首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 218 毫秒
1.
Phosphogypsum is a waste by-product of the phosphate fertilizer industry that has relatively high concentrations of some U decay-series radionuclides such as ^226Ra and ^210Pb. The distribution and environmental mobility of radionuclides in phosphogypsum are an important concern because this gypsum by-product is used for wallboard, in agriculture and as a soil amendment. This study determined the distribution of ^226Ra, ^210Pb, within phosphogypsum stacks of varying age and among three size fractions （coarse： 〈0.212 mm; medium： 0.212-0.053 mm; fine： 〈0.053 mm）, in phosphogypsum derived from Aqaba and Eshidiya fertilizer plants. The results indicated that ^226Ra and ^210Pb were generally uniformly distributed in phosphogypsum stacks and showed no significant difference in the concentration of these elements with the age of stack. In the Aqaba phosphogypsum ^226Ra was slightly 10% enriched in the coarse fraction, while ^210Pb was 10% enriched in the free size fraction. In the Eshidiya phosphogypsum ^226Ra and ^210Pb contents were both relatively enriched （10%） in the fine size fraction.  相似文献   

2.
Settling particles were collected from six stations at the Okinawa Trough and the East China Sea continental margin. Activities of U, Th, Pu isotopes and ^210Pb were determined for the particles to elucidate their transport processes. Surface sediment samples were also analyzed for their isotopes. There was a tendency for ^210Pb activities to increase almost linearly with depth from 72 m on the continental shelf edge to 1019 m in the Okinawa Trough. Increasing ^210Pb activities in settling particles with depth on the continental margin may be attributable to enhanced ^210Pb scavenging by particles and removal near the front. There also was a clear tendency for total mass fluxes and the radionuclide fluxes to increase with depth, with an especially large increase near the bottom. The ratio of the observed ^210Pb flux to the ^210Pb deficiency flux in the near-bottom traps ranged between 8.9 and 46. These high values show a strong ^210Pb excess which would be attributable to large advective import to the near-bottom and resuspended particles that have settled through the water column but have not been incorporated into the sediments. High variability of radionuclide fluxes occurred in very short time periods. Activities of ^238U, ^232Th, ^230Th, ^228Th, ^210Pb and ^239Pu＋^240Pu in settling particles were significantly higher than those in the underlying surface sediments.  相似文献   

3.
In the East China Sea （ECS）, there are some mud areas, including the south coastal mud area, the north coastal mud area, and the mud area to the southwest of Cheju Island. X-ray fluorescence （XRF） techniques and Thermal Ionization Mass Spectrometry （TIMS） were used to study the high-resolution sedimentary record of Pb concentrations and Pb stable isotopic compositions in the past one hundred and fifty years in the coastal mud of the ECS. Pb concentrations of a ^210Pb dating S5 core in the study area have increased rapidly since 1980, and reached the maximal value with 65.08 μg/g in 2000, corresponding to the fast economic development of China since the implementation of the ＂Reform and Open Policy＂ in 1978; ^206Pb/^207Pb ratios generally had stabilized at 1.195 from 1860 to 1966, and decreased gradually from 1966 to 2000, indicating that the anthropogenic source Pb contribution to the ECS has increased gradually since 1966, especially since 1980. Pb concentrations decreased distinctly from 2000 to 2003 and ^206Pb/^207Pb ratios increased from 2001 to 2003, corresponding closely to the ban of lead gasoline from 2000 in China. From 1950 to 2003, there occurred four distinct decrease events of ^206Pb/^207Pb, possibly responding to the Changjiang River （Yangtze River） catastrophic floods in 1998, 1991, 1981 and 1954; from 1860 to 1966, there were two decrease periods of ^206Pb/^207Pb, which may respond to the catastrophic floods of Changjiang River in 1931 and 1935, and 1870. As a result of the erosion and drowning by the catastrophic floods, the anthropogenic lead accumulated in soil and water environments over a long period of time was brought into the Changjiang River, then part of them was finally transported into the ECS, which leads to changes in Pb stable isotopic composition.  相似文献   

