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1.
The character of convergence along the Arabian–Iranian plate boundary changes radically eastward from the Zagros ranges to
the Makran region. This appears to be due to collision of continental crust in the west, in contrast to subduction of oceanic
crust in the east. The Makran subduction zone with a length of about 900 km display progressively older and highly deformed
sedimentary units northward from the coast, together with an increase in elevation of the ranges. North of the Makran ranges
are large subsiding basins, flanked to the north by active volcanoes. Based on 2D seismic reflection data obtained in this
study, the main structural provinces and elements in the Gulf of Oman include: (i) the structural elements on the northeastern
part of the Arabian Plate and, (ii) the Offshore Makran Accretionary Complex. Based on detailed analysis of these data on
the northeastern part of the Arabian Plate five structural provinces and elements—the Musendam High, the Musendam Peneplain,
the Musendam Slope, the Dibba Zone, and the Abyssal Plain have been identified. Further, the Offshore Makran Accretionary
Complex shown is to consist Accretionary Prism and the For-Arc Basin, while the Accretionary Prism has been subdivided into
the Accretionary Wedge and the Accreted/Colored Mélange. Lastly, it is important to note that the Makran subduction zone lacks
the trench. The identification of these structural elements should help in better understanding the seismicity of the Makran
region in general and the subduction zone in particular. The 1945 magnitude 8.1 tsunamigenic earthquake of the Makran and
some other historical events are illustrative of the coastal region’s vulnerability to future tsunami in the area, and such
data should be of value to the developing Indian Ocean Tsunami Warning System. 相似文献
2.
The La Luna Formation (Maraca section), Maracaibo Basin, was studied by means of V and Ni analysis of the bitumen, total organic carbon (TOC), total sulfur (St), major elements (Si, Al, Fe, Mg, Mn, Ca, Ti, Na, K, P), trace elements (V, Ni, Co, Cr, Cu, and Zn), and electron microprobe analysis (EPMA) of the whole rock, and St, major elements (Si, Al, Fe, Mg, Mn, Ca, Ti, Na, K, P), trace elements (V, Ni, Co, Cr, Cu, Zn, Mo, Ba, U, Th) and rare earth elements (La, Ce, Nd, Sn, Eu, Th, Yb, Lu) of the carbonate-free fraction. The results are discussed based on the organic and inorganic association of trace elements and their use as paleoenvironmental indicators of sedimentation. An association between V and organic matter is suggested by means of correlation between V and Ni vs. TOC, the use of EPMA (whole rock) and V and Ni concentrations (carbonate-free fraction), whereas Ni is found in the organic matter and the sulfide phase. Fe is present as massive and framboidal pyrite, whereas Zn precipitates into a separate phase (sphalerite), and Ni, Cu and, in some cases, Zn, can be found as sulfides associated with pyrite. Concentrations of V and Ni (bitumen), TOC, St, V, Ni, Cr, Cu and Zn (whole rock), U, Th, Mo (carbonate-free fraction) are indicative of changes in the dysoxic sedimentation conditions in the chert layers (TOC, St, V, Ni, Cu and low Zn and V/Cr <4) to euxinic anoxic conditions in the argillaceous limestone (TOC, St, V, Ni, Cu and high Zn and V/Cr >4). In the sequence corresponding to the argillaceous limestone, variations in the concentrations of TOC, St, V, Ni, Zn, Cu and Cr (whole rock) can be observed, also suggesting variable sedimentation conditions. The following is proposed: (i) sedimentation intervals under euxinic conditions associated with high contribution and/or preservation of organic matter, allowing a high concentration level of V and Ni in the organic phase and the accumulation of Cu, Zn and Ni (in a smaller proportion) in the sulfide phase; (ii) sedimentation intervals under anoxic conditions and in the presence of relatively lower H2S, which allowed lower concentrations of V and Ni in the organic phase and higher concentrations of Cu, Zn, and Ni in the sulfide phase. Rare earth elements (REE) concentrations exhibit a marked increase in Ce, Nd, Sm, Eu, Y and Lu for the QM-3 interval, relative to Post-Archean Average Shale (PAAS). REE enrichment in shales has been related to the presence of phosphate minerals such as monazite or apatite. However, these minerals were not detected through XRD or EPMA in the whole rock or in the carbonate-free fraction. The association of REE with organic matter is suggested due to the absence of phosphate minerals, although assessment of these elements require further analysis. 相似文献
3.
