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1.
《Marine Chemistry》2002,79(1):27-36
Preformed Cd and PO4 were investigated in the northwestern Pacific (Station CM05) and the Okhotsk Sea (Station CM06), and the relationship between the two elements was examined. At CM05, from the apparent oxygen utilization (AOU)–Cd and PO4 plot, the different molecular ratios of consumed O2 to regenerated Cd and PO4 were calculated to be 254,000 (Cd) and 96 (PO4) for the shallow layer (30–99 m) and 613,000 (Cd) and 170 (PO4) for the deep layer (below the oxygen minimum layer), which suggested the preferential remineralization of Cd and PO4 in the shallow layer. At CM06, regeneration ratios of O2/Cd, PO4 were obtained only in the shallow layer (29–124 m) as 227,000 (Cd) and 75 (PO4). The calculated preformed Cd and PO4 concentrations in the shallow layer were 0.59 nM of Cd and 1.6 μM of PO4 at CM05 and 0.35 nM of Cd and 0.95 μM of PO4 at CM06. These concentrations were much higher than those (close to 0) in the low-latitude area, which was attributable to the supply of these constituents from deep water by the strong winter convection. In the deep layer, at CM05, preformed concentrations were 0.64 nM of Cd and 1.4 μM of PO4. Preformed PO4 generally agreed with previously reported values in the Pacific, which suggested that the concentrations of the initial PO4 in the deep water were preserved as preformed through the movement to the northwestern Pacific. On the other hand, obtained preformed Cd in the northwestern Pacific deep water showed a somewhat higher value than that in the southwest Pacific. The possibility of the terrestrial input and remineralization of Cd by CaCO3 dissolution during the northward movement was considered. A plot of Cd and PO4 showed a linear relationship with slopes of 0.34 and 0.40 (nM/μM) at CM05 and CM06, respectively, which generally agreed with the reported values in the North Pacific.  相似文献   

2.
Total dissolvable metals (Co, Ni, Cu, Cd, and Pb) in both surface waters and the water columns were acquired in the southern East/Japan Sea during a cruise around the Ulleung Basin in June 2001 to understand the spatial distributions of the metals. Concentrations in offshore surface waters were found to be Co 60 ± 12 pM, Ni 2.16 ± 0.25 nM, Cu 1.85 ± 0.55 nM, Cd 0.134 ± 0.018 nM, and Pb 155 ± 40 pM. Spatial distributions in surface waters showed that metal levels were generally enhanced at coastal sites in both Korea and Japan, where the metal distributions indicated complex patterns due to inputs, biogeochemical processes, and physical factors including upwelling. The Co distributions in the water columns seemed to be influenced predominantly by surface and bottom inputs, scavenged rather than regenerated at depth. For Cd, there was generally good agreement between the Cd and PO4 depth distributions, in agreement with the literature. The Cd/PO4 ratio from the water columns was found to be 0.133–0.203, lower than that in other marginal seas (e.g. the East/South China Seas and the Philippine Sea) of the western Pacific Ocean; this might be a result of the fast ventilation rate in this sea. The vertical Pb profile showed typical scavenged-type behavior with a surface maximum and deep minimum. From a comparison of inputs from the atmosphere and the Tsushima Warm Current, atmospheric deposition is substantial enough that it cannot be ignored, and its role in metal cycling is more significant in the offshore zone.  相似文献   

3.
Cadmium is a biologically important trace metal that co-varies with phosphate (PO43− or Dissolved Inorganic Phosphate, DIP) in seawater. However, the exact nature of Cd uptake mechanisms and the relationship with phosphate and other nutrients in global oceans remain elusive. Here, we present a time series study of Cd and PO43− from coastal Antarctic seawater, showing that Cd co-varies with macronutrients during times of high biological activity even under nutrient and trace metal replete conditions. Our data imply that Cd/PO43− in coastal surface Antarctic seawater is higher than open ocean areas. Furthermore, the sinking of some proportion of this high Cd/PO43− water into Antarctic Bottom Water, followed by mixing into Circumpolar Deep Water, impacts Southern Ocean preformed nutrient and trace metal composition. A simple model of endmember water mass mixing with a particle fractionation of Cd/P (αCd–P) determined by the local environment can be used to account for the Cd/PO43− relationship in different parts of the ocean. The high Cd/PO43− of the coastal water is a consequence of two factors: the high input from terrestrial and continental shelf sediments and changes in biological fractionation with respect to P during uptake of Cd in regions of high Fe and Zn. This implies that the Cd/PO43− ratio of the Southern Ocean will vary on glacial–interglacial timescales as the proportion of deep water originating on the continental shelves of the Weddell Sea is reduced during glaciations because the ice shelf is pinned at the edge of the continental shelf. There could also be variations in biological fractionation of Cd/P in the surface waters of the Southern Ocean on these timescales as a result of changes in atmospheric inputs of trace metals. Further variations in the relationship between Cd and PO43− in seawater arise from changes in population structure and community requirements for macro- and micronutrients.  相似文献   