4.
The nearshore mud area along the Changjiang （Yangtze River） estuary and the coast of Zhejiang and Fujian provinces, and the distal mud area to the southeast of Cheju Island, Korea are the modem accumulative centers, thus, being the ＂sinks＂ of pollutants such as Polycyclic Aromatic Hydrocarbons （PAHs） in the East China Sea （ECS）. PAHs of surface sediment samples from the mud areas of the ECS and a ^210Pb dating sediment core collected using a gravity core from the coastal mud area in the ECS were quantified by GC/MSD with the internal standard materials.  相似文献   

5.
Rapid urbanization and industrialization in South China has placed a great strain on the environment and human health. In the present study, the total suspended particulate matter （TSP） in the urban and suburban areas of Hong Kong and Guangzhou, the two largest urban centres in South China, was sampled from December 2003 to January 2005. The samples were analyzed for their concentrations of major elements （Al, Fe, Mg and Mn） and trace metals （Cd, Cr, Cu, Pb, V and Zn）, and for Pb isotopic composition. Elevated concentrations of metals, especially Cd, Pb, V and Zn, were observed in the urban and suburban areas of Guangzhou, showing significant atmospheric trace element pollution. Distinct seasonal patterns were observed in the heavy metal concentrations of aerosols in Hong Kong, with higher metal concentrations during the winter monsoon period, and lower concentrations during summer time. The seasonal variations in metal concentrations of the aerosols of Guangzhou were less distinct, suggesting the dominance of local sources of pollution around the city. The Pb isotopic composition in the aerosols of Hong Kong had higher ^206Pb/^207Pb and ^208Pb/^207Pb ratios in winter, showing the influence of Pb from the northern inland areas of China and the Pearl River Delta （PRD） region, and lower ^206Pb/^207Pb and ^208Pb/^207Pb ratios in summer, indicating the influence of Pb from the South Asian region and from marine sources.  相似文献   

6.
《中国地球化学学报》2006,25(B08):17-17
Lago Verde is a fresh water maar found in the San Martin volcano, at the Sierra of Los Tuxtlas, Mexico, currently the northernmost remnant of the tropical rain forest in America. A sediment core from Lago Verde was analyzed for ^210Pb and ^137Cs in order to assess the evolution of the accretion rates in the lake and to reconstruct the historical fluxes of heavy metals （Ag, Cd, Cu, Pb, Hg and Zn） to the site during the last -140 years. C/N ^13C were used to evaluate the provenance of the organic atomic ratios and matter accumulated in the sediments. Modem sediments from Lago Verde were found enriched in Pb （26-fold natural concentration level, NCL＇s） and moderately enriched in Cd〉Cu〉Zn and Hg （6, 5, 4 and 4 fold corresponding NCL＇s）. The excess fluxes of Cu, Hg, Pb and Zn have importantly increased during the last 60 years, with peak ratios of total modem to preindustrial fluxes （FR） of 11, 11, 19 and 49, respectively. The lake occupies a relatively pristine, non-industrialized basin, surrounded mostly by pasture lands and sugar cane fields; therefore the increased metal fluxes recorded in the sediment core are most likely related to the enhanced rate of erosion within the watershed, promoted by changes in land use and the irrational deforestation of the tropical rain forest, which have occurred during the past.  相似文献   