《Chemie der Erde / Geochemistry》2017,77(3):443-458
The elemental composition of organic matter and the major and trace element compositions of stream sediments from Myanmar (Ayeyarwady and Sittaung rivers) and Thailand (Mekong and Chao Phraya rivers, and their tributaries) were determined to examine their distributions, provenance, and chemical weathering processes. Higher total organic carbon (TOC) and total nitrogen (TN) contents in the finer grained sediments indicate hydrodynamic energy may control their distributions. TOC/TN ratios indicate inputs of both aquatic macrophyte and higher vascular plant material to the river sediments. The major element abundances of the sediments are characterized by predominance of SiO2 in coarser fractions and a marked negative correlation with Al2O3, representing primary grain size primarily control on SiO2 content. Marked depletion of most labile elements (Na2O, CaO, K2O, Ba and Sr) relative to UCC (upper continental crust), indicate destruction of feldspar during chemical weathering in the source area or during transport. However, enrichment of some high field strength elements (Zr, Th, Ce and Y) relative to UCC and higher Zr/Sc ratios indicate moderate concentration of resistant heavy minerals in finer-grained samples. Discriminant diagrams and immobile trace element characteristics indicate that the Mekong, and Chao Phraya river sediments were largely derived from felsic sources with compositions close to typical rhyolite, dacite/granodiorite, UCC, I- and S-type granites. Relative enrichment of ferromagnesian elements (e.g. MgO, Cr, Ni) and high Cr/V and low Y/Ni ratios in Ayeyarwady and Sittaung sediments indicate the presence of a mafic or ultramafic component in their sources. The ICV (Index of Compositional Variability), CIA (Chemical Index of Alteration), PIA (Plagioclase Index of Alteration), αAl, Rb/Sr and K2O/Rb ratios indicate that the Ayeyarwady and Sittaung sediments record low to moderate degrees of chemical weathering in their source, compared to moderate to intense chemical weathering in the Mekong and Chao Phraya river basins. These results are compatible with existing major ion data for river waters collected at the same locations. 相似文献
4.
《Chemie der Erde / Geochemistry》2017,77(2):303-321
Geochemical characteristics of stream sediments [n = 31; Upstream section: Zahuapan River (1–12) and Atoyac River (13–20); Downstream section (21–31)] from Atoyac River basin of Central Mexico have been evaluated. The study focuses on the textural, petrography and chemical composition of the fluvial sediments with the aim of analyzing their provenance, the chemical weathering signature and their potential environmental effects. The fluvial sediments are mostly composed of sand and silt sized particles dominated by plagioclase, pyroxenes, amphiboles, K-feldspar, biotite, opaque and quartz. The sediments were analyzed for determination of major (Al, Fe, Ca, Mg, Na, K, P, Si, Ti), trace elements (As, Ba, Be, Co, Cr, Cu, Mo, Mn, Ni, Pb, Sc, V, Y, Zn, Zr, Ga) and compared with Upper continental crust (UCC), source area composition and local background values. The elemental concentrations were comparable with the average andesite and dacitic composition of the source area and the local background values except for enrichment of Cu (56.27 ppm), Pb (34 ppm) and Zn (235.64 ppm) in the downstream sediments suggesting a significant external influence (anthropogenic). The fluvial sediments of Atoyac River basin display low CIA and PIA values implying predominantly weak to moderate weathering conditions in the source region. Based on the provenance discrimination diagrams and elemental ratios, it is understood that the collected sediments are derived from intermediate to felsic volcanic rocks dominated in the study region. Metal contamination indices highlight the enrichment of Cu, Pb, Zn, Mo, Cr and S clearly indicating the influences from natural (weathering and volcanic activity) and external (anthropogenic) sources. Ecological risk assessment results indicate that Cr, Ni and Zn will cause adverse biological effects to the riverine environment. 相似文献
5.
