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1.
ABSTRACT A silica–carbonate deposit is forming from the dilute alkali chloride waters of Pavlova spring, a small thermal pool and outflow channel (85 to <40 °C), situated at the northern extent of the South Orakonui area of the Ngatamariki geothermal field, Taupo Volcanic Zone (TVZ), New Zealand. It is one of a small but growing number of thermal spring features known to yield deposits of mixed mineralogy. At Pavlova, a distinctive, crustose, chalk‐white, meringue‐like sinter, comprising non‐crystalline opal‐A silica with subordinate calcite, is actively precipitating both around the margins of and as small islets within the spring, with an average accumulation rate of ≈ 2 mm year?1. Both emergent and partly submerged substrates host the sinter, including fallen pine branches, twigs, needles and cones, gum leaves, grass blades, bracken fronds, pumice, sediment and microbial mats. The sinter is thin (25–35 mm thickness), finely laminated and contains three distinct types of stacked horizons. Submerged basal layers constitute stratiform to undulatory microstromatolites with pseudocolumns, which grew outwards and upwards on narrow twig nuclei. Emergent middle layers comprise discontinuous, spicular microstromatolites (to 10 mm height), with prostrate and erect microbial filaments, silica spheres and silicified mucus, overlain by silicified structures of probable fungal origin. In places, lower and middle sinter layers are capped by white, smooth, convex surfaces that coalesce into subdued, curved ridges, resembling laterally continuous peaks of egg‐white meringue. The meringue is internally laminated, with fossilized microbes preserved in thin horizons. Small lensoid masses of calcite crystals nestle between silica laminae throughout the sinter. The near‐neutral (pH ≈ 7·2) spring water is a dilute chloride‐carbonate type (HCO≈ 470 µg g?1, Cl–≈ 600 µg g?1) with low (≈ 50 µg g?1), typical of TVZ thermal fields where deep chloride fluid mixes with CO2‐rich, steam‐heated shallow waters before discharge. The hot water changed little in composition from 1993 to 1999 and, despite dilution by meteoric waters, contains sufficient SiO2 (≈ 220 µg g?1) for opal‐A to deposit at the surface upon cooling. However, the concentration of Ca2+ (≈ 6 µg g?1) is such that the precipitation of calcite is not expected without modification of spring waters. Precipitation occurs by evaporation of thin water films at exposed substrate surfaces, via meniscoid as well as capillary creep (wicking), through porous sinter horizons and across emergent vegetative surfaces in contact with spring water or steam. The height of the deposit above the water surface is restricted by the upper limit of moisture bathing these substrates. Splash and spray are not involved in the formation of Pavlova spicular microstromatolites, as is the case for other texturally similar deposits from hotsprings elsewhere. This young (< 15 years), mineralogically and morphologically complex hot‐spring deposit exhibits > 10 times lower accumulation rates than typical siliceous sinters in the TVZ, and deposition of both silica and calcite is controlled by microchemical conditions and local temperature gradients, rather than by bulk spring water chemistry.  相似文献   

2.
The siliceous sinter deposits of El Tatio geothermal field in northern Chile have been examined petrographically and mineralogically. These sinters consist of amorphous silica (opal-A) deposited around hot springs and geysers from nearly neutral, silica-saturated, sodium chloride waters. Water cooling and evaporation to dryness are the main processes that control the opal-A deposition in both subaqueous and subaerial settings, in close spatial relation to microbial communities. All fingerprints of organisms observed in the studied sinter samples represent microbes and suggest that the microbial community is moderately diverse (cyanobacteria, green bacteria, and diatoms). The most important ecological parameter is the temperature gradient, which is closely related to the observed depositional settings: 1) Geyser setting: water temperature = 70–86 °C (boiling point at El Tatio: 4200 m a.s.l.); coarse laminated sinter macrostructure with rapid local variations; biota comprises non-photosynthetic hyperthermophilic bacteria. 2) Splash areas around geysers: water temperature = 60–75 °C; laminated spicule and column macrostructure, locally forming cupolas (< 30 cm); predominant Synechococcus-like cyanobacteria. 3) Hot spring setting: water temperature = 40–60 °C; laminated spicules and columns and subspherical oncoids characterize the sinter macrostructure; filamentous cyanobacteria Phormidium and diatoms (e.g., Synedra sp.) are the most characteristic microbes. 4) Discharge environments: water temperature = 20–40 °C; sinter composed of laminated spicules and oncoids of varied shape; cyanobacterial mats of Phormidium and Calothrix and diatoms (e.g., Synedra sp.) are abundant. El Tatio is a natural laboratory of great interest because the sedimentary macrostructures and microtextures reflect the geological and biological processes involved in the primary deposition and early diagenesis of siliceous sinters.  相似文献   