7.
Whole-rock Pb isotopic compositions of the high-pressure (HP) metamorphic rocks, consisting of two-mica albite gneisses and eclogites, and foliated granites from the HP metamorphic unit of the Tongbai-Dabie orogenic belt are firstly reported in this paper. The results show that the tip metamorphic rocks in different parts of this orogenic belt have similar Pb isotopic compositions. The twomica albite gneisses have ^206 pb/^204 Pb=17. 657 -18. 168, ^207pb/^204 Pb=15. 318-15. 573,^ 208Pb/^204ob=38.315-38. 990, and the eclogites have ^206Pb/^204 Pb=17. 599 -18. 310, ^207Pb/^204 Pb=15. 465 -15. 615,^208Pb/^204Pb=37. 968-39. 143. The HP metamorphic rocks are characterized by upper crustal Pb isotopic composition. Although the Pb isotopic composition of the HP metamorphic rocks partly overlaps that of the ultrahigh-pressure (UHP) metamorphic rocks, as a whole, the former is higher than the latter. The high radiogenic Pb isotopic composition for the HP metamorphic rocks confirms that the subducted Yangtze continental crust in the Tongbai-Dabie orogenic belt has the chemical structure of increasing radiogenic Pb isotopic composition from lower crust to upper crust. The foliated granites, intruded in the HP metamorphic rocks post the HP/UHP metamorphism, have ^206Pb/^204 Pb=17. 128- 17. 434,^207Pb/^204pb=15. 313-15. 422 and ^208Pb/^204Pb=37. 631-38. 122, which are obviously different from the Pb isotopic compositions of the HP metamorphic rocks but similar to those of the UHP metamorphic rocks and the foliated garnet-bearing granites in the UHP unit. This shows that the foliated granites from the HP and UHP units have common magma source. Combined with the foliated granites having the geochemical characteristics of A-type granites, it is suggested that the magma for the foliated granites in the UHP and HP unit would be derived from the partial melting of the retrometamorphosed UHP metamorphic rocks exhumed into middle to lower crust, and partial magmas were intruded into the HP unit.  相似文献   

8.
Sequential core sediments from northwestern Taihu Lake in China were analyzed for grain size, organic carbon and heavy metal content. The sediments are composed of organic-poor clayey-fine silts. The chemical speciations of Cu, Fe, Mn, Ni, Pb, and Zn were also analyzed using the BCR sequential extraction procedure. Cu, Fe, Ni, and Zn are mainly associated with the residue fraction; Mn is concentrated mainly in exchangeable/carbonate fraction and residue fraction; and Pb mainly in Fe/Mn oxide fraction and organic/sulfide fraction. The exchangeable/carbonate fractions of Cu, Fe, Ni, Zn and Pb are lower. The fractions of Ni, Pb and Zn bound to the Fe/Mn oxide have significant correlations with reducible Mn; the organic/sulfide fractions of Cu, Mn, Ni, Pb, and Zn have significant correlations with TOC. The extractable fractions of Cu, Mn, Ni, Pb, and Zn are high at the top 4 cm of the core sediments as compared to those in the deeper layers, showing the anthropogenic input of heavy metals is due to rapid industrial development. The heavy metal pollution history of the sediments has been recorded since the late 1970s, determined by the result of ^137Cs dating.  相似文献   

9.
Western Hunan Province is one of the most typical assembling areas of cryogenic metallic deposit in China, as well as a main ore-forming zone for some heavy metals. In the region, Hg and Pb pollution was caused by abnormally high concentrations of Hg, Pb in the natural environment and Hg, Pb exploiting/smelting and other human activities, which make the damage to human health more complicated. Generally, heavy metal pollutants in soil are often long-lasting and consequent, with their emission and/or transport into the environment, resulting in growing hazards to human health posed by elevated heavy metal concentrations in air, water, and food. Therefore, monitoring and understanding their behaviors in soil environment is the most important and urgent task. In this paper, the environmental behaviors and pollution characteristics of soil polluted by Hg and Pb in typical Hg and Pb mining areas in western Hunan were studied. Main results are presented as follows： （1） Western Hunan Province is a high regional geochemical abnormal region on Hg and Pb. The concentrations of Hg and Pb in soils in mercury mining areas were 1 315 and 3. l times higher than the average background of soils in China, respectively. While those in soils in lead mining areas are 14.1 and 6.1 times higher. By using the index of geoaccumulation （Igeo）, it was found that either mercury mining area or lead mining area in western Hunan Province has been polluted by the two elements, the majority of soils in mercury mining areas are seriously polluted by Hg, moderately or light polluted by Pb, while the majority of soils in lead mining areas are moderately or moderately-highly polluted by Pb and moderately-highly polluted by Hg. （2） By the BCR extraction procedures, both Hg and Pb in soils are dominated by residual form, followed by organic-sulfide form. Fe-Mn oxides and acid-exchangeable form are rather low. The total concentrations and each species of Hg and Pb in soils show positive correlations with the concentrations of sands, and negative ones with the concentrations of clays in soils.  相似文献   