6.
H. A. Al-Darwish E. A. Abd El-Gawad F. H. Mohammed M. M. Lotfy 《Environmental Geology》2005,49(2):240-250
Coastal uses and other human activities have inevitably impinged on the Gulf environment; therefore, these regions require continuous monitoring. The investigated area covered the maximum fragments of Dubai coastal region in the Arabian Gulf. The determination of major oxides and trace metal concentrations in Dubai sediments revealed three heavily and moderately contaminated regions. One is in the far northeastern part at Al-Hamriya Sts 1–3 and contaminated by Fe, Cu, Pb, and Zn; the second is in the mid-northeastern part at Dry Docks and contaminated by Cu, Ni, Pb, and Zn; and finally, the third is in the near southwestern part at Dubal and contaminated by Fe, Mg, Cr, Ni, and Zn. Al-Hamriya St 3 represented the highest values of Cu, Pb, and Zn, whereas Dubal exhibited the maximum values of Fe, Mg, Ba, Cr, Mn, Ni, and V. The anthropogenic discharge and natural deposits are the main sources of contamination. In general, all trace and major elements showed the minimal levels at Jebel Ali Sanctuary (Sts 11, 12, 13) except for Sr and Ca, which showed their maximum values. The highest concentrations of Ca and Sr are mainly attributed to carbonate gravel sands and sands, which cover most stations. Each of V and Ni showed negative correlation with TPH, which may be indicated that the source of oil contamination in the region is not related to crude oil but mostly attributable to anthropogenic sources. The significant positive correlation, which was found between trace metals and TOC indicates that organic matter plays an important role in the accumulation of trace metals in case of Cu, Zn, and Pb. 相似文献
7.
Partitioning of heavy metals in surface Black Sea sediments 总被引：1，自引：0，他引：1
Bulk heavy metal (Fe, Mn, Co, Cr, Ni, Cu, Zn and Pb) distributions and their chemical partitioning, together with TOC and carbonate data, were studied in oxic to anoxic surface sediments (0–2 cm) obtained at 18 stations throughout the Black Sea. TOC and carbonate contents, and available hydrographic data, indicate biogenic organic matter produced in shallower waters is transported and buried in the deeper waters of the Black Sea. Bulk metal concentrations measured in the sediments can be related to their geochemical cycles and the geology of the surrounding Black Sea region. Somewhat high Cr and Ni contents in the sediments are interpreted to reflect, in part, the weathering of basic-ultrabasic rocks on the Turkish mainland. Maximum carbonate-free levels of Mn (4347 ppm), Ni (355 ppm) and Co (64 ppm) obtained for sediment from the shallow-water station (102 m) probably result from redox cycling at the socalled ‘Mn pump zone’ where scavenging-precipitation processes of Mn prevail. Chemical partitioning of the heavy metals revealed that Cu, Cr and Fe seem to be significantly bound to the detrital phases whereas carbonate phases tend to hold considerable amounts of Mn and Pb. The sequential extraction procedures used in this study also show that the metals Fe, Co, Ni, Cu, Zn and Pb associated with the ‘oxidizable phases’ are in far greater concentrations than the occurrences of these metals with detrital and carbonate phases. These results are in good agreement with the recent studies on suspended matter and thermodynamic calculations which have revealed that organic compounds and sulfides are the major metal carriers in the anoxic Black Sea basin, whereas Fe-Mn oxyhydroxides can also be important phases of other metals, especially at oxic sites. This study shows that, if used with a suitable combination of the various sequential extraction techniques, metal partitioning can provide important information on the varying geological sources and modes of occurrence and distribution of heavy metals in sediments, as well as, on the physical and chemical conditions prevailing in an anoxic marine environment. 相似文献
8.
