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基于反射光谱预测土壤重金属元素含量的研究 总被引：5，自引：0，他引：5
本文利用实验室实测的土壤反射光谱以及铅、镉、汞等重金属元素数据,进行土壤重金属元素含量快速预测的可行性研究。本文利用偏最小二乘回归方法,研究了反射率(R)、一阶微分(FDR)、反射率倒数的对数(lg(1/R))和波段深度(BD)等对预测精度的影响,对这几种光谱指标预测土壤重金属含量的能力进行了分析和评价,同时分析了多光谱数据估算土壤重金属元素含量的可行性。结果表明,反射率倒数的对数lg(1/R)是估算土壤重金属元素含量最好的光谱指标,尤其是Cd和Pb,检验精度R超过0.82。有机质、铁锰氧化物和黏土矿物对土壤重金属元素的吸附是可见光—近红外—短波红外光谱估算其含量的机理。多光谱数据同样具有估算土壤重金属元素含量的能力,但实际数据则要考虑多种因素的影响。 相似文献
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基于GIS的县域土壤重金属生态风险评价 总被引：2，自引：0，他引：2
为研究经济快速发展区农田土壤中重金属的含量及污染状况,本文以浙江省慈溪市为研究对象,研究土壤中铜、汞、镉、铅、砷、铬、锌七种重金属含量特征,并采用潜在生态危害指数法对其进行评价,并绘制生态风险危害指数分级图。结果表明:土壤中除汞元素含量较高外,其他各元素含量仅稍高于当地土壤背景值。七种元素的单因子污染指数Cfi值均属于中等的污染参数,综合污染指数Cd上限值已处于高污染指数的范围,但平均值为属于中等污染水平。从潜在生态风险评价结果来看,七种元素的单项潜在生态风险参数Eri的值也只有汞达到了强生态危害,七种元素综合潜在生态危害指数RI刚刚达到中等生态危害水平,说明该区农田土壤尚处于较低的生态风险状态。生态危害指数插值结果表明,慈溪市重金属元素的高风险区分布在中南部人类活动较为活跃、城乡工业较发达的区域,在今后的土地利用中,应高度重视人类活动对土壤重金属污染的影响。 相似文献
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针对遥感影像反射率与重金属元素间的光谱响应弱,土壤重金属经典反演模型精度较低等问题,本文以Sentinel-2号遥感影像为数据源,利用像元二分模型进行影像光谱解混,筛选出相关性较高的特征光谱作为光谱参量,构建基于像元线性解混和不同光谱变换下土壤反射率与重金属Cr含量的PLS模型和GMDH模型。研究结果表明,解混后的光谱与重金属Cr含量间的显著相关波段数增多,相关性增强。基于解混后的土壤光谱与重金属Cr含量构建的GMDH模型,其模型稳定性较好,预测能力更强,精度更好。该方法拓展了传统的利用遥感影像进行反演的思路,可为大范围监测土壤重金属的污染状况提供有益参考。 相似文献
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大气降尘可以反映大气颗粒物的自然沉降量,具有重要的环境指示意义.其携带的有毒重金属易沉积在植物、土壤和水体中,通过食物链的传递和累积,对人体健康、植物和水生生物等造成严重的危害,已经引起人们的广泛关注.研究大气降尘的元素特征、重金属污染评价及成因分析对于大气环境治理以及居民健康防护意义重大.针对北京大气降尘重金属污染成因这一科学问题,论文首先基于北京及周边地区大气降尘、地表土以及典型污染端元样品的元素含量IC P-M S测试结果,分析了北京大气降尘的元素特征;基于 G IS地统计分析理论交叉验证并选取了北京降尘中主要重金属的最优空间插值模型,并探讨了北京降尘重金属污染的空间分布;其次,在传统的单一重金属污染评价方法的基础上提出并构建了"降尘重金属综合污染指数"模型,对北京降尘重金属污染状况进行了综合评价;然后,通过各污染端元显著因子识别方法构建了北京降尘局部污染源重金属成分谱,并综合应用多元统计分析解析了北京大气降尘重金属的局地污染源;同时探讨了地表土重金属污染以及下垫面土地利用类型对北京降尘重金属污染的影响;最后,利用HYSPLIT-4区域传输模型,并结合区域站点实测数据,综合分析了北京大气降尘重金属污染受区域传输的影响.主要结论如下. 相似文献
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土壤污染是全球三大环境污染之一,目前、重金属污染是造成我国土壤污染主要原因之一,土壤中的重金属元素会严重危害相关农作物的生长,且传统的土壤重金属污染研究和污染模型的建立大部分是通过单一的数据表格来对结果进行分析说明,不够直观和简明。因此,基于地理信息系统十分强大的空间数据管理及空间分析能力,结合相关算法,构建出土壤中重金属污染扩散迁移模型,并将WebGIS技术和土壤重金属污染扩散迁移起来,对土壤重金属污染数据用GIS技术进行分析和展示。研究表明:改进之后的模型及程序与传统模型及程序相比,数据的展示更加直观,对数据展示更加多维,可以辅助政府环保相关部门对土壤中的重金属污染制订更加精准的治理方案。 相似文献
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《测绘科学技术学报》2018,(5)
快速、准确地测定土壤重金属含量,对防治土壤重金属污染、改善土壤环境和保障食品安全有着重要意义。以山东省烟台市采集的70个土壤样本为基础,首先分析土壤重金属铬含量的分组光谱特性;然后利用6种变换方法对土壤光谱反射率进行变换,根据极大相关性原则选取反演因子;最后利用灰色关联度模型初步估测铬含量,并对估测结果进行修正,采用决定系数和平均相对误差评价模型的有效性。结果表明,土壤光谱反射率随铬含量的升高而降低,二者呈负相关性;利用灰色关联度模式识别方法对重金属铬含量进行估测后的决定系数为R~2=0.656,平均相对误差为16.590%,而利用灰色关联度修正模型对估测值进行修正后,决定系数为R~2=0.912,平均相对误差为6.632%。研究表明,利用灰色关联度修正模型定量估侧土壤重金属铬含量有效。 相似文献
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针对城市绿化带土壤重金属污染问题,该文利用射线荧光光谱仪测量重金属含量,引用单因子与负荷污染指数法并依据国家标准进行污染评价;引入人体暴露风险评价模型,对致癌和非致癌健康风险进行评价。结果表明,研究区土壤重金属污染较严重;经手-口直接摄入是健康风险的主要暴露途径,儿童总的非致癌风险为0.573,成人总的非致癌风险为0.088,均未超过限制1,表明8种重金属不存在明显的非致癌风险;Cr、Co、Ni、As的致癌风险均低于美国环境保护部推荐标准10~(-6),表明重金属的致癌风险均在可接受范围内。研究区内土壤重金属含量及污染状况空间分异显著。研究结果对城市绿化带内土壤重金属污染评价有一定借鉴意义。 相似文献
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土壤重金属污染灰色综合评价模型 总被引：1，自引：1，他引：0
针对稀疏采样难以准确估测区域土壤重金属综合污染情况和迁移变化规律的问题,提出基于GIS的多属性决策组合赋权灰色综合评价模型。首先采用GIS技术揭示土壤重金属空间变异和污染分布格局;然后利用最大化熵理论集成主客观因素,架构优化组合赋权的土壤重金属污染灰色综合评价体系;最后以试验区土壤中8种(铜、锌、铅、镉、砷、铬、汞、镍)重金属的综合污染情况为例,检验该方法应用效果。结果表明:最优组合权重的灰色综合分析方法兼顾主观偏好和客观属性,其评价结果具有更高的可信度和风险辨识度,提高了综合评价的合理性与有效性,可为土壤重金属污染监测提供方案参考。 相似文献
