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1.
It has generally been assumed that diffusive sediment transport on soil‐mantled hillslopes is linearly dependent on hillslope gradient. Fieldwork was done near Santa Barbara, California, to develop a sediment transport equation for bioturbation by the pocket gopher (Thomomys bottae) and to determine whether it supports linear diffusion. The route taken by the sediment is divided into two parts, a subsurface path followed by a surface path. The first is the transport of soil through the burrow to the burrow opening. The second is the discharge of sediment from the burrow opening onto the hillslope surface. The total volumetric sediment flux, as a function of hillslope gradient, is found to be: qs (cm3 cm−1 a−1) = 176(dz/dx)3 − 189(dz/dx)2 + 68(dz/dx) + 34(dz/dx)0·4. This result does not support the use of linear diffusion for hillslopes where gopher bioturbation is the dominant mode of sediment transport. A one‐dimensional hillslope evolution program was used to evolve hillslope profiles according to non‐linear and linear diffusion and to compare them to a typical hillslope. The non‐linear case more closely resembles the actual profile with a convex cap at the divide leading into a straight midslope section. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

2.
A multi‐element ion‐pair extraction method was described for the preconcentration of Cd(II), Co(II), Cr(III), Cu(II), Fe(III), Mn(II), Ni(II), Pb(II), and Zn(II) ions in environmental samples prior to their determinations by flame atomic absorption spectrometry (FAAS). As an ion‐pair ligand 2‐(4‐methoxybenzoyl)‐N′‐benzylidene‐3‐(4‐methoxyphenyl)‐3‐oxo‐N‐phenyl‐propono hydrazide (MBMP) was used. Some analytical parameters such as pH of sample solution, amount of MBMP, shaking time, sample volume, and type of counter ion were investigated to establish optimum experimental conditions. No interferences due to major components and some metal ions of the samples were observed. The detection limits of the proposed method were found in the range of 0.33–0.9 µg L?1 for the analyte ions. Recoveries were found to be higher than 95% and the relative standard deviation (RSD) was less than 4%. The accuracy of the procedure was estimated by analyzing the two certified reference materials, LGC6019 river water and RTC‐CRM044 soil. The developed method was applied to several matrices such as water, hair, and food samples.  相似文献   

3.
Aerodynamic roughness length (z0), the height above the ground surface at which the extrapolated horizontal wind velocity profile drops to zero, is one of the most poorly parameterised elements of the glacier surface energy balance equation. Microtopographic methods for estimating z0 have become prominent in the literature in recent years, but are rarely validated against independent measures and are yet to be comprehensively analysed for scale or data resolution dependency. Here, we present the results of a field investigation conducted on the debris covered Khumbu Glacier during the post‐monsoon season of 2015. We focus on two sites. The first is characterised by gravels and cobbles supported by a fine sandy matrix. The second comprises cobbles and boulders separated by voids. Vertical profiles of wind speed recorded by a tower comprising five cup anemometers and deployed over both sites enable us to derive measurements of aerodynamic roughness that reflect their observed surface characteristics (0.0184 m and 0.0243 m, respectively). At the second site, z0 also varied through time following snowfall (0.0055 m) and during its subsequent melt (0.0129 m), showing the importance of fine resolution topography for near‐surface airflow. To compare the wind profile data with microtopographic methods, we conducted structure from motion multi‐view stereo (SfM‐MVS) surveys across each patch and calculated z0 using three previously published approaches. The fully three‐dimensional cloud‐based approach is shown to be most stable across different scales and these z0 values are most correct in relative order when compared with the wind tower data. Popular profile‐based methods perform less well providing highly variable values across different scales and when using data of differing resolution. These findings hold relevance for all studies using microtopographic methods to estimate aerodynamic roughness lengths, including those in non‐glacial settings. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