涡阳花沟西10号煤中微量元素的有机亲和性 总被引：1，自引：0，他引：1
为研究淮北矿区涡阳花沟西勘查区10号煤中微量元素的有机亲和性,共采集10个勘探钻孔煤样品,采用电感耦合等离子质谱仪ICP-MS分析了12种微量元素的含量;应用LECO碳硫分析仪测定了煤的总有机碳TOC,并通过两者的相关关系分析了元素的有机亲和性,结合元素的地球化学特征和煤样XRD物相鉴定结果,通过聚类分析进一步推断元素的赋存状态。结果表明:V、Cr、Co、Ni、Mo、Cd、Sb、Pb和Zn元素含量低于全国均值,没有异常富集,Be、Cu和Tl略高于全国均值;Cd具有较强的有机亲和性,Co、Zn、Be和Cr的有机亲和性较弱,V、Ni、Cu、Mo、Sb、Pb和Tl不具有机亲和性;V、Sb、Cu、Cr、Pb、Co和Ni主要以铝硅酸盐吸附态赋存,Cd主要以有机结合态赋存。 相似文献
9.
Z. Touati 《Arabian Journal of Geosciences》2017,10(13):291
Detailed chemostratigraphy across the Cenomanian-Turonian boundary in northern Tunisia points to several prevailing paleoceanographic conditions during the deposition of organic-rich beds of Bahloul Formation. The sedimentological study shows that there is no correlation between color and CaCO3 content because both dark and light-colored intervals of Bahloul Formation are carbonate-rich. Stable isotope analysis displays a positive carbon isotope excursion characterized by four significant peaks (I to IV) which are ranging from 3.2 to 3.5‰. These peaks represent episodes of elevated rates of organic carbon burial during the C/T oceanic anoxic event (C/T boundary OAE2). The Cenomanian-Turonian boundary could be situated between the third isotopic peak and the filament event. The total organic carbon (TOC) measurements show values ranging from 0.28 to 6.19% with average value of 3.5%. This indicates that the Bahloul Formation shale is a very good oil source rock. The Hydrogen Index (HI) values range from 359 to 698 mg HC/g TOC. The T max values range from 390 to 438 °C. Binary diagrams HI vs. T max indicate a type II with values falling within the immature organic-matter range. The concentrations major elements reveal low values of Ti and K. The correlation between Al and Ti and K shows a significant correlation pointing to homogeneous provenance. Primary productivity indicators (Cu, Ba, and Ni) record its association with organic matter. Redox-sensitive elements such as U, V, and Mo and the high values of V/(V + Ni) ratio indicate a strongly reducing environment which led to the better preservation of the organic matter. 相似文献
10.
11.
本文研究桂中坳陷西北部中泥盆统页岩氧化还原条件和古沉积环境。利用该区典型页岩气调查井(桂页1井)岩心,通过X射线荧光光谱分析(XRF)和电感耦合等离子体质谱分析(ICPMS),对中泥盆统岩心(320.35m~938.5m)以1.5m采样间隔进行了微量元素测试。结果显示,纳标组地层V/(V+Ni)、V/Cr和Ni/Co平均值分别大于0.67、4.65和7.71,且富集竹节石、菊石等生物组合,指示其沉积时期海平面相对上升,处于有利于有机质保存的深水陆棚环境;罗富组和塘丁组V/(V+Ni)、V/Cr和Ni/Co分别为0.38~0.65、0.73~4.10和3.70~6.72,指示沉积阶段海平面相对下降,水体变浅,沉积环境为弱氧化的浅水陆棚环境;同时,有机碳含量(TOC)的变化与Ba元素的富集程度相关性较高,表明缺氧环境有利于机质的富集和保存;此外,通过微量元素指标判别,认为桂中坳陷西北部中泥盆统沉积时期,自下而上经历了海平面的相对上升到相对下降的沉积旋回,纳标组时期相对海平面上升至最高,沉积了厚度稳定且有机质含量高的富有机质页岩,可作为本区有利的勘探目标层段。 相似文献
12.
