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碳质气溶胶的放射性碳同位素(~(14)C)源解析:原理、方法和研究进展 总被引：2，自引：0，他引：2
碳质气溶胶(或颗粒物)作为大气气溶胶的重要组成,对环境、气候和人类健康造成了巨大的危害。其主要组成成分有机碳和元素碳具有不同的来源特征,且对人类健康和气候系统的影响也具有明显的差异。放射性碳同位素(14C)不仅能定性区分生物源和化石源,还能定量分析不同来源对有机碳和元素碳的贡献比率。重点评述了放射性碳同位素法对气溶胶源解析的技术原理、分离测试方法以及在我国应用的研究进展;最后提出了国内研究应加强的领域和利用放射性碳同位素法研究大气气溶胶的发展趋势。 相似文献
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鄂尔多斯自流盆地地下水来源争议问题讨论 总被引：12，自引：0，他引：12
本文讨论了鄂尔多斯自流盆地地下水来源存在争议的两种学术观点,指出了前人关于鄂尔多斯地下水补给、径流、排泄模型所存在的问题:①在四水转化过程中缺少了最重要的研究内容——土壤水的运动,通过概念模型得到的地下水循环模型不能解释地下水分水岭与基底断裂带重合的事实.②部分学者在进行地球化学反向模拟的的研究中,没有对白云石、方解石中的同位素进行对比分析,碳同位素不支持模拟分析结果.③采用14C测定地下水年龄中受到深部CO2的干扰,在中国北方地区不适合采用14C测定地下水的年龄.笔者等通过黄土剖面土壤水中的氘—氧同位素与Cl-分布特征,指出鄂尔多斯盆地的降水非但不能补给到地下水中,而且土壤水的主要来源是地下水.鄂尔多斯自流盆地的主要补给源是外源水,深大断裂带是导水的主要通道. 相似文献
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《地球科学进展》2017,(11)
自Eglinton等(1996)首次将单体放射性碳同位素分析技术(CSRA)应用于海洋沉积物中生物标志物14C研究以来,该技术发展迅速,广泛应用于海洋科学、生物地球化学和古气候学等领域。但是,自然环境样品中生物标志物大多含量低、干扰基质复杂而且难以分离。因此,如何从基质组成复杂的样品中分离富集高纯度的目标化合物已经成为限制CSRA技术发展和应用的瓶颈。近些年来,不断改进的色谱分离富集技术不仅提高了目标化合物分离的纯度和回收效率,同时也扩展了生物标志物的碳同位素示踪应用。综合介绍了自然环境研究中单体化合物放射性碳同位素分析技术中常见生物标志物单体分离纯化的技术方法以及发展现状。 相似文献
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北羌塘盆地中侏罗统夏里组蒸发岩锶同位素地球化学特征及物质来源 总被引：1，自引：1，他引：0
北羌塘盆地位于青藏高原的中部,属东特提斯构造域,是一个具有成盐远景的蒸发岩盆地.前人对盆地的研究多局限于层序地层、构造运动、油气成藏等,对于盆地内蒸发岩的研究,特别是其成矿流体来源的研究报道较少.文章通过对北羌塘盆地龙尾湖QY-1钻孔中硬石膏岩层锶同位素进行测定,首次对盆地中侏罗统夏里组蒸发岩成矿流体的来源进行探讨.结果表明,笔者所分析的样品的锶同位素比值变化范围为0.707475～0.709048,均值0.708331,与同时期全球海水锶同位素比值(0.706860～0.707081)相比略高,表明成矿流体来源主要是海水.结合前人对羌塘盆地构造运动与盆地演化的认识,认为陆源锶的输入造成了本区的锶同位素比值高于同期海水.此外,钻孔中的同位素组成与前人公布的全球中侏罗世(164～160.2 Ma)海水锶同位素曲线具有较好的对比性,中晚侏罗世羌塘盆地海侵海退作用的强弱是控制盆地夏里组锶同位素演化的主要因素. 相似文献
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《矿物岩石地球化学通报》2019,(6)
大气细颗粒物(PM_(2.5))对气候变化和人体健康具有重要影响。PM_(2.5)中的元素碳(EC)在大气中不发生反应,所以其来源变化可以指示PM_(2.5)一次燃烧源的变化。本文结合放射性碳同位素(~(14)C)和稳定碳同位素(~(13)C)方法,分析了西安2008/2009年和2015/2016年冬季PM_(2.5)中EC的同位素组成。~(14)C的分析结果表明,西安冬季EC的主要来源为化石燃料燃烧,2008/2009年和2015/2016年化石燃料燃烧对EC的贡献分别为77%±4%和72%±5%。~(13)C的分析结果表明,2015/2016年西安冬季EC排放源主要来自液体化石燃料燃烧(机动车排放)(δ~(13)C_(EC):-25.04‰～-24.64‰,-24.80‰±0.21‰),而2008/2009年冬季燃煤对EC的贡献更为显著(δ~(13)C_(EC):-23.72‰～-22.81‰,-23.22‰±0.39‰)。对比~(14)C和~(13)C的数据发现,近十年西安冬季EC排放源的变化显著,燃煤的相对贡献降低,而机动车排放的贡献升高,这与煤改气和机动车保有量的急速增加有关。 相似文献
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Black carbon (BC) is the combustion-altered, solid residue remaining after biomass burning and fossil fuel combustion. Radiocarbon measurements of BC provide information on the residence time of BC in organic carbon pools like soils and sediments, and also provide information on the source of BC by distinguishing between fossil fuel and biomass combustion byproducts. We have optimized dichromate-sulfuric acid oxidation for the measurement of radiocarbon in BC. We also present comparisons of BC 14C measurements on NIST aerosol SRM 1649a with previously published bulk aromatic 14C measurements and individual polycyclic aromatic hydrocarbon (PAH) 14C measurements on the same NIST standard.Dichromate-sulfuric acid oxidation belongs to the chemical class of BC measurement methods, which rely on the resistance of some forms of BC to strong chemical oxidants. Dilute solutions of dichromate-sulfuric acid degrade BC and marine-derived carbon at characteristic rates from which a simple kinetic formula can be used to calculate concentrations of individual components (Wolbach and Anders, 1989). We show that: (1) dichromate-sulfuric acid oxidation allows precise, reproducible 14C BC measurements; (2) kinetics calculations give more precise BC yield information when performed on a % OC basis (vs. a % mass basis); (3) kinetically calculated BC concentrations are similar regardless of whether the oxidation is performed at 23°C or 50°C; and (4) this method yields 14C BC results consistent with previously published aromatic 14C data for an NIST standard.For the purposes of intercomparison, we report % mass and carbon results for two commercially available BC standards. We also report comparative data from a new thermal method applied to SRM 1649a, showing that thermal oxidation of this material also follows the simple kinetic sum of exponentials model, although with different time constants. 相似文献