4.
To enhance the understanding of solute dynamics within the stream‐to‐riparian continuum during flood event‐driven water fluctuation (i.e., flood wave), a variable saturated groundwater flow and solute transport model were developed and calibrated against in situ measurements of the Inbuk stream, Korea, where seasonal flooding prevails. The solute dynamics were further investigated for flood waves (varying by amplitude [A], duration [T], roundness [r], and skewness [tp]) that were parameterised by real‐time stream stage fluctuations. We found that the solute transferred faster and farther in the riparian zone, especially within the phreatic zone, above which in the variable saturated zone the concentration required a significantly longer time, particularly at higher altitudes, to return to the initial state. By comparison, solute transferred shallowly in the streambed where the solute plume exhibited an exponential growth trend from the centre to the bank. The dynamic changes of solute flux and mass along the stream–aquifer interface and stream concentration were linked to the shape of flood wave. As the flood wave became higher (A↗), wider (T↗), rounder (r↘), and less skewed (tp↗), the maximum solute storage in aquifer increased. Maximum stream concentration (Cstr?max) not only presented a positive linear relationship with A or tp but also showed a negative logarithmic trend with increasing T or r. The sensitivity of Cstr_max to A was approximately two times that of tp, and between these values, the r was slightly more sensitive than T. Cstr?max linearly increased as hydraulic conductivity increased and logarithmically increased as longitudinal dispersivity increased. The former relationship was more sensitive than the latter.  相似文献   

5.
Estimates of the wind shear stress exerted on Earth's surface using the fully rough form of the law‐of‐the‐wall are a function of the aerodynamic roughness length, z0. Accurate prediction of aeolian sediment transport rates, therefore, often requires accurate estimates of z0. The value of z0 is determined by the surface roughness and the saltation intensity, both of which can be highly dynamic. Here we report field measurements of z0 values derived from velocity profiles measured over an evolving topography (i.e. sand ripples). The topography was measured by terrestrial laser scanning and the saltation intensity was measured using a disdrometer. By measuring the topographic evolution and saltation intensity simultaneously and using available formulae to estimate the topographic contribution to z0, we isolated the contribution of saltation intensity to z0 and document that this component dominates over the topographic component for all but the lowest shear velocities. Our measurements indicate that the increase in z0 during periods of saltation is approximately one to two orders of magnitude greater than the increase attributed to microtopography (i.e. evolving sand ripples). Our results also reveal differences in transport as a function of grain size. Each grain‐size fraction exhibited a different dependence on shear velocity, with the saltation intensity of fine particles (diameters ranging from 0.125 to 0.25 mm) saturating and eventually decreasing at high shear velocities, which we interpret to be the result of a limitation in the supply of fine particles from the bed at high shear velocities due to bed armoring. Our findings improve knowledge of the controls on the aerodynamic roughness length and the grain‐size dependence of aeolian sediment transport. The results should contribute to the development of improved sediment transport and dust emission models. © 2018 John Wiley & Sons, Ltd.  相似文献   

6.
To improve quantitative understanding of mixed‐land‐use impacts on nutrient yields, a nested‐scale experimental watershed study design (n = 5) was applied in a 303(d), clean water act impaired urbanizing watershed of the lower Missouri River Basin, USA. From 2010 to 2013, water samples (n = 858 sample days per site) were analysed for total inorganic nitrogen (TIN‐N), nitrite (NO2–N) nitrate (NO3–N), ammonia (NH3–N), and total phosphorus (TP‐P). Annual, seasonal, and monthly flow‐weighted concentrations (FWCs) and nutrient yields were estimated. Mean nutrient concentrations were highest where agricultural land use comprised 58% of the drainage area (NH3 = 0.111 mg/l; NO2 = 0.045 mg/l; NO3 = 0.684 mg/l, TIN = 0.840 mg/l; TP = 0.127 mg/l). Average TP‐P increased by 15% with 20% increased urban land use area. Highly variable annual precipitation was observed during the study with highest nutrient yields during 2010 (record setting wet year) and lowest nutrient yields during 2012 (extreme drought year). Annual TIN‐N and TP‐P yields exceeded 10.3 and 2.04 kg ha?1 yr?1 from the agricultural dominated headwaters. Mean annual NH3–N, NO2–N, NO3–N, TIN‐N, and TP‐P yields were 0.742, 0.400, 4.24, 5.38, and 0.979 kg ha?1 yr?1, respectively near the watershed outlet. Precipitation accounted for the majority of the explained variance in nutrient yields (R2 values from 0.68 to 0.85). Nutrient yields were also dependent on annual precipitation of the preceding year (R2 values from 0.87 to 0.91) thus enforcing the great complexity of variable mixed‐land‐use mediated source‐sink nutrient yield relationships. Study results better inform land managers and best management practices designed to mitigate nutrient pollution issues in mixed‐land‐use freshwater ecosystems. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

