu, Japan, was determined by inductively coupled plasma quadrupole mass spectrometry (ICP–MS). It ranges from 1.3 to 4.6 mg/kg. The highest gold content was obtained from the siliceous deposit formed from acidic waters. In this siliceous deposit, hydrous iron(III) oxide of amorphous state is a major constituent, suggesting that hydrous iron(III) oxide might play an important role when gold is concentrated into siliceous deposits formed from acidic and iron-rich geothermal waters.  相似文献   

14.
Post‐glacial, neritic cool‐water carbonates of the Western Mediterranean Sea were examined by means of hydroacoustic data, sediment surface sampling and vibrocoring to unravel geometries and to reconstruct sedimentary evolution in response to the last sea‐level rise. The analysed areas, located on the Alboran Ridge, in the Bay of Oran, and at the southern shelf of the island of Mallorca, are microtidal and bathed by oligotrophic to weakly mesotrophic waters. Seasonal water temperature varies between 13 °C and 27 °C. Echosounder profiles show that the Bay of Oran and the southern shelf of Mallorca are distally steepened ramps, while the Alboran Ridge forms a steep‐flanked rugged plateau around the Alboran Island. In the three areas, an up to 10 m thick post‐glacial sediment cover overlies an unconformity. In Oran and Mallorca, stacked lowstand wedges occur in water depths of 120 to 130 m. On the Alboran Ridge and in the Bay of Oran, highstand wedges occur at 35 to 40 m. Up to 5 m long cores of upper Pleistocene to Holocene successions were recovered in water depths between 40 and 81 m. Deposits contain more than 80% carbonate, with mixed carbonate‐volcaniclastics in the lower part of some cores in Alboran. The carbonates consist of up to 53% of aragonite and up to 83% of high magnesium calcite. Radiocarbon dating of bivalve shells, coralline algae and serpulid tubes indicates that deposits are as old as 12 400 cal yr bp . The carbonate factories in the three areas are dominated mostly by red algae, but some intervals in the cores are richer in bivalves. A facies rich in the gastropod Turritella, reflecting elevated surface productivity, is restricted to the Mallorca Shelf. Rhodoliths occur at the sediment surface in most areas at water depths shallower than 70 m; they form a 10 to 20 cm thick veneer overlying rhodolith‐poor bioclastic sediments which, nonetheless, contain abundant red algal debris. This rhodolith layer has been developing for the past 800 to 1000 years. Similar layers at different positions in the cores are interpreted as reflecting in situ growth of rhodoliths at times of reduced net sedimentation. Sedimentary successions in the cores record the post‐glacial sea‐level rise and the degree of sediment exposure to bottom currents. Deepening‐upward trends in the successions are either reflected by shallow to deep facies transitions or by a corresponding change of depth‐indicative red algae. There are only weak downcore variations of carbonate mineralogy, which indicate that no dissolution or high magnesium to low magnesium calcite neomorphism occurs in the shallow subsurface. These new data support the approach of using the Recent facies distribution for interpretation of past cool‐water, low‐energy, microtidal carbonate depositional systems. Hydroacoustic data show that previous Pleistocene transgressive and highstand inner ramp deposits and wedges were removed during sea‐level lowstands and accumulated downslope as stacked lowstand wedges; this suggests that, under conditions of high‐amplitude sea‐level fluctuations, the stratigraphic record of similar cool‐water carbonates may be biased.  相似文献   

15.
Shallowing‐upward, decametre‐scale, Palaeoproterozoic iron formation cycles in northern Wisconsin record the combined effects of tectonism and changing oceanographic conditions on a storm‐dominated shelf. Cycles consist of a lower unit of laminated, Fe‐ and Si‐rich chemical mudstone that is transitional into an upper unit dominated by trough cross‐stratified chert grainstone. Grainstone lenses become progressively thicker upwards in cycles with the largest at cycle tops, where they are sharply overlain by a unit of slumped chemical mudstone. The cycles developed through progradation when offshore‐directed storm currents transported chert sand intraclasts that were formed in nearshore settings into middle and distal shelf environments. Abrupt subsidence events, probably resulting from normal faulting associated with extensional tectonism, repeatedly terminated chert grainstone accumulation and may also have generated the slumped units at cycle boundaries. The episodic storm currents are also interpreted to have transported biologically oxygenated waters from the shallow‐water, inner shelf into otherwise anoxic bottom waters of the strongly stratified distal shelf. The consequence of such transport and mixing was rapid deposition of chemical mud, mainly as precipitated Fe‐oxide. In many cases, the resultant decrease in Fe2+ in the water column, together with pelagic inorganic precipitation of SiO2 and rainout of terrigenous clays, resulted in submillimetre‐ to millimetre‐thick, chemically graded laminae. The concomitant decreasing Fe2+/Mn2+ ratio also led to increasing Mn‐compound precipitation and enrichment in the upper portions of some chemically graded layers.  相似文献   