Surface slices of 20 sediment cores, off southwestern Taiwan, and bed sediment of River Kaoping were measured for major and
trace elements (Al, As, Ca, Cd, Cl, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Pb, S, Si, Ti, V, and Zn) to evaluate the geochemical
processes responsible for their distribution, including elemental contamination. Major element/Al ratio and mean grain size
indicate quartz-dominated, coarse grained sediments that likely derived from sedimentary rocks of Taiwan and upper crust of
Yangtze Craton. Bi-plot of SiO2 versus Fe2O3T suggests the possible iron enrichment in sediments of slag dumping sites. Highest concentrations of Cr, Mn, P, S, and Zn
found in sediments of dumping sites support this. Correlation analysis shows dual associations, detrital and organic carbon,
for Cr, P, S, and V with the latter association typical for sediments in dumping sites. Normalization of trace elements to
Al indicates high enrichment factors (>2) for As, Cd, Pb, and Zn, revealing contamination. Factor analysis extracted four
geochemical associations with the principal factor accounted for 25.1% of the total variance and identifies the combined effects
of dumped iron and steel slag-induced C–S–Fe relationship owing to authigenic precipitation of Fe–Mn oxyhydroxides and/or
metal sulfides, and organic matter complexation of Fe, Mn, Ca, Cr, P, and V. Factors 2, 3, and 4 reveal detrital association
(Ti, Al, Ni, Pb, Cu, and V), effect of sea salt (Cl, Mg, Na, and K) and anthropogenic component (As and Zn)-carbonate link,
respectively, in the investigated sediments. 相似文献
13.
The major (Al, Ti, Ca, Mg, Fe, Mn, Si) and trace element (Cd, Cr, Cu, Hg, Li, Ni, Pb, V, Zn) concentrations in surficial
(<20 cm) sediments from fjords and open coastal waters around Greenland have been determined. Regionally, high concentrations
of Fe, Ti, Mg, Cr, Cu, Ni, and V occur in some west and east coast sediments, but they appear to be natural in origin, as
there is no indication of anthropogenic influence. Chemical partition indicates that most of the heavy metals are structurally
bound in various silicate, oxide, and sulfide minerals. These host minerals occur more or less equally in the coarse and fine
sediment fractions (material >63 μm and <63 μm) and have accumulated at the same rate as other detrital clastic material.
Provenance and glaciomarine deposition are the main factors controlling the abundance and distribution of the major and trace
elements. The chemical composition reflects the mineralogical differences in the provenance of glacial marine material deposited
by water and ice adjacent to Greenland. The main source of the sediments enriched in Ti, Fe, Mg, Cr, Cu, Ni, and V appears
to be material derived from the volcanic rocks of the Mesozoic-Tertiary Provinces of Greenland by glacial erosion.
Received: 26 June 1995 · Accepted: 11 August 1995 相似文献
14.