7.
A three year monitoring programme of gully‐head retreat was established to assess the significance of sediment production in a drainage network that expanded rapidly by gully‐head erosion on the low‐angled alluvio‐lacustrine Njemps Flats in semi‐arid Baringo District, Kenya. This paper discusses the factors controlling the large observed spatial and temporal variation in gully‐head retreat rates, ranging from 0 to 15 m a?1. The selected gullies differed in planform and in runoff‐contributing catchment area but soil material and land use were similar. The data were analysed at event and annual timescales. The results show that at annual timescale rainfall amount appears to be a good indicator of gully‐head retreat, while at storm‐event timescale rainfall distribution has to be taken into account. A model is proposed, including only rainfall (P) and the number of dry days (DD) between storms: which explains 56 per cent of the variation in retreat rate of the single‐headed gully of Lam1. A detailed sediment budget has been established for Lam1 and its runoff‐contributing area (RCA). By measuring sediment input from the RCA, the sediment output by channelized flow and linear retreat of the gully head for nine storms, it can be seen that erosion shifts between different components of the budget depending on the duration of the dry period (DD) between storms. Sediment input from the RCA was usually the largest component for the smaller storms. The erosion of the gully head occurred as a direct effect of runoff falling over the edge (GHwaterfall) and of the indirect destabilization of the adjacent walls by the waterfall erosion and by saturation (GHmass/storage). The latter component (GHmass/storage) was usually much larger that the former (GHwaterfall). The sediment output from the gully was strongly related to the runoff volume while the linear retreat, because of its complex behaviour, was not. Overall, the results show that the annual retreat is the optimal timescale to predict retreat patterns. More detailed knowledge about relevant processes and interactions is necessary if gully‐head erosion is to be included in event‐based soil erosion models. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

8.
. Kaste  P. J. Dillon 《水文研究》2003,17(12):2393-2407
In‐lake retention of inorganic nitrogen species (nitrate and ammonium) was estimated from mass balances in five acid‐sensitive lakes in southern Norway and eight in southern Ontario, Canada, to evaluate an empirical in‐lake N retention (RN) model. This model is included in the First‐order Acidity Balance (FAB) model, which currently is used for calculation of critical acid loads and exceedances in many countries. To estimate in‐lake RN, the FAB model uses a recommended mass transfer coefficient (SN) of 5 m year−1, which mainly is derived from NO3− mass balances in Canadian lakes. To date, the in‐lake RN model has not been evaluated for large parts of Europe. At the Norwegian study sites receiving the highest N deposition (>120 meq m−2 year−1) the net in‐lake retention of inorganic N (TIN) exceeded the corresponding terrestrial retention by a factor of 1·1–2·6. Despite differences in N loading and hydrology at the Norwegian and Canadian sites, both the mean mass transfer coefficients for NO3− (SNO3; 6·5 versus 5·6 m year−1) and TIN (STIN; 7·9 versus 7·0 m year−1) were of comparable magnitude. Both mean values and ranges of SNO3 suggest that the default SN value presently recommended for FAB model applications seems valid over a large range in N inputs and areal water loads (qs). However, owing to the relatively few data available for lakes with high qs values (15–150 m year−1), it is recommended that more lakes within this range be included in future studies to obtain a more precise prediction of in‐lake N retention over a wide qs gradient. Also, when considering that the FAB model treats all inorganic N leaching from a catchment as NO3−, it seems reasonable to use a default STIN value instead of just SNO3 when estimating in‐lake RN. In that case, the in‐lake RN presently calculated by the FAB model might be slightly underestimated. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

