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1.
Searching for traces of extinct and/or extant life on the surface of Mars is one of the major objectives for remote-sensing and in-situ exploration of the planet. In the present paper we study the infrared (IR) spectral modifications induced by thermal processing on differently preserved calcium carbonate fossils, in order to discriminate them from their abiotic counterparts.The main conclusion of this study is that the degree of alteration of the fossils, derived from IR spectral analysis, seems to be well correlated with the sample age, and that terrestrial fossils after a billion years are so altered that it becomes impossible to trace their biotic origin. Since it is reasonable to assume that the putative Martian fossils should be at least 3.5 billion years old, this would imply that our spectroscopic method could not be able to detect them, if their degradation rate were the same as that we have found in usual conditions for the terrestrial fossils. However, due to the different climate evolution of the two planets, there is the possibility of having two different degradation rates, much lower for Mars than for Earth, especially if the fossils are embedded in a protective layer, such as a clay deposit. In this case IR spectroscopy, coupled with thermal processing, can be a useful tool for discriminating between abiotic and biotic (fossil) carbonate samples collected on the Martian surface.  相似文献   

2.
Searching for traces of extinct and/or extant life on Mars is one of the major objectives for remote-sensing and in situ exploration of the planet. In previous laboratory works we have investigated the infrared spectral modifications induced by thermal processing on different carbonate samples, in the form of fresh shells and fossils of different ages, whose biotic origin is easily recognizable. The goal was to discriminate them from their abiotic counterparts. In general, it is difficult to identify biotic signatures, especially when the organisms inducing the carbonate precipitation have low fossilization potential (i.e. microbes, bacteria, archaea). A wide variety of microorganisms are implicated in carbonate genesis, and their direct characterization is very difficult to evaluate by traditional methods, both in ancient sedimentary systems and even in recent environments.In the present work we apply our analysis to problematic carbonate samples, in which there is no clear evidence of controlled or induced biomineralization. This analysis indicates a very likely biotic origin of the aragonite samples under study, in agreement with the conclusion previously reported by Guido et al. (2007) who followed a completely different approach based on a complex set of sedimentary, petrographic, geochemical and biochemical analyses. We show that our method is reliable for discriminating between biotic and abiotic carbonates, and therefore it is a powerful tool in the search for life on Mars in the next generation of space missions to the planet.  相似文献   

3.
The search for biosignatures in the soil of Mars is a major objective of the planet exploration, but the detection of such structures is not straightforward due to the degradation of the organic material. In a previous work our group has analyzed the spectral reaction to thermal processing of biomineral carbonate samples including fresh and fossil shells. We found that two terrestrial fossil shells collected from clay deposits preserve their biomineral characteristics much better than coeval fossils not embedded in clay layers.In the present paper we extend our analysis to a set of fossils found in three different terrestrial clay deposits. Our results confirm that the level of degradation may be much lower than the standard values if fossils are surrounded by clay minerals. As a result these fossils have a spectroscopic response to thermal treatment which make them much more distinguishable from their abiotic counterparts than coeval fossils not collected from clay deposits. This result implies that the phyllosilicates regions recently discovered on Mars may represent very interesting environments that can provide conditions favorable to preserve evidence of biomarkers, and hence can be regarded as good candidate locations for their detection.  相似文献   

4.
Abstract– CM chondrites are primitive solar‐system materials that have undergone high degrees of aqueous alteration, resulting in the formation of secondary minerals including carbonates. Two different carbonate minerals (calcite/aragonite and dolomite) together constitute 1.4–2.8 vol% of CM chondrites. In contrast, CI chondrites contain four different carbonate minerals: calcite/aragonite, dolomite, breunnerite, and siderite. CI chondrites have abundant dolomite, a mineral that seems to be absent in the most aqueously altered CM chondrites. In this study, carbonates in seven CM chondrites (Y‐791198, LaPaz Icefield 04796, Cold Bokkeveld, Nogoya, Queen Alexandra Range 93005, Allan Hills 83100, and Meteorite Hills 01070) were studied petrographically and by electron microprobe. The results indicate that carbonate formation in CM chondrites differs from that in CI chondrites and is more complex than previously recognized. Our studies of CM chondrites indicate that (1) carbonates formed on the parent asteroid in an aqueous environment that gradually changed in composition, (2) at some stage, Ca and Mg activities in the environment were high enough to form metastable dolomite, and (3) dolomites disappeared in the most aqueously altered CM chondrites.  相似文献   

