Experimental simulation of Titan's atmosphere: Detection of ammonia and ethylene oxide     

J. -M. Bernard  P. Coll  A. Coustenis  F. Raulin 《Planetary and Space Science》2003,51(14-15):1003

For several years now, an experimental simulation of Titan's atmosphere has been on going at LISA. A cold plasma is established in a gas mixture representative of the atmosphere of the satellite. In these experiments, more than 70 organic compounds have been identified, including the first identification in this type of experimental simulation of C₄N₂ already detected in its solid form on Titan, which suggests that the setup correctly mimics the chemistry of Titan's atmosphere.We have carried out the first experimental simulation including O-containing compounds in order to study the influence of the presence of CO on the chemical behavior of Titan's atmosphere. With the help of gas chromatography–mass spectrometry (GC–MS) and infrared spectroscopy (IRS) we can thus determine which minor species still undetected in Titan's atmosphere are likely to be present and understand the complex chemistry of the atmosphere of this satellite. Surprisingly we have identified unpredicted O-containing gaseous compounds, mainly ethylene oxide (also named oxirane, C₂H₄O). This molecule has been observed in the interstellar medium by observation in the millimeter region (Astrophys. J. 489 (1997) 553; Astron. Astrophys. 337 (1998) 275). On the contrary, the predicted O-compounds (formaldehyde and methanol) have not been identified in this experiment. Furthermore, we have identified NH₃ in the gaseous products with an initial mixture of N₂ (98%) and CH₄ (2%).The paper describes the experimental device used in this work, in particular the IRS and GC–MS techniques. We also comment the results related to the detection of the O-containing compounds and NH₃ and their implications on our knowledge of the chemistry of Titan's atmosphere and on the retrieval of the future Titan data expected from Cassini-Huygens.  相似文献   

The Grand Brûlé exploration drilling: New data on the deep framework of the Piton de la Fournaise volcano. Part 2: Secondary minerals     

Patrice Lerebour  J.Philippe Ranon  Thierry Aug 《Journal of Volcanology and Geothermal Research》1989,36(1-3)

The Grand Brûlé borehole intersects a thick pile of basaltic lavas, down to 1010 m, and a basic-ultrabasic intrusive complex, from 1010 to 3003.50 m.The lavas are, in general, unaltered except in two fractured zones, where hydrothermal fluids circulated at temperatures not exceeding 350 ° C. The main secondary minerals there are pyroxene, feldspar, epidote, actinolite and chlorite.The entire thickness of the intrusive body intersected contains secondary minerals representing three stages of cooling:

1. 1. A late magmatic episode (600–900°C) characterized by biotite, kaersutite, edenite and pargasite.

2. 2. A hydrothermal episode (T<- 350°C) characterized by epidote, albite, biotite, actinolite and chlorite.

3. 3. A phase of serpentinization (T≤ 350°C).

It is very likely that the two later events occurred simultaneously, with physical and chemical interference.  相似文献   

ENCORE: the effect of nutrient enrichment on coral reefs. Synthesis of results and conclusions   总被引：10，自引：0，他引：10  

Koop K  Booth D  Broadbent A  Brodie J  Bucher D  Capone D  Coll J  Dennison W  Erdmann M  Harrison P  Hoegh-Guldberg O  Hutchings P  Jones GB  Larkum AW  O'Neil J  Steven A  Tentori E  Ward S  Williamson J  Yellowlees D 《Marine pollution bulletin》2001,42(2):91-120

