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1.
Small euhedral chromite crystals are found in olivine macrophenocrysts (Fo80–84) from the basaltic andesites (150 ppm Cr) erupted in 1943–1947, and in orthopyroxene macrophenocrysts of the andesites (75 ppm Cr) erupted in 1947–1952. The majority of the chromite octahedra are 5–20 μm in diameter, and some are found in clusters and linear chains of three or more oriented chromite crystals. The composition of the majority of the chromite grains within olivine and orthopyroxene macrophenocrysts is Fe2+/(Fe2++Mg)=0.5–0.6, Cr/(Cr+Al)=0.5–0.6 and Fe3+/(Fe3++Al+Cr)=0.2–0.3. The chromite crystals in contact with the groundmass are larger, subhedral, and grade in composition from chromite cores to magnetite rims. Comparison of the composition of chromite with those of other volcanic rocks shows that the most primitive Paricutin chromite is richer in total iron and higher in Fe3+/(Fe3++Al+Cr) than primary chromite in most lavas. The linear chains of oriented chromite octahedra are found in olivine and orthopyroxene macrophenocrysts, and in the groundmass. These chromite chains are thought to result from diffusion-controlled crystallization because of the very high partition coefficient (1000) of Cr between chromite and melt. We conclude that chromite was a primary phase in the lavas at the time of extrusion and that magnetite only crystallized after extrusion during cooling of the lava flows. The presence of chromite microphenocrysts in andesitic lavas containing as little as 70 ppm Cr can be explained by dissolved H2O in the melt depressing the liquidus temperature for orthopyroxene such that chromite becomes a liquidus phase. The influence of dissolved H2O can also explain the lack of plagioclase macrophenocrysts in most of the lavas and the relatively high partition coefficient (20) of Ni between olivine and melt and the high partition coefficient (40) of Cr between orthopyroxene and melt. The liquidus temperature of the basaltic andesite is estimated to have been less than 1140°C, assuming H2O>1 wt.%, and the log fO2 to have been above that of the QFM buffer. The chromite and orthopyroxene liquidus temperature of the andesites, assuming H2O>1 wt.%, is estimated to have been 1100°C or less. The derivation of the later andesites from the earlier basaltic andesites has been explained by a combination of fractional crystallization of olivine, orthopyroxene and plagioclase, and assimilation of xenoliths. The significantly lower Cr, Ni and Mg of the andesites may have been in part due to the separation of olivine macrophenocrysts plus enclosed chromite crystals from the earlier basaltic andesites.  相似文献   

2.
An Aleutian high-alumina basalt from the island of Atka at one atmosphere crystallizes plagioclase (1275°C) followed by olivine (1170°C) and clinopyroxene (1115°C). At oxygen fugacities along NNO, magnetite crystallizes below 1070°C, but its liquidus increases to at least 1175°C at an oxygen fugacity two log units above NNO. Phase relations at two kilobars pressure of melts containing small amounts of water are similar, although orthopyroxene and magnetite are observed to follow clinopyroxene. Amphibole crystallizes at near-liquidus temperatures only at water contents of melts approaching 4.5%. Amphibole assumes the liquidus in melts containing 5% water.Anhydrous melts crystallize plagioclase to 19 kbar, where garnet and clinopyroxene assume the liquidus. Olivine yields to clinopyroxene as the highest-temperature subliquidus phase at about 9 kbar.The array of compositions of basaltic Atka rocks, as displayed on appropriate pseudoternary projections, can be interpreted as a crystal fractionation path at moderate pressure (8 kbar) and small melt-water contents. The interpreted fractionating minerals are olivine, clinopyroxene, plagioclase, and (probably) magnetite. (The actual phenocrysts in Atka basalts like AT-1, which lacks phenocrystic clinopyroxene, must have crystallized at pressure less than 8 kbar, however.) The compositions of two-pyroxene andesites from Atka can be interpreted to lie on a lower-pressure fractionation trend at melt water contents of 2–3%. Such water contents are consistent with the complete absence of amphibole in any Atka rocks and are suggestive that water contents of the basaltic magmas, if the basalts are parental to the andesites, were 1–2%.  相似文献   