5.
The detection and identification of carbonates on Mars are of prime importance to establish the evolution of its atmosphere, correlated to the history of the liquid water, or even to determine the existence of a possible ancient biological activity. Till date, no large deposits of carbonates have been found. In fact, their detection is specific to local areas and in very low amounts. The absence of such deposits is commonly attributed to the harsh environmental conditions at the surface of Mars. Additionally, the presence of UV radiation has been proposed to explain their photodecomposition and hence their absence. However, contradictory results from laboratory experiments mimicking Mars’ surface UV radiation did not resolve the behaviour of carbonates in such an environment, which is why we exposed, in low Earth orbit and in laboratory experiments, both abiotic and biotic calcium carbonates to UV radiation of wavelength above 200 nm, the same spectral distribution as the one reaching the surface of Mars. For low Earth orbit (LEO) exposure, this was done for the UVolution experiment on board the BIOPAN ESA module, which was set outside a Russian Foton automated capsule, and exposed to space conditions for 12 days in September 2007. The targeted carbonates are biominerals and abiotic samples. Our laboratory results mainly show that the exposed carbonates appear to be stable to UV radiation if directly exposed to it. The LEO experiment results tend to the same conclusion, but the integrated exposition time to Solar UV during the experiment is not sufficient to be conclusive. However, the stability of the biominerals derived from the laboratory experiment could strengthen the interest to explore deeper their potential as life records at Mars. Hence, they should be considered as primary targets for in situ analyses during future missions.  相似文献   

6.
We simulated entrainment of carbonates (calcite, dolomite) in silicate impact melts by 1-bar laser melting of silicate–carbonate composite targets, using sandstone, basalt, calcite marble, limestone, dolomite marble, and iron meteorite as starting materials. We demonstrate that carbonate assimilation by silicate melts of variable composition is extremely fast (seconds to minutes), resulting in contamination of silicate melts with carbonate-derived CaO and MgO and release of CO2 at the silicate melt–carbonate interface. We identify several processes, i.e., (1) decomposition of carbonates releases CO2 and produces residual oxides (CaO, MgO); (2) incorporation of residual oxides from proximally dissociating carbonates into silicate melts; (3) rapid back-reactions between residual CaO and CO2 produce idiomorphic calcite crystallites and porous carbonate quench products; (4) high-temperature reactions between Ca-contaminated silicate melts and carbonates yield typical skarn minerals and residual oxide melts; (5) mixing and mingling between Ca- or Ca,Mg-contaminated and Ca- or Ca,Mg-normal silicate melts; (6) precipitation of Ca- or Ca,Mg-rich silicates from contaminated silicate melts upon quenching. Our experiments reproduce many textural and compositional features of typical impact melts originating from silicate–carbonate targets. They reinforce hypotheses that thermal decomposition of carbonates, rapid back-reactions between decomposition products, and incorporation of residual oxides into silicate impact melts are prevailing processes during impact melting of mixed silicate–carbonate targets. However, by comparing our results with previous studies and thermodynamic considerations on the phase diagrams of calcite and quartz, we envisage that carbonate impact melts are readily produced during adiabatic decompression from high shock pressure, but subsequently decompose due to heat influx from coexisting silicate impact melts or hot breccia components. Under certain circumstances, postshock conditions may favor production and conservation of carbonate impact melts. We conclude that the response of mixed carbonate–silicate targets to impact might involve melting and decomposition of carbonates, the dominant response being governed by a complex variety of factors.  相似文献   

7.
Abstract— The matrix of the CM2 carbonaceous chondrite Murray contains rare micrometer‐sized prismatic crystals of aragonite that formed during late‐stage parent body aqueous alteration. The aragonite was identified by X‐ray microanalysis coupled with electron backscatter diffraction (EBSD), TEM selected area electron diffraction and cathodoluminescence spectroscopy. The sixteen crystals found all occur within loose and elongate submillimeter‐sized clusters and one cluster is present in each of the two thin sections studied. Orientation determinations using EBSD show that the c axes of aragonite crystals within each cluster lie roughly in a plane, itself aligned approximately parallel to the long axis of the host cluster. Aragonite is inferred to have crystallized after calcite but before completion of static/impact‐related compaction. The clusters developed by growth of aragonite within films of aqueous fluids that had a relatively high Mg/Ca ratio. These fluids were focused within zones of high porosity and permeability along a weak compactional fabric in the matrix and this fabric is also likely to have influenced the orientations of aragonite crystals as they grew. These results suggest that aragonite probably occurs in most of those carbonaceous chondrites that have undergone moderate degrees of parent body aqueous alteration and may provide further insights into the evolution of pore fluid compositions and volumes and the chronology of asteroidal evolution.  相似文献   