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Radiocarbon Dating of Soil Organic Matter 总被引：2，自引：0，他引：2
Radiocarbon ages of soil organic matter are evaluated with a model which incorporates the dynamics of the14C content of soil organic matter. Measured14C ages of soil organic matter or its fractions are always younger than the true ages of soils due to continuous input of organic matter into soils. Differences in soil C dynamics due to climate or soil depth will result in significantly different14C signatures of soil organic matter for soils of the same age. As a result, the deviation of the measured14C age from the true age of soil formation could differ significantly among different soils or soil horizons. Our model calculations also suggest that14C ages of soil organic matter will eventually reach a steady state provided that no climatic or ecological perturbations occur. Once a soil or a soil horizon has reached a steady state,14C dating of soil organic matter will provide no useful information regarding the age of the soil. However, for soils in which steady state has not been reached, it is possible to estimate the age of soil formation by modeling the measured14C contents of soil organic matter. Radiocarbon dating of buried soils could, in general, overestimate the true age of the burial by as much as the steady-state age of the soil or soil horizon. 相似文献
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The accuracy of Arctic lake chronologies has been assessed by measuring the14C activities of modern carbon sources and applying these isotopic mass balances to dating fossil lake materials. Small (<1 km2) shallow (<25 m) Arctic lakes with watersheds <12 km2have soil and peat stratigraphic sections with14C activities ranging from 98 to 51% Modern. The14C activity of particulate organic carbon, dissolved organic carbon, and dissolved inorganic carbon from lake and stream waters ranges from 121 to 95% Modern. The sediment–water interface of the studied lakes shows consistent14C ages of ∼100014C yr, although the14C activity of living aquatic vegetation is 115% Modern. Radiocarbon measurements of components of the lacustrine carbon pool imply that the ∼100014C yr age of the sediment–water interface results from deposition of14C-depleted organic matter derived from the watershed. 相似文献
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《Quaternary Science Reviews》2003,22(10-13):1077-1084
This study is part of a multidisciplinary project dealing with the investigation of geoarchaeological sites on the Egyptian Plateau. With the aim of reconstructing the palaeoecological background, providing age assessment which put the various results in an age frame that is of special interest. Here, results of one particular section have been selected because of a discrepancy in age determination based on different approaches. Radiocarbon ages were inconsistent with the age range provided by the archaeological context in this area. The underestimation observed is inferred to be caused by poor 14C-sample quality. An attempt to overcome this problem was the determination of the depositional ages of the non-organic sediments by using optically stimulated luminescence (OSL). Equivalent doses of four sediment samples were estimated from OSL measurements carried out on sand-sized quartz grains using the single-aliquot regenerative-dose (SAR) protocol. Dose rates were calculated from neutron activation analysis results. From the OSL ages obtained, we conclude that the sediment sequence exposing an alternation of lacustrine and eolian layers was deposited in a short period of time during the mid-Holocene (mean of OSL ages ∼7.8 ka). Compared to the 14C ages, the luminescence ages fit better into the archaeological context confirmed by surface dating. 相似文献