Evaluation of environmental status and geochemical assessment of sediments,Manasbal Lake,Kashmir, India 总被引：1，自引：1，他引：0
The present study was conducted on the Manasbal Lake (34°14′N: 74°40′E) to assess the geochemical characteristics of the lake bottom sediments, its environmental implications and its response in the local catchment area. This study tracks the spatial distribution of grain size, geochemical analysis, C/N ratio, calcium carbonate (CaCO3) and organic matter (OM) of the lake bottom sediments. It is observed that the clay fraction (49.79%) is predominant in the lake bottom sediments, followed by silt (35.88%) and sand (14.33%) and its spatial distribution is controlled by water depth. Geochemistry and normalized diagrams for the major oxides and trace elements reveal enrichment of CaO, K2O, P2O5, S, Cl, Ni, Zn and Sr. Chemical index of alteration (CIA) reflects low to moderate weathering intensity and near compositional similarity with the bedrock exposed in the catchment area around the lake. Environmental indices (EF, Igeo) suggest that the sediments are enriched in Cu, Ni, Zn, Cr, Co, Pb followed by Mn content. Pollution load index (PLI) reveal that all the sampling sites reflect low to moderately polluted category except for few stations that are towards the southern and southeastern side of the lake. OM (16.85%), CaCO3 (14.04%) and C/N ratio (15.5) of the lake bottom sediments is attributed to high organic activity within the lake, shell fragments, contributions from the lake flora and fauna adhering to the clayey silty sediments. The C/N ratio of 15.5 suggests a mixed source of organic matter both terrestrially and in situ formation within the lake. Sulphur and chlorine are high amongst the trace elements suggesting anthropogenic detritus input into the lake and this is due to the chemical fertilizers from the agricultural runoff and organic load into the lake. Thus, the present study suggests that in order to preserve the pristine lake ecology and the environment; continued monitoring and restoration efforts need to be undertaken. 相似文献
15.
华北克拉通南缘古-中元古代构造-沉积演化的俯冲说、裂解说之争由来已久,兵马沟组作为熊耳群形成后的第一套碎
屑沉积岩层,对解释上述过程有重要意义。该文通过对豫西伊川地区的兵马沟组泥质岩微量及稀土元素的地球化学特征分析,
探讨了其沉积环境、物源,进而揭示了其发育的大地构造背景。结果表明：（1）兵马沟组泥质岩稀土元素含量高,球粒陨石标准
化后轻重稀土分异明显,δEu负异常,δCe异常不明显,富集Rb、Th、La、Ce、Nd、Zr、Hf 等,较上地壳平均值富集Sc、V、Cr、Co、Ni、
Rb;（2）Ceanom指数、V/V + Ni反映了泥质岩沉积时的还原环境,Sr/Ba、B/Ga表明其为由陆相至海相的过渡型沉积;（3）Cr/Zr、Th/U
等元素比值关系反应其物源无深部物质加入,La/Yb-Ce、Co/Th-La/Sc图解表明物源为中酸性火山岩及少量稳定陆壳物质;
（4）Th-Sc-Zr/10、Th-Co-Zr/10图解表明其物源主要来自大陆岛弧。综合上述分析结果,结合区域地质信息,可以得出中元古界
兵马沟组形成于大陆岛弧弧后盆地,熊耳群分布区为中元古代俯冲成因的大陆岛弧区。 相似文献
16.
《Journal of Geochemical Exploration》2005,86(2):86-103
An elucidation of the background levels of heavy metals, including certain toxic elements, is very essential to accomplish an important environmental assessment. A regional geochemical mapping in Hokkaido, Japan was undertaken by the Geological Survey of Japan, AIST as part of a nationwide geochemical mapping for this purpose. There were 692 stream sediments collected from the active channel (1 sample) / (100 km2) in Hokkaido and the fine fraction sieved through a 180 μm screen was analyzed using the AAS, ICP-AES, and ICP-MS techniques. The regional geochemical maps for 51 elements were created as a 2000 m mesh map using the geographic information system software. Spatial distribution patterns of elemental concentrations in stream sediments, particularly Neogene–Quaternary volcanic and pyroclastic rocks, are primarily determined by surface geology. The correspondence of elemental concentrations in stream sediments to parent lithology is clearly indicated by ANOVA and a multiple comparison. Sediment samples supplied from mafic volcanic and felsic–mafic pyroclastic rocks are significantly rich in MgO, Al2O3, P2O5, CaO, Sc, TiO2, V, MnO, Total (T)-Fe2O3, Co, Zn, Sr, and heavy rare earth elements (REEs) (Y and Eu–Lu), but significantly lacking in alkali elements, Be, Nb, light REEs (La–Nd), Ta, Tl, Th, and U. Accretionary complexes with sedimentary rocks derived from sediments are in stark contrast to volcanic and pyroclastic rocks. Accretionary complexes with mafic–ultramafic rock have significantly elevated Nb, Ta, and Th abundances in sediments besides MgO, Cr, Ni, Co, and Cu. This inexplicable result is caused by the mixed distributions of granite and ultramafic–mafic rocks.The watersheds with mineral deposits relate to the high concentrations of certain elements such as Zn, As, and Hg. The geochemically anomalous pattern, which is a map of the regional anomalies, and a scatter diagram were applied to examine the contribution of mineral deposits to MnO, T-Fe2O3, Cr, Cu, Zn, As, Cd, Sb, Hg, Pb, and Bi concentrations. Consequently, they were grouped into four types: 1) Mineral deposits with no outliers resulting from mineralization (MnO, T-Fe2O3, and Cr), 2) sediments supplied from watersheds without metal deposits conceal high metal inputs from known mineral deposits (Cu), 3) deposits from a geochemically anomalous area that closely relates to the presence of mineral deposits (As, Sb, and Hg), and 4) deposits from the widely altered zone associated with the Kuroko as well as hydrothermal deposits corresponding to geochemically anomalous patterns (Zn, Cd, and Pb). This study provides an important regional geochemical database for a young island-arc setting and interpretational problems, such as complicated geology and active erosion, that are unique to Japan. 相似文献
17.
滇黔北坳陷五峰组-龙马溪组下段页岩岩相与沉积环境 总被引：1，自引：0，他引：1
滇黔北坳陷为南方海相地层的有利研究区域,发育多套海相页岩。上奥陶统五峰组与下志留统龙马溪组地层,尤其是五峰组-龙马溪组下段页岩作为优质烃源岩而备受重视。通过岩芯观察、薄片鉴定、X衍射分析及微量元素地球化学指标判识,对其进行页岩岩相划分与沉积环境分析。结果显示:滇黔北坳陷五峰组-龙马溪组下段地层共划分出六种页岩岩相:硅质页岩、黏土质页岩、钙质页岩、黏土质硅质混合页岩、黏土质钙质混合页岩、钙质硅质混合页岩,其中硅质页岩和黏土质页岩的TOC含量明显高于其余四种岩相。V/（V+Ni）、V/Cr、Ni/Co和U/Th指标指示五峰组-龙马溪组下段总体处于低能、滞留、局限条件,与深水陆棚环境匹配,Mo元素含量与四川盆地均值相当。五峰早期与龙马溪早期海侵的发生形成了以深水陆棚占主导的沉积格局,低能、滞留、局限的厌氧环境与快速海侵是有机质富集与保存的重要条件。 相似文献
18.
《Chemie der Erde / Geochemistry》2015,75(2):185-195
Chabahar Bay in SE of Iran is a shallow semi-enclosed environment affected by anthropogenic activities. In this paper, 19 sediment samples were collected and concentration of selected metals (Cu, Pb, Zn, Cd, Ni, Cr, Co, V and Fe) was determined using ICP-MS analytical method. Sediment samples from five stations were also selected for sequential extraction analysis and concentration of metals in each fraction was determined using ICP-OES. In order to investigate the environmental quality of Chabahar Bay, geographic information system (GIS) along with geochemical data, environmental indices and statistical analyses were used. Calculated contamination degree (Cd) revealed that most contaminated stations (Ch3, S1 and S3) are located SE of Chabahar Bay and contamination decreases in a NW direction. The S9 station, west of the bay, is also contaminated. High organic matter (OM) content in the sediments is most likely the result of fuel and sewage discharge from fishing vessels along with discharge of fishing leftovers. Significant correlation coefficient among OM, Fe, Cu, Pb, Zn and Cd seemingly reflects the importance of the role that OM and Fe oxy-hydroxides play in the metals mobility. The results of hierarchical cluster analysis (HCA), computed correlation coefficient and sequential extraction analysis suggest that Cu, Pb, Zn and Cd probably come from antifouling and sea vessel paints, while Ni, Cr, Co, V and Fe are most likely contributed by ophiolitic formations located north of the bay and/or deep sea sediments. Average individual contamination factors (ICFs) indicated that the highest health hazard from the bay is posed by Cu, Pb and Zn. 相似文献
19.