8.
A study of pure, single crystal calcite shocked to pressures from 9.0 to 60.8 GPa was conducted to address contradictory data for carbonate shock behavior. The recovered materials were analyzed optically and by transmission electron microscopy (TEM), as well as by thermogravimetry (TGA), X‐ray diffraction (XRD), and Raman‐spectroscopy. In thin section, progressive comminution of calcite is observed although grains remain birefringent to at least 60.8 GPa. TGA analysis reveals a positive correlation between percent of mass loss due to shock and increasing shock pressure (R = 0.77) and suggests that shock loading leads to the modest removal of structural volatiles in this pressure range. XRD patterns of shocked Iceland spar samples produce peaks that are qualitatively and quantitatively less intense, more diffuse, and shift to lower o2θ. However, the regularity observed in these shocked powder patterns suggests that structures with very uniform unit cell separations persist to shock pressures as high as 60.8 GPa. Raman spectral analyses indicate no band asymmetry and no systematic peak shifting or broadening. TEM micrographs display progressively diminishing crystallite domain sizes. Selected area electron diffraction (SAED) patterns reveal no signatures of amorphous material. These data show that essentially intact calcite is recovered at shock pressures up to 60.8 GPa with only slight mass loss (~7%). This work suggests that the amount of CO2 gas derived from shock devolatilization of carbonate by large meteorite impacts into carbonate targets has been (substantially) overestimated.  相似文献   

9.
Abstract— We report a comprehensive imaging study including confocal microRaman spectroscopy, scanning electron microscopy (SEM), and 3‐D extended focal imaging light microscopy of carbonate globules throughout a depth profile of the Martian meteorite Allan Hills (ALH) 84001 and similar objects in mantle peridotite xenoliths from the Bockfjorden volcanic complex (BVC), Svalbard. Carbonate and iron oxide zoning in ALH 84001 is similar to that seen in BVC globules. Hematite appears to be present in all ALH 84001 carbonate‐bearing assemblages except within a magnesite outer rim found in some globules. Macromolecular carbon (MMC) was found in intimate association with magnetite in both ALH 84001 and BVC carbonates. The MMC synthesis mechanism appears similar to established reactions within the Fe‐C‐O system. By inference to a terrestrial analogue of mantle origin (BVC), these results appear to represent the first measurements of the products of an abiotic MMC synthesis mechanism in Martian samples. Furthermore, the ubiquitous but heterogeneous distribution of hematite throughout carbonate globules in ALH 84001 may be partly responsible for some of the wide range in measured oxygen isotopes reported in previous studies. Using BVC carbonates as a suitable analogue, we postulate that a low temperature hydrothermal model of ALH 84001 globule formation is most likely, although alteration (decarbonation) of a subset of globules possibly occurred during a later impact event.  相似文献   

10.
Carbonates from the impact melt-bearing breccia in the 2016 IODP/ICDP Expedition 364 drill core at Site M0077 were systematically documented and characterized petrographically and geochemically. Calcite, the only carbonate mineral present, is abundant throughout this deposit as five distinct varieties: (1) subangular carbonate clasts (Type A); (2) subround/irregular carbonate clasts with clay altered rims (Type B); (3) fine-crystalline matrix calcite (Type C); (4) void-filling sparry calcite (Type D); and (5) microcrystalline carbonate with flow textures (Type E). Quantitative geochemical analysis shows that calcite in all carbonate varieties are low in elemental impurities (<2.0 cumulative wt% on average); however, relative concentrations of MgO and MnO vary, which provides distinction between each variety: MgO is highest in calcite from Types A, B, and C carbonates (0.2–0.8 wt% on average); MnO is highest in calcite from Types B, C, and D carbonates (0.2–1.3 wt% on average); and calcite from Type E carbonate is most pure (<0.1 wt% on average MgO and MnO, cumulatively). Based on textural and geochemical variations between carbonate types, we interpret that some of the carbonate target rocks melted during impact and were immiscible within the silicate-dominated melt sheet prior to the resurgence of seawater. Type B clasts were formed by molten fuel–coolant interaction, as the incoming seawater eroded through the melt sheet and encountered carbonate melt (Type E). Post-impact meteoric-dominated hydrothermal activity produced the Mn-elevated calcite from Type C and D carbonates, and altered the Type B clasts to be elevated in Mn and host a clay-rich rim.  相似文献   

