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1.
Chlorophyll and carotenoid pigments were measured at stations in the Bismarck Sea north of Papua New Guinea and along the equator between 143°E and 152°E as part of the Tropical River Ocean Processes In Coastal Settings (TROPICS) programme in August 1997 and January/February 2000. Algal class abundances were estimated from these pigments using the CHEMTAX programme. The algal classes likely to be present (based on microscopy, HPLC chromatograms, literature and unpublished data from the region) and estimated by CHEMTAX were diatoms, cryptophytes, chlorophytes, haptophytes, chrysophytes, Synechococcus and Prochlorococcus. The first period corresponded to the SE tradewind season, when there was a drought in Papua New Guinea and the discharge from the Sepik River was unusually low. Samples were collected on four N–S transects (approximately 150 km in length): one to the east of the Sepik River, one from the mouth of the Sepik River and two to the west of the Sepik River. Stations in the central Bismarck Sea and along the equator were characterised by a deep chlorophyll maximum (DCM), and haptophytes and Prochlorococcus were the major algal classes. Stations affected by the Sepik River plume were characterised by a more homogeneous distribution of chlorophyll with chlorophytes making a significant contribution, particularly at shallower depths. Synechococcus and chrysophytes were moderately abundant, while cryptophytes and diatoms were of minor importance. The second cruise occurred during the NW monsoon under conditions of high river flow, and samples were collected along a transect from the mouth of the Sepik River to Manus Island and in the central Bismarck Sea. Chlorophyll concentrations were higher than in 1997, particularly in near surface waters, while a DCM was generally not observed at any station in the Bismarck Sea—even at stations upstream (and upwind) and far removed from the mouth of the Sepik River. Prochlorococcus made a smaller, and chlorophytes a larger, contribution to chlorophyll than in 1997. Unlike the situation in 1997, there were large station to station variations in the vertical profiles of chlorophyll and algal class distributions which cannot be attributed directly to the plume from the Sepik River. Pigment ratios, fitted by the CHEMTAX programme, were generally in good agreement with literature values.  相似文献   

2.
Distributions of cadmium, copper and nickel at four stations in the eastern part of the Atlantic Ocean from 30 ° S to 34 ° N are described based on analytical results from three laboratories. The Cd and Ni profiles show nutrient-like distributions with concentrations in the deep waters increasing from north to south. Copper profiles all show gradual increases from surface to bottom with the highest concentrations occurring near bottom on the most northerly station.Variations in the deep-water Cd and Ni concentrations can be understood in terms of mixing of southern source waters with high concentrations with lower concentration northern source waters. The deep-water Cu distributions indicate a significant near-bottom source to the northern end of the section.Cadmium vs. phosphate relationships show features that result from both regeneration and mixing. Higher Cd:PO4 ratios are seen in the southern source waters than in the northern waters, thus discounting the suggestion that the inflection in the global Cd:PO4 relationship at PO4 ≈ 1.3 μM originates in the southern ocean. Differential regeneration of Cd and PO4 is seen through the equatorial oxygen minimum.  相似文献   

3.
Variation in the cadmium (Cd) concentration related to phosphate (PO4) in the surface layer (0–150 m) of the equatorial Pacific (175°E, 170°W, and 160°W) was investigated in January of 2001 and 2002. A plot of Cd against PO4 from 0 to 150 m showed good linearity, and plotted points shifted in the direction of the origin along the regression line from 2001 to 2002. The variation of the Cd concentration in the surface layer was attributed to biological uptake-regeneration, the variation of subsurface water concentration, and the upwelling effect at each station in connection with the El Nino phenomenon.  相似文献   