9.
A practical method is presented for determining three‐dimensional S‐wave velocity (VS) profile from microtremor measurements. Frequency–wave number (f–k) spectral analyses of microtremor array records are combined, for this purpose, with microtremor horizontal‐to‐vertical (H/V) spectral ratio techniques. To demonstrate the effectiveness of the proposed method, microtremor measurements using arrays of sensors were conducted at six sites in the city of Kushiro, Japan. The spectral analyses of the array records yield dispersion characteristics of Rayleigh waves and H/V spectra of surface waves, and joint inversion of these data results in VS profiles down to bedrock at the sites. Conventional microtremor measurements were performed at 230 stations within Kushiro city, resulting in the H/V spectra within the city. Three‐dimensional VS structure is then estimated from inversion of the H/V spectra with the VS values determined from the microtremor array data. This reveals three‐dimensional VS profile of Kushiro city, together with an unknown hidden valley that crosses the central part of the city. The estimated VS profile is consistent with available velocity logs and results of subsequent borings, indicating the effectiveness of the proposed method. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

10.
This study develops a straightforward approximate method to estimate inelastic displacement ratio, C1 for base‐isolated structures subjected to near‐fault and far‐fault ground motions. Taking into account the inelastic behavior of isolator and superstructure, a 2 degrees of freedom model is employed. A total of 90 earthquake ground motions are selected and classified into different clusters according to the frequency content features of records represented by the peak ground acceleration to peak ground velocity ratio, Ap/Vp. A parametric study is conducted, and effective factors in C1 (i.e., fundamental vibration period of the superstructure, Ts; postyield stiffness ratio of the superstructure, αs; strength reduction ratio, R; vibration period of the isolator, Tb; strength of the isolator, Q; ratio of superstructure mass to total mass of the system, γm) are recognized. The results indicate that the practical range of C1 values could be expected for base‐isolated structures. Subsequently, effective parameters are included in simple predictive equations. Finally, the accuracy of the proposed approximate equations is evaluated and verified through error measurement, and comparisons are made in the analyses.  相似文献   

11.
In order to investigate the response of structures to near‐fault seismic excitations, the ground motion input should be properly characterized and parameterized in terms of simple, yet accurate and reliable, mathematical models whose input parameters have a clear physical interpretation and scale, to the extent possible, with earthquake magnitude. Such a mathematical model for the representation of the coherent (long‐period) ground motion components has been proposed by the authors in a previous study and is being exploited in this article for the investigation of the elastic and inelastic response of the single‐degree‐of‐freedom (SDOF) system to near‐fault seismic excitations. A parametric analysis of the dynamic response of the SDOF system as a function of the input parameters of the mathematical model is performed to gain insight regarding the near‐fault ground motion characteristics that significantly affect the elastic and inelastic structural performance. A parameter of the mathematical representation of near‐fault motions, referred to as ‘pulse duration’ (TP), emerges as a key parameter of the problem under investigation. Specifically, TP is employed to normalize the elastic and inelastic response spectra of actual near‐fault strong ground motion records. Such normalization makes feasible the specification of design spectra and reduction factors appropriate for near‐fault ground motions. The ‘pulse duration’ (TP) is related to an important parameter of the rupture process referred to as ‘rise time’ (τ) which is controlled by the dimension of the sub‐events that compose the mainshock. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