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《Quaternary Science Reviews》2004,23(3-4):261-281
The organic carbon content of marine sediments is commonly used as a proxy for export production. However, in continental margin sediments a large fraction of the organic matter may be of terrestrial origin, and it is necessary to correct the total organic carbon data accordingly. Radiocarbon dating of bulk organic carbon, organic geochemistry and isotope data (δ13C and δ15N) are used here to characterize the type of organic matter present in Core JT96-09 collected at a water depth of 920 m on the slope off Western Canada. The quantities of marine and terrestrial organic carbon are then estimated using the δ13C data. The 16 kyr record obtained from Core JT96-09 suggests that accumulation of total organic carbon was highest during the late glacial and deglacial, but geochemical data indicate that as much as 70% of this carbon is terrestrial in origin. When the palaeo-record is corrected for this terrigenous input it is observed that accumulation of marine organic matter, and presumably marine export production, increased at the end of the last glacial contemporaneous with the Bølling, and that it peaked during the Allerød. Data from other palaeoproductivity proxies (i.e., bio-barium, opal and alkenones) also indicate relatively high productivity during the deglacial. These results indicate a return to modern upwelling conditions and high marine export production at ∼14.3 calendar kyr BP and a period of enhanced upwelling, relative to the present, during the Allerød. 相似文献
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Large old landslides are common in the Three Gorges area. Baota landslide, a large rockslide, is one of the largest landslides
in the Three Gorges area. In the landslide body there are two terraces to be recognized. The two terrace deposits is not a
two-grade terrace, but mainly remnants left by an occurrence of Baota landslide. Optically stimulated luminescence (OSL) dating
suggests that the age of the terrace deposits is 38–32 kyr BP. The OSL ages along with other Thermoluminescence (TL) and Radiocarbon
(14C) ages support the conclusion that the Baota landslide was originally triggered by strong precipitation occurred in a warm
climate period of 30,000–40,000 years BP. 相似文献
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A comparison of uranium-series geochronology and radiocarbon dating, the first systematic test of its kind applied to authigenic marine apatite, has been made for nine seafloor phosphate nodules sampled from the Peruvian and Chilean shelves. Radiocarbon ages agree well with the 230Th ages for all six samples with 230Th ages younger than the practical dating limit of the 14C technique for marine samples. Two of three “old” samples contain no significant 14C activities, as expected. However, one sample with a high concentration of phosphate pellets contains more than 30% of the modern 14C activity. The discrepancy between the 14C and U-series age for this sample is thought to be due to post-depositional adsorption of the particle-reactive elements thorium and protactinium onto pellet surfaces. 相似文献
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Isotopes in pyrogenic carbon: A review 总被引：1，自引：0，他引：1