3.
Calcite veins hosted in the Triassic Stockton, Lockatong and Passaic formations of the Newark Basin are investigated to reconstruct the fluid evolution. To constrain the parameters of calcite precipitation, a microthermometry study was carried, which reveals precipitation of calcite from a low to moderate saline H2O-NaCl fluid (0.4 to 13.2 wt% NaCl equiv.) under low to moderate hydrothermal (137 °C to 232 °C) conditions. This fluid composition is interpreted to reflect mixing between a deep basement-derived heated diluted fluid and relatively low to moderate saline diagenetic formation waters hosted in the different Triassic formations. Carbon and strontium isotope analysis on the vein calcites suggests that these elements are derived from the pre-Triassic basement and the sedimentary cover through fluid-rock interactions. The aforementioned geochemical findings are supported by Rare Earth Elements and Yttrium (REY) systematics and oxygen isotope data.The Late Triassic extensional activity and gravity-driven fluid flow mechanism facilitated the infiltration of meteoric waters to deeper lithostratigraphic units (i.e., Precambrian-Paleozoic basement-Triassic Stockton Formation) where they became heated. In response to the extensional tectonics, the deep-seated hydrothermal basement-derived diluted fluids migrated upward along the tectonic-related fractures and the major faults to upper shallow crustal levels. Here, the heated, diluted meteoric waters were mixed with low, moderately saline, and relatively cooler formation waters, leading to calcite precipitation. The pH increase is suggested to be a contributing factor in the precipitation of calcite.  相似文献   

4.
This research provides an ancient analogue for biologically mediated dolomite precipitation in microbial mats and biofilms, and describes the involvement of highly structured extracellular polymeric secretion (EPS) templates in dolomite nucleation. The structure of EPS is shown to match the hexagonal–trigonal lattice geometry of dolomite, which favoured the epitaxial crystallization of dolomite on the organic substrate. This structure of EPS also matches the arrangement of silica nanospheres in opal, which further accounts for the organically‐templated formation of opal enabling the non‐replacive co‐existence of dolomite and silica. The study is focused on a 50 m thick dolomite succession that is exposed in central areas of the Tertiary Duero Basin and was deposited in a mudflat‐saline lake sedimentary complex during the Middle to Late Miocene (9 to 15 Ma). In the intermediate intervals of the succession, poorly indurated dolomite beds pass gradually into silica beds. On the basis of sedimentological, compositional, geochemical and petrographic data, silica and dolomite beds have been interpreted as mineralized microbial mats. The silica beds formed in marginal areas of the lake in response to intense evaporative concentrations; this resulted in the rapid and early precipitation of opal. Silicification accounted for the exceptional preservation of the microbial mat structure, including biofilms, filamentous and coccoid microbes, and EPS. Extracellular polymeric secretions have a layered structure, each layer being composed of fibres which are arranged in accordance with a reticular pattern, with frequent intersection angles at 120° and 60°. Therefore, the structure of EPS matches the lattice geometry of dolomite and the arrangement of silica nanospheres in opal. Additionally, EPS binds different elements, with preference to Si and Mg. The concurrence of suitable composition and surface lattice morphologies in the EPS favoured the crystallization of dolomite on the substrate. In some cases, dolomite nucleation took place epicellularly on coccoid micro‐organisms, which gave way to spheroid crystals. Organic surfaces enable the inorganic mineral precipitation by lowering the free energy barrier to nucleation. Most of the microbial mats probably developed on the lake floor, under sub‐aqueous conditions, where the decomposition of organic matter took place. The subsequent formation of openly packed dolomite crystals, with inter‐related Si‐enriched fibrils throughout, is evidence for the pre‐existence of fibrillar structures in the mats. Miocene dolomite crystals are poorly ordered and non‐stoichiometric, with a slight Ca‐excess (up to 5%), which is indicative of the low diagenetic potential the microbial dolomite has towards a more ordered and stoichiometric structure; this confirms that microbial imprints can be preserved in the geological record, and validates their use as biosignatures.  相似文献   

