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1.
The geochemical and mineralogical characteristics of pre-Holocene core sediments from Haenam Bay, southwest coast of Korea,
were examined for post-depositional diagenetic changes and used to assess the provenance of fine-grained sediments in the
region. The geochemical and mineralogical compositions of the sediments vary very little with core depth (Holocene to pre-Holocene
age), except for the upper part of the pre-Holocene sedimentary layer. In this case, smectite and chlorite are depleted, presumably
due to intensive subaerial weathering and low pH conditions. Highly mobile elements (Ca, Mg, Na and K) were likely removed
with the breakdown of labile minerals, such as carbonate minerals, feldspar, and clay minerals, during subaerial exposure
of this layer, resulting in low weathering indices. In particular, the low smectite content (<5%) and low V/Al ratio (<13)
suggest that the Holocene and pre-Holocene sediments along the southwestern coast of Korea did not originate from mainland
China but rather mostly from the Korean Peninsula. This aspect has been a subject of debate since the mid-1970s. 相似文献
2.
黏土矿物研究在示踪物源、源区风化历史乃至洋流变迁能力等方面具有重要的作用,尽管目前对南海表层沉积物黏土矿物宏观分布特征已获得了较系统的认识,但在受珠江和海南岛物源共同影响的南海西北部其高分辨率的黏土矿物学工作还未开展。本文对南海西北部表层沉积物中的黏土矿物组成、结晶学特征进行了分析,讨论了研究区黏土矿物的物质来源。结果表明,南海西北部表层沉积物的黏土矿物组成以伊利石为主（平均45%）,蒙脱石（平均27%）与高岭石（平均21%）次之,绿泥石含量最少（平均6%）。在区域空间分布上,蒙脱石含量呈现西南高东北低的特征,伊利石含量则与之相反;高岭石含量表现为近岸高离岸低,而绿泥石含量呈现离岸高近岸低的特征。总体上,研究区表层沉积物黏土矿物组成与现代珠江沉积物组成差异较大,而与珠江口2.5 ka前的沉积物黏土矿物组成比较接近,并且结合研究区岩心揭露的全新世以来极低的沉积速率（4 cm/ka）以及上部很薄（小于0.6 m）的泥质沉积,推测该区表层沉积物可能并非是现代沉积的结果,更可能主要来自全新世末期古珠江输送的沉积物。除古珠江作为研究区表层沉积物中蒙脱石的一个主要来源外,海南岛北部河流也贡献了少量蒙脱石到其邻近的东南海域。运用高岭石/伊利石比值和伊利石化学指数等进一步对比分析表明,珠江是研究区沉积物中伊利石、高岭石和绿泥石的主要物源,其次台湾和海南岛也可能分别提供了少量富含伊利石/绿泥石和高岭石的沉积物。本工作对于南海西北部沉积物源-汇过程和相应的古环境研究有重要的参考意义。 相似文献
3.
A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE. 相似文献
4.
Krupskaya V. V. Miroshnikov A. Yu. Dorzhieva O. V. Zakusin S. V. Semenkov I. N. Usacheva A. A. 《Oceanology》2017,57(1):215-221
We have analyzed the specific features of the mineralogical composition of bottom sediments of Blagopoluchiya, Tsivol’ki, and Abrosimov bays and soils on Cape Zhelaniya and the coasts of Abrosimov and Stepovoi bays. The data were obtained during two scientific expeditions of the R/V Professor Shtokman in 2014 (cruise 128) and R/V Akademik Mstislav Keldysh in 2015 (cruise 63). These investigations revealed patterns in the transportation of terrigenous material in the coastal zone of the bays: a decrease in the share of nonclay minerals and an increase in that of clay minerals with distance from shore. The increase in kaolinite and smectite content in soil horizons is related to biochemical weathering, while illite is mainly formed as a result of physical weathering.
相似文献5.