4.
The concentration level of cadmium (Cd) and the regeneration related to phosphate (PO4) were examined at two stations (CM10, CM12) in the eastern Japan Basin in July 1998. The observed Cd concentrations were around 0.2–0.3 nM and 0.5–0.6 nM in the surface and deep layers (Japan Sea Proper Water; JSPW), respectively; the concentration of Cd in the JSPW was much lower than that in the Pacific deep water, which is attributed to its specific formation system (which driven by the winter convection of the surface layer within the Japan Sea, thereafter descending to the deep layer) connected with the relatively active vertical mixing in the Japan Sea. A plot of Cd against PO4 showed good linearity with positive y-intercept values, suggesting that the excess Cd was apparently not available in the biogeochemical cycle. The molecular ratios of consumed O2 to regenerated Cd and PO4 in the JSPW were 688,000, 140 and 881,000, 146 for CM10 and CM12, respectively, and a lower preformed Cd concentration (around 0.37 nM) was also estimated in the JSPW, different from that of the North Pacific deep water (613,000 for Cd, 170 for PO4, and 0.64 nM of preformed Cd).  相似文献   

5.
Changes in the sea surface heights (SSH) and geostrophic currents along the eastern boundaries of the Pacific (North, Central and South America) are examined during the 1997–1998 El Niño using altimeter data and proxy winds. These show that ‘symmetric’ SSH signals left the equator and propagated into both Hemispheres in two episodes, with primary periods of high equatorial SSH during May–July and October–December 1997. These are the ‘distant signals’ from the mid-latitude perspective. As the signals spread poleward in each Hemisphere, their loss of symmetry demonstrates the degree to which they were altered by topographic features, local winds, and/or local currents. The first four EOFs are calculated for 2-D SSH fields in 10° wide strips along the eastern margins (60°N–60°S) and extending out along the equator from the coast to 110°W. These account for approximately 40% of the overall variability and represent the main features of the seasonal cycles and El Niño interannual variability. Snapshots of the 2-D SSH fields depict the structure of the El Niño signal at different phases of its evolution.  相似文献   

6.
Changes in the sea surface heights (SSH) and geostrophic transports in the NE Pacific are examined during the 1997–1998 El Niño using altimeter data, sea level pressure (SLP) fields, proxy winds and satellite sea surface temperature (SST). Most of the signal occurs along the boundaries of the basin from Panama to the Alaska Peninsula. Changes in the SSH and alongshore transports along the boundaries are caused both by propagation of signals from the south (stronger between the equator and the Gulf of California) and by local and basin-scale winds (stronger between the Pacific Northwest and the Alaska Peninsula). Two periods of high SSH occur at the equator, May–July 1997 and October 1997–January 1998. The first coastal SSH signal moved quickly polewards to approximately 24°N in early June, then stalled and moved farther north during transient events in July–September. Large-scale wind forcing combined with the equatorial signals during the second period of high equatorial SSH (Fall 1997) to move the high SSH and poleward transports quickly around the Alaska Gyre. A connection between the boundary currents and the interior North Pacific developed as part of the large-scale response to the basin-scale winds, after changes in the boundaries. Decreases in anomalies of SSH and poleward transports began in January 1998 south of 40°N and in February 1998 farther north.  相似文献   