12.
This study uses instrumented buildings and models of code‐based designed buildings to validate the results of previous studies that highlighted the need to revise the ASCE 7 Fp equation for designing nonstructural components (NSCs) through utilizing oversimplified linear and nonlinear models. The evaluation of floor response spectra of a large number of instrumented buildings illustrates that, unlike the ASCE 7 approach, the in‐structure and the component amplification factors are a function of the ratio of NSC period to the supporting building modal periods, the ground motion intensity, and the NSC location. It is also shown that the recorded ground motions at the base of instrumented buildings in most cases are significantly lower than design earthquake (DE) ground motions. Because ASCE 7 is meant to provide demands at a DE level, for a more reliable evaluation of the Fp equation, 2 representative archetype buildings are designed based on the ASCE 7‐16 seismic provisions and exposed to various ground motion intensity levels (including those consistent with the ones experienced by instrumented buildings and the DE). Simulation results of the archetype buildings, consistent with previous numerical studies, illustrate the tendency of the ASCE 7 in‐structure amplification factor, [1 + 2(z/h)] , to significantly overestimate demands at all floor levels and the ASCE 7 limit of to in many cases underestimate the calculated NSC amplification factors. Furthermore, the product of these 2 amplification factors (that represents the normalized peak NSC acceleration) in some cases exceeds the ASCE 7 equation by a factor up to 1.50.  相似文献   

13.
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14.
In spite of important differences in structural response to near‐fault and far‐fault ground motions, this paper aims at extending well‐known concepts and results, based on elastic and inelastic response spectra for far‐fault motions, to near‐fault motions. Compared are certain aspects of the response of elastic and inelastic SDF systems to the two types of motions in the context of the acceleration‐, velocity‐, and displacement‐sensitive regions of the response spectrum, leading to the following conclusions. (1) The velocity‐sensitive region for near‐fault motions is much narrower, and the acceleration‐sensitive and displacement‐sensitive regions are much wider, compared to far‐fault motions; the narrower velocity‐sensitive region is shifted to longer periods. (2) Although, for the same ductility factor, near‐fault ground motions impose a larger strength demand than far‐fault motions—both demands expressed as a fraction of their respective elastic demands—the strength reduction factors Ry for the two types of motions are similar over corresponding spectral regions. (3) Similarly, the ratio um/u0 of deformations of inelastic and elastic systems are similar for the two types of motions over corresponding spectral regions. (4) Design equations for Ry (and for um/u0) should explicitly recognize spectral regions so that the same equations apply to various classes of ground motions as long as the appropriate values of Ta, Tb and Tc are used. (5) The Veletsos–Newmark design equations with Ta=0.04 s, Tb=0.35 s, and Tc=0.79 s are equally valid for the fault‐normal component of near‐fault ground motions. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

15.
Late Triassic A‐type granites are identified in this study in Sarudik, SW Sumatra. We present new data on zircon U–Pb geochronology, whole‐rock major and trace elements and Sr‐Nd‐Hf isotope geochemistry, aiming to study their petrogenesis and tectonic implications. LA‐ICP‐MS U–Pb dating of zircon separated from one biotite monzogranite sample yields a concordia age of 222.6 ±1.0 Ma, indicating a Late Triassic magmatic event. The studied granites are classified as weakly peralumious, high‐K calc‐alkaline granites. They exhibit high SiO2, K2O + Na2O, FeO/(FeO + MgO) and Ga/Al ratios and low Al2O3, CaO, MgO, P2O5 and TiO2 contents, with enrichment of Rb, Th and U and depletion of Ba, Sr, P and Eu, showing the features of A‐type granites. The granites have zircon εHf(t) values from ?4.6 to ?0.4 and whole‐rock εNd(t) values from ?5.51 to ?4.98, with Mesoproterozoic TDM2 ages (1278–1544 Ma) for both Hf and Nd isotopes. Geochemical and isotopic data suggest that the source of these A‐type granites is the Mesoproterozoic continental crust, without significant incorporation of mantle‐derived component, and their formation is controlled by subsequent fractional crystallization. The Sarudik A‐type granites are further assigned to A2‐type formed in post‐collisional environment. Combined with previous knowledge on the western SE Asia tectonic evolution, we conclude that the formation of the Late Triassic A‐type granites is related to the post‐collisional extension induced by the crustal thickening, gravitational collapse, and asthenosphere upwelling following the collision between the Sibumasu and the East Malaya Block.  相似文献   