10.
The estuarine and coastal systems play an important role in sedimentary deposition which acts as a sink of particle-associated contaminants （PACs） such as heavy metals and polycyclic aromatic hydrocarbons. These pollutants are supposed to be harmful to biota in aquatic systems by their persistence, bio-accumulation and toxicity. Therefore, it is needed to understand how anthropogenic activities change the concentrations of potential contaminants in the aquatic environment. In addition, chronologies of metal concentrations can be constructed by ^137Cs and ^210Pbex in dated core sediments. In the present work, the concentrations of the heavy metals As, Cd, Cr, Pb, Cu, Zn, Co, Fe, and Mn were measured in sediment cores collected from four stations （W0, W2, W6, W9） around the Guangdong Nuclear Power Station （GNPS） at the Daya Bay （China）. Methods： after dissolved by mixed mineral acids, the concentrations of heavy metals were determined by PE AAnalysit-700 atomic absorption spectroscopy. The composition of total organic mater （TOC） and total nitrogen （TN） was also evaluated by elemental analysis instruments （CHN-O-RAPID, Heraeus, Germany）. Activities of ^210Pbex and ^137Cs were determined on a Gamma-ray spectrometer （EG ＆ G ORTEC ADCAM-2000, P-type, relative efficiency 35%）. Results and discussion： the experimental data showed that the average values of heavy metals are 18.6, 0.035, 32.9, 38.1, 10.6, 74.9, 4.1, 29100 and 543 mg/kg for As, Cd, Cr, Pb, Cu, Zn, Co, Fe and Mn, respectively, which are obviously larger than the background abundances of those heavy metals in sediment cores.  相似文献   

11.
松花湖沉积物~(137)Cs和~(210)Pb分布及沉积速率   总被引：2，自引：1，他引：1  
松花湖沉积物柱心中存在3个明显的137Cs蓄积峰,分别是37 cm处的1964年蓄积峰、27 cm处的1971年蓄积峰和23 cm处的1975年蓄积峰.利用137Cs核素1964年和1975年对应蓄积峰计算的沉积速率分别为0.86 cm/a和0.71 cm/a.采用210Pb计年的常量初始浓度模式(CIC)计算的平均沉积速率为0.71 cm/a,两者估算的沉积速率吻合.松花湖1964-1975年间的沉积速率明显高于1975-2006年间的沉积速率.137Cs和210Pb计年方法的结合有助于提高沉积速率估算的准确性.  相似文献   

12.
选取崇明岛北侧由东至西4个潮滩沉积柱,分析137Cs、226Ra和210Pb放射性比活度,应用210Pb和137Cs放射性同位素定年方法计算崇明岛潮滩沉积物沉积速率。对于东西两端,210Pb方法测得速率分别为3.08cm/a和2.34 cm/a,而137Cs测得速率分别为6.19 cm/a和2.06 cm/a。结果表明,137Cs定年方法计算出的潮滩沉积速率普遍大于210Pb方法结果;但两者反映了相同的速率规律。崇明岛主力生长方向为东和东北,西侧沉积作用相对较弱,表现出"东快西慢"的特点。沉积纵向上,1954年以来,自下而上沉积速率逐渐减缓。  相似文献   