Charles Q. Barrie 《Marine Geology》1983,53(3):199-209
Makkovik Bay, a low-relief fjord on the coast of Labrador at 55°N, has a complex sequence of Late Glacial to contemporary sediments. X-ray diffraction analysis of the <2-μm fraction of glacial detritus, a 10,000-yrs B.P. proglacial marine horizon and contemporary estuarine sediments shows dominance of feldspar and mica, lesser amounts of quartz, chlorite and amphibole, and minor quantities of smectite and kaolinite. Significant down-fjord variations in mica were observed only in proglacial marine sequences, and are attributed to physical sorting by size in the upper water layer in a highly stratified estuary. The lack of variation of clay minerals in the contemporary muds is related to the origin of the mud from erosion, mixing and redistribution of proglacial sediments as relative sea level fell during glacio-isostatic rebound. 相似文献
6.
Core 7710, recovered on the George Bligh/Rockall Channel, is composed of fine grained ocher-colored sediments rich in ferriferous smectite (montmorillonite, beidellite). These sediments were deposited during early Eocene in a shallow marine environment. Their mineralogic, chemical and isotopic constituents indicate subaerial weathering of lower Eocene intermediate igneous rocks (ferrodiorite, marscoiite) eroded from the still-emergent George Bligh and Rockall Banks. Lack of any post Eocene Sediments may be due to major morphologic and hydrologic changes forming sedimentation gaps. 相似文献
7.
南海南部沉积物中黏土矿物组成变化及其古沉积信息记录初探 总被引：7，自引：1，他引：6
通过对南海南部2个代表13万a以来柱状沉积样品高分辨率的黏土矿物组成分析,认为所研究的黏土矿物主要为陆源碎屑成因,埋藏过程中的成岩变化或黏土矿物自生特征不明显,而以采样点南面加里曼丹岛、菲律宾东、西两侧的火山群岛和湄公河流域为主要陆源的地质条件、风化环境及物质迁移途径的差异控制了南海南部沉积物中黏土矿物组成的空间和时间变化.研究发现,沉积物样品中较高的蒙皂石含量对应于地质历史上的暖期,而较低的蒙皂石含量对应于冷期.伊利石的行为及其古海洋指示意义则与蒙皂石相反.将柱状沉积物样品上高分辨率的黏土矿物组成分析作为一种研究方法,有助于研究晚第四纪以来南海陆源碎屑物的源区特征、迁移途径及海区古环境演变. 相似文献
8.
南海东北部晚更新世以来沉积环境演变的矿物-地球化学记录 总被引：11，自引：6，他引：5
对南海东北部69柱(20°07.10'N,118°49.0'E)沉积物岩心进行碎屑矿物-地球化学特征研究,结果表明,以孔深165cm为界可划分出晚更新世末次冰期沉积和全新世冰后期沉积,这一地层划分结果与根据浮游有孔虫氧、碳同位素分析得出的结果是一致的.末次冰期时自生黄铁矿和硫元素高度富集,钠与铝、镁与铝和钠与钾的比值均较高,重矿物和SiO2含量较高,CaCO3含量较低,反映当时是一种相对闭塞的缺氧环境,气候干寒,化学风化作用较弱,以机械风化作用为主;研究区主要接受粒径较粗的硅质沉积;陆源物质的稀释作用可能是造成碳酸盐含量相对较低的主要原因.冰后期褐铁矿出现高含量,钠与铝、镁与铝和钠与钾的比值均降低,Al2O3和CaCO3含量增高,反映沉积环境渐变为开放的氧化环境,气候转变为化学风化作用较强的湿热气候;研究区以接受较细粒的铝硅酸盐沉积为主,冰消期时还出现了碳酸盐保存高峰事件. 相似文献
9.
LIU Yanguang OLE Bjφrslev Nielsen ZHANG Deyu DU Dewen JAN Heinemeier WU Yonghua 《海洋学报(英文版)》2006,25(1):78-89
1 Introduction Volcanic activities have played an important role in the process of global climatic changes. Being good stratigraphic markers, widespread tephra layers in ma- rine sediments can provide reliable evidences for the regional paleoceanographic … 相似文献
10.
黄河口毗邻渤海陆架区悬浮体成分 总被引：1，自引：0，他引：1
扫描电镜配合能谱分析、X射线衍射及光学显微镜分析表明,黄河口毗邻的渤海陆架区悬浮体主要由矿物、浮游生物和有机包膜三类成分组成。在悬浮体中鉴别出23种矿物,主要是石英、长石、云母、方解石和粘土矿物(依次为伊利石、蒙皂石、绿泥石和高岭石),特征矿物是云母、方解石、蒙皂石和角闪石。辨识出21种藻类,大多数是硅藻,少数为钙藻和鞭毛藻。生物成分主要集中在水体上层。首次在渤海悬浮体中发现了有机包膜。并讨论了悬浮体成因及其沉积作用。 相似文献
11.