4.
The relationship between dissolved cadmium (Cd) and phosphate (PO4) was examined at three stations in the subtropical area near the Ryukyu Islands in May 1999. Preformed PO4 was obtained using the Redfield ratio in order to separate the surface water and the other layers in this study area. Almost 0 μM (−0.043 μM to 0.094 μM) was estimated in the layers above 300 m and 250 m at Sts. 1 and 3 and at St. 2, respectively. Up to these depths, water was considered to be uniform, and these layers were defined as the surface water in this study area. In the surface water, the slopes of the regression lines of the Cd-PO4 plot were 0.162, 0.156, and 0.226 (nM/μM) at Sts. 1, 2, and 3, respectively, and these values were much closer to the estimated regenerated ratio of Cd to PO4 from the Apparent Oxygen Utilization (AOU)-Cd/PO4 plots, which was 0.197 (nM/μM) in this study area. Below surface layers, the slopes of the Cd-PO4 plot changed to 0.371, 0.352, and 0.362 (nM//μM) at Sts. 1, 2, and 3, respectively. In the relationships between Cd and PO4, clear deviations or kinks were observed at three stations at a PO4 concentration of approximately 0.2 μM in the plot, which was attributable to the discontinuity of surface water and the other layers across the North Pacific subtropical mode water. In studies of the interaction between surface water and biogenic particles concerning the Cd/PO4 ratio, separate analyses of seawater (surface water and the other layers) should be carried out to obtain the individual surface water ratio because the Cd/PO4 ratio in the surface water is expected to differ from that of the underlying water. Furthermore, the biological fractionation of these constituents is based on the surface water ratio. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

5.
Variation in the cadmium (Cd) concentration related to phosphate (PO4) in the surface layer (0–150 m) of the equatorial Pacific (175°E, 170°W, and 160°W) was investigated in January of 2001 and 2002. A plot of Cd against PO4 from 0 to 150 m showed good linearity, and plotted points shifted in the direction of the origin along the regression line from 2001 to 2002. The variation of the Cd concentration in the surface layer was attributed to biological uptake-regeneration, the variation of subsurface water concentration, and the upwelling effect at each station in connection with the El Nino phenomenon.  相似文献   

6.
The fluorescence of dissolved organic matter in seawater   总被引：3，自引：0，他引：3  
A total of 28 vertical profiles of seawater fluorescence was measured in the Sargasso Sea, the Straits of Florida, the Southern California Borderlands, and the central Pacific Ocean. In all cases, surface seawater fluorescence was low as a result of photochemical bleaching which occurs on the timescale of hours. Fluorescence of deep water was 2–2.5 times higher than that of surface waters, and was constant, implying a long residence time for fluorescent organic matter, possibly of the order of thousands of years. Fluorescence correlates well with nutrients (NO3−, PO43−) in mid-depth waters (100–1000 m) in the Sargasso Sea and the central North Pacific, consistent with results in the central Pacific and the coastal seas of Japan. This suggests that regeneration or formation of fluorescent materials accompanies the oxidation and remineralization of settling organic particles.The various sources and sinks of fluorescent organic matter in the global oceans are assessed. The major sources are particles and in situ formation; rivers, rain, diffusion from sediments, and release from organisms are minor sources. The major sink is photochemical bleaching.  相似文献   