5.
This study reports on the seepage of metals, metalloids and radionuclides from the Mary Kathleen uranium mill tailings repository. Since rehabilitation in the 1980s, the capped tailings have developed a stratified hydrochemistry, with acid (pH 3.7), saline, metal-rich (Fe, Mn, Ni, U ± As, Pb, Zn), oxygenated (1.05 mg L−1 DO), radioactive waters in the upper tailings pile and near-neutral pH (pH 7.57), metal-poor, reduced (0.08 mg L−1 DO) waters at depth. Seepage (∼0.5 L s−1) of acid (pH 5.5), metal-rich (Fe, Mn ± Ni, U, Zn), radioactive (U-235, U-238, Ra-226, Ra-228, Ac-227) waters occurs from the base of the tailings dam retaining wall into the former evaporation pond and local drainage system. Oxygenation of the seepage waters causes the precipitation of Fe and coprecipitation and adsorption of other metals (U, Y), metalloids (As), rare earth elements (Ce, La) and radionuclides (U-235, U-238). By contrast, alkalis and alkaline–earth elements (Ca, K, Mg, Na, Sr), Mn, sulfate and to some degree metals (U, Zn, Ni), rare earth elements (Ce, La) and radionuclides (U-235, U-238, Ra-226, Ra-228) remain in solution until pH neutralisation and evaporation lead to their precipitation in efflorescences and sulfate-rich evaporative sediments. While the release of contaminant loads from the waste repository through seepage is insignificant (e.g. ∼5 kg of U per year), surface waters downstream of the tailings impoundment possess TDS, U and SO4 concentrations that exceed Australian water quality guideline values in livestock drinking water. Thus, in areas with a semi-arid climate, even insignificant load releases of contaminants from capped tailings repositories can still cause the deterioration of water quality in ephemeral creek systems.  相似文献   

6.
Hot spring deposits in the Roosevelt thermal area consist of opaline sinter and sintercemented alluvium. Alluvium, plutonic rocks, and amphibolite-facies gneiss have been altered by acidsulfate water to alunite and opal at the surface, and alunite, kaolinite, montmorillonite, and muscovite to a depth of 70 m. Marcasite, pyrite, chlorite, and calcite occur below the water table at about 30 m.The thermal water is dilute (ionic strength 0.1–0.2) sodium-chloride brine. The spring water now contains 10 times as much Ca, 100 times as much Mg, and up to 2.5 times as much SO4 as the deep water. Although the present day spring temperature is 25°C, the temperature was 85°C in 1950.A model for development of the observed alteration is supported by observation and irreversible mass transfer calculations. Hydrothermal fluid convectively rises along major fractures. Water cools by conduction and steam separation, and the pH rises due to carbon dioxide escape. At the surface, hydrogen and sulfate ions are produced by oxidation of H2S. The low pH water percolates downward and reacts with feldspar in the rocks to produce alunite, kaolinite, montmorillonite, and muscovite as hydrogen ion is consumed.  相似文献   