《Marine Geology》2003,193(3-4):177-194
Sediment cores from a tidal flat in the southeastern Yellow Sea, Korea, contain two major depositional units, a Holocene unit (Unit I) and an underlying late Pleistocene unit (Unit II). Unit I (up to 15 m thick) is a middle to late Holocene, coarsening-upward transgressive deposit. Unit II (about 10 m thick) is interpreted as tidal-flat deposits from the last interglacial period (probably oxygen-isotope stage 5e), based on its many tide-influenced signatures such as laminated silt/clay, tidal rhythmites, fossil crab burrows, authigenic minerals (pyrite and halite), clay mineral composition and a dinoflagellate cyst assemblage comparable to that of Unit I. Units I and II are separated by a regional unconformity which is highlighted by a yellow ‘oxidized layer’ in uppermost Unit II. The layer contains abundant evidence of subaerial exposure, including a yellowish sediment color, semi-consolidation, desiccation cracks, cryoturbation structures, and high degree of magnetic susceptibility. Two major interglacial highstands (Units I and II) and one glacial lowstand (uppermost oxidized layer of Unit II) thus characterize coastal to nearshore tidal deposits along the eastern margin of the Yellow Sea (western Korea). 相似文献
12.
北冰洋西部表层沉积物粘土矿物分布及环境指示意义 总被引：7，自引：1，他引：6
楚科奇海及邻近的北冰洋深水区表层沉积物中粘土矿物的分布受源区母岩和海区环流结构所制约。来自加拿大马更些河的物质富含高岭石和伊利石,对研究区东北部和北部沉积物的影响较大;来自阿拉斯加西北部的河流和海岸带物质富含绿泥石,高岭石含量变化较大,对阿拉斯加西北部近海沉积物的影响明显;来自西伯利亚的物质富含绿泥石,对研究区西部沉积物的影响较为明显。自白令海峡进入的太平洋水携带富含蒙皂石的育空河物质横穿楚科奇海陆架向北扩散,导致楚科奇海中部沉积物中的蒙皂石含量高;同时,粘土矿物自身的粒度分异在某种程度上也促使蒙脱石在离岸距离较远的中部海区富集。 相似文献
13.
The Upper Quaternary seismic stratigraphy and active faults of the Gulf of İzmit were investigated by means of high-resolution
shallow seismic profiling data in the source region of 1999 İzmit earthquake. High-resolution seismic reflection data correlated
with borehole data indicate that the stratigraphy of İzmit Bay consists of three distinct depositional sequences formed in
response to middle Pleistocene-Holocene sea-level changes. Reflector R, separating the pre-Holocene sequences (1 and 2) from
the Holocene sequence (3), represents an erosional unconformity produced by the subaerial fluvial erosion of the continental
shelves at the time of the last glacial maximum. Occasional, anomalous reflections (acoustic turbidity) observed within the
Holocene sequence are interpreted as gas accumulations. The maximum thickness of the Holocene sediments is found to be about
25 m. The isopach map of Holocene sediment implies that the thickness of the Holocene decreases from the east towards the
central and western basins of İzmit Bay. Two distinct fault systems are interpreted in İzmit Bay. The main fault system extending
roughly in an E-W direction along the Gulf of İzmit is an active right lateral strike slip fault with a normal component.
The secondary faults are normal faults striking in different directions and these are identified as being both active and
inactive. In addition, prominent compressive features are identified in the seismic cross-sections of some profiles acquired
to the east of Hersek Peninsula where the focal mechanisms of the aftershocks of the 1999 İzmit earthquake also reveal predominantly
reverse faulting mechanisms, as identified by a local dense seismic network. 相似文献
14.