3.
A series of experiments and petrographic analyses have been run to determine the pre-eruption phase equilibria and ascent dynamics of dacitic lavas composing Black Butte, a dome complex on the flank of Mount Shasta, California. Major and trace element analyses indicate that the Black Butte magma shared a common parent with contemporaneously erupted magmas at the Shasta summit. The Black Butte lava phenocryst phase assemblage (20 v.%) consists of amphibole, plagioclase (core An77.5), and Fe–Ti oxides in a fine-grained (< 0.5 mm) groundmass of plagioclase, pyroxene, Fe–Ti oxides, amphibole, and cristobalite. The phenocryst assemblage and crystal compositions are reproduced experimentally between 890 °C and 910 °C, ≥ 300 MPa, XH2O = 1, and oxygen fugacity = NNO + 1. This study has quantified the extent of three crystallization processes occurring in the Black Butte dacite that can be used to discern ascent processes. Magma ascent rate was quantified using the widths of amphibole breakdown rims in natural samples, using an experimental calibration of rim development in a similar magma at relevant conditions. The majority of rims are 34 ± 10 μm thick, suggesting a time-integrated magma ascent rate of 0.004–0.006 m/s among all four dome lobes. This is comparable to values for effusive samples from the 1980 Mount St. Helens eruption and slightly faster than those estimated at Montserrat. A gap between the compositions of plagioclase phenocryst cores and microlites suggests that while phenocryst growth was continuous throughout ascent, microlite formation did not occur until significantly into ascent. The duration of crystallization is estimated using the magma reservoir depth and ascent rate, as determined from phase equilibria and amphibole rim widths, respectively. Textural analysis of the natural plagioclase crystals yields maximum growth rates of plagioclase phenocryst rims and groundmass microlites of 8.7 × 10− 8 and 2.5 × 10− 8 mm/s, respectively. These rates are comparable to values determined from time-sequenced samples of dacite erupted effusively from Mount St. Helens during 1980 and indicate that syneruptive crystallization processes were important during the Black Butte eruptive cycle.  相似文献   

4.
The equilibrium distribution of CO2H2O fluids in synthetic rock samples (principally dunite and quartzite) has been characterized by measurements of the dihedral wetting angle, θ, resulting from 5-day annealing periods at 950–1150°C and 1 GPa. For fluids in equilibrium with polycrystalline quartz, θ varies systematically from 57° for pure H2O to 90° at XCO2 0.9. Similarly, for San Carlos olivine, θ varies from 65° for pure H2O to 90° at XCO2 0.9. The addition of solutes (NaCl, KCl, CaF2, Na2CO3) to H2O causes a major decrease in θ in the quartz/fluid system (to values as low as 40°), but has no effect on fluid wetting in dunite. Reconnaissance experiments on other mono- and polymineralic aggregates indicate universally high wetting angles (θ 60°) in upper mantle assemblages and for CO2 in felsic compositions. For diopside + H2O, θ 80°, with large variation due to crystalline anisotropy. In no case does θ approach 0°, the condition necessary for fluid to be present along all grain boundaries.Because a value of θ greater than 60° precludes the existence of an interconnected fluid phase in a rock, our results have important implications not only for fluid transport but also for the physical properties of the bulk fluid/rock system. Any static fluid present in the upper mantle must exist as isolated pores located primarily at grain corners, and transport can occur only by hydrofracture. In the continental crust, aqueous fluids (especially saline ones) are likely to form an interconnected network along grain edges, thus contributing to high electrical conductivity and allowing the possibility of fluid transport by porous flow or surface energy-driven infiltration.  相似文献   

5.
Among the series of eruptions at Miyakejima volcano in 2000, the largest summit explosion occurred on 18 August 2000. During this explosion, vesiculated bombs and lapilli having cauliflower-like shapes were ejected as essential products. Petrological observation and chemical analyses of the essential ejecta and melt inclusions were carried out in order to investigate magma ascent and eruption processes. SEM images indicate that the essential bombs and lapilli have similar textures, which have many tiny bubbles, crystal-rich and glass-poor groundmass and microphenocrysts of plagioclase, augite and olivine. Black ash particles, which compose 40% of the air-fall ash from the explosion, also have similar textures to the essential bombs. Whole-rock analyses show that the chemical composition of all essential ejecta is basaltic (SiO2=51–52 wt%). Chemical analyses of melt inclusions in plagioclase and olivine phenocrysts indicate that melt in the magma had 0.9–1.9 wt% H2O, <0.011 wt% CO2, 0.04–0.17 wt% S and 0.06–0.1 wt% Cl. The variation in volatile content suggests degassing of the magma during ascent up to a depth of about 1 km. The ratio of H2O and S content of melt inclusions is similar to that of volcanic gas, which has been intensely and continuously emitted from the summit since the end of August 2000, indicating that the 18 August magma is the source of the gas emission. Based on the volatile content of the melt inclusions and the volcanic gas composition, the initial bulk volatile content of the magma was estimated to be 1.6–1.9 wt% H2O, 0.08–0.1 wt% CO2, 0.11–0.17 wt% S and 0.06–0.07 wt% Cl. The basaltic magma ascended from a deeper chamber (10 km) due to decrease in magma density caused by volatile exsolution with pressure decrease. The highly vesiculated magma, which had at least 30 vol% bubbles, may have come into contact with ground water at sea level causing the large explosion of 18 August 2000.Editorial responsibility: S. Nakada, T. DuittAn erratum to this article can be found at  相似文献   

