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1.
Subslab soil gas sampling and analysis is a common line of evidence for assessing human health risks associated with subsurface vapor intrusion to indoor air for volatile organic compounds; however, conventional subslab sampling methods have generated data that show substantial spatial and temporal variability, which often makes the interpretation difficult. A new method of monitoring has been developed and tested that is based on a concept of integrating samples over a large volume of soil gas extracted from beneath the floor slab of a building to provide a spatially averaged subslab concentration. Regular field screening is also conducted to assess the trend of concentration as a function of the volume removed to provide insight into the spatial distribution of vapors at progressive distances away from the point of extraction. This approach minimizes the risk of failing to identify the areas of elevated soil vapor concentrations that may exist between discrete sample locations, and can provide information covering large buildings with fewer holes drilled through the floor. The new method also involves monitoring the extraction flow rate and transient vacuum response for mathematical analysis to help interpret the vapor concentration data and to support an optimal design for any subslab venting system that may be needed.  相似文献   

2.
Soil-gas sampling and analysis is a common tool used in vapor intrusion assessments; however, sample collection becomes more difficult in fine-grained, low-permeability soils because of limitations on the flow rate that can be sustained during purging and sampling. This affects the time required to extract sufficient volume to satisfy purging and sampling requirements. The soil-gas probe tubing or pipe and sandpack around the probe screen should generally be purged prior to sampling. After purging, additional soil gas must be extracted for chemical analysis, which may include field screening, laboratory analysis, occasional duplicate samples, or analysis for more than one analytical method (e.g., volatile organic compounds and semivolatile organic compounds). At present, most regulatory guidance documents do not distinguish between soil-gas sampling methods that are appropriate for high- or low-permeability soils. This paper discusses permeability influences on soil-gas sample collection and reports data from a case study involving soil-gas sampling from silt and clay-rich soils with moderate to extremely low gas permeability to identify a sampling approach that yields reproducible samples with data quality appropriate for vapor intrusion investigations for a wide range of gas-permeability conditions.  相似文献   

3.
This paper presents model simulation results of vapor intrusion into structures built atop sites contaminated with volatile or semivolatile chemicals of concern. A three-dimensional finite element model was used to investigate the importance of factors that could influence vapor intrusion when the site is characterized by nonhomogeneous soils. Model simulations were performed to examine how soil layers of differing properties alter soil-gas concentration profiles and vapor intrusion rates into structures. The results illustrate difference in soil-gas concentration profiles and vapor intrusion rates between homogeneous and layered soils. The findings support the need for site conceptual models to adequately represent a site's geology when conducting site characterizations, interpreting field data, and assessing the risk of vapor intrusion at a given site. For instance, in layered geologies, a lower permeability and diffusivity soil layer between the source and building often limits vapor intrusion rates, even if a higher permeability layer near the foundation permits increased soil-gas flow rates into the building. In addition, the presence of water-saturated clay layers can considerably influence soil-gas concentration profiles. Therefore, interpreting field data without accounting for clay layers in the site conceptual model could result in inaccurate risk calculations. Important considerations for developing more accurate conceptual site models are discussed in light of the findings.  相似文献   

4.
A soil-gas survey was conducted at a gasoline service station and a former fire training facility to determine if surveying for hydrogen sulfide could be useful in locating nonaqueous phase hydrocarbon fuel in the subsurface. Relative; to total organic vapor, oxygen, and carbon dioxide distributions, detectable hydrogen sulfide concentrations were much more restricted to the suspected source vicinity at both sites. Appreciable levels of soil-gas hydrogen sulfide. up to 600 Vppb. were observed in areas characterized by anaerobic or microaerophilic conditions having bulk oxygen levels below 4 percent. Based on the hydrogen sulfide distribution, nonaqueous phase hydrocarbon fuel was located at each site. These results suggest that soil-gas surveying for hydrogen sulfide may help locale mobile or residual gasoline and other nonaqueous phase hydrocarbons in the subsurface.  相似文献   