7.
Profiles of total dissolvable Cd, Cu, Mn and Ni are reported for samples collected from the southwest Pacific in 1989, from the western equatorial Pacific along 155°E at 5°S, 0° and 5°N in 1990 and 1993, and along the equator from 143°E to 152°E and in the Bismarck Sea in 1997 and 2000. Profiles of Cd along 155°E in 1990 and along the equator were essentially the same but, in 1993, Cd values at 5°N were higher by a factor of about 1.5–2 than at 5°S over the depth range 500–1500 m. Similar, but less pronounced, differences were observed for PO4 and Ni. Cd and Ni were both strongly correlated with PO4, and an even stronger correlation was found between Ni and Cd. The concentration of Ni did not fall below ≈2 nmolkg−1, even in the nitrate-depleted waters of the western equatorial Pacific, where primary production is strongly dependent on recycled nitrogen (mainly ammonia and urea). It is proposed that this residual Ni is not bioavailable and that Ni could be biolimiting, since the metabolism of urea requires the nickel-containing enzyme urease. The impact of the Sepik River on Cd, Cu and Ni concentrations was small but elevated concentrations of Mn were observed near the Sepik River and close to the coast suggesting that the rivers and sediments on the north coast of New Guinea are a significant local source of Mn to the Bismarck Sea. Simple mass balance calculations show that the elevated levels of Mn observed in the Equatorial Undercurrent cannot be due to input from the rivers of New Guinea and they were attributed to the trapping of particulate matter due to strong current shear. A strong hydrothermal source of Mn was observed in the central Bismarck Sea.  相似文献   

8.
The time series of dissolved oxygen (DO) concentration in the Japan Sea Proper Water (JSPW) shows clear interdecadal oscillation with about 20-year periodicity since the 1970s. This interdecadal variation in the DO concentration is positively correlated with the Arctic Oscillation (AO) index; the DO concentration tends to be high during a positive AO phase when the East Asian winter monsoon (EAWM) is relatively weak, which is considered to be an unfavorable condition for the JSPW formation. To clarify the discrepancy, the cause of the interdecadal oscillation was investigated using the wind at Wajima and sea surface temperature (SST) in the JSPW formation area. The cold-air outbreaks determined from the wind at Wajima are synchronized with the interdecadal oscillation of the AO; during a positive AO phase the cold-air outbreaks over the Japan Sea are more active, as reported by Isobe and Beardsley (2007). Since the SST in the JSPW formation area is negatively correlated with cold-air outbreaks, the activity of cold-air outbreaks is more important to the JSPW formation than the EAWM, at least on an interdecadal timescale. Significant correlations of the indicator of low pressure migration with the AO and cold-air outbreaks confirm that atmospheric disturbances move frequently into the Japan Sea from the East China Sea in a positive AO phase. A detailed examination of cold-air outbreaks revealed that the passing of atmospheric low pressures temporarily enhances the east-west pressure gradient over the Japan Sea and effectively brings cold air into the JSPW formation area.  相似文献   

9.
The relationship between Cd and PO4 in the Kuroshio and Oyashio regions and the Okhotsk Sea was examined. The resultant equations are as follows: Cd (ng l–1)=37.0 PO4 (M)+2.6; Cd(ng l–1)=32.1 PO4 (M)+1.2 and Cd (ng l–1)=34.1 PO4 (M)+7.9, respectively. These results are in good agreement with previously reported studies, and indicate that during removal from surface waters to deeper waters by biological assimilation and regeneration in deeper waters Cd and PO4 maintain the same ratio in the open ocean. The relationship between Cd and PO4 in coastal waters, however, differed from that in the open ocean.  相似文献   