13.
The representative 210Pb and 137Cs age-depth profiles were selected from more than 100 sites in the Circum Bohai Sea (CBS) coastal region to examine the sedimentation rates and associated environmental changes. There are three unique 210Pbexc distribution patterns: 1) ideal-decaying type, representing relatively constant sediment supply and quieter environmental setting; 2) wiggling type, but with approximately equivalent amplitude, representing coarser sediments and associated stronger flow current environment; and 3) episodic-eventinfluencing type, each representing typhoon storm-influenced depositional environment. Our results also show that there is a lower sedimentation rate (ca. 0.1 cm/a) in the coastal lowlands, a higher sedimentation rate (ca. 0.5–3 cm/a) in the intertidal flat and an intermediate rate of ca. 0.58 cm/a in the subtidal zone near the Huanghua Harbor. The interbedded silt layer occurring in the core sediment reveals lower 210Pb activities, indicating a discontinuous sedimentation mostly due to typhoon events which dwarfs against 210Pb and 137Cs applicability. Overall, the 210Pb and 137Cs measurements of the present study provide physical insight into the evaluation of the coastal-marine ecological environment and associated management.  相似文献   

14.
内蒙古乌梁素海~(210)Pb和~(137)Cs测年与现代沉积速率   总被引：6，自引：2，他引：4  
对乌梁素海沉积物柱心样品进行210Pb、137Cs测年分析表明,柱心剖面上有明显的1963年蓄积峰,这个蓄积峰对乌梁素海的现代沉积有明显的时标意义。根据210Pb的CRS模式,可以计算出每个样品深度所对应的年代,在该沉积柱心中与137Cs时标吻合较好。乌梁素海的沉积速率并不稳定,变化比较大,表明乌梁素海近113 a来沉积环境不稳定。210Pb、137Cs两种计年方法的结合有助于认识沉积速率变化较大的沼泽的沉积状况,也有助于对核素计年方法的理解。  相似文献   

15.
137Cs剖面的沉积信息提取——以香港贝澳湿地为例   总被引：8，自引：1，他引：7  
通过建立模型,对采自香港大屿山岛贝澳湿地三个站位的沉积样品的137Cs实测剖面与模型计算剖面的比较分析,得出三个站位的沉积速率分别为0.24 cm/a、0.21 cm/a、0.34 cm/a,除P1站位外,P2、P3站位由于受到潮水的作用,表层沉积物受到侵蚀,侵蚀量分别为4.8 cm和7 cm。该结果与常用的时标方法所的结果进行了比较,P1站位由上述模型所得的结果与常用的时标方法所得的结果一致。可以看出,在稳定的沉积环境下,常用的确定时标的方法可以较准确地计算出沉积速率,而在堆积与侵蚀变化的沉积环境下,常用的确定时标的方法就存在一定的缺陷。该工作为137Cs剖面的沉积信息提取进行了有益的尝试。但上述模型中,由于采用日本东京地区的137Cs大气沉降通量记录替代香港地区的137Cs大气沉降通量记录,并没有考虑 137Cs的扩散效应,所以该模型还有待进一步的改进。  相似文献   

16.
现代沉积的210Pb计年   总被引：74，自引：10，他引：74       下载免费PDF全文
万国江 《第四纪研究》1997,17(3):230-239
210Pb具有百年时间尺度沉积计年的重要价值。210Pbex计年假设：沉积物是封闭系统；进入水体的210Pb能有效地转移到沉积物中并不发生沉积后迁移；非过剩210Pb与其母体226Ra保持平衡。210Pbex计年可用稳定输入通量-稳定沉积物堆积速率模式、常量初始浓度模式或恒定补给速率模式。沉积物柱芯必须保持原态并以0．5～1cm间隔分截；用相应层节226Ra校正。沉积物表层混合作用及222Rn的丢失可能导致顶部210Pbex异常。季节性缺氧湖泊沉积物顶部可能存在210Pb及210Po的再迁移。210Pb与137Cs两种计年方法原理上具有根本差别。210Pb，137Cs与沉积纹理方法对比是准确计年的重要保证。  相似文献   