Geochemical changes of the terrigenous sediments in the southern South China Sea and their paleoenvironmental implications during the last 31 ky 总被引：1，自引：0，他引：1
Shuqing Fu Zhaoyu Zhu Tingping Ouyang Yan Qiu Zhenquan Wei 《Journal of Oceanography》2011,67(3):337-346
Fifty-six subsamples of the 86GC core were collected from the southern South China Sea continental slope. Major and trace
elements, including rare earth elements (REEs), of detrital matters in these sediments were measured. The patterns of chondrite
normalized REEs and the discrimination plots based on major and trace elements, respectively, indicate that the terrigenous
sediments around this area had been supplied with one dominating provenience during the last 31 ky. The co-operation of sea
level changes with the East Asian winter monsoon-related rainfall and sea water circulations should be the main mechanism
causing the geochemical characteristics variations. Higher ratios of Al/Ti and some other elements to Ti, except P/Ti and
Mn/Ti, are present during the last glacial sea-level low stand and the winter monsoon periods owing to increased fluvial input
of material with low Ti content from the Mekong River, followed by strengthened chemical weathering intensity, causing higher
Al2O3 and most other elements contents. The elemental patterns imply general warm and very humid climate in the tropical areas
during the last glacial times; however, the climate since the last deglaciation was very changeable, especially during the
Holocene. Even so, it can still be certain that the climate during the early part (29–24 ky B.P.) of the last glacial maximum
was much worse than during other stages. Additionally, it is very likely that the 8 k cold event and the Younger Dryas event
have been impressed in the geochemical record of this core. 相似文献
15.
《Journal of Sea Research》1999,41(1-2):119-128
With the help of about 500 samples of surface sediments from the North Sea crude maps of the distributions of the clay minerals illite, chlorite, smectite and kaolinite were constructed. Illite, with 51%, is the dominant clay mineral, followed by smectite (27%), chlorite (12%), and kaolinite (10%). There are well-distinguished areas of different concentrations of the individual clay mineral associations. Illite and chlorite show highest values in the north, kaolinite concentrations are high in a corridor a few hundred kilometres wide between the east coast of the UK and the Danish/south Norwegian coast. Smectite is high in the German Bight and in the southwestern North Sea. The distribution patterns of the clay mineral associations are mainly explained by late Quaternary history and by recent to sub-recent sedimentary processes. During the Pleistocene cold periods illite- and chlorite-rich sediments from the Fennoscandian Shield were transported by the great inland ice-masses in a southward direction. The present high sea-level erosion on the east coast of Great Britain provides the North Sea with kaolinite-rich fine-grained sediments. Smectites inherited from Elsterian deposits in the southeast corner and probably from sub-recent Elbe sediments are responsible for their higher values in the German Bight. The high values of smectite in the southwest may have originated from Cretaceous sediments eroded on the banks of the Strait of Dover. The present contribution of riverine suspended load to the North Sea appears to be low. 相似文献
16.
Th. Leipe A. Loeffler K. -C. Emeis S. Jaehmlich R. Bahlo K. Ziervogel 《Estuarine, Coastal and Shelf Science》2000,51(6):789
Suspended particulate matter samples were collected from the water column, the bottom nepheloid layer and the ‘ fluffy layer ’ from four stations along a coastal-basin transect in the Pomeranian Bight, western Baltic Sea. Sampling was performed nine times between October 1996 and December 1998 for various analyses, including electron probe x-ray micro analysis for detailed mineralogical investigations.Specific vertical patterns of clay mineral distributions were found. Suspended particulate matter (SPM) in the bottom nepheloid layer and the ‘ fluffy layer ’ overlying sediments was enriched in organic carbon and hydrated three layer clay minerals, whereas the non-aggregated SPM was dominated by quartz and biogenic opal. It appears that separation effects operate during aggregation of mineral particles and organic matter in repeated cycles of resuspension and settling. No clear seasonal variations in the composition of the SPM were found, in spite of high spatial and temporal variability of biological and physical variables. The results suggest that preferential incorporation, possibly aided by microbiological colonization, of hydrated three layer silicates into the organic flocs is a process that occurs under a wide range of conditions. Because aggregates sink faster than individual particles, aggregate formation led to a relative enrichment of illite and smectite in the near-bottom layers. Considering the affinity of organic contaminants and heavy metals to organic matter, the selective removal of aggregated organic matter and hydrated three-layer clay minerals from the water column and enhanced transport in the near-bottom fluffy layer may be a natural cleansing mechanism operating in the shallow waters of the bight. 相似文献
17.