A. V. Maslov V. P. Shevchenko V. N. Podkovyrov Yu. L. Ronkin O. P. Lepikhina A. N. Novigatsky A. S. Filippov N. V. Shevchenko 《Lithology and Mineral Resources》2014,49(6):433-460
The paper discusses results of the lithogeochemical examination of recent bottom sediments in the lower course of the Severnaya Dvina River and White Sea. It has been established that the average concentration of several trace elements (Hf, Sc, Co, Y, Ni, V, Cr, Zr, Ba, and others) therein correlates with the content of the silt-pelite fraction. Maximal concentrations of the majority of above elements are confined to the silty-clayey sediments at the Basin/Dvina Bay boundary. They localized near the coastal zone only for some clastophile (Zr, Cr, and others). Typical values of the hydrolyzate module, chemical index of alteration, and Al2O3/SiO2 ratio in the aleuropelitic and pelitic sediments of the Severnaya Dvina River delta, Dvina Bay, and the Dvina Bay Basin boundary suggest that these sediments are confined to sufficiently cold climate settings. Data points of sediment composition in discriminant paleotectonic diagrams are scattered over a large field probably due to high contents of the weakly weathered plagioclases, micas, and amphiboles, as well as the hydrogenic process promoting the accumulation of Fe and Mn. The PAAS-normalized spectra of rare earth elements (REE) in bottom sediments of the Pinega and Severnaya Dvina rivers, marginal filter of the latter river, Dvina Bay, and the Dvina Bay Basin boundary are similar to the REE distribution in clayey rocks of the ancient platform cover (except for a slight positive Eu anomaly). The REE systematics and distribution pattern of compositional data points of recent bottom sediments in the GdN/YbN-Eu/Eu* and Eu/Eu*-Cr/Th diagrams and values of several indicator ratios of trace elements suggest that the studied rocks were formed by the mixing of clastic materials from geochemically contrast provenances: northwestern provenance (Kola-Karelia geoblock), which is mostly composed of the Archean and Early Proterozoic crystalline complexes, and the southeastern provenance (northwestern periphery of the Mezen syncline), which is almost totally composed of Phanerozoic sedimentary rocks. The latter provenance likely played a crucial role in the geochemical signature of recent bottom sediments over a significant area of the White Sea. 相似文献
20.
Jaya K. Gurung Hiroaki Ishiga Mohan S. Khadka Nav R. Shrestha 《Environmental Geology》2007,52(3):503-517
The geochemical analyses of fluvial-lacustrine aquifer sediments of the Kathmandu Valley have been made as a step in assessing
the environment for the mobilization of arsenic in groundwater. Elements measured by X-ray fluorescence (XRF) include 4 major
oxides (Fe2O3, TiO2, CaO, P2O5) and 14 trace elements (As, Pb, Zn, Cu, Ni, Cr, V, Sr, Y, Nb, Zr, Th, Sc and TS). Elution tests of 15 selected core samples
were also carried out to determine the potential leaching of arsenic from the sediments. The XRF results show that average
bulk concentrations of the major oxides and trace elements are similar to modern unconsolidated sediments and average upper
continental crust. However, the abundance of elements varies with grain size, with higher concentrations in finer-size grades.
Variations in elemental abundances within the basin are strongly controlled by sediment facies. The elution tests show that
greater amounts of arsenic are generally eluted from the fine sediments, although the rates are variable. The results overall
suggest that As concentrations in the bulk sediments are not a controlling factor for elevated As in the Kathmandu Basin groundwater,
and the roles of other factors such as redox conditions and organic matter contents are likely to be more significant. 相似文献