11.
To assess whether life existed on Mars, it is crucial to identify geochemical biosignatures that are relevant to specific Martian environments. In this paper, thermochemical modeling was used to investigate fluid chemistries and secondary minerals that would have evolved biotically over geological time scales in Martian fluvio-lacustrine and evaporitic settings, and that could be used as potential inorganic biosignatures for life detection on Mars. Modeling was performed using fluid and rock chemistries relevant to Gale crater aqueous environments. Potential inorganic biosignatures were identified investigating alteration deposits found at the surface of a simulant exposed to short-term bio-mediated weathering and comparing experimental and modeling results. In a fluvio-lacustrine setting (water/rock of 2000–278), models suggest that less complex mineral assemblages form during biotic basalt dissolution and subsequent brine evaporation compared to what would happen in an abiotic system. Mainly nontronite, kaolinite, and quartz form under biotic conditions, whereas celadonite, talc, and goethite would also precipitate abiotically. Quartz, sepiolite, and gypsum would precipitate from the evaporation of fluids evolved biotically, whereas nontronite, talc, zeolite, and gypsum would form in an abiotic evaporitic environment. These results could be used to distinguish products of abiotic and biotic processes, aiding the interpretation of data from Mars exploration missions.  相似文献   

12.
Spectroscopic studies of Mars analog materials combining multiple spectral ranges and techniques are necessary in order to obtain ground truth information for interpretation of rocks and soils on Mars. Two hydrothermal rocks from Yellowstone National Park, Wyoming, were characterized here because they contain minerals requiring water for formation and they provide a possible niche for some of the earliest organisms on Earth. If related rocks formed in hydrothermal sites on Mars, identification of these would be important for understanding the geology of the planet and potential habitability for life. XRD, thermal properties, VNIR, mid-IR, and Raman spectroscopy were employed to identify the mineralogy of the samples in this study. The rocks studied here include a travertine from Mammoth Formation that contains primarily calcite with some aragonite and gypsum and a siliceous sinter from Octopus Spring that contains a variety of poorly crystalline to amorphous silicate minerals. Calcite was detected readily in the travertine rock using any one of the techniques studied. The small amount of gypsum was uniquely identified using XRD, VNIR, and mid-IR, while the aragonite was uniquely identified using XRD and Raman. The siliceous sinter sample was more difficult to characterize using each of these techniques and a combination of all techniques was more useful than any single technique. Although XRD is the historical standard for mineral identification, it presents some challenges for remote investigations. Thermal properties are most useful for minerals with discrete thermal transitions. Raman spectroscopy is most effective for detecting polarized species such as CO3, OH, and CH, and exhibits sharp bands for most highly crystalline minerals when abundant. Mid-IR spectroscopy is most useful in characterizing Si-O (and metal-O) bonds and also has the advantage that remote information about sample texture (e.g., particle size) can be determined. Mid-IR spectroscopy is also sensitive to structural OH, CO3, and SO4 bonds when abundant. VNIR spectroscopy is best for characterizing metal excitational bands and water, and is also a good technique for identification of structural OH, CO3, SO4, or CH bonds. Combining multiple techniques provides the most comprehensive information about mineralogy because of the different selection rules and particle size sensitivities, in addition to maximum coverage of excitational and vibrational bands at all wavelengths. This study of hydrothermal rocks from Yellowstone provides insights on how to combine information from multiple instruments to identify mineralogy and hence evidence of water on Mars.  相似文献   

13.
We examine the applicability of Principal Component Analysis (PCA) and Artificial Neural Network (ANN) methods of data analysis to biosignature detection. These techniques show promise in classifying and simplifying the representation of patterns of amino acids resulting from biological and non-biological syntheses. PCA correctly identifies glycine and alanine as the amino acids contributing the most information to the task of discriminating biotic and abiotic samples. Trained ANNs correctly classify between 86.1 and 99.5% of a large set of amino acid samples as biotic or abiotic. These and similar techniques are important in the design of automated data analysis systems for robotic missions to distant planetary bodies. Both techniques are robust with respect to noisy and incomplete data. Analysis of the performance of PCA and ANNs also lends insight into the localization of useful information within a particular data set, a feature that may be exploited in the selection of experiments for efficient mission design.  相似文献   