17.
用137Cs计年法确定湖泊沉积物沉积速率研究进展   总被引：15，自引：0，他引：15  
137Cs计年法利用137Cs固有的理化和沉降特性,在湖泊沉积物的137Cs垂直分布与大气137Cs沉降间确立对应关系,找出有异常137Cs含量的沉积层作为时标,但需注意137Cs从水体表面至湖底的时间和粘粒含量对各层137Cs含量的影响,并用其它方法校验时标的可靠性。再求取不同时标层间的年均沉积厚度,或因克服了压实效应而更能反映真实沉积速率的年均沉积通量,且结合GIS等手段进一步估算湖泊各区域的沉积总量;还可延伸研究湖泊内源污染负荷及相关环境演变和湖泊演化。但是,沉积柱样的分割厚度取多少才能既满足计年精度要求又不使工作量过大,137Cs的大气沉降时间与进入沉积物时间还与泥沙的陆地迁移时间有关,沉积物中究竟是否发生137Cs下渗及其机理等都还是此法应用中有待解决的问题。  相似文献   

18.
陈静  赵宝成  战庆 《沉积学报》2014,32(4):692-699
随着长江入海泥沙减少,长江三角洲响应问题越来越受到关注。本文选取对水动力变化较为敏感的水下三角洲与陆架过渡区域,通过对钻孔沉积物进行210Pb 和137Cs同位素定年和粒度参数分析,并提取敏感粒级含量及平均粒径垂向变化,尝试探讨其对近百年来长江河口河势变化以及入海泥沙减少的响应。研究发现1954年之前,该区沉积物颗粒较细,粒度参数特征接近现代河口泥质区沉积物,敏感粒径特征反映出河流作用影响较强,说明当时处于泥质区沉积范围;之后沉积物明显粗化,参数特征向陆架残留砂过渡,海洋动力的影响明显增强,并带入陆架粗颗粒物质,说明当时泥质区南移,该区处于河口和陆架沉积过渡区。推测这一变化主要和1954年后长江口北支河道萎缩有关,该区从长江水沙覆盖范围内变为水沙向海输运的边界上,海洋动力对沉积物改造加剧,导致沉积物粗化。同时,并未发现该区沉积物对1980年代后长江入海泥沙显著下降有所响应。近期发现的长江口外泥-砂分界线的西移很可能也包含着河口河势变化而导致的沉积物粗化的贡献。  相似文献   

19.
现代侵蚀作用核素示踪研究新进展   总被引：11，自引：1，他引：10  
利用放射性核素示踪环境地球化学过程是国际地球科学的前缘课题。介绍了利用宇宙线成因的短寿命散落核素7Be示踪土壤季节性侵蚀及其与湖泊沉积耦合关系的最新研究进展;证实了利用核爆炸散落核素137Cs示踪累计性土壤侵蚀和沉积计年的可靠性;阐述了226Ra和228Ra在土壤中比活度的形态变化分异具有很好的侵蚀－堆积示踪价值;揭示了在不同生物化学条件下,210Pb的行为特征和影响因素,并将210Pbex示踪碳酸盐岩区域土壤侵蚀速率结果与湖泊沉积速率相耦合,证明了利用210Pb示踪土壤侵蚀的可行性。  相似文献   

20.
围海造地工程对香港维多利亚港现代沉积作用的影响   总被引：17，自引：1，他引：16  
对采自香港维多利亚港的 4个 6m长的沉积柱状样作了2 10 Pb及Pb、Zn、Cu含量分析。结果表明,维多利亚港开阔区域现代沉积速率在 0.3～ 2cm/a之间变化,西部大于东部。在九龙海峡主航道上,基本上处于冲淤平衡状态。由于近百年来围海造地、海岸工程建设,使维多利亚港的岸线发生了较大的变化,在台风避风塘等潮流作用较弱的区域及靠近城市排污口的地方沉积速率可达 3～ 5cm/a,这表明围海造地、海岸工程等造成的岸线变化是影响维多利亚港堆积侵蚀的主要因素。Pb、Zn、Cu等重金属在沉积柱状样中的分布表明,在沉积速率较快的区域,重金属的污染也较为严重。  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号