Pyrogenic carbon (PC; also known as biochar, charcoal, black carbon and soot) derived from natural and anthropogenic burning plays a major, but poorly quantified, role in the global carbon cycle. Isotopes provide a fundamental fingerprint of the source of PC and a powerful tracer of interactions between PC and the environment. Radiocarbon and stable carbon isotope techniques have been widely applied to studies of PC in aerosols, soils, sediments and archaeological sequences, with the use of other isotopes currently less developed. This paper reviews the current state of knowledge regarding (i) techniques for isolating PC for isotope analysis and (ii) processes controlling the carbon (13C and 14C), nitrogen, oxygen, hydrogen and sulfur isotope composition of PC during formation and after deposition. It also reviews the current and potential future applications of isotope based studies to better understand the role of PC in the modern environment and to the development of records of past environmental change. 相似文献
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The various sources of pyrogenic and coalified carbon (black carbon, BC) in soil have considerable structural heterogeneity, making the quantification of BC a challenge. This study was aimed at evaluating the capability of different detection procedures to recover different types of BC from soil. We added defined quantities of urban dust (UD, NIST SRM1649a), diesel particulate matter (DPM, NIST SRM2975), charcoal, lignite, bituminous coal and wood to four topsoil samples. Mixtures were analyzed by way of chemo-thermal oxidation (CTO), thermal gradient oxidation (ThG), the benzene polycarboxylic acid method (BPCA) and mid-infrared spectroscopy (MIRS). CTO returned good quantification of soot BC in the pure DPM, yet the recovery of soot BC from soil was unsatisfactory (18–270%). ThG gave good precision but lower values for pure soot BC. It severely overestimated the BC content for all soil-standard mixtures. The BPCA method gave a low return for soot BC, but for the spiked soil it reliably detected charcoal and coalified C (69–107% avg. recovery) but underestimated soot BC (52–90% recovery of DPM). Linear coherence in specific MIR vibrations was found in one component soil-BC mixtures for each BC type. Applying these standard calibrations to multi-component mixtures allowed detecting charcoal and a quantification of soot BC (88% avg. recovery) via MIRS, but ignored the presence of diagenetic C. We see the greatest potential in differentiating soot from charcoal in soil by employing a combination of chemical and thermal oxidation and MIRS, while the differentiation from diagenetic C is not possible yet. 相似文献
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QiShun Fan HaiZhou Ma ZhiBang Ma HaiCheng Wei FengQing Han 《Environmental Earth Sciences》2014,71(3):1227-1237
The age framework of Qarhan Salt Lake in arid western China is still controversial due in part to (1) age discrepancy between conventional 14C and 230Th dating results, and (2) no AMS 14C ages of organic carbon from drilling cores in Qarhan Salt Lake were reported until now. In order to discuss these chronological problems, upper 54.50 m lacustrine sediments from a drilling core (ISL1A) recovered from Qarhan Salt Lake were dated based on 230Th and AMS 14C dating techniques. Results show that (1) AMS 14C ages of total organic carbon (TOC) from 4.65 to 30.29 m are almost in stratigraphic order and consistent with 230Th ages of halite in the corresponding layers; (2) AMS 14C ages of TOC from 30.29 to 54.50 m are younger with increasing depth. This phenomenon was also found in Shell Bar in the study area, suggesting that AMS 14C ages from upper 30.29 m are more reliable while those from lower 24.21 m in ISL1A may be underestimated; (3) 230Th ages of halite from lower 24 m lacustrine sediments are obviously older than AMS 14C ages of TOC in the corresponding layers, which results into different age framework of salt lake sediments in Qarhan Salt Lake; (4) if extrapolating these reliable AMS 14C ages in ISL1A, similar age framework with 230Th ages in this core confirms that 230Th ages are much close to the true ages of these sediments, which suggests that the forming timing of the bottom salt layer is ~50 ka. 相似文献