6.
The origin of Arenal basaltic andesite can be explained in terms of fractional crystallization of a parental high-alumina basalt (HAB), which assimilates crustal rocks during its storage, ascent and evolution. Contamination of this melt by Tertiary calc-alkalic intrusives (quartz–diorite and granite, with 87Sr/86Sr ratios ranging 0.70381–0.70397, nearly identical with those of the Arenal lavas) occurs at upper crustal levels, following the interaction of ascending basaltic magma masses with gabbroic–anorthositic layers. Fragments of these layers are found as inclusions within Arenal lavas and tephra and may show reaction rims (1–5 mm thick, consisting of augite, hypersthene, bytownitic–anorthitic plagioclase, and granular titanomagnetite) at the gabbro–lava interface. These reaction rims indicate that complete `assimilation' was prevented since the temperature of the host basaltic magma was not high enough to melt the gabbroic materials (whose mineral phases are nearly identical to the early formed liquidus phases in the differentiating HAB). Olivine gabbros crystallized at pressure of about 5–6 kbar and equilibrated with the parental HAB at pressures of 3–6 kbar (both under anhydrous and hydrous conditions), and temperatures ranging 1000–1100°C. In particular, `deeper' interactions between the mafic inclusions and the hydrous basaltic melt (i.e., with about 3.5 wt.% H2O) are likely to occur at 5.4 (±0.4) kbar and temperatures approaching 1100°C. The olivine gabbros are thus interpreted as cumulates which represent crystallized portions of earlier Arenal-type basalts. Some of the gabbros have been `mildly' tectonized and recrystallized to give mafic granulites that may exhibit a distinct foliation. Below Arenal volcano a zoned magma chamber evolved prior the last eruptive cycle: three distinct andesitic magma layers were produced by simple AFC of a high-alumina basalt (HAB) with assimilation of Tertiary quartz–dioritic and granitic rocks. Early erupted 1968 tephra and 1969 lavas (which represent the first two layers of the upper part of a zoned magma chamber) were produced by simple AFC, with fractionation of plagioclase, pyroxene and magnetite and concomitant assimilation of quartz–dioritic rocks. Assimilation rates were constant (r1=0.33) for a relative mass of magma remaining of 0.77–0.80, respectively. Lavas erupted around 1974 are less differentiated and represent the `primitive andesitic magma type' residing within the middle–lower part of the chamber. These lavas were also produced by simple AFC: assimilation rates and the relative mass of magma remaining increased of about 10%, respectively (r1=0.36, and F=0.89). Ba enrichment of the above lavas is related to selective assimilation of Ba from Tertiary granitic rocks. Lava eruption occurred as a dynamic response to the intrusion of a new magma into the old reservoir. This process caused the instability of the zoned magma column inducing syneruptive mixing between portions of two contiguous magma layers (both within the column itself and at lower levels where the new basalt was intruded into the reservoir). Syneruptive mixing (mingling) within the middle–upper part of the chamber involved fractions of earlier gabbroic cumulitic materials (lavas erupted around 1970). On the contrary, within the lower part of the chamber, mixing between the intruded HAB and the residing andesitic melt was followed by simple fractional crystallization (FC) of the hybrid magma layer (lavas erupted in 1978–1980). By that time the original magma chamber was completely evacuated. Lavas erupted in 1982/1984 were thus modelled by means of `open system' AFCRE (i.e., AFC with continuous recharge of a fractionating magma batch during eruption): in this case assimilation rates were r1=0.33 and F=0.86. Recharge rates are slightly higher than extrusion rates and may reflect differences in density (between extruded and injected magmas), together with dynamic fluctuations of these parameters during eruption. Ba and LREE (La, Ce) enrichments of these lavas can be related to selective assimilation of Tertiary granitic and quartz–dioritic rocks. Calculated contents for Zr, Y and other REE are in acceptable agreement with the observed values. It is concluded that simple AFC occurs between two distinct eruption cycles and is typical of a period of repose or mild and decreasing volcanic activity. On the contrary, magma mixing, eventually followed by fractional crystallization (FC) of the hybrid magma layer, occurs during an ongoing eruption. Open-system AFCRE is only operative when the original magma chamber has been totally replenished by the new basaltic magma, and seems a prelude to the progressive ceasing of a major eruptive cycle.  相似文献   