7.
Hydrogeochemistry and environmental isotope data were utilized to understand origin, geochemical evolution, hydraulic interconnection, and renewability of groundwater in Qingshuihe Basin, northwestern China. There are four types of groundwater: (1) shallow groundwater in the mountain front pluvial fans, originating from recent recharge by precipitation, (2) deep paleo-groundwater of the lower alluvial plains, which was formed long ago, (3) shallow groundwater in the lower alluvial plains, which has undergone evaporation during the recharge process, and (4) mixed groundwater (shallow and deep groundwater in the plain). The main water types are Na–HCO3, which dominates type (1), and Na–SO4, which dominates types (2) and (3). Geochemical evolution in the upper pluvial fans is mainly the result of CO2 gas dissolution, silicates weathering and cation exchange; in the lower alluvial plains, it is related to mineral dissolution. The evaporative enrichment only produces significant salinity increases in the shallow groundwater of the lower alluvial plains. Shallow groundwater age in the upper plain is 10 years or so, showing a strong renewability. Deep groundwater ages in the lower plain are more than 200 years, showing poor renewability. In the exploitation areas, the renewability of groundwater evidently increases and the circulation period is 70–100 years.  相似文献   

8.
Structural changes of synthetic opal by heat treatment   总被引：1，自引：0，他引：1  
The structural changes of synthetic opal by heat treatment up to 1,400 °C were investigated using scanning electron microscopy, X-ray diffraction, and Fourier transform infrared and Raman spectroscopies. The results indicate that the dehydration and condensation of silanol in opal are very important factors in the structural evolution of heat-treated synthetic opal. Synthetic opal releases water molecules and silanols by heat treatment up to 400 °C, where the dehydration of silanol may lead to the condensation of a new Si–O–Si network comprising a four-membered ring structure of SiO4 tetrahedra, even at 400 °C. Above 600 °C, water molecules are lost and the opal surface and internal silanol molecules are completely dehydrated by heat effect, and the medium-temperature range structure of opal may begin to thermally reconstruct to six-membered rings of SiO4 tetrahedra. Above 1,000 °C, the opal structure almost approaches that of silica glass with an average structure of six-membered rings. Above 1,200 °C, the opal changes to low-cristobalite; however, minor evidence of low-tridymite stacking was evident after heat treatment at 1,400 °C.  相似文献   

9.
Glendonites, calcite pseudomorphs after the metastable mineral ikaite (CaCO3 · 6H2O), occur in the Late Aptian interval of the Bulldog Shale in the Eromanga Basin, Australia and in other Early Cretaceous basins at high paleolatitudes. Ikaite precipitation in the marine environment requires near-freezing temperatures (not higher than 4°C), high alkalinity, increased levels of orthophosphate, and high PCO2. The rapid and complete transformation of ikaite to calcite at temperatures between 5 and 8°C provides an upper limit on the oxygen isotopic composition of the pore waters: −2.6 <δw <−3.4‰SMOW. If it is assumed that these pore waters are representative of the shallow Eromanga Basin, the calculated δw can be used to reassess belemnite fossil oxygen isotopic paleotemperatures—temperature recorded by fauna living in the basin at the time of ikaite precipitation. Data previously reported as 11 to 16°C (assuming δw = 0.0‰SMOW) yield paleotemperatures ranging from −1 to 5°C, squarely in the range of ikaite stability. The low δw indicates hyposaline conditions, most likely caused by mixing high latitude meteoric waters with seawater. The 18O depleted, low temperature waters suggest that the region was at least seasonally colder than previously accepted.  相似文献   

10.
Northeastern Morocco is characterised by a large number of surface geothermal manifestations. Thermal waters are hosted within sedimentary rocks, and in particular the Liassic dolomitic limestones act as a reservoir. The presence of geothermal waters is closely related to important fault systems. Meteoric water infiltrates along those fractures and faults, gets heated, and then returns to the surface through hydrothermal conduits. Most of the thermal waters are of Na–Cl and Ca–Mg–HCO3 types. In this paper different geochemical approaches were applied to infer the reservoir temperature. Na–K–Mg1/2 ternary diagram points to temperatures ranging from 100 to 180 °C. Cation geothermometers suggest an average reservoir temperature of about 100 °C. Mineral solution equilibria analysis yields temperatures ranging from 50 to 185 °C. The silica enthalpy mixture model gives an average value (about 110 °C) higher than that inferred from cation geothermometers.  相似文献   