14.
We shocked calcite in an unconfined environment by launching small marble cylinders at 0.8–5.5 km s?1 into aluminum or copper plates, producing shock stresses between 5 and 79 GPa. The resulting 5–20 mm craters contained intimately mixed clastic and molten projectile residues over the entire pressure range, with melting commencing already at 5 GPa. Stoichiometrically pure calcite melts were not observed as all melts contained target metal. Some of these residues were distinctly depleted in CO2 and some contained even tiny CaO crystals, thus illustrating partial to complete loss of CO2. We interpret a thin seam of finely crystalline calcite to be the product of back reactions between CaO and CO2. The amount of carbonate residue in these craters, especially those at low velocities (<2 km s?1), is dramatically less than that of silicate impactors in similar cratering experiments, and we suggest that this is due to substantial outgassing of CO2. Similarly, the volume of carbonate melts relative to the volume of limestone or dolomite in many terrestrial crater structures seems insignificant as well, as is the volume of carbonate melt compared to the volume of impact melts derived from silicates. These volume considerations suggest that volatilization of CO2 is the dominant process in carbonate‐containing targets. Because we have difficulties in explaining naturally occurring calcite melts by shock processes in dolomite‐dominated targets, we speculate—essentially via process of elimination—that such carbonate melt blebs might be condensation products from an impact‐produced vapor cloud.  相似文献   

15.
Abstract— Studies of two separate stones of the CV3 chondrite Vigarano have revealed the presence of previously unreported occurrences of calcite. In the first stone, calcite occurs as thin veins in a type B CAI. In contrast, observations of the second stone, which was recovered one month after its fall, show three calcite occurrences: networks of veins, vesicle fillings in the fusion crust, and pseudomorphic replacement of augite associated with a porphyritic olivine chondrule. The most common occurrence is as veins ranging in thickness from <1 μm to 25 μm and extending for more than several hundred μm. Some veins crosscut the fusion crust and are connected to a carbonate coating on the exterior of the meteorite. Extensive minor element zoning occurs in carbonate masses, indicating variations in the fluid composition and/or redox potential during carbonate growth. Based on the textural evidence and a comparative study with carbonate veins in the CV3 chondrite Leoville, we conclude that the veins are terrestrial in origin. We propose a model for rapid carbonate formation in which calcite precipitation is driven by hydrolysis and oxidation in the meteorite interior that move the fluid composition to alkaline values. In addition, both stones also contain minor occurrences of carbonate that are not readily explained by terrestrial alteration. Minor carbonate in a type B CAI occurs in the first stone and calcite occurs as pseudomorphic replacement of augite in the second stone. Both of these occurrences appear to be preterrestrial, probably asteroidal in origin.  相似文献   

16.
Assuming steady state of carbon dioxide levels in a “pressure-cooker” atmosphere/ocean system (10–20 bars, near 100°C) produced by a land weathering sink and volcanic source (BLAG model), an abiotic Earth model for 3.8 Ga requires present biotic enhancements of weathering to be on the order of 100 or greater, consistent with the limit inferred from experimental and field studies. Using a plausible ratio of the present biotic enhancement (from higher plants) to enhancements produced by microbial activity alone, along with models for continental growth and outgassing rates consistent with geologic evidence, we find that computed surface temperatures hover near 20°C over geologic time, slowly decreasing to present, after a rapid initial decline as a result of microbial colonization of land. Results are consistent with the first possibility for glaciation in the late Archean/early Proterozoic. Useful modeling of climatic evolution, taking into account biotic enhancement of weathering, can now apparently be extended into the Precambrian, assuming operation of the carbonate-silicate buffer.  相似文献   

17.
Mechanisms affecting the heat and carbon content of the Glacial Tropical Ocean (21,000 years BP) remain controversial. Exchange with the deep ocean via vertical mixing and the overturning circulation is one aspect that is clearly relevant to greenhouse gas concentrations and future climate change. We examined evidence of the possible role of the shallow overturning contribution on the Glacial Tropical Ocean temperature and carbonate ion concentration. Compared to the present, we find that the Glacial tropical upper ocean (0–1000 m) had enhanced vertical gradients in temperature and carbonate ion concentration, reduced turbulent diffusivity (vertical mixing rate) (by 20% or more), and weakened Ekman pumping in middle-latitudes, all consistent with reduced shallow overturning. The weakened property exchanges between the tropical upper ocean and the ocean below (cold with high total dissolved carbon-dioxide concentration) provide a unified explanation for both the unexpectedly-small sea surface cooling and the lower carbon-dioxide content in the Glacial tropical upper ocean and the atmosphere.  相似文献   