Coral reef degradation resulting from nutrient enrichment of coastal waters is of increasing global concern. Although effects of nutrients on coral reef organisms have been demonstrated in the laboratory, there is little direct evidence of nutrient effects on coral reef biota in situ. The ENCORE experiment investigated responses of coral reef organisms and processes to controlled additions of dissolved inorganic nitrogen (N) and/or phosphorus (P) on an offshore reef (One Tree Island) at the southern end of the Great Barrier Reef, Australia. A multi-disciplinary team assessed a variety of factors focusing on nutrient dynamics and biotic responses. A controlled and replicated experiment was conducted over two years using twelve small patch reefs ponded at low tide by a coral rim. Treatments included three control reefs (no nutrient addition) and three + N reefs (NH4Cl added), three + P reefs (KH2PO4 added), and three + N + P reefs. Nutrients were added as pulses at each low tide (ca twice per day) by remotely operated units. There were two phases of nutrient additions. During the initial, low-loading phase of the experiment nutrient pulses (mean dose = 11.5 microM NH4+; 2.3 microM PO4(-3)) rapidly declined, reaching near-background levels (mean = 0.9 microM NH4+; 0.5 microM PO4(-3)) within 2-3 h. A variety of biotic processes, assessed over a year during this initial nutrient loading phase, were not significantly affected, with the exception of coral reproduction, which was affected in all nutrient treatments. In Acropora longicyathus and A. aspera, fewer successfully developed embryos were formed, and in A. longicyathus fertilization rates and lipid levels decreased. In the second, high-loading, phase of ENCORE an increased nutrient dosage (mean dose = 36.2 microM NH4+; 5.1 microM PO4(-3)) declining to means of 11.3 microM NH4+ and 2.4 microM PO4(-3) at the end of low tide) was used for a further year, and a variety of significant biotic responses occurred. Encrusting algae incorporated virtually none of the added nutrients. Organisms containing endosymbiotic zooxanthellae (corals and giant clams) assimilated dissolved nutrients rapidly and were responsive to added nutrients. Coral mortality, not detected during the initial low-loading phase, became evident with increased nutrient dosage, particularly in Pocillopora damicornis. Nitrogen additions stunted coral growth, and phosphorus additions had a variable effect. Coral calcification rate and linear extension increased in the presence of added phosphorus but skeletal density was reduced, making corals more susceptible to breakage. Settlement of all coral larvae was reduced in nitrogen treatments, yet settlement of larvae from brooded species was enhanced in phosphorus treatments. Recruitment of stomatopods, benthic crustaceans living in coral rubble, was reduced in nitrogen and nitrogen plus phosphorus treatments. Grazing rates and reproductive effort of various fish species were not affected by the nutrient treatments. Microbial nitrogen transformations in sediments were responsive to nutrient loading with nitrogen fixation significantly increased in phosphorus treatments and denitrification increased in all treatments to which nitrogen had been added. Rates of bioerosion and grazing showed no significant effects of added nutrients. ENCORE has shown that reef organisms and processes investigated in situ were impacted by elevated nutrients. Impacts were dependent on dose level, whether nitrogen and/or phosphorus were elevated and were often species-specific. The impacts were generally sub-lethal and subtle and the treated reefs at the end of the experiment were visually similar to control reefs. Rapid nutrient uptake indicates that nutrient concentrations alone are not adequate to assess nutrient condition of reefs. Sensitive and quantifiable biological indicators need to be developed for coral reef ecosystems. The potential bioindicators identified in ENCORE should be tested in future research on coral reef/nutrient interactions. Synergistic and cumulative effects of elevated nutrients and other environmental parameters, comparative studies of intact vs. disturbed reefs, offshore vs. inshore reefs, or the ability of a nutrient-stressed reef to respond to natural disturbances require elucidation. An expanded understanding of coral reef responses to anthropogenic impacts is necessary, particularly regarding the subtle, sub-lethal effects detected in the ENCORE studies.  相似文献   

Impact of meteorological data resolution on the forecasted ozone concentrations during the ESCOMPTE IOP2a and IOP2b     

Laurent Menut  Isabelle Coll  Sylvie Cautenet 《Atmospheric Research》2005,74(1-4):139-159

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The impact of the hexos programme     

Stuart D. Smith  Kristina B. Katsaros  Wiebe A. Oost  Patrice G. Mestayer 《Boundary-Layer Meteorology》1996,78(1-2):121-141