10.
A column concentration-high resolution inductively coupled plasma mass spectrometry (ICP-MS) determination was applied to measure the total dissolved concentrations of Fe, Co, Ni, Cu and Zn in seawater collected from the subarctic North Pacific (~45°N) and the Bering Sea in July–September 1997. Total adsorbable Mn was determined on board by column electrolysis preconcentration and chemiluminescence detection. The vertical profiles for Fe, Ni and Zn were nutrient-like. The deep water concentration of Fe was ~0.5 nM in the northeast Pacific (18°-140°W) and increased to ~1 nM in the northwest Pacific (161°E) and ~2 nM in the Bering Sea (57°N, 180°E). The deep water concentrations for Ni and Zn in the Bering Sea were also 1.3–2 times higher than in the North Pacific. The profiles for Co and Cu were examined in the subarctic North Pacific, and results obtained were consistent with previous reports. There was a significant correlation between the concentrations of Co and Mn except for surface mixed layer. The profiles for total adsorbable Mn were similar to the reported profiles for total dissolvable Mn. The deep water concentration of Mn in the Bering Sea was also 4 times higher than in the North Pacific. Iron and zinc were depleted in surface water of the subarctic North Pacific. The relationship between these trace elements and nutrients suggests that these elements could be a limiting factor of phytoplankton productivity. In the Bering Sea, surface water contained ~0.3 nM of Fe. The Zn concentration, which was less than the detection limit in surface water, increased at shallower depths (~30 m) compared with the subarctic North Pacific. These results imply a higher flux of Fe and Zn to surface water in the Bering Sea. This in turn may cause the ecosystem in the Bering Sea characterized by a dominance of diatoms and high regenerated production.  相似文献   

11.
Excess CO2 and pHexcess showing an increase in dissolved inorganic carbon and a decrease in pH from the beginning of the industrial epoch (middle of the 19th century) until the present time have been calculated in the intermediate water layer of the northwestern Pacific and the Okhotsk Sea. It is concluded that: (1) The Kuril Basin (Okhotsk Sea) and the Bussol' Strait areas are characterized by the greatest concentrations of excess CO2 at isopycnal surfaces due to the processes of formation and transformation of intermediate water mass. (2) The largest difference in excess CO2 concentration between the Okhotsk Sea and the western subarctic Pacific (about 8 µmol/kg) is found at the = 27.0. (3) The difference in excess CO2 between the western subarctic Pacific and subtropical regions is significant only in the upper part of the intermediate water layer ( = 26.7–27.0). (4) About 10% of the excess CO2 accumulation in the subtropical north Pacific is determined by water exchange with the subarctic Pacific and the Okhotsk Sea.  相似文献   

12.
The vertical distribution of density, salinity, temperature, dissolved oxygen, apparent oxygen utilization, nutrients, preformed phosphate, pH, alkalinity, alkalinity: chlorinity ratio, in situ partial pressure of carbon dioxide, and percent saturation of calcite and aragonite, for the Southeastern Bering Sea, is studied and explained in terms of biological and physical processes. Some hydrological interactions between the Bering Sea and the North Pacific Ocean are explained. The horizontal distribution of dissolved oxygen at 2000 and 2500 m depths, throughout the Bering Sea, indicates that deep water is flowing from the Pacific, through the Kamchatka Strait, and then northward and eastward in the Bering Sea. Based on the dissolved oxygen distribution we estimate roughly that it takes 20 years for the deep waters to move from the Kamchatka Strait to the Southeastern part of the eastern basin. The surface concentration of nutrients is higher in the Bering Sea than in the North Pacific Ocean, probably because of upwelling and intense vertical mixing in the Bering Sea. A multivariable regression analysis of dissolved oxygen as a function of phosphate concentration and potential temperature was applied for the region where the potential temperature-salinity diagram is straight, and the confidence interval of the PO4 coefficient, at the 95% probability level, was found consistent with theRedfield biochemical oxidation model. The calcium carbonate saturation calculations show that the Bering Sea is supersaturated with aragonite in the upper 100 m, and with calcite in the upper 200 m. Below these depths seawater is undersaturated with respect to these two minerals.  相似文献   

13.
Marked fluctuation of concentrations of90Sr and137Cs was observed in the bottom waters at the entrance of Wakasa Bay during 1987–1992, and the cause was investigated. The concentrations of90Sr and137Cs in the bottom waters were significantly low when the upper level of the Japan Sea Proper Water (JSPW) was high and covered the sampling depth, but high when the upper level of the JSPW was low. The cause of the fluctuation observed in the bottom waters is, therefore, suggested to be the vertical fluctuation of the upper level of the JSPW on the shelf slope, which has been little described before.  相似文献   