11.
Two springs (Cuihua Spring, Shuiqiuchi Spring) in Cuihua Mountain of the Qinling Mountains were observed and sampled monthly during 2004 and 2005 to trace their physical properties and chemical compositions with seasons. Although both pH values and cation (Ca2+, Mg2+, K+, and Na+) contents of Cuihua Spring are higher than those of Shuiqiuchi Spring, seasonal variations in both springs are obvious. The pH values of both spring waters are between 5.69 and 6.98, lower than that of rainwater during summer and autumn. From January to November, the pH values of both springs similarly vary from high to low and then to high again. Variations in electric conductivities of two spring waters are contrary, although their electric conductivities are positively correlative with the cation content respectively. This can be attributed to different water sources of the two springs or different acidic rocks they passed. The contents of HCO3 −, Ca2+, Mg2+, K+, and Na+ are low, indicating a low silicate weathering that the strata in this district are mainly composed of granite and schist of quartz and mica. Differing from change in spring water in karst regions of South China where abundant precipitation and dilution of rainwater cause low pH and electric conductivity in summer and autumn, the seasonal variations in the pH values and the electric conductivities of two springs in Qinling Mountains are attributed to seasonal changes in CO2 produced by microorganisms’ activity in soil within respective year, rather than rainfall. The microorganisms’ activity in soil produces more CO2 during summer and autumn. Therefore, the water nature of springs in silicate regions chiefly reflects the seasonal changes of CO2 produced by the microorganisms in soil.  相似文献   

12.
The means and timing of the formation of Australian sediment-hosted precious opal remain a subject of continuing debate. In this study, the question of which water formed the opal is addressed by examination of rare earth element data for opals and host rocks. The available data, mainly for Lightning Ridge, NSW, suggest a positive Eu anomaly, relative to the neighbouring Sm and Dy, occurs in opals whereas no such anomaly was found for the weathered Cretaceous sediments hosting the opal. Such anomalies may be inherited from the source rock with a similar positive Eu anomaly or generated in situ by severe reduction. There is no indication of major reduction processes during the opal formation that could have led to such a Eu anomaly so this is likely inherited from a source rock. As the opal host rocks did not show this anomaly, the source rocks must be external to the opal fields. Calcite cements within rocks hosting the aquifers of the Eromanga and Surat basins of the Great Artesian Basin have been reported to have a positive Eu anomaly, which strongly suggests that opal was formed by upwelling Great Artesian Basin artesian waters. This work has also highlighted variations in trace-element concentrations in opals, which indicate significant variation in the source water composition during opal formation or different water sources were involved. Either of these is indicative of the source for the opal with its trace elements derived from external sources. These conclusions have significant implications to considerations of how opal formed, and hence, for the exploration for other deposits and to the chemistry and timing that led to the formation of opal.  相似文献   

13.
A sloping travertine mound, approximately 85 m across and a few metres thick is actively forming from cool temperature waters issuing out of Crystal Geyser, east‐central Utah, USA. Older travertine deposits exist at the site, the waters having used the Little Grand Wash Fault system as conduits. In contrast, the present Crystal Geyser travertine mound forms from 18°C waters which have been erupting for the last 80 years from an abandoned oil well. The present Crystal Geyser travertine accumulation forms from a ‘man‐made’ cool temperature geyser system; nevertheless, the constituents are an analogue for ancient geyser‐fed carbonate deposits. The travertine primary fabric is composed of couplets of highly porous, thin micritic laminae intercalated with thicker iron oxide rich laminae. Low Mg‐calcite is the dominant mineralogy; however, aragonite is a major constituent in deposits proximal to the vent and decreases in abundance distally. Cements exhibit a variety of fabrics, isopachous being common. Constituents include micro‐stromatolites, clasts, pisoids and the common occurrence of Frutexites‐like iron oxide precipitates. Leptothrix, a common iron‐oxidizing bacterium, is believed to be responsible for the production of the dense iron‐rich laminae. Pisoids litter the ground around the vent and rapidly decrease distally in abundance and size.  相似文献   