In HEXOS, a programme of coordinated laboratory, field and model studies, an international group of participants has extended the range of measurements of evaporation from the sea and has investigated the role of droplets in the transfer of water to the atmosphere. Predictions of a rapid rise in the evaporation coefficient at wind speeds above 15 m s^-1 have not been substantiated. Wind stress measurements showed a relationship with wave age. New methods were developed for coping with flow distortion.  相似文献   

Feature based image processing methods applied to bathymetric measurements from airborne remote sensing in fluvial environments   总被引：1，自引：0，他引：1  

Patrice E. Carbonneau  Stuart N. Lane  Normand Bergeron 《地球表面变化过程与地形》2006,31(11):1413-1423

Bathymetric maps produced from remotely sensed imagery are increasingly common. However, when this method is applied to fluvial environments, changing scenes and illumination variations severely hinder the application of well established empirical calibration methods used to obtain predictive depth–colour relationships. In this paper, illumination variations are corrected with feature based image processing, which is used to identify areas in an image with a near‐zero water depth. This information can then be included in the depth–colour calibration process, which results in an improved prediction quality. The end product is an automated bathymetric mapping method capable of a 4 m² spatial resolution with a precision of ±15 cm, which allows for a more widespread application of bathymetric mapping. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

The Cap Roux MPA (Saint-Raphael, French Mediterranean): changes in fish assemblages within four years of protection     

Seytre  Catherine; Francour  Patrice 《ICES Journal of Marine Science》2009,66(1):180-187

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Comparative studies on compounds occluded inside asphaltenes hierarchically released by increasing amounts of H₂O₂/CH₃COOH     

Jing Zhao  Zewen Liao  Lühui Zhang  Patrice Creux  Chupeng Yang  Anna Chrostowska  Haizu Zhang  Alain Graciaa 《Applied Geochemistry》2010

Being the heaviest fraction of crude oils, asphaltenes are liable to aggregate, and other molecules in the oils can be steadily adsorbed onto, and even occluded inside the macromolecular structures of the asphaltenes. These occluded compounds inside the asphaltenes can survive over geological time in oil reservoirs owing to effective protection by the macromolecular structures of the asphaltenes. The asphaltenes of a crude oil (ZG31) from the central Tarim Basin, NW China, were hierarchically degraded by increasing the amount of H₂O₂/CH₃COOH to release the occluded compounds. Besides the common components, series of even numbered n-alk-1-enes and 3-ethylalkanes were detected among the occluded compounds. Comparison of the biomarker distributions and the compound-specific C isotopic results between the compounds from the maltenes and those from the occluded fraction, the ZG31 reservoir was suggested to have been charged multiple times, with different charges being derived from different strata of source rocks.  相似文献   

Preliminary investigation of the surficial sediments in the Cap-Breton Canyon (southwest France) and the surrounding continental shelf     

George P. Allen  Patrice Castaing  Andre Klingebiel 《Marine Geology》1971,10(5):M27-M32

A total of 120 grab samples of the surficial sediments in the Cap-Breton submarine canyon and surrounding continental shelf were collected and analyzed by grain-size sieving. A Q-mode Factor Analysis was made on the grain-size data in order to define the most meaningful facies types. Four distinct lithological facies were found to exist: silt and clay, very fine sand, fine sand, and coarse sand. Comparison with previous work and a ¹⁴C date on the silt and clay facies showed that the facies are not contemporaneous. The sands and coarse sands on the shelf were emplaced during the pre-Würm and Würm regressions, and later probably reworked during the Holocene (Flandrian) transgression. The silty clays found in the canyon and on the shelf to the south are younger and represent sediments brought in as suspended load by the Adour and other nearby rivers during the Holocene (Flandrian) transgression.  相似文献   

Rotating thermal flows in natural and industrial processes     

Patrice Le Gal  Michael Le Bars 《地球物理与天体物理流体动力学》2013,107(6):720-723

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