14.
Like most other deep basins in Southeast Asia, the deep Sulu Sea (SS) basin is isolated from the neighboring seas by surrounding topography. While the near-surface circulation is mainly governed by the seasonally reversing monsoon winds, below the warm and fresh surface layer, the core of the incoming Subtropical Lower Water from the West Philippine Sea (WPS), by way of the South China Sea (SCS), can be seen, at a depth of around 200 m, to have a distinct salinity maximum. It lies well above the sill depth (420 m) in the Mindoro Strait and thus, its spreading is not hampered by topography. The deep circulation is forced by an inflow of upper North Pacific Intermediate Water (NPIW) from the SCS through the Mindoro Str. Below 1000 m, the physico-chemical properties are remarkably homogeneous. The higher temperature, but lower salinity, oxygen and nutrients, of the deep SS waters, compared to those of the SCS, is indicative of the intrusion of NPIW above the sill depth. The excess, anthropogenic CO2 penetrates the entire water column, because of the over-spill of the excess CO2-laden water from the SCS.It has been reported that the bottom of the SS is CaCO3 rich, relative to the SCS. Previous investigators attribute this to the higher θ in the SS. Indeed, the aragonite does not become undersaturated in the SS until below 1400 m, compared to 600 m in both the WPS and SCS; and the calcite does not become undersaturated until below 3800 m in the SS, compared to 2500 m in the SCS and around 1600 m in the WPS. However, the temperature effect is relatively small. These large differences are, in fact, largely a result of higher CO32− concentrations in the SS, relative to the WPS and SCS. The higher CO32− concentration in the SS, in turn, is mainly caused by the smaller amounts of organic carbon decomposition.  相似文献   

15.
We have collected fifty-five seawater samples at seven stations at various depths in the Yamato and Japan Basins of the Japan Sea and measured their helium isotopic ratios. The 3He/4He ratios vary from 0.997 Ratm to 1.085 Ratm where Ratm is the atmospheric ratio. The maximum 3He excesses about 8%, are observed at mid-depth (1000 m), and these values are significantly lower than those observed in deep Pacific waters. This implies that mantle-derived helium in deep Pacific water cannot enter the Japan Sea since it is an almost landlocked marginal sea. The observed 8% excess 3He may be attributable to the decay product of tritium. Slightly higher 3He/4He ratios in the Bottom Water were observed in the Yamato Basin than in the Japan Basin. The ventilation ages of seawater shallower than 1000 m are calculated as about 5 to 20 years, which is consistent with the CFC ages reported in the literature. There is a positive correlation between the apparent oxygen utilization and 3H-3He ages. The estimated oxygen utilization rate from the correlation in a layer between 500 m and 1000 m is about 3 μmol/kg/yr, which is similar to that in the eastern subtropical North Atlantic.  相似文献   

16.
More than 14,000 measurements of surface water xCO2 were obtained during two cruises, 3 weeks apart in June 2000, along 155°E between 34 and 44°N in the western North Pacific Ocean. Based on the distributions of salinity and sea surface temperature (SST), the region has been divided into 6 subregions; Oyashio, Oyashio front, Transition, Kuroshio front, and Kuroshio extension I and II zones, from north to south. The surface waters were always undersaturated with respect to atmospheric CO2. The Oyashio water was the least undersaturated: its xCO2 decreased slightly by 7 ppm, while SST increased by 2°C. The xCO2 normalized to a constant temperature decreased considerably. In the two frontal zones, a large drawdown of 30–40 ppm was observed after 18–19 days. In the Kuroshio extension zones, the xCO2 increased, but the normalized xCO2 decreased considerably. The Transition zone water may be somewhat affected by mixing with the subsurface water, as indicated by the smallest SST rise, an undecreased PO4 concentration, and a colder and less stable surface layer than the Oyashio front water. As the uncertainty derived from the air-sea CO2 flux was not large, the xCO2 data allowed us to calculate the net biological productivity. The productivities around 60 mmol C m−2d−1 outside the Transition zone indicate that the northwestern North Pacific, especially the two frontal zones, can be regarded as one of the most productive oceans in the world.  相似文献   