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It is necessary to estimate heavy metal concentrations within soils for understanding heavy metal contaminations and for keeping the sustainable developments of ecosystems. This study, with the floodplain along Le’an River and its two branches in Jiangxi Province of China as a case study, aimed to explore the feasibility of estimating concentrations of heavy metal lead (Pb), copper (Cu) and zinc (Zn) within soils using laboratory-based hyperspectral data. Thirty soil samples were collected, and their hyperspectral data, soil organic matters and Pb, Cu and Zn concentrations were measured in the laboratory. The potential relations among hyperspectral data, soil organic matter and Pb, Cu and Zn concentrations were explored and further used to estimate Pb, Cu and Zn concentrations from hyperspectral data with soil organic matter as a bridge. The results showed that the ratio of the first-order derivatives of spectral absorbance at wavelengths 624 and 564 nm could explain 52% of the variation of soil organic matter; the soil organic matter could explain 59%, 51% and 50% of the variation of Pb, Cu and Zn concentrations with estimated standard errors of 1.41, 48.27 and 45.15 mg·kg?; and the absolute estimation errors were 8%–56%, 12%–118% and 2%–22%, and 50%, 67% and 100% of them were less than 25% for Pb, Cu and Zn concentration estimations. We concluded that the laboratory-based hyperspectral data hold potentials in estimating concentrations of heavy metal Pb, Cu and Zn in soils. More sampling points or other potential linear and non-linear regression methods should be used for improving the stabilities and accuracies of the estimation models. 相似文献
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GIS的矿区土壤重金属污染评价及空间分布 总被引：2，自引：0，他引：2
针对土壤中的重金属含量超标会对人体健康造成极大危害的问题,为检测矿区土壤重金属含量超标状况及空间分布特征,以江西省信丰县4个矿区为例,在28个点位的20~60cm处测定Hg、Cd、As、Cu、Pb、Ni的含量,采用地统计学和地理信息系统相结合的方法进行分析。结果表明,单因子污染指数显示Pb的污染程度最大,污染程度为中度污染;插值分析图显示Cu以西南方向的虎山矿区含量较高,Ni以西南方向的虎山矿区和北部的赤岗矿区含量较高,Pb的污染区域贯穿于整个分布区;重金属含量随深度的增加无明显变化。结合在污染修复方面的经验,建议通过植物修复技术、物理与化学方法进行污染治理和修复。 相似文献
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It is necessary to estimate heavy metal concentrations within soils for understanding heavy metal contaminations and for keeping the sustainable developments of ecosystems.This study,with the floodplain along Le’an River and its two branches in Jiangxi Province of China as a case study,aimed to explore the feasibility of estimating concentrations of heavy metal lead(Pb),copper(Cu) and zinc(Zn) within soils using laboratory-based hyperspectral data.Thirty soil samples were collected,and their hyperspectral data,soil organic matters and Pb,Cu and Zn concentrations were measured in the laboratory.The potential relations among hyperspectral data,soil organic matter and Pb,Cu and Zn concentrations were explored and further used to estimate Pb,Cu and Zn concentrations from hyperspectral data with soil organic matter as a bridge.The results showed that the ratio of the first-order derivatives of spectral absorbance at wavelengths 624 and 564 nm could explain 52% of the variation of soil organic matter;the soil organic matter could ex-plain 59%,51% and 50% of the variation of Pb,Cu and Zn concentrations with estimated standard errors of 1.41,48.27 and 45.15 mg·kg-1;and the absolute estimation errors were 8%-56%,12%-118% and 2%-22%,and 50%,67% and 100% of them were less than 25% for Pb,Cu and Zn concentration estimations.We concluded that the laboratory-based hyperspectral data hold potentials in esti-mating concentrations of heavy metal Pb,Cu and Zn in soils.More sampling points or other potential linear and non-linear regression methods should be used for improving the stabilities and accuracies of the estimation models. 相似文献
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Kai Liu Dong Zhao Jun-yong Fang Xia Zhang Qing-yun Zhang Xue-ke Li 《Journal of the Indian Society of Remote Sensing》2017,45(5):805-813