5.
A detailed seasonal study of soil vapor intrusion at a cold climate site with average yearly temperature of 1.9 °C was conducted at a house with a crawlspace that overlay a shallow dissolved‐phase petroleum hydrocarbon (gasoline) plume in North Battleford, Saskatchewan, Canada. This research was conducted primarily to assess if winter conditions, including snow/frost cover, and cold soil temperatures, influence aerobic biodegradation of petroleum vapors in soil and the potential for vapor intrusion. Continuous time‐series data for oxygen, pressure differentials, soil temperature, soil moisture, and weather conditions were collected from a high‐resolution monitoring network. Seasonal monitoring of groundwater, soil vapor, crawlspace air, and indoor air was also undertaken. Petroleum hydrocarbon vapor attenuation and biodegradation rates were not significantly reduced during low temperature winter months and there was no evidence for a significant capping effect of snow or frost cover that would limit oxygen ingress from the atmosphere. In the residual light nonaqueous phase liquid (LNAPL) source area adjacent to the house, evidence for biodegradation included rapid attenuation of hydrocarbon vapor concentrations over a vertical interval of approximately 0.9 m, and a corresponding decrease in oxygen to less than 1.5% v/v. In comparison, hydrocarbon vapor concentrations above the dissolved plume and below the house were much lower and decreased sharply within a few tens of centimeters above the groundwater source. Corresponding oxygen concentrations in soil gas were at least 10% v/v. A reactive transport model (MIN3P‐DUSTY) was initially calibrated to data from vertical profiles at the site to obtain biodegradation rates, and then used to simulate the observed soil vapor distribution. The calibrated model indicated that soil vapor transport was dominated by diffusion and aerobic biodegradation, and that crawlspace pressures and soil gas advection had little influence on soil vapor concentrations.  相似文献   

6.
Generic indoor air:subslab soil gas attenuation factors (SSAFs) are important for rapid screening of potential vapor intrusion risks in buildings that overlie soil and groundwater contaminated with volatile chemicals. Insufficiently conservative SSAFs can allow high‐risk sites to be prematurely excluded from further investigation. Excessively conservative SSAFs can lead to costly, time‐consuming, and often inconclusive actions at an inordinate number of low‐risk sites. This paper reviews two of the most commonly used approaches to develop SSAFs: (1) comparison of paired, indoor air and subslab soil gas data in empirical databases and (2) comparison of estimated subslab vapor entry rates and indoor air exchange rates (IAERs). Potential error associated with databases includes interference from indoor and outdoor sources, reliance on data from basements, and seasonal variability. Heterogeneity in subsurface vapor plumes combined with uncertainty regarding vapor entry points calls into question the representativeness of limited subslab data and diminishes the technical defensibility of SSAFs extracted from databases. The use of reasonably conservative vapor entry rates and IAERs offers a more technically defensible approach for the development of generic SSAF values for screening. Consideration of seasonal variability in building leakage rates, air exchange rates, and interpolated vapor entry rates allows for the development of generic SSAFs at both local and regional scales. Limitations include applicability of the default IAERs and vapor entry rates to site‐specific vapor intrusion investigations and uncertainty regarding applicability of generic SSAFs to assess potential short‐term (e.g., intraday) variability of impacts to indoor air.  相似文献   

7.
Vapor intrusion (VI) occurs when volatile contaminants in the subsurface migrate through the vadose zone into overlying buildings. The 2015 U.S. EPA petroleum VI guidance recommends that additional investigation of the VI risk from gasoline hydrocarbons at the underground storage tank (UST) sites is not necessary where the vertical distance between a building and a vapor source exceeds a recommended vertical screening distance. However, due to the lack of soil-gas data on the attenuation of ethylene dibromide (EDB), additional VI investigations to evaluate VI risk from EDB are recommended at UST sites with leaded gasoline releases containing EDB. We analyzed soil-gas and groundwater concentrations of EDB from eight petroleum UST sites using a new analytical method with soil-gas detection limit <0.16 μg/m3 EDB (VI screening level at the 10−6 risk level). The analysis included (1) assessing the frequency of EDB detections ≤0.16 μg/m3 at various vertical separation distances and (2) predicting vertical screening distances for EDB using the U.S. EPA PVIScreen model for different soil types in the vadose zone above dissolved-phase and LNAPL sources. Ranges of estimated aerobic biodegradation rate constants for EDB, air exchange rates for residential buildings, and source vapor concentrations for other constituents were combined with conservative estimates of EDB source concentrations as model inputs. Concentrations of EDB in soil-gas indicated that the U.S. EPA recommended vertical screening distances are protective of VI risk from EDB. Conversely, vertical screening distances predicted by modeling were >6 ft (1.8 m) for sites with sand and loam soil above dissolved phase sources and >15 ft (4.6 m) for sites with sand soil above LNAPL sources. This predicted dependence on the vapor source type and soil type in the vadose zone highlights the importance of soil characterization for VI screening at sites with EDB sources.  相似文献   