16.
The relative influences of biotic and abiotic processes on travertine fabrics are still not well understood, despite increasing interest in the last decade to better understand the record of ancient microbial life and sedimentary fabrics in microbial hydrocarbon reservoirs. This study examines travertines at Satono‐yu hot spring in Japan (the temperature of water flowing over the travertine was ca 35°C), to better understand the interaction between depositional, hydrochemical and microbial parameters at different flow settings. Characteristics of the bulk hydrochemistry, mineralogy (exclusively aragonite) and the driving force for precipitation (primarily abiotic CO2 degassing with some photosynthetic microbial contribution) were similar among all of the flow settings. Conversely, the increase in flow velocity suppressed the influence of photosynthesis and enhanced the abiotic precipitation due to the thinner diffusive boundary layer at the travertine surface–water interface. Additionally, the increase in flow velocity changed the microbial composition and decreased the bacterial diversity by reflecting their adhesion efficiency on the travertine substrate. The acidity of the cyanobacterial sheaths controls the aragonite nucleation rate and the resulting calcification, even at significantly high equilibrium CO2 partial pressure (ca 22 to 28 matm), high dissolved inorganic carbon concentration (ca 35 to 38 mmol l?1), and elevated aragonite saturation state (ca 20‐fold to 34‐fold). Therefore, the increase in flow velocity suppresses the microbial influence with respect to the increase in the saturation state, the nucleation site supply and pore space generation. Overall, this results in the predominance of abiotic precipitation under high flow velocities. Consequently, a sparse‐micritic fabric with abundant interlamina porosity forms under lower flow velocity where the microbial influence is effective, while a dense‐sparitic fabric with little inter‐crystalline porosity forms under higher flow velocity where abiotic precipitation prevails. These findings provide an essential base for assessing the formation processes of ancient travertines and comparable deposits from petrological fabrics.  相似文献   

17.
Li Guo  & Robert Riding 《Sedimentology》1999,46(6):1145-1158
Holocene hot water travertine continues to form at Terme San Giovanni, near Rapolano Terme, central Italy, although artificial diversion of the water has reduced deposition. Mesothermal water (≈38–39 °C) emerging from fault-controlled vents located on a hilltop has created a linear fissure ridge 240 m long and up to 10 m high. Active parts of the ridge crest are covered by small cones; inactive parts are locally neotectonically fissured and have small pools. Ridge deposits include crystalline crust, paper-thin raft and shrub lithotypes. The ridge has both smooth and terraced marginal slopes, dominated by crystalline crusts with small shrubs in terrace pools. At the base of the ridge, there is a rapid transition to lateral flats and depressions, where water from the ridge collects and deposits shrub, irregular pisoid, reed, paper-thin raft and fine-grained and organic-rich travertines. Water channelled to nearby valley sides deposits thick crystalline crusts on valley slopes and waterfall overhangs, locally with small pools filled by smooth spherical pisoids. On the valley floor, mixing of waters forms varied stream-fill deposits that include micritic reed, paper-thin raft and coated bubble travertines. The diversity of travertine facies observed results from the location of the Terme San Giovanni hot springs on a hill crest, thus providing a wide array of downslope locations for further deposition. The abrupt facies transitions observed are characteristic of hot spring carbonates and result from a combination of rapid decrease in precipitation away from vents, variations in local surface topography and the feedback effect of travertine deposition itself, which dams and diverts water flow.  相似文献   