采用X射线物相分析,对大凌河和辽河13个表层沉积物样品和4个柱状样中168个现代沉积物样品的主要黏土矿物含量组成进行分析。研究结果表明:大凌河沉积物黏土矿物组合为蒙脱石-伊利石-高岭石-绿泥石,辽河沉积物黏土矿物组合为伊利石-蒙脱石-绿泥石-高岭石。大凌河沉积物中蒙脱石与伊利石百分含量比值多大于1,而辽河沉积物该比值都小于1,且通过ISKc端元图能较清晰地区分两类沉积物,黏土矿物可以作为两条河流沉积物的判别标志。大凌河流域和辽河流域均以物理风化为主,辽河流域物理风化略强。流域内地质背景和气候条件等因素的差异造成了两条河流沉积物黏土矿物组成的不同。 相似文献
18.
S. García-Gil E. de Blas N. Martínez-Carreño J. Iglesias R. Rial-Otero J. Simal-Gándara A.G. Judd 《Estuarine, Coastal and Shelf Science》2011
Ría de Vigo is a river valley flooded by the sea, with a bay (San Simón Bay) at its innermost part. The accumulation of Holocene sediment in San Simón Bay has been studied by the integration of 1) large scale high resolution seismic data, and 2) detailed geochemical analysis of a gravity core. In San Simón Bay the majority of the seismic records are obscured by acoustic turbidity which represents gassy sediments, but on records from Rande Strait it is possible to distinguish two Quaternary seismic sequences; an Upper Pleistocene sequence (SQ1) and a Holocene sequence (SQ2). Only SQ2 is recognized in San Simón Bay where it is comprised of two seismic units; the upper unit represents the HST sediment, i.e. the period of highest sea level. A gravity core taken within the gassy zone at 10 m water depth provided 3.55 m of fine-grained sediments (muds) from the youngest seismic unit (4 m thick). Geochemical analysis show high values (4 to 10%) of TOC. Sediment and porewater analyses indicate a distinct sulphate–methane transition zone (SMTZ) between 60 and 80 cm where sulphate is depleted (to <1.7 mM) and methane increases (to >0.4 mM). The top of the acoustic turbidity (the gas front) at 80 cm corresponds to the lower limit of the SMTZ. The methane cannot have been derived from the underlying metamorphic and granitic rocks, but was probably derived by microbial degradation of the organic matter in the Holocene sediments. We estimate that the sediments of the Bay contain approximately 1.8 × 106 m3 of organic carbon and 275 ton of methane. 相似文献
19.
Fine fractions (<2 μm) from smectite-rich flood-plain sediments from the Elbe and Weser rivers in Germany were treated in the laboratory with synthetic sea salt solutions at different concentrations and for different periods of time to document sheet delamination of smectite particles at the fluvial/marine interface and thus simulate changes in clay minerals at the mouth of a river. The project consisted of two steps: (1) Pilot tests were made in 0.5% salt solutions (brackish environment) showing a nearly 2-min delay of the clearing of the clayey suspensions, when the suspension was redispersed 15 and 30 min later after the first measurement. This was due to an obviously increased number of fine laminae from disintegrated smectite particles. (2) X-ray diffraction studies (XRD) of the clayey material from suspensions in 0.0, 0.5, 1.0, and 3.0% salt solutions after standing 10 min, and one and three weeks were made to document alteration reactions of smectite. An aliquot was pipetted periodically from each series, and oriented clay-mineral specimens were analyzed by XRD in air-dried, glycol- and glycerin-solvated states. The peak intensities in the XRD patterns of the clay minerals smectite, random-ordered mixed-layer illite/smectite (I–S), kaolinite, chlorite, and illite did not change in the salt-free series during the experiments. In contrast the peak intensities of smectite and I–S mineral in the air-dried and glycerin-solvated states after suspension in saline solutions decreased significantly. The d-values of the smectitic materials in the air-dried state also decreased after contact with the saline solutions, and in the glycerin-solvated state the full-width-at-half-maximum (FWHM) of the 001 smectite reflection increased by about 20%, indicating a reduction in grain size. 相似文献