8.
Vapor intrusion (VI) involves migration of volatile contaminants from subsurface through unsaturated soil into overlying buildings. In 2015, the US EPA recommended an approach for screening VI risks associated with gasoline releases from underground storage tank (UST) sites. Additional assessment of the VI risk from petroleum hydrocarbons was deemed unnecessary for buildings separated from vapor sources by more than recommended vertical screening distances. However, these vertical screening distances did not apply to potential VI risks associated with releases of former leaded gasoline containing 1,2-dichloroethane (1,2-DCA), because of a lack of empirical data on the attenuation of 1,2-DCA in soil gas. This study empirically evaluated 144 paired measurements of 1,2-DCA concentrations in soil gas and groundwater collected at 47 petroleum UST sites combined with BioVapor modeling. This included (1) assessing the frequency of 1,2-DCA detections in soil gas below 10−6 risk-based screening levels at different vertical separation distances and (2) comparing the US EPA recommended vertical screening distances with those predicted by BioVapor modeling. Vertical screening distances were predicted for different soil types using aerobic biodegradation rate constants estimated from the measured soil-gas data combined with conservative estimates of source concentrations. The modeling indicates that the vertical screening distance of 6 feet (1.8 m) recommended for dissolved-phase sources is applicable for 1,2-DCA below certain threshold concentrations in groundwater, while 15 feet (4.6 m) recommended for light nonaqueous phase liquid (LNAPL) sources is applicable for sites with clay and loam soils in the vadose zone, but not sand, if 1,2-DCA concentrations in groundwater exceed 150 μg/L. This dependence of the predicted vertical screening distances on soil type places added emphasis on proper soil characterization for VI screening at sites with 1,2-DCA sources. The soil-gas data suggests that a vertical screening distance of 15 feet (4.6 m) is necessary for both dissolved-phase and LNAPL sources.  相似文献   

9.
Purging influence on soil‐gas concentrations for volatile organic compounds (VOCs), as affected by sampling tube inner diameter and sampling depth (i.e., system volume) for temporary probes in fine‐grained soils, was evaluated at three different field sites. A macro‐purge sampling system consisted of a standard, hollow, 3.2‐cm outer diameter (OD) drive probe with a retractable sampling point attached to an appropriate length of 0.48‐cm inner diameter (ID) Teflon® tubing. The macro‐purge sampling system had a purge system volume of 24.5 mL at a 1‐m depth. In contrast, the micro‐purge sampling systems were slightly different between the field sites and consisted of a 1.27‐cm OD drive rod with a 0.10‐cm ID stainless steel tube or a 3.2‐cm OD drive rod with a 0.0254‐cm inner diameter stainless steel tubing resulting in purge system volumes of 1.2 and 7.05 mL at 1‐m depths, respectively. At each site and location within the site, with a few exceptions, the same contaminants were identified in the same relative order of abundances indicating the sampling of the same general soil atmosphere. However, marked differences in VOC concentrations were identified between the sampling systems, with micro‐purge samples having up to 27 times greater concentrations than their corresponding macro‐purge samples. The higher concentrations are the result of a minimal disturbance of the ambient soil atmosphere during purging. The minimal soil‐gas atmospheric disturbance of the micro‐purge sampling system allowed for the collection of a sample that is more representative of the soil atmosphere surrounding the sampling point. That is, a sample that does not contain an atmosphere that has migrated from distance through the geologic material or from the surface in response to the vacuum induced during purging soil‐gas concentrations. It is thus recommended that when soil‐gas sampling is conducted using temporary probes in fine‐grained soils, the sampling system use the smallest practical ID soil‐gas tubing and minimize purge volume to obtain the soil‐gas sample with minimal risk of leakage so that proper decisions, based on more representative soil‐gas concentrations, about the site can be made.  相似文献   

10.
Several regulatory agencies recommend screening petroleum vapor intrusion (PVI) sites based on vertical screening distance between a petroleum hydrocarbon source in soil or groundwater and a building foundation. U.S. Environmental Protection Agency (U.S. EPA) indicate the risk of PVI is minimal at buildings that are separated by more than 6 feet (1.8 m) from a dissolved-phase source and 15 feet (4.6 m) from a light nonaqueous phase liquid (LNAPL) source. This vertical screening distance method is not, however, recommended at sites with leaded gasoline sources containing ethylene dibromide (EDB) because of a lack of field data to document EDB attenuation in the vadose zone. To help address this gap, depth-discrete soil-gas samples were collected at a leaded gasoline release site in Sobieski, Minnesota (USA). The maximum concentration of EDB in groundwater (175 μg/L) at the site was high relative to those observed at other leaded gasoline release sites. Soil gas was analyzed for EDB using a modification of U.S. EPA Method TO-14A that achieved analytical detection limits below the U.S. EPA Vapor Intrusion Screening Level (VISL) for EDB based on a 10−6 cancer risk (<0.16 μg/m3). Concentrations of EDB in soil gas above LNAPL reached as high as 960 μg/m3 and decreased below the VISL within a source-separation distance of 7 feet. This result coupled with BioVapor model predictions of EDB concentrations indicate that vertical screening distances recommended by regulatory agencies at PVI sites are generally applicable for EDB over the range of anticipated source concentrations and soil types at most sites.  相似文献   