7.
A coupled physical–biological model was developed to simulate the low-silicate, high-nitrate, and low-chlorophyll (LSHNLC) conditions in the equatorial Pacific Ocean and used to compute a detailed budget in the Wyrtki box (5°N–5°S, 180–90°W) for the major sources and cycling of nitrogen and silicon in the equatorial Pacific. With the incorporation of biogenic silicon dissolution, NH4 regeneration from organic nitrogen and nitrification of ammonia in the model, we show that silicon recycling in the upper ocean is less efficient than nitrogen. As the major source of nutrients to the equatorial Pacific, the Equatorial Undercurrent provides slightly less Si(OH)4 than NO3 to the upwelling zone, which is defined as 2.5°N–2.5°S. As a result, the equatorial upwelling supplies less Si(OH)4 than NO3 into the euphotic zone in the Wyrtki box, having a Si/N supply ratio of about 0.85 (2.5 vs. 2.96 mmolm−2 day−1). More Si(OH)4 than NO3 is taken up with a Si/N ratio of 1.17 (2.72 vs. 2.33 mmolm−2 day−1) within the euphotic zone. The difference between upwelling supply and biological uptake is balanced by nutrient regeneration and horizontal advection. Excluding regeneration, the net silicate and nitrate uptakes are nearly equal (1.76 vs. 1.84 mmolm−2 day−1). However, biogenic silica export production is slightly higher than organic nitrogen (1.74 vs. 1.59 mmolm−2 day−1) following a 1.1 Si/N ratio. In the central equatorial Pacific, low silicate concentrations limit diatom growth; therefore non-diatom new production accounts for most of the new production. Higher silicate supply in the east maintains elevated diatom growth rates and new production associated with diatoms dominate upwelling zone. In contrast, the new production associated with small phytoplankton is nearly constant or decreases eastward along the equator. The total new production has a higher rate in the east than in the west, following the pattern of surface silicate. This suggests that silicate regulates the diatom production, total new production, and thereby carbon cycle in this area. The modeled mean primary production is 48.4 mmolCm−2 day−1, representing the lower end of direct field measurements, while new production is 15.0 mmolCm−2 day−1, which compares well with previous estimates.  相似文献   

8.
Based on the TOGA-TAO buoy chain observed data in the equatorial Pacific and the assimilation analysis results from SODA(simple ocean data assimilation analysis), the role of the meridional cells in the subsurface of the tropical Pacific was discussed. It was found that, the seasonal varying direction of EUC (the quatorial Undercurrent)in the Peacific is westwards beginning from the eastern equatorial Pacific in the boreal spring. The meridional cell south of the equator plays important role on this seasonal change of EUC.On the other hand, although the varying direction is westwards,the seasonal variation of temperature in the same region gets its minimum values in the boreal autumn beginning from the eastern equatorial Pacific.The meridional cell north of the equator is most responsible for the seasonal temperature variation in the eastern equatorial Pacific while the meridional cell south of the equator mainly controls the seasonal temperature change in the central Pacific. It is probably true that the asymmetry by the equator is an important factor influencing the seasonal cycle of EUC and temperature in the tropical Pacific.  相似文献   

9.
The large-scale circulation of the Pacific Ocean consists of two great anticyclonic gyres that contract poleward at increasing depth, two high-latitude cyclonic gyres, two westward flows along 10° to 15° north and south that are found from the surface to abyssal depths, and an eastward flow that takes place just north of the equator at the surface and at about 500m, but lies along the equator at all other depths.This pattern is roughly symmetric about the equator except for the northward flow across the equator in the west and the southward flow in the east.As no water denser than about 26.8 in σ0 is formed in the North Pacific, the denser waters of the North Pacific are dominated by the inflow from the South Pacific. Salinity and oxygen in the deeper water are higher in the South Pacific and the nutrients are lower. These characteristics define recognizable paths as they move northward across the equator in the west and circulate within the North Pacific. Return flow is seen across the equator in the east. Part of it turns westward and then southward with the southward limb of the extended cyclonic gyre, and part continues southward along the eastern boundary and through the Drake Passage.The important differences from earlier studies are that the equatorial crossings and the deep paths of flow are defined, and that there are strong cyclonic gyres in the tropics on either side of the equator.  相似文献   