14.
Using modern pollen and radiolarian distributions in sediments from the northwest Pacific and seas adjacent to Japan to interpret floral and faunal changes in core RC14-103 (44°02′N, 152°56′E), we recognize two major responses of the biota of eastern Hokkaido and the northwest Pacific to climatic changes since the last interglaciation. Relatively stable glacial environments (～80,000–20,000 yr B.P.) were basically cold and wet (<4°C and ～1000 mm mean annual temperature and precipitation, respectively) with boreal conijers and tundra/park-tundra on Hokkaido, and cool (<16°C) summer and cold (<1.0°C) winter surface temperatures offshore. Contrasting nonglacial environments (～10,000–4000 yr B.P.) were warm and humid (>8°C and >1200 mm mean annual temperature and precipitation, respectively), supporting climax broadleaf deciduous forest with Quercus and Ulmus/Zelkova, with surface waters in the northwest Pacific characterized by warm (>1.5°C) winter and cold (10.4°–14.3°C) summer temperatures. Climatic evidence from RC14-103 shows a high degree of local and regional variation within the context of global climatic change. Correlative ocean and land records provide the detailed input necessary to assess local/regional responses to variations in other key elements (i.e., solar radiation, monsoonal variations) of the northeast Asian climate system.  相似文献   

15.
Groundwater-dependent, spring-fed ecosystems of the Cuatrociénegas Basin, Coahuila, Mexico, host >70 endemic species. These desert springs occur primarily aligned along the base of an anticline that bisects the Cuatrociénegas Basin, but the hydrogeologic controls of the springs are poorly understood. The hypothesis that spring locations are controlled by subsurface geology, such as buried anticlines or faulting, versus stratigraphic controls is tested by evaluating: (1) regional structural styles; (2) fracture models of analogous structures; (3) hydrogeologic data; and (4) geophysical surveys. Jurassic and Cretaceous siliciclastic and carbonate rocks deposited on the Coahuila Block west of the Cuatrociénegas Basin have dips <10° and lack faults because of a structurally rigid granodiorite basement. To the east of the Coahuila Block and around the Cuatrociénegas Basin, the Coahuila Folded Belt has anticlines associated with basement-involved faults, 10–25° backlimb dips, and forelimb dips up to vertical or slightly overturned. Springs in the western sub-basin that represent 85% of total basin discharge are located on zones of highest anticipated fracture density predicted by fracture models of analogous anticlines. Spring waters reveal elevated temperature (32–35°C) and low tritium (<1 tritium unit). Gravimetry and time-domain electromagnetic surveys correspond with a best-fit Cuatrociénegas Basin hydrogeologic model of fractures associated with reverse faulting controlling spring locations in the western Cuatrociénegas Basin. Springs in the eastern sub-basin are located where ephemeral streams have eroded through confining beds along the base of alluvial fans and lack faulting. Regional variations in structural style are an important control on the location of springs in the Cuatrociénegas Basin.  相似文献   