7.
A new version of COMAGMAT-3.5 model designed for computer simulations of equilibrium and fractional crystallization of basaltic magmas at low to high pressures is presented. The most important modifications of COMAGMAT include an ability to calculate more accurately the crystallization of magnetite and ilmenite, allowing the user to study numerically the effect of oxygen fugacity on basalt magma fractionation trends. Methodological principles of the use of COMAGMAT were discussed based on its thermodynamical and empirical basis, including specific details of the model calibration. Using COMAGMAT-3.5 a set of phase equilibria calculations (called Geochemical Thermometry) has been conducted for six cumulative rocks from the Marginal Border Series of the Skaergaard intrusion. As a result, initial magma temperature (1165±10°C) and trapped melt composition proposed to be parental magma to the Skaergaard intrusion were determined. Computer simulations of perfect fractionation of this composition as well as another proposed parent produced petrochemical trends opposite to those followed from natural observations. This is interpreted as evidence for an initial Skaergaard magma containing a large amount of olivine and plagioclase crystals (about 40–45%), so that the proposed and calculated parents are related through the melt trapped in the crystal–liquid mixture. This promotes the conclusion that the Skaergaard magma fractionation process was intermediate between equilibrium and fractional crystallization. In this case the classic Wager's trend should be considered an exception rather than a rule for the differentiation of ferro-basaltic magmas. A polybaric version of COMAGMAT has been applied for the genetic interpretation of a volcanic suite from the Klyuchevskoi volcano, Kamchatka, Russia. To identify petrological processes responsible for the observed suite ranging from high-magnesia to high-alumina basalts, we used the model to simulate the Klyuchevskoi suite assuming isobaric crystallization of a parental HMB magma at a variety of pressures and a separate set of simulations assuming fractionation during continuous magma ascent from a depth of 60 km. These results indicate that the Klyuchevskoi trend can be produced by 40% fractionation of Ol–Aug–Sp±Opx assemblages during ascent of the parental HMB magma over the pressure range 19–7 kbar with the rate of decompression being 0.33 kbar/% crystallized (at 1350–1110°C), with 2 wt.% of H2O in the initial melt and 3 wt.% of H2O in the resultant high-Al basalt.  相似文献   

8.
Paleomagnetic data from 46 sites (674 specimens) of the Westcoast Crystalline Gneiss Complex on the west coast of Vancouver Island using AF and thermal demagnetization methods yields a high blocking temperature WCB component (> 560°C) with a pole at 335°W, 66°N (δp = 4°, δm = 6°) and a lower coercivity WCA component ( 25 mT, < 500°C) with a pole at 52°W, 79°N (δp = 7°, δm = 8°). Further thermal demagnetization data from 24 sites in the Jurassic Island Intrusions also defines two high blocking temperature components. The IIA component pole is at 59°W, 79°N (δp = 7°, δm = 8°) and IIB pole at 130°W, 73°N (δp = 12°, δm = 13°). Combined with previous data from the Karmutsen Basalts and mid-Tertiary units on Vancouver Island and from the adjacent Coast Plutonic Complex, the geotectonic motions are examined for the Vancouver Island segment of the Wrangellian Subterrane of composite Terrane II of the Cordillera. The simplest hypothesis invokes relatively uniform translation for Terrane II from Upper Triassic to Eocene time producing 39° ± 6° of northward motion relative to the North American craton, combined with 40° of clockwise rotation during the Lower Tertiary.  相似文献   