17.
The first iron (Fe) – fertilization experiment in the western North Pacific was carried out using SF6 to trace the Fe-fertilized water mass. A solution in 10,800 liters of seawater of 350 kg of Fe and 0.48 M of SF6 tracer was released into the mixed layer over a 8 × 10 km area. On the first underway transects through the patch after the Fe release, we observed a significant increase of dissolved Fe (ave. 2.89 nM). The fertilized patch was traced for 14 days by on-board SF6 analysis. A Lagrangian frame of reference was maintained by the use of a drogued GPS buoy released at the center of the patch. The patch moved westward at a rate of 6.8 km d−1. Mixed layer depth increased from 8.5 to 15 m during the experiment. Horizontal diffusivity was determined by the change of SF6 concentration in the patch. The horizontal diffusivity increased during the experiment. We evaluate here the fate of Fe in a Fe-fertilized patch using the dilution rate determined from sulphur hexafluoride (SF6) concentration. Dissolved Fe concentrations subsequently decreased rapidly to 0.15 nM on Day 13. However, the dissolved Fe half-life of 43 h was relatively longer than in previous Fe-enrichment studies, and we observed a larger increase of the centric diatom standing stock and corresponding drawdown of macro-nutrients and carbon dioxide than in the previous studies. The most important reason for the larger response was the phytoplankton species in the western North Pacific. In addition, the smaller diffusivity and shallower mixed layer were effective to sustain the higher dissolved Fe concentration compared to previous experiments. This might be one reason for the larger response of diatoms in SEEDS.  相似文献   

18.
本文利用World Ocean Atlas 2013（WOA2013）气候态的温盐资料和the Simple Ocean Data Assimilation （SODA v3.3.1）流场数据，分析印尼贯穿流东部源区马鲁古海和哈马黑拉海的水团垂向分布特征及其来源，特别是次表层、中层及深层水的来源和路径。结果表明，气候态下，马鲁古海次表层的高温高盐水来自于北太平洋，与北太平洋热带水性质接近，哈马黑拉海次表层主要是来自南太平洋热带水；中层水以低温低盐为特征，马鲁古海的中层水来自南太平洋，受南极中层水控制，哈马黑拉海的中层水可能是从马鲁古海而来的南太平洋水；对于次表层和中层之间的过渡层，马鲁古海与哈马黑拉海的水源为南、北太平洋的混合水，且两个海域之间也存在着水团交换；在深层，马鲁古海的水源更倾向于班达海北部及塞兰海，而与太平洋水无关，哈马黑拉海由于地形阻挡也难以与太平洋直接发生水团交换。  相似文献   

19.
The distribution of228Ra in surface and subsurface waters in the Japan Sea was studied. The concentrations of228Ra in surface waters were around 100 dpm/1000l which were much higher than those reported for Pacific surface waters. The concentrations of228Ra decreased with increasing depth to less than 10 dpm/1000l in the Japan Sea Proper Water. Based on the comparison between observed values of228Ra and calculated profile through the near-surface water mass and the underlying main water mass in the Japan Sea, the apparent vertical eddy diffusion coefficient was estimated to be about 2 cm2 s–1.  相似文献   

20.
The relation between the nitrate and phosphate concentrations in the Sea of Okhotsk and the bordering waters of the Pacific Ocean were studied. The surveys were carried out in the autumn, spring, and summer of 2001–2002. For the deepwater part of the sea, the relation [NO? 3] = ((14.88 ± 0.07) × [PO3? 4] ? 5.46 ± 0.17) was found. The coefficients in the equation given are statistically different from those in the similar equation for the Pacific waters: [NO? 3] = (16.05 ± 0.15) × [PO3? 4]-(7.23 ± 0.36). In the northern part of the sea; on the shelf; in the slope area; and, especially, in the deep waters of the TINRO Depression, the linear dependence between the phosphate and nitrate concentrations was distorted. This feature was described in terms of nitrate deficiency. The maximum values of this deficiency were found in the near-bottom waters. The principal processes that might cause the nitrate deficiency were considered: the difference in the oxidation rates of the nitrogen and phosphorus organic compounds, the matter transfer between the continent and the sea, the different efficiency of the biogenic burial of nitrogen and phosphorus in the bottom sediments, and the denitrification in the upper layer of the bottom sediments. It was shown that the most probable cause of the nitrate deficiency was the denitrification. The loss of inorganic nitrogen owing to the supply of the waters of the Sea of Okhotsk to the Pacific Ocean was estimated as ～2.5 × 1011 mol N/year.  相似文献   

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