Heavy-metal-contaminated soil is a critical environmental issue in suburban regions. This paper focuses on utilizing field spectroscopy to predict the heavy metal contents in soil for two suburban areas in the Jiangning District (JN) and the Baguazhou District (BGZ) in China. The relationship between the surface soil heavy metal contents and spectral features was investigated through statistical modeling. Spectral features of several spectral techniques, including reflectance spectra (RF), the logarithm of reciprocal spectra (LG) and continuum-removal spectra (CR), were employed to establish and calibrate models regarding to Cd, Hg and Pb contents. The optimal bands for each spectral feature were first selected based on the spectra of soil samples with artificially added heavy metals using stepwise multiple linear regressions. With the chosen bands, the average predictive accuracies of the cross-validation, using the coefficient of determination R2, for estimating the heavy metal contents in the two field regions were 0.816, 0.796 and 0.652 for Cd; 0.787, 0.888 and 0.832 for Pb; and 0.906 and 0.867 for Hg based on partial least squares regression. Results show that better prediction accuracies were obtained for Cd and Hg, while the poorest prediction was obtained for Pb. Moreover, the performances of the LG and CR models were better than that of the RF model for Pb and Hg, indicating that LG and CR can provide alternative features in determining heavy metal contents. Overall, it’s concluded that Cd, Hg and Pb contents can be assessed using remote-sensing spectroscopy with reasonable accuracy, especially when combined with library and field-collected spectra. 相似文献
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B.B. Maruthi Sridhar Robert K. Vincent Sheila J. Roberts Kevin Czajkowski 《International Journal of Applied Earth Observation and Geoinformation》2011
The accumulation of heavy metals in the biosolid amended soils and the risk of their uptake into different plant parts is a topic of great concern. This study examines the accumulation of several heavy metals and nutrients in soybeans grown on biosolid applied soils and the use of remote sensing to monitor the metal uptake and plant stress. Field and greenhouse studies were conducted with soybeans grown on soils applied with biosolids at varying rates. The plant growth was monitored using Landsat TM imagery and handheld spectroradiometer in field and greenhouse studies, respectively. Soil and plant samples were collected and then analyzed for several elemental concentrations. The chemical concentrations in soils and roots increased significantly with increase in applied biosolid concentrations. Copper (Cu) and Molybdenum (Mo) accumulated significantly in the shoots of the metal-treated plants. Our spectral and Landsat TM image analysis revealed that the Normalized Difference Vegetative Index (NDVI) can be used to distinguish the metal stressed plants. The NDVI showed significant negative correlation with increase in soil Cu concentrations followed by other elements. This study suggests the use of remote sensing to monitor soybean stress patterns and thus indirectly assess soil chemical characteristics. 相似文献
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针对矿区土壤重金属含量高度变异性及样本不均衡导致重金属污染状况分类误差较大的问题，本文在光谱预处理及光谱变换基础上，采用主成分分析（PCA）对光谱进行降维处理，并通过SMOTE算法生成虚拟样本均衡各污染等级样本，最后应用随机森林（RF）对Cd、Pb进行回归与分类。研究结果表明：定量反演重金属Pb、Cd含量精度很低；在定性分析试验中对降维前光谱样本应用SMOTE算法，土壤重金属Pb、Cd污染等级分类精度较原始样本分类精度均有较大提升，且少数类别误判率也降低明显。其研究为大面积监测矿区土壤重金属污染状况提供了一种有效、精确的方法。 相似文献