10.
A column concentration-high resolution inductively coupled plasma mass spectrometry (ICP-MS) determination was applied to measure the total dissolved concentrations of Fe, Co, Ni, Cu and Zn in seawater collected from the subarctic North Pacific (~45°N) and the Bering Sea in July–September 1997. Total adsorbable Mn was determined on board by column electrolysis preconcentration and chemiluminescence detection. The vertical profiles for Fe, Ni and Zn were nutrient-like. The deep water concentration of Fe was ~0.5 nM in the northeast Pacific (18°-140°W) and increased to ~1 nM in the northwest Pacific (161°E) and ~2 nM in the Bering Sea (57°N, 180°E). The deep water concentrations for Ni and Zn in the Bering Sea were also 1.3–2 times higher than in the North Pacific. The profiles for Co and Cu were examined in the subarctic North Pacific, and results obtained were consistent with previous reports. There was a significant correlation between the concentrations of Co and Mn except for surface mixed layer. The profiles for total adsorbable Mn were similar to the reported profiles for total dissolvable Mn. The deep water concentration of Mn in the Bering Sea was also 4 times higher than in the North Pacific. Iron and zinc were depleted in surface water of the subarctic North Pacific. The relationship between these trace elements and nutrients suggests that these elements could be a limiting factor of phytoplankton productivity. In the Bering Sea, surface water contained ~0.3 nM of Fe. The Zn concentration, which was less than the detection limit in surface water, increased at shallower depths (~30 m) compared with the subarctic North Pacific. These results imply a higher flux of Fe and Zn to surface water in the Bering Sea. This in turn may cause the ecosystem in the Bering Sea characterized by a dominance of diatoms and high regenerated production.  相似文献   

11.
In this study we document how model biases in extratropical surface wind and precipitation, due to ocean–atmosphere coupling, are communicated to the equatorial Pacific thermocline through Pacific Subtropical Cell (STC) pathways. We compare the simulation of climate mean Pacific Subtropical Cells (STCs) in the NCAR Community Climate System Model version 3 (CCSM3) to observations and to an uncoupled ocean simulation (the ocean component of the CCSM3 forced by observed wind stress and surface fluxes). We use two versions of the CCSM3 with atmospheric resolution of 2.8° (T42) and 1.4° (T85) to investigate whether the climate mean STCs are sensitive to the resolution of the atmospheric model.Since STCs provide water that maintains the equatorial thermocline, we first document biases in equatorial temperature and salinity fields. We then investigate to what extent these biases are due to the simulation of extratropical–tropical water mass exchanges in the coupled models. We demonstrate that the coupled models’ cold and fresh bias in the equatorial thermocline is due to the subduction of significantly fresher and colder water in the South Pacific. This freshening is due to too much precipitation in the South Pacific Convergence Zone. Lagrangian trajectories of water that flows to the equatorial thermocline are calculated to demonstrate that the anomalously large potential vorticity barriers in the coupled simulations in both the North and South Pacific prevent water in the lower thermocline from reaching the equator. The equatorial thermocline is shown to be primarily maintained by water that subducts in the subtropical South Pacific in both the coupled and uncoupled simulations. It is shown that the zonally integrated transport convergence at the equator in the subsurface branch of the climate mean STCs is well simulated in the uncoupled ocean model. However, coupling reduces the net equatorward pycnocline transport by 4 Sv at 9°S and 1 Sv at 9°N. An increase in the atmospheric resolution from T42 to T85 results in more realistic equatorial trades and off-equatorial convergence zones.  相似文献   

12.
《Marine Chemistry》2002,79(1):27-36
Preformed Cd and PO4 were investigated in the northwestern Pacific (Station CM05) and the Okhotsk Sea (Station CM06), and the relationship between the two elements was examined. At CM05, from the apparent oxygen utilization (AOU)–Cd and PO4 plot, the different molecular ratios of consumed O2 to regenerated Cd and PO4 were calculated to be 254,000 (Cd) and 96 (PO4) for the shallow layer (30–99 m) and 613,000 (Cd) and 170 (PO4) for the deep layer (below the oxygen minimum layer), which suggested the preferential remineralization of Cd and PO4 in the shallow layer. At CM06, regeneration ratios of O2/Cd, PO4 were obtained only in the shallow layer (29–124 m) as 227,000 (Cd) and 75 (PO4). The calculated preformed Cd and PO4 concentrations in the shallow layer were 0.59 nM of Cd and 1.6 μM of PO4 at CM05 and 0.35 nM of Cd and 0.95 μM of PO4 at CM06. These concentrations were much higher than those (close to 0) in the low-latitude area, which was attributable to the supply of these constituents from deep water by the strong winter convection. In the deep layer, at CM05, preformed concentrations were 0.64 nM of Cd and 1.4 μM of PO4. Preformed PO4 generally agreed with previously reported values in the Pacific, which suggested that the concentrations of the initial PO4 in the deep water were preserved as preformed through the movement to the northwestern Pacific. On the other hand, obtained preformed Cd in the northwestern Pacific deep water showed a somewhat higher value than that in the southwest Pacific. The possibility of the terrestrial input and remineralization of Cd by CaCO3 dissolution during the northward movement was considered. A plot of Cd and PO4 showed a linear relationship with slopes of 0.34 and 0.40 (nM/μM) at CM05 and CM06, respectively, which generally agreed with the reported values in the North Pacific.  相似文献   