16.
The Jurassic Shir‐Kuh granitoid batholith in Central Iran intrudes Lower Jurassic sandstones and shales. The batholith consists of three main facies: (i) a granodioritic facies to the north; (ii) a monzogranitic facies spread throughout the batholith; and (iii) a leucogranitic facies along the northwestern margin. The granodiorites are composed mainly of plagioclase, quartz, K‐feldspar, biotite, and some muscovite, garnet, cordierite, ilmenite, zircon, apatite, and monazite. This facies contains variable amounts of restite minerals which are mainly defined by calcic plagioclase cores and small aggregates of biotite. The monzogranites, with mineral assemblages similar to those in the granodiorites, range from relatively mafic (cordierite‐bearing) to felsic (muscovite‐rich) rocks. The leucogranites, exposed as small stock and dykes, consist mainly of quartz, K‐feldspar, and sodic plagioclase. The batholith is peraluminous, calc‐alkaline, and typical of S‐type, as indicated by Na2O content (2.74%), molecular Al2O3/(CaO + Na2O + K2O) (A/CNK) ratio (1.17), K2O/Na2O ratio (1.39), and isotopic data ([87Sr/86Sr]i = 0.715). The rocks are characterized by enrichment in large ion lithophile elements such as Rb, Th and K and depletion in high field strength elements such as Nb and Ti. Chondrite‐normalized rare earth element (REE) patterns are characterized by light rare earth element (LREE) enrichment, with values of (La/Yb)N between 4.5 and 19.53, unfractionated heavy rare earth element (HREE) with values of (Gd/Yb)N between 0.98 and 2.88, and a distinct negative Eu. The parental magma of the Shir‐Kuh Granite was derived from a plagioclase‐rich metasedimentary source (local anatexis of metagreywacke) in the crust, with heat input from mantle melt components. The separation of restite crystals from the primary melt followed by the fractional crystallization appears to have been an effective differentiation process in the batholith.  相似文献   

17.
The declining costs of small Unmanned Aerial Systems (sUAS), in combination with Structure‐from‐Motion (SfM) photogrammetry have triggered renewed interest in image‐based topography reconstruction. However, the potential uptake of sUAS‐based topography is limited by the need for ground control acquired with expensive survey equipment. Direct georeferencing (DG) is a workflow that obviates ground control and uses only the camera positions to georeference the SfM results. However, the absence of ground control poses significant challenges in terms of the data quality of the final geospatial outputs. Notably, it is generally accepted that ground control is required to georeference, refine the camera calibration parameters, and remove any artefacts of optical distortion from the topographic model. Here, we present an examination of DG carried out with low‐cost consumer‐grade sUAS. We begin with a study of surface deformations resulting from systematic perturbations of the radial lens distortion parameters. We then test a number of flight patterns and develop a novel error quantification method to assess the outcomes. Our perturbation analysis shows that there exists families of predictable equifinal solutions of K1‐K2 which minimize doming in the output model. The equifinal solutions can be expressed as K2 = f (K1) and they have been observed for both the DJI Inspire 1 and Phantom 3 sUAS platforms. This equifinality relationship can be used as an external reliability check of the self‐calibration and allow a DG workflow to produce topography exempt of non‐affine deformations and with random errors of 0.1% of the flying height, linear offsets below 10 m and off‐vertical tilts below 1°. Whilst not yet of survey‐grade quality, these results demonstrate that low‐cost sUAS are capable of producing reliable topography products without recourse to expensive survey equipment and we argue that direct georeferencing and low‐cost sUAS could transform survey practices in both academic and commercial disciplines. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