18.
Travertine is present at 20% of the ca 60 hot springs that discharge on Loburu delta plain on the western margin of saline, alkaline Lake Bogoria in the Kenya Rift. Much of the travertine, which forms mounds, low terraces and pool‐rim dams, is sub‐fossil (relict) and undergoing erosion, but calcite‐encrusted artefacts show that carbonate is actively precipitating at several springs. Most of the springs discharge alkaline (pH: 8·3 to 8·9), Na‐HCO3 waters containing little Ca (<2 mg l?1) at temperatures of 94 to 97·5°C. These travertines are unusual because most probably precipitated at temperatures of >80°C. The travertines are composed mainly of dendritic and platy calcite, with minor Mg‐silicates, aragonite, fluorite and opaline silica. Calcite precipitation is attributed mainly to rapid CO2 degassing, which led to high‐disequilibrium crystal morphologies. Stratigraphic evidence shows that the travertine formed during several stages separated by intervals of non‐deposition. Radiometric ages imply that the main phase of travertine formation occurred during the late Pleistocene (ca 32 to 35 ka). Periods of precipitation were influenced strongly by fluctuations in lake level, mostly under climate control, and by related changes in the depth of boiling. During relatively arid phases, meteoric recharge of ground water declines, the lake is low and becomes hypersaline, and the reduced hydrostatic pressure lowers the level of boiling in the plumbing system of the hot springs. Any carbonate precipitation then occurs below the land surface. During humid phases, the dilute meteoric recharge increases, enhancing geothermal circulation, but the rising lake waters, which become relatively dilute, flood most spring vents. Much of the aqueous Ca2+ then precipitates as lacustrine stromatolites on shallow firm substrates, including submerged older travertines. Optimal conditions for subaerial travertine precipitation at Loburu occur when the lake is at intermediate levels, and may be favoured during transitions from humid to drier conditions.  相似文献   

19.
Optically stimulated luminescence (OSL) has been employed successfully to determine the ages of palaeosols from earthen mounds in the southeastern USA, providing archaeologists with a means of dating monument construction in the absence of carbonaceous materials and geologists with a setting for understanding factors that can affect the luminescence intensity (i.e., burial dose) of soils. However, OSL dating has not been adequately tested on mounds whose principal component is sand, shell, or a combination of these two, despite the fact that monuments composed of such materials are common to the coasts and interior coastal plains of the region. Radiocarbon dating of bone collagen and soil‐carbon and OSL dating of quartz grains extracted from the fill of mounds at the Crystal River and Roberts Island sites on the west‐central coast of Florida, USA are used to determine the timing and history of mound construction at the sites. Comparison of OSL and radiocarbon ages on materials from the same or closely related contexts provides insight into factors influencing age determinations in mound fill deposits, particularly the type of construction material (sand or shell) and the manner in which these were deposited. The results contribute to the understanding of the temporal context of platform mound construction in southeastern USA.  相似文献   

20.
Long-standing controversy persists over the presence and role of iron–rich melts in the formation of volcanic rock-hosted iron deposits. Conjugate iron–rich and silica–rich melt inclusions observed in thin-sections are considered as direct evidence for the presence of iron-rich melt, yet unequivocal outcrop-scale evidence of iron-rich melts are still lacking in volcanic rock-hosted iron deposits. Submarine volcanic rock-hosted iron deposits, which are mainly distributed in the western and eastern Tianshan Mountains in Xinjiang, are important resources of iron ores in China, but it remains unclear whether iron-rich melts have played a role in the mineralization of such iron ores. In this study, we observed abundant iron-rich agglomerates in the brecciated andesite lava of the Heijianshan submarine volcanic rock–hosted iron deposit, Eastern Tianshan, China. The iron-rich agglomerates occur as irregular and angular masses filling fractures of the host brecciated andesite lava. They show concentric potassic alteration with silicification or epidotization rims, indicative of their formation after the wall rocks. The iron-rich agglomerates have porphyritic and hyalopilitic textures, and locally display chilled margins in the contact zone with the host rocks. These features cannot be explained by hydrothermal replacement of wall rocks(brecciated andesite lava) which is free of vesicle and amygdale, rather they indicate direct crystallization of the iron-rich agglomerates from iron-rich melts. We propose that the iron-rich agglomerates were formed by open-space filling of volatile-rich iron-rich melt in fractures of the brecciated andesite lava. The iron-rich agglomerates are compositionally similar to the wall-rock brecciated andesite lava, but have much larger variation. Based on mineral assemblages, the iron-rich agglomerates are subdivided into five types, i.e., albite-magnetite type, albite-K-feldsparmagnetite type, K-feldspar–magnetite type, epidote-magnetite type and quartz-magnetite type, representing that products formed at different stages during the evolution of a magmatic-hydrothermal system. The albite-magnetite type represents the earliest crystallization product from a residual ironrich melt; the albite-K-feldspar-magnetite and K-feldspar-magnetite types show features of magmatichydrothermal transition, whereas the epidote-magnetite and quartz-magnetite types represent products of hydrothermal alteration. The occurrence of iron-rich agglomerates provides macroscopic evidence for the presence of iron-rich melts in the mineralization of the Heijianshan iron deposit. It also indicates that iron mineralization of submarine volcanic rock-hosted iron deposits is genetically related to hydrothermal fluids derived from iron-rich melts.  相似文献   

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