13.
In situ observation of downward solar radiation in the Western Pacific were carried out with voluntary merchant ships for five years from autumn 1990 through autumn 1995. Daily means of the short wave radiation were computed from the observed solar radiation. Then, the effects of shadows of the ship's superstructures on the observed radiation were corrected if needed. A 5-year average of short wave radiation along the main sea-lanes in the Western Pacific was calculated based on the observed daily mean solar radiation. Maximum values of 270–280 Wm–2 are found around 15°–20°N in May and June, while those of 290 Wm–2 are observed south of 18°S in November and December along the lanes. Small annual variations are found in the equatorial region. Annual mean values at the equator are about 230 Wm–2 between New Guinea and Indonesia, and 200 Wm–2 east of New Guinea. The 5-year average of short wave radiation was compared with the climatologies given in previous studies. We have concluded that some of results of previous studies are significantly underestimated.  相似文献   

14.
The variability of the New Guinea Coastal Current (NGCC) and New Guinea Coastal Undercurrent (NGCUC) were examined from one year time series of current data from ADCP moorings at 2°S, 142°E and 2.5°S, 142°E. Change in the hydrographic structure induced by monsoonal wind forcing was also examined from hydrographic data along the 142°E covering consecutively two winter seasons and two summer seasons. The westward NGCUC was observed to persist year around. The annual mean depth of the current core was 220 m, the mean speed of the zonal component was 54 cm/s with a standard deviation of 15 cm/s at the 2.5°S site. Velocity fluctuations at 20–30 day period were observed year around. Seasonal reversal of the surface intensified NGCC was clearly observed. In the boreal summer characterized by the southeasterly monsoon, westward currents of over 60 cm/s were dominant in the surface layer. The warm, low-salinity layer thickened at this time and sloped down toward the New Guinea coast from the equator. This surface water accumulation may be caused by onshore Ekman drift at the New Guinea coast, combined with weak Ekman upwelling at the equator. In the boreal winter, an eastward surface current developed to 100 cm/s extending down to 100 m depth in response to the northwesterly monsoonal winds. Coastal upwelling was indicated in this season and the surface water accumulated at the equator due to Ekman convergence. Shipboard ADCP data indicated that the NGCUC intensified in boreal summer as the width and depth of the NGCUC increased.  相似文献   

15.
North Pacific Tropical Water (NPTW) is characterized as a subsurface salinity maximum flowing in the North Equatorial Current and is the main source of salt for the North Pacific. We briefly describe the climatological features of its formation and circulation, and then examine temporal changes in its properties associated with the climate regime shift in the 1970s. We use a variety of data, which include the repeat hydrographic sections along 130°E, 137°E, 144°E and 155°E meridians, the hydrographic data from the Hawaii Ocean Time-series, the World Ocean Atlas 1994, and available gridded data of wind stress and evaporation. The classical idea that NPTW originates from the zone of the highest sea surface salinity at 20°–30°N centered around the international date line and spreads along the isopycnal geostrophic flow patterns is confirmed. Further, it is shown that the meridional extent of NPTW along 137°E is from 10°N to 23°N on average and the highest salinity core lies at about 15°N and 24.0σθ, and that the portion of NPTW north (south) of about 15°N originates from the formation region west (east) of the date line. NPTW in the 137°E section changed remarkably associated with the mid-1970s regime shift. North of 15°N NPTW increased both in its salinity and thickness while to the south of 15°N only its salinity increased and its thickness remained unchanged. The westward geostrophic velocity is increased significantly in both the southern and northern parts of NPTW. The northern thickening and speedup and the southern speedup increased NPTW transport across 137°E. The changes in the thermohaline forcing such as evaporation and Ekman salt convergence in the NPTW formation region possibly contributed to the increases in salinity in the southern part of NPTW, but not to that of the northern part. On the other hand, the increased Ekman pumping accounts for the increase of the NPTW inventory and transport at 137°E. The increased salinity of NPTW at 137°E, especially its northern portion, was presumably caused by an increase in its formation rate rather than changes in the sea surface salinity in its formation region; the thicker the NPTW layer is, the saltier is the core that tends to survive the mixing processes.  相似文献   