18.
In wind‐driven rains, wind velocity and direction are expected to affect not only energy input of rains but also shallow ?ow hydraulics by changing roughness induced by raindrop impacts with an angle on ?ow and the unidirectional splashes in the wind direction. A wind‐tunnel study under wind‐driven rains was conducted to determine the effects of horizontal wind velocity and direction on sediment transport by the raindrop‐impacted shallow ?ow. Windless rains and the rains driven by horizontal wind velocities of 6 m s?1, 10 m s?1, and 14 m s?1 were applied to three agricultural soils packed into a 20 by 55 cm soil pan placed on both windward and leeward slopes of 7 per cent, 15 per cent, and 20 per cent. During each rainfall application, sediment and runoff samples were collected at 5‐min intervals at the bottom edge of the soil pan with wide‐mouth bottles and were determined gravimetrically. Based on the interrill erosion mechanics, kinetic energy ?ux (Ern) as a rainfall parameter and product of unit discharge and slope in the form of qbSco as a ?ow parameter were used to explain the interactions between impact and ?ow parameters and sediment transport (qs). The differential sediment transport rates occurred depending on the variation in raindrop trajectory and rain intensity with the wind velocity and direction. Flux of rain energy computed by combining the effects of wind on the velocity, frequency, and angle of raindrop impact reasonably explained the characteristics of wind‐driven rains and acceptably accounted for the differences in sediment delivery rates to the shallow ?ow transport (R2 ≥ 0·78). Further analysis of the Pearson correlation coef?cients between Ern and qSo and qs also showed that wind velocity and direction signi?cantly affected the hydraulics of the shallow ?ow. Ern had a smaller correlation coef?cient with the qs in windward slopes where not only reverse splashes but also reverse lateral raindrop stress with respect to the shallow ?ow direction occurred. However, Ern was as much effective as qSo in the sediment transport in the leeward slopes where advance splashes and advance lateral raindrop stress on the ?ow occurred. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

19.
In this study, a new solid‐phase extraction procedure has been developed for preconcentration and determination of Co ions in different water samples by flame atomic absorption spectrometry (FAAS). Cobalt was preconcentrated as N,N′‐bis(pyridine‐2‐yl‐methyl)benzene‐1,4‐diamine (Co‐BPMBDA) from sample solutions using a column containing Amberlite XAD‐7 and was determined. In order to achieve the best performance for the method, effects of several parameters such as pH, concentrations of ligand, sample flow rate, eluent, and matrix ions on the method efficiency were investigated. Under optimum conditions, the preconcentration factor was found to be 200 for 1000 mL waters samples. Detection limit based on the 3Sb criterion was calculated as 0.24 µg/L for 100 mL of sample solution and relative standard deviation was found to be 1.8%. The method was applied to determine the trace amounts of cobalt in water samples.  相似文献   

20.
A stable extractor of metal ions was synthesized through azo linking of o‐hydroxybenzamide (HBAM) with Amberlite XAD‐4 (AXAD‐4) and was characterized by elemental analyses, IR spectral, and thermal studies. Its water regain value and hydrogen ion capacity were found to be 12.93 and 7.68 mmol g?1, respectively. The optimum pH range (with the half‐loading time [min], t1/2) for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) ions were 2.0–4.0 (5.5), 2.0–4.0 (7.0), 2.0–4.0 (8.0), 4.0–6.0 (9.0), 4.0–6.0 (12.0), and 2.0–4.0 (15.0), respectively. Comparison of breakthrough and overall capacities of the metals ascertains the high degree of column utilization (>70%). The overall sorption capacities for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) ions were found to be 0.29, 0.22, 0.20, 0.16, 0.13, and 0.11 mmol g?1 with the corresponding preconcentration factor of 400, 380, 380, 360, 320, and 320, respectively. The limit of preconcentration was in the range of 5.0–6.3 ng mL?1. The detection limit for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) were found to be 0.39, 0.49, 0.42, 0.59, 0.71, and 1.10 ng mL?1, respectively. The AXAD‐4‐HBAM has been successfully applied for the analysis of natural water, multivitamin formulation, infant milk substitute, hydrogenated oil, urine, and fish.  相似文献   

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