首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 46 毫秒
1.
^32Si是宇宙成因的放射性同位素,其半衰期约为200a,应用^32Si作为示踪剂测定地下水年龄的范围为50-1000a。本文介绍了应用F e(OH)3共沉法从天然水中提取SiO2的制备方法。  相似文献   

2.
热液体系中Si的络合作用   总被引:1,自引:0,他引:1  
在不同温度、PH和硅浓度条件下,实验标定了Au-SiO以及Sn-SiO2之间的络合反应:Au^++H3SiO4^-之间的络合反应:Au^++H4SiO=AuH3SiO4 lgK=-1.65436+9611.21/T;Sn^4++4H3SiO4^-=Sn(H3SiO4)4;lgK200c=42.73。通过与Au-Cl、Au-HS以及Sn-OH络合物迁移能力的比较,表明在具地质意义的P睡EH条件下,A  相似文献   

3.
地下水化学组分存在形式的计算及其意义   总被引:4,自引:0,他引:4  
地下水化学组分形式的定量研究是水岩作用模拟计算的基础,本文系统地介绍了利用化学热力学平衡理论定量计算化学组分形式的理论与方法,并石家庄平原地下水中化学组分形式的分布,结果表明,构成地下水化学组分形式主要为络阴离子和单一离子,但CaSO^04,MgSO^04和CaCHO^+3是地下水化学组成不可忽视的络合形式,这些络合组分随着TDS和SO^2-4总量的升高上游到下民占比例逐渐升高,络合形式的存在不仅  相似文献   

4.
金在碱性富硅热液中溶解和迁移的实验研究   总被引:17,自引:3,他引:17  
樊文苓  王声远 《矿物学报》1995,15(2):176-184
实验测定了金在碱性富硅溶液中的溶解度,并标定了Au与SiO2之间的配合关系Au^+H2SiO^-4=AuH3SiO^04在80 ̄250℃的温度范围内,其平衡常数为lgK=-1.9889+10085。18/T(T为绝对温度)各温度下的平衡常数值与Au-HCl-SiO2-H2O体系中得到的结果一致。它表明溶液在酸性和碱性条件下,SiO2均作为配位体,与Au形成AuH3SiO^04在热液中溶解、迁移。A  相似文献   

5.
重铬酸钾法测定废水COD条件改进的研究   总被引:3,自引:0,他引:3  
本提出用CuSO4作催化剂,在H2SO4-H2PO4溶液中,重铬酸钾回流测定废水COD的方法,实验表明,最佳测定条件为:CuSO4浓度为7×10^-2mol.L^-1(混酸溶液):H2SO4:H3PO4=5:1(体积比)回流时间2h,通过与标准方法对比,测定结果满意,本方法的优点是:不需用贵重金试剂Ag2SO4,改用CuSO4作催化剂,精密度高,准确性好,具有一定的实用价值。  相似文献   

6.
示波极谱法测定矿石中的金   总被引:4,自引:0,他引:4  
在PT-H3PO4-NaH2PO4体系中,金有一个络合吸附波,峰电位为-0.32V(Vs.SCE),检测下限为8.2×10^-9mol.L^-1峰电流与金含量在0.020~0.80μg.ml^-1范围内呈线性关系,该法可用于金矿中金的测定。  相似文献   

7.
等离子体发射光谱法测定重晶石中钡铁和硅   总被引:3,自引:0,他引:3  
杨德君  陈利平 《岩矿测试》1998,17(4):317-318
重晶石经Na2CO3熔融,水浸取,过滤。沉淀经HCl溶解后,用电感耦合等离子体发射光谱法同时测定主成分BaSO4和次量成分Fe2O3以及滤液中的SiO2,结果与部颁标准方法符合。方法精密度好,主量组分BaSO4测定的RSD(n=6)为0.24%,次量组分Fe2O3和SiO2的RSD(n=6)分别是3.69%和1.45%。  相似文献   

8.
将样品滤膜一起用HF、HNO3及HClO4消化,制成10%的HNO3溶液,用ICP-AES测定Cu,Pb,Zn。检出限分别为1.4、8.1、0.7,RSD%分别为3.7、7.3、1.8,已用于测定青岛市区的大气颗粒物样品。  相似文献   

9.
地下水^32硅年龄的测定方法—液体闪烁计数法   总被引:1,自引:0,他引:1  
周炼  刘存富  王佩仪 《岩矿测试》2000,19(2):97-100
用Fe(OH) 3共沉淀从天然水中提取纯化SiO2 ,回收率在 30 %~ 98% ,然后提取32 P ,将H3PO4溶液和PicoflourLLT混合制备计数溶液 ,用液体闪烁计数法测量32 P的放射性 ,计算32 Si的放射性浓度 ,最后确定地下水的年龄。通过对河北平原浅层地下水的32 Si年龄进行测定 ,所得的32 Si年龄为 92 9 89a± 1 7 87a,与1 4 C的校正年龄一致  相似文献   

10.
硫脲浸取—光度法测定硫化矿中金   总被引:3,自引:0,他引:3  
刘建  闫英桃 《岩矿测试》2000,19(1):74-76,79
常温下在H2C2O4-H2SO4介绍中,用50g/L硫脲(Tu)溶液可完全浸提含金硫化矿中Au,对金的浸取率可达99.8%,然后作用CL-P204萃淋树脂事集含金分解液中Au(Tu)2^+,结晶紫分光度法测定。方法用于硫化原生矿及含硫浮选精矿中Au的测定,所得结果与王水分解原子吸收法测定相符,其RSD(n=5)〈3%。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
15.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

16.
正20141520 Bo Ying(Key Laboratory of Metallogeny and Mineral Assessment,MLR,Beijing 100037,China);Liu Chenglin Saline Spring Hydrochemical Characteristics and Indicators for Potassium Exploration in Southwestern and Northern Tarim Basin,Xinjiang(Acta Geoscientica Sinica,ISSN1006-3021,CN11-3474/P,34(5),2013,p.594-602,5 illus.,3 tables,28 refs.)  相似文献   

17.
正20141243Chen Ge(Hangzhou Research Institute of Petroleum Geology,PetroChina,Hangzhou 310023,China);Si Chunsong Study on Sedimentary Numerical Simulation Method of Fan Delta Sand Body(Journal of Geology,  相似文献   

18.
正20142599Chen Sanming(Guangxi Key Laboratory of Concealed Deposits Exploration,Guilin University of Technology,Guilin541004,China);He Yuzhou Block Model and Reserves Estimation of Panzhihua Iron Deposit Based on 3D Geological Modeling(Journal of Guilin University of Technology,ISSN1674-9057,CN45-1375/N,33(4),2013,p.610-615,9illus.,1table,15refs.)  相似文献   

19.
正20140594 Bai Daoyuan(Hunan Institute of Geology Survey,Changsha 410016,China);Zhong Xiang Faults in the Jingzhou Basin and Their Tectonic Settings(Geotectonica et Metallogenia,ISSN1001-1552,CN44-1595/P,37(2),2013,p.173-183,6illus.,59refs.)Key words:basin evolution,tectonic setting,South China In the Upper Paleozoic and Jurassic se-  相似文献   

20.
正20141912Cao Hui(State Key Laboratory for Continental Tectonics and Dynamics,Institute of Geology,Chinese Academy of Geological Sciences,Beijing 100037,China)Gravitational Collapse and Folding during Orogenesis:A Comparative Study of FIA Trends and Fold Axial Plane Traces(Geology in China,ISSN1000-3657,CN11-1167/P,40(6),2013,p.1818-1828,9illus.,35refs.,with  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号