16.
The meridional distribution of autotrophic picoplankton groups in the central north Pacific was studied during the late northern summer of 1990. Sampling was along a section at 175°N which extended from 45°N to 8°S. The section is far from coastal regions and included subarctic, central gyre, and equatorial areas. Five autotrophic picoplankton groups, autotrophic microflagellate, red-fluorescing picoplankton,Synechococcus, prochlorophyte, and orange-fluorescing picoplankton, were identified from samples taken at stations distributed along this section. These five groups showed distinctive differences in their meridional and vertical distributions. The autotrophic microflagellates and red-fluorescing picoplankton showed distributions that were similar to that of chlorophyll a, which was dominated by the <3 μm size fraction. However, the vertical distribution of these groups was different.Synechococcus was found mostly in surface waters (PAR<10%) and was particularly abundant in the Kuroshio Extension and south of the equatorial region where the nitracline was shallow (50–75 m). Prochlorophytes were abundant in the deep euphotic layer (PAR 1-0.1%) from the south of the Kuroshio Extension to the south of the equatorial area. Orange-fluorescing picoplankton, which may be one kind of cyanobacteria but is larger than typical Synechococcus, were mostly distributed in the oligotrophic surface waters of the central gyre. The carbon biomass estimates for these organisms showed that these five groups dominated in different areas. The vertical distribution of carbon biomass did not correspond to that of chlorophyll a in the central gyre and south of the equator because of the larger carbon/ chlorophyll a ratio of Synechococcus and orange-fluorescing picoplankton relative to that of the other picoplankton.  相似文献   

17.
The relationship between Cd and PO4 in the Kuroshio and Oyashio regions and the Okhotsk Sea was examined. The resultant equations are as follows: Cd (ng l–1)=37.0 PO4 (M)+2.6; Cd(ng l–1)=32.1 PO4 (M)+1.2 and Cd (ng l–1)=34.1 PO4 (M)+7.9, respectively. These results are in good agreement with previously reported studies, and indicate that during removal from surface waters to deeper waters by biological assimilation and regeneration in deeper waters Cd and PO4 maintain the same ratio in the open ocean. The relationship between Cd and PO4 in coastal waters, however, differed from that in the open ocean.  相似文献   

18.
Deep-circulation flow at mid-latitude in the western North Pacific   总被引：1，自引：1，他引：1  
Direct current measurements with five moorings at 27–35°N, 165°E from 1991 to 1993 and with one mooring at 27°N, 167°E from 1989 to 1991 revealed temporal variations of deep flow at mid-latitude in the western North Pacific. The deep-circulation flow carrying the Lower Circumpolar Deep Water from the Southern Ocean passed 33°N, 165°E northwestward with a high mean velocity of 7.8 cm s−1 near the bottom and was stable enough to continue for 4–6 months between interruptions of 1- or 2-months duration. The deep-circulation flow expanded or shifted intermittently to the mooring at 31°N, 165°E but did not reach 35°N, 165°E although it shifted northward. The deep-circulation flow was not detected at the other four moorings, whereas meso-scale eddy variations were prominent at all the moorings, particularly at 35°N and 29°N, 165°E. The characteristics of current velocity and dissolved oxygen distributions led us to conclude that the deep-circulation flow takes a cyclonic pathway after passing through Wake Island Passage, passing 24°N, 169.5–173°E and 30°N, 168–169°E northward, proceeds northwestward around 33°N, 165°E, and goes westward through the south of the Shatsky Rise. We did not find that the deep-circulation flow proceeded westward along the northern side of the Mid-Pacific Seamounts and eastward between the Hess Rise and the Hawaiian Ridge toward the Northeast Pacific Basin.  相似文献   