9.
The morphology and composition of spinel in rapidly quenched Pu’u ’O’o vent and lava tube samples are described. These samples contain glass, olivine phenocrysts (3–5 vol.%) and microphenocrysts of spinel (0.05 vol.%). The spinel surrounded by glass occurs as idiomorphic octahedra 5–50 μm in diameter and as chains of octahedra that are oriented with respect to each other. Spinel enclosed by olivine phenocrysts is sometimes rounded and does not generally form chains. The temperature before quenching was calculated from the MgO content of the glass and ranges from 1150°C to 1180°C. The oxygen fugacity before quenching was calculated by two independent methods and the log fO2 ranged from −9.2 to −9.9 (delta QFM=−1). The spinel in the Pu’u ’O’o samples has a narrow range in composition with Cr/(Cr+Al)=0.61 to 0.73 and Fe2+/(Fe2++Mg)=0.46 to 0.56. The lower the calculated temperature for the samples, the higher the average Fe2+/(Fe2++Mg), Fe3+ and Ti in the spinel. Most zoned spinel crystals decrease in Cr/(Cr+Al) from core to rim and, in the chains, the Cr/(Cr+Al) is greater in the core of larger crystals than in the core of smaller crystals. The occurrence of chains and hopper crystals and the presence of Cr/(Cr+Al) zoning from core to rim of the spinel suggest diffusion-controlled growth of the crystals. Some of the spinel crystals may have grown rapidly under the turbulent conditions of the summit reservoir and in the flowing lava, and the crystals may have remained in suspension for a considerable period. The rapid growth may have caused very local (μm) gradients of Cr in the melt ahead of the spinel crystal faces. The crystals seem to have retained the Cr/(Cr+Al) ratio that developed during the original growth of the crystal, but the Fe2+/(Fe2++Mg) ratio may have equilibrated fairly rapidly with the changing melt composition due to olivine crystallization. Six of the samples were collected on the same day at various locations along a 10-km lava tube and the calculated pre-collection temperatures of the samples show a 5°C drop with distance from the vent. The average Fe2+/(Fe2++Mg) of the spinel in these samples shows a weak positive correlation with decreasing MgO in the glass of these samples. The range in Cr2O3 (0.041–0.045 wt.%) of the glass for these six samples is too small to distinguish a consistent change along the lava tube. The spinel in the Pu’u ’O’o samples shows a zoning trend in a Cr–Al–Fe3+ diagram almost directly away from the Cr apex. This compares with a zoning trend in rapidly quenched MORB samples away from Cr coupled with decreasing Fe3+. The trend away from Cr displayed by spinel in rapidly quenched samples is in marked contrast to the trend of increasing Fe3+ shown by spinel in slowly cooled lava.  相似文献   

10.
Peridotite xenoliths with a broad range of textures provides evidence for consistent microstructural evolution in a vertical transect of the shallow lithospheric mantle (35–55 km depth) beneath the Persani Mountains, SE Carpathians, Romania, due to ongoing plate convergence in the Carpathian Arc nearby. The recrystallized grain size, crystal preferred orientations strength, and resulting seismic anisotropy vary continuously and display a strong correlation to equilibrium temperatures, suggesting a continuous change in deformation conditions with depth. The shallowmost xenoliths have microstructures typical of high stress deformation, marked by strong recrystallization to fine grain sizes, which results in weak crystal preferred orientations and anisotropy. The deepest xenoliths have coarse-grained porphyroclastic microstructures and strong crystal preferred orientations. Replacive orthopyroxene structures, consuming olivine, and high H2O concentrations in the pyroxenes are observed in some xenoliths indicating limited percolation of fluids or volatile-rich melts. Despite the high stress deformation and high H2O contents in some of the studied xenoliths, analysis of olivine crystallographic orientations indicates that [100] slip systems, rather than “wet” [001] accommodate most of the deformation in all samples. Seismic anisotropy estimated from the measured olivine and pyroxene crystal preferred orientations suggests that the strike-parallel fast SKS polarization directions and ~ 1 s delay times measured in the SE Carpathians are likely the consequence of convergence-driven belt-parallel flow in the lithospheric mantle.  相似文献   