16.
Vegetation and climate since the LGM in eastern Hokkaido were investigated based on a pollen record from marine core GH02-1030 from off Tokachi in the northwestern Pacific. We also examined pollen spectra in surface samples from Sakhalin to compare and understand the climatic conditions of Hokkaido during the last glacial period. Vegetation in the Tokachi region in the LGM (22–17 ka) was an open boreal forest dominated by Picea and Larix. During the last deglaciation (17–10 ka), vegetation was characterized by abundant Betula. In the Kenbuchi Basin, central Hokkaido, a remarkable increase of Larix and Pinus occurred in the LGM and the last deglaciation, which was assigned as the “Kenbuchi Stadial.” Comparison of climatic data between the core GH02-1030 and that of Kenbuchi Basin demonstrates that variations in temperature and precipitation were larger in inland Hokkaido than in the maritime area of the Pacific coast. During the LGM in the Tokachi region, the August mean temperature was about 5 °C lower, and annual precipitation was about 40% lower than today. In the Kenbuchi Basin, central Hokkaido, the August mean temperature was about 8 °C lower, and annual precipitation was half that of today. During the last deglaciation, August mean temperatures were about 3 °C lower, and annual precipitation was about 30% lower than today in the Tokachi region. In the Kenbuchi Basin, August mean temperatures were about 5–8 °C lower, and annual precipitation was about 40–60% lower than today. Cold ocean water and a strengthened summer monsoon after 15 ka may have resulted in the formation of advection fogs, reduced summer temperatures, and a decrease in the seasonal temperature difference in the Tokachi district, which established favorable maritime conditions for Betula forests.  相似文献   

17.
The integration of core sedimentology, seismic stratigraphy and seismic geomorphology has enabled interpretation of delta‐scale (i.e. tens of metres high) subaqueous clinoforms in the upper Jurassic Sognefjord Formation of the Troll Field. Mud‐prone subaqueous deltas characterized by a compound clinoform morphology and sandy delta‐scale subaqueous clinoforms are common in recent tide‐influenced, wave‐influenced and current‐influenced settings, but ancient examples are virtually unknown. The data presented help to fully comprehend the criteria for the recognition of other ancient delta‐scale subaqueous clinoforms, as well as refining the depositional model of the reservoir in the super‐giant Troll hydrocarbon field. Two 10 to 60 m thick, overall coarsening‐upward packages are distinguished in the lower Sognefjord Formation. Progressively higher energy, wave‐dominated or current‐dominated facies occur from the base to the top of each package. Each package corresponds to a set of seismically resolved, westerly dipping clinoforms, the bounding surfaces of which form the seismic ‘envelope’ of a clinoform set and the major marine flooding surfaces recognized in cores. The packages thicken westwards, until they reach a maximum where the clinoform ‘envelope’ rolls over to define a topset–foreset–toeset geometry. All clinoforms are consistently oriented sub‐parallel to the edge of the Horda Platform (N005–N030). In the eastern half of the field, individual foresets are relatively gently dipping (1° to 6°) and bound thin (10 to 30 m) clinothems. Core data indicate that these proximal clinothems are dominated by fine‐grained, hummocky cross‐stratified sandstones. Towards the west, clinoforms gradually become steeper (5° to 14°) and bound thicker (15 to 60 m) clinothems that comprise medium‐grained, cross‐bedded sandstones. Topsets are consistently well‐developed, except in the westernmost area. No seismic or sedimentological evidence of subaerial exposure is observed. Deposition created fully subaqueous, near‐linear clinoforms that prograded westwards across the Horda Platform. Subaqueous clinoforms were probably fed by a river outlet in the north‐east and sculpted by the action of currents sub‐parallel to the clinoform strike.  相似文献   