11.
Groundwater monitoring wells are present at most hydrocarbon release sites that are being assessed for cleanup. If screened across the vadose zone, these wells provide an opportunity to collect vapor samples that can be used in the evaluation of vapor movement and biodegradation processes occurring at such sites. This paper presents a low purge volume method (modified after that developed by the U.S. EPA) for sampling vapor from monitoring wells that is easy to implement and can provide an assessment of the soil gas total petroleum hydrocarbon (TPH) and O2 concentrations at the base of the vadose zone. As a result, the small purge method allows for sampling of vapor from monitoring wells to support petroleum vapor intrusion (PVI) risk assessment. The small purge volume method was field tested at the Hal's service station site in Green River, Utah. This site is well‐known for numerous soil gas measurements containing high O2 and high TPH vapor concentrations in the same samples which is inconsistent with well‐accepted biodegradation models for the vapor pathway. Using the low purge volume method, monitoring wells were sampled over, upgradient, and downgradient of the light nonaqueous phase liquid (LNAPL) footprint. Results from our testing at Hal's show that vapor from monitoring wells over LNAPL contained very low O2 and high TPH concentrations. In contrast, vapor from monitoring wells not over LNAPL contained high O2 and low TPH concentrations. The results of this study show that a low purge volume method is consistent with biodegradation models especially for sampling at sites where low permeability soils exist in and around a LNAPL source zone.  相似文献   

12.
This paper considers the distribution of technogenic 137Cs and naturally occurring radionuclides:238 U,232 Th and40 R concentrations in soils and 137Cs in atmospheric dry depositions by altitudinal belts of the Aragats mountain massif,Republic of Armenia.Undisturbed soil samples were collected at altitudes from 1000 to 3200 m.For the determination of geochemical variability,two soil sampling campaigns were undertaken.Atmospheric dry depositions were sampled from five stations at1100-3200 m collected onto organic fiber filters between June and December 2016.137Cs activity was measured using a high-purity Germanium detector coupled to a multichannel analyzer(Canberra).Results indicated that specific activity of 137Cs in soils at 1000 m is495-528 Bq m^-2,andat3200 mis10,500-11,470 Bq m^-2.No correlation observed for 137Cs versus naturally occurring radionuclides,which varies in distribution by altitude.Specific activities of 137Cs in dry atmospheric depositions varies from 1.06 at 846 m to2.37 Bq m^-2 per quarter at 3200 m and increases as the altitude increases.Activities of 137Cs in soil and dry atmospheric deposition correlated significantly,and 137Cs activity in soils and atmospheric dry depositions decrease as the absolute altitude decreases.The 50-year effective dose from exposure to 137Cs fallout varies with altitude from 0.007 to 1.42 m Sv.  相似文献   

13.
An evaluation of the Hg distribution in soils of the Long Valley, California, geothermal area, was made. A1-horizon soil samples were collected utilizing a grid system from the resurgent dome area and the Long Valley area. In addition, samples were collected in five traverses across three fault systems and four traverses across east-west-oriented gullies to measure the importance of aspect. Additional samples were collected in an analysis of variance design to evaluate natural variability in soil composition with sampling interval distance.The primary objectives of this study were to further evaluate the applicability of anomalously high Hg concentration in soils to exploration for geothermal systems and the importance of secondary controls on Hg concentration in soils above geothermal systems.Statistical analysis indicates that there are two populations of Hg concentrations in soils; one affected by geothermal activity and the other unaffected. Samples from the resurgent dome are shown to be statistically different from the samples collected in Long Valley proper with respect to Hg, organic carbon, and pH. This suggests that secondary influences may be important in controlling Hg distribution in soils.Organic carbon in soils is shown by stepwise multiple regression to be the most important secondary parameter controlling Hg concentration. For the most part, the secondary controls of Hg are overwhelmed in an area of prominent geothermal activity. Some faults exhibit prominent anomalies in total Hg concentration and others do not, indicating the possibility of low levels of hydrothermal activity or effective sealing of faults to gas leakage.The analysis of variance results indicate that there is a regional trend in Hg concentration across the resurgent dome. Soils can be sampled for Hg by utilizing a grid of about 0.4 km spacing. However, some local irregularities appear in this pattern and anomalous areas should be prospected at intervals of 100 m or less.  相似文献   