18.
Comet 81P/Wild 2 samples returned by NASA's Stardust mission provide an unequalled opportunity to study the contents of, and hence conditions and processes operating on, comets. They can potentially validate contentious interpretations of cometary infrared spectra and in situ mass spectrometry data: specifically the identification of phyllosilicates and carbonates. However, Wild 2 dust was collected via impact into capture media at ~6 km s?1, leading to uncertainty as to whether these minerals were captured intact, and, if subjected to alteration, whether they remain recognizable. We simulated Stardust Al foil capture conditions using a two‐stage light‐gas gun, and directly compared transmission electron microscope analyses of pre‐ and postimpact samples to investigate survivability of lizardite and cronstedtite (phyllosilicates) and calcite (carbonate). We find the phyllosilicates do not survive impact as intact crystalline materials but as moderately to highly vesiculated amorphous residues lining resultant impact craters, whose bulk cation to Si ratios remain close to that of the impacting grain. Closer inspection reveals variation in these elements on a submicron scale, where impact‐induced melting accompanied by reducing conditions (due to the production of oxygen scavenging molten Al from the target foils) has resulted in the production of native silicon and Fe‐ and Fe‐Si‐rich phases. In contrast, large areas of crystalline calcite are preserved within the calcite residue, with smaller regions of vesiculated, Al‐bearing calcic glass. Unambiguous identification of calcite impactors on Stardust Al foil is therefore possible, while phyllosilicate impactors may be inferred from vesiculated residues with appropriate bulk cation to Si ratios. Finally, we demonstrate that the characteristic textures and elemental distributions identifying phyllosilicates and carbonates by transmission electron microscopy can also be observed by state‐of‐the‐art scanning electron microscopy providing rapid, nondestructive initial mineral identifications in Stardust residues.  相似文献   

19.
Abstract— Previous X‐ray powder diffraction (XRD) studies revealed that shock deformed carbonates and quartz have broader XRD patterns than those of unshocked samples. Entire XRD patterns, single peak profiles and Rietveld refined parameters of carbonate samples from the Sierra Madera impact crater, west Texas, unshocked equivalent samples from 95 miles north of the crater and the Mission Canyon Formation of southwest Montana and western Wyoming were used to evaluate the use of X‐ray powder diffraction as a potential tool for distinguishing impact deformed rocks from unshocked and tectonically deformed rocks. At Sierra Madera dolostone and limestone samples were collected from the crater rim (lower shock intensity) and the central uplift (higher shock intensity). Unshocked equivalent dolostone samples were collected from well cores drilled outside of the impact crater. Carbonate rocks of the Mission Canyon Formation were sampled along a transect across the tectonic front of the Sevier and Laramide orogenic belts. Whereas calcite subjected to significant shock intensities at the Sierra Madera impact crater can be differentiated from tectonically deformed calcite from the Mission Canyon Formation using Rietveld refined peak profiles, weakly shocked calcite from the crater rim appears to be indistinguishable from the tectonically deformed calcite. In contrast, Rietveld analysis readily distinguishes shocked Sierra Madera dolomite from unshocked equivalent dolostone samples from outside the crater and tectonically deformed Mission Canyon Formation dolomite.  相似文献   

20.
Reflectance spectroscopy in the infrared is a powerful tool to characterise the optical properties of analogue materials for Mars. In this work we present laboratory studies of four Martian analogues: calcite, montmordlonite, palagonite and andesite. Diffuse and specular reflectance and transmittance spectra in the IR are shown. The spectral effect produced by small grains clung to the larger ones is analysed for calcite. Significant variations in the diffuse reflectance spectrum, especially in the reststrahlen region, are observed. The diffuse reflectance spectra of the other materials show the shift of the reststrahlen features with Si content in the materials. Optical constants of andesite are retrieved, by using the Lorentz model, from the specular reflectance spectrum. These values are fundamental in performing modelling of the radiance coming from the planet Mars.  相似文献   

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