18.
Late Quaternary paleotemperatures and paleosalinities of surface waters of the Gulf of Mexico were estimated using a multivariate statistical analysis of census data of planktonic foraminifera. Two climatic extremes were selected for detailed basinwide study, the climatic optimum 125,000 yr ago and the glacial maximum 18,000 yr ago. In addition, patterns of climatic change were examined in seven piston cores from 127,000 yr ago to the present day. During the climatic optimum 125,000 yr ago temperature distributions in surface waters were similar to those of the present. The 22°C winter isotherm trended northeastward across the central basin and paleotemperatures decreased northward. Summer distributions were nearly homogeneous and ranged between 28° and 29°C. Winter salinities were 1‰ fresher than present values in the northmost Gulf and 0.4‰ fresher in the central basin. Summer salinities were similar during both times. In contrast, during the last glacial maximum temperatures were 1° to 2°C cooler in winter and 1°C cooler in summer, and isotherms formed a circular pattern in the Gulf during both seasons. Salinity was 0.3‰ fresher in winter than at present but 0.6‰ saltier in summer. Conditions deteriorated from the climatic optimum to the glacial maximum. In the Mexico Basin, winter temperatures were 2°C cooler from 75,000 to 45,000 yr ago (Y6 to Y3 Subzones), summer temperatures reached a minimum (3°C cooler) 32,000 yr ago (Y2–Y3 boundary), and seasonality reached minimal values (5°C) from 45,000 to 15,000 yr ago. All three parameters became similar in value to those in the Straits of Florida from 45,000 to 15,000 yr ago, suggesting that the exchange of surface waters was enhanced at this time between the two regions. Summer salinities remained similar to present conditions in the Mexico Basin, whereas, winter salinities increased 2‰ by 32,000 yr ago and then fell 0.5‰ until the glacial maximum ended. The Westerlies may have migrated southward over the Mexico Basin in winter from 32,000 to 15,000 yr ago.  相似文献   

19.
This study focuses on the hydrochemical characteristics of 47 water samples collected from thermal and cold springs that emerge from the Hammam Righa geothermal field, located in north-central Algeria. The aquifer that feeds these springs is mainly situated in the deeply fractured Jurassic limestone and dolomite of the Zaccar Mount. Measured discharge temperatures of the cold waters range from 16.0 to 26.5 °C and the hot waters from 32.1 to 68.2 °C. All waters exhibited a near-neutral pH of 6.0–7.6. The thermal waters had a high total dissolved solids (TDS) content of up to 2527 mg/l, while the TDS for cold waters was 659.0–852.0 mg/l. Chemical analyses suggest that two main types of water exist: hot waters in the upflow area of the Ca–Na–SO4 type (Hammam Righa) and cold waters in the recharge zone of the Ca–Na–HCO3 type (Zaccar Mount). Reservoir temperatures were estimated using silica geothermometers and fluid/mineral equilibria at 78, 92, and 95 °C for HR4, HR2, and HR1, respectively. Stable isotopic analyses of the δ18O and δD composition of the waters suggest that the thermal waters of Hammam Righa are of meteoric origin. We conclude that meteoric recharge infiltrates through the fractured dolomitic limestones of the Zaccar Mount and is conductively heated at a depth of 2.1–2.2 km. The hot waters then interact at depth with Triassic evaporites located in the hydrothermal conduit (fault), giving rise to the Ca–Na–SO4 water type. As they ascend to the surface, the thermal waters mix with shallower Mg-rich groundwater, resulting in waters that plot in the immature water field in the Na–K–Mg diagram. The mixing trend between cold groundwaters from the recharge zone area (Zaccar Mount) and hot waters in the upflow area (Hammam Righa) is apparent via a chloride-enthalpy diagram that shows a mixing ratio of 22.6 < R < 29.2 %. We summarize these results with a geothermal conceptual model of the Hammam Righa geothermal field.  相似文献   

20.
This study reports 144 new analyses of short-chain aliphatic acid anions (acetate, propionate, butyrate, and valerate) in formation waters from eight localities: Eastern Venezuelan Basin, Denver Basin, Eastern Green River Basin (Red Desert and Washakie Basins, Wamsutter Arch), San Juan Basin, Piceance Basin, Raton Basin, Gulf Coast Basin, and the Western Overthrust. Reservoir temperature does not predict total or relative abundance of aliphatic acid anions, but does predict maximum total concentrations of these species. Maximum concentrations increase to ~90°C. Above ~90°C, maximum concentrations decrease. Above ~250°C, maximum concentrations should not exceed ~1 mg/1. The general order of dominance is acetate > propionate > butyrate > valerate, but for coal-associated waters is propionate > acetate > butyrate > valerate. Lack of longer-chain aliphatic acid anion dominance over acetate at low reservoir temperatures may suggest hydrologie communication with deeper reservoirs.  相似文献   

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