19.
Total dissolvable metals (Co, Ni, Cu, Cd, and Pb) in both surface waters and the water columns were acquired in the southern East/Japan Sea during a cruise around the Ulleung Basin in June 2001 to understand the spatial distributions of the metals. Concentrations in offshore surface waters were found to be Co 60 ± 12 pM, Ni 2.16 ± 0.25 nM, Cu 1.85 ± 0.55 nM, Cd 0.134 ± 0.018 nM, and Pb 155 ± 40 pM. Spatial distributions in surface waters showed that metal levels were generally enhanced at coastal sites in both Korea and Japan, where the metal distributions indicated complex patterns due to inputs, biogeochemical processes, and physical factors including upwelling. The Co distributions in the water columns seemed to be influenced predominantly by surface and bottom inputs, scavenged rather than regenerated at depth. For Cd, there was generally good agreement between the Cd and PO4 depth distributions, in agreement with the literature. The Cd/PO4 ratio from the water columns was found to be 0.133–0.203, lower than that in other marginal seas (e.g. the East/South China Seas and the Philippine Sea) of the western Pacific Ocean; this might be a result of the fast ventilation rate in this sea. The vertical Pb profile showed typical scavenged-type behavior with a surface maximum and deep minimum. From a comparison of inputs from the atmosphere and the Tsushima Warm Current, atmospheric deposition is substantial enough that it cannot be ignored, and its role in metal cycling is more significant in the offshore zone.  相似文献   

20.
The multiple-parameter linear regression method (Monitoring global ocean carbon inventories. Ocean Observing System Development Panel, Texas A&M University, College Station, TX, 1995, 54pp; Global Biogeochem. Cycles 13 (1999) 179) is used to compare inorganic carbon data from the GEOSECS CO2 survey in the Pacific Ocean in 1973 to the WOCE/JGOFS global CO2 survey in the 1990s. A model of total dissolved inorganic carbon (DIC) as a function of five variables (AOU, θ, S, Si, and PO4) has been developed from the recent CO2 survey data (namely CGC91 and CGC96) in the Pacific Ocean. After correcting for a systematic DIC offset of −30.3±7 μmol kg−1 from the GEOSECS data, the residual DIC based on this model as computed from GEOSECS data has been used to estimate the anthropogenic CO2 penetration in the Pacific Ocean. In the Northeast Pacific, we obtained an increase of CO2 of 21.3±7.9 mol m−2 over the period from GEOSECS in 1973 to CGC91 in 1991. This gives a mean anthropogenic CO2 uptake rate of 1.3±0.5 mol m−2 yr−1 over this 17 year time period. In the South Pacific, north of 50°S between 180° and 120°W region, the integrated anthropogenic CO2 inventory is estimated to be 19.7±5.7 mol m−2 over the period from GEOSECS in 1974 to CGC96 in 1996. The equivalent mean CO2 uptake rate is estimated to be 0.9±0.3 mol m−2 yr−1 over the 22 years. These results are compared with the isopycnal method (Nature 396 (1998) 560) to estimate the anthropogenic CO2 signal in the Northeast Pacific (30°N, 152°W) at the crossover region between CGC91 and GEOSECS. The results of the isopycnal method are consistent with those derived from the MLR method. Both methods show an increase in anthropogenic CO2 inventory in the ocean over two decades that is consistent with the increase expected if the ocean uptake has kept pace with the atmospheric CO2 increase.  相似文献   

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