14.
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15.
The sudden and catastrophic, or slow and continuous, release at surface of naturally occurring toxic gases like CO2, H2S and Rn poses a serious health risk to people living in geologically active regions. In general this problem receives little attention from local governments, although public concern is raised periodically when anomalous toxic-gas concentrations suddenly kill humans or livestock. For example, elevated CO2 concentrations have been linked to the death of at least 10 people in the central Italian region of Lazio over the last 20 years, while it was the CO2 asphyxiation of 30 cows in a heavily populated area near Rome in 1999 which prompted the present soil-gas study into the distribution of the local health risk. A detailed geochemical survey was carried out in an area of about 4 km2 in the Ciampino and Marino districts, whereby a total of 274 soil-gas samples were collected and analysed for more than 10 major and trace gas species. Data were then processed using both statistical and geostatistical methods, and the resulting maps were examined in order to highlight areas of elevated risk. General trends of elevated CO2 and Rn concentrations imply the presence of preferential pathways (i.e. faults and fractures) along which deep gases are able to migrate towards the surface. The CO2 and Rn anomalous trends often correspond to and are usually elongated parallel to the Apennine mountain range, the controlling structural feature in central Italy. Because of this fundamental anisotropy in the factors controlling the soil-gas distribution, it was found that a geostatistical approach using variogram analysis allowed for a better interpretation of the data. With regard to the health risk to local inhabitants, it was found that although some high risk areas had been zoned as parkland, others had been heavily developed for residential purposes. For example, many new houses were found to have been built on ground which has soil-gas CO2 concentrations of more than 70% and radon values of more than 250 kBq m−3. It is recommended that land-use planners incorporate soil-gas and/or gas flux measurements in environmental assessments in areas of possible risk (i.e. volcanic or structurally active areas).  相似文献   

16.
Factors influencing the response of total organic vapor detection instruments used in soil-gas surveying for subsurface gasoline leakage were investigated through performing theoretical assessments and laboratory experiments. Theoretical assessments indicate that total organic vapor measurements will depend on response conditions and the relative concentration of constituents in soil gas, in addition to absolute constituent levels. Laboratory tests conducted using flame ionization, photoionization and explosimeter devices indicated that conditions influencing their responses included instrument flow rate and soil-air permeability when performing direct-probe sampling; the linear range of the instrument; the multicomponent nature of gasoline vapors; and levels of oxygen, nitrogen, carbon dioxide and relative humidity in soil air. If an instrument's response to these conditions is not taken into account, survey results may be misleading. To circumvent adverse instrument responses, a serial dilution technique is presented.  相似文献   

17.
Abstract

An estimated 50 000 1 of diesel fuel contaminated soil over a depth of 1.5 to 3.5 m (approximately 1.5% by weight in the soil) following fuel recovery operations at the site of a diesel spill. Laboratory treatability identified oxygen supply treatment as having significant potential to enhance bioremediation of the soil in situ. A bioventing system was designed and tested on a quarter of the site. Venting alone over a period of six months reduced total hydrocarbon concentrations by 10 to 30% to a depth of 3 m. Venting with nutrient addition resulted in a further reduction of 30% over a subsequent 6 month period to the full depth of 3.5 m.  相似文献   

18.
This study investigated the distribution of six pollutant elements(Cr, Cu, Pb, Zn, Cd, and As), and their relationship to soil organic carbon(SOC) in five soil profiles in the Puding area. Results show SOC content decreased exponentially to the depth of soil profiles; the vertical distribution patterns of SOC in soil profiles were partially controlled by land use. The concentrations of these pollutant elements in most soils were lower than background values, indicating that the local soil was less likely to be contaminated by foreign inputs. Geo-accumulation index values of these elements in most soil samples were less than 1, suggesting that the soil of this area may not be polluted. The concentrations of Cr, Cu, As, and Zn in soils from all land use types were significantly negatively correlated with SOC contents. Geochemical approaches confirmed that the soil of this area was less influenced by pollutant elements.  相似文献   

19.
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20.
We have measured the concentration of the cosmogenic isotope10Be in soil samples from various horizons at six sites, including three independently dated Rappahannock River terraces and a previously undated Piedmont soil to which we have assigned an age. All of the incident10Be can be accounted for in one of these soils and a second is within a factor of two. In three soils, whose concentrations vary widely with depth, a significant fraction of the incident10Be cannot be accounted for. Incomplete sampling, and enhanced Be mobility caused by organic components, are the probable reasons for the low inventory of Be from these three soils. Overall, the data from these six sites indicate that10Be accumulation could be used to assign ages to soils if Be is not mobilized and lost from the soil profile.  相似文献   

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