11.
The products emitted by Mount Etna in the 1977–1983 period are porphyric, sodic trachybasalts («etnaïtes») that, though substantially higher in K2O, resemble most of the historic lavas.The 1983 flows, for instance, are composed of 50–55% glassy groundmass and abundant phenocrysts or microphenocrysts: plagioclase (25–30%), clinopyroxene (12–15%), olivine (3–5%), titanomagnetite (2%). Scarce olivine Fo 83-78 and diopsidic pyroxene are present in the cores of some phenocrysts. Outer zones and/or more numerous crystals are olivine Fo 75-68, salite En 43-37 Fs 10-15, plagioclase An 83-55 an Al-Mg rich magnetite Usp 43-33. The chemical composition of glass inclusions interpreted as trapped liquids suggests that olivine and magnetite crystallize first and are followed by pyroxene and plagioclase. The early appearance of olivine has been determined by optical thermometry to about 1170°C, soon followed by plagioclase and pyroxene (1160–1140°C). Pre-eruptive crystallization further progresses until 1073°C which is the field-measured temperature at the lava vent. Then, the appearance and composition of microlites (and outer rims of phenocrysts) depend upon the cooling rate of the samples (water quenching or natural cooling). Electron microprobe analyses of chlorine and sulphur have been performed on crystal trapped and groundmass glasses. Sulphur ranges from an initial content of 1500 ppm to 400 ppm in residual glass, leading to an average sulphur emission of 1500 tons/day (3000 t/d SO2), as estimated from the volume of erupted lava.The most striking chemical feature of the 1977–1983 lavas lies in the abnormal potassium behaviour, especially in the earliest flows of the 1978–1979 fissure eruptions. Although these lavas are amongst the most femic of the period, they are relatively high in K2 O, leading to an aberrant K/Na ratio (i.e. increasing with increasing basicity). Furthermore, a less pronounced but steady increase of K2 O/Na2 O is evidenced in all the lavas of the past 12 years. This ratio ranges from 0.42 in the 1971 lavas to 0.51 in the 1983 ones, for about the same differentiation index. Such an abnormal potassium behaviour first appeared during the 1974 eruption on the west slope of the volcano. It is unknown, however, in any other historic lava, nor in any lava of entire Etna so far analyzed.
Resume Les produits rejetés par l'Etna de 1977 à 1983 sont des trachybasaltes porphyriques («etnaïtes») semblables à ceux qui caractérisent la majorité des laves de ce volcan, mais avec une teneur en K plus élevée.Les coulées de 1983, par exemple, sont formées de 50–55% de mésostase et par de nombreux phéno et microphénocristaux de plagioclase (25–30%), clinopyroxène (12–15%), olivine (3–5%), titanomagnétite (2%). De l'olivine Fo 83-78 et un peu de diopside-salite cristallisent d'abord, passant rapidement à une olivine Fo 78-68, une salite (Wo 47,5 — En 43/37 — Fs 10/15), du plagioclase An 83-55, une titanomagnétite Usp 43-33 riche en Al et Mg. Le domaine de température de cristallisation commençante des phénocristaux établi par thermométrie optique est compris entre 1170° et 1140°C. La cristallisation intratellurique progresse ensuite jusqu'à 1073°C, qui représente la température d'émission de la lave mesurée sur le terrain. La nature et la quantité des microlites, la composition des stades terminaux de cristallisation des phénocristaux et celle du verre résiduel de la mésostase dépendent du mode de refroidissement de la lave: trempe à l'eau, à l'air, ou refroidissement lent naturel. La quantité de soufre dans les verres inclus et la mésostase varie de 1500 à 400 ppm, celle du chlore de 1700 à 2800 ppm.La composition chimique est celle d'un trachybasalte sodique (hawaiite basaltique). Le caractère le plus marquant réside dans le comportement anormal du potassium, en particulier dans les laves du début des éruptions de 1978 et 1979. Alors que ces produits sont parmi les plus basiques de la période considérée, leur teneur en K est relativement élevée, ce qui conduit à un rapport K/Na aberrant (augmentant avec la basicité de la roche). En dehors de ces cas extrêmes, on note une augmentation régulière, quoique plus faible, de K/Na dans tous les produits des 12 dernières années. Ce comportement anormal du potassium était déjà apparu dans les produits de l'éruption excentrique de 1974 sur le versant ouest. Cependant, on ne trouve aucune variation aberrante du potassium dans les autres laves historiques, ni même dans aucun des produits connus de l'Etna.
  相似文献   

12.
Major-element, Cl, S, F analyses have been performed on a wide selection of melt inclusions trapped in olivine (Fo81–87) from scoria and crystal-rich lapilli samples of Piton de la Fournaise volcano. As a whole, they display a transitional basaltic composition. The melt inclusions (8–9 wt.% MgO, 0.62–0.73 wt.% K2O) are in equilibrium with olivines (Fo81–85) in the samples from the Central Feeding Zone and the South-East Feeding Zone and show a slight alkaline affinity. The melt inclusions in olivines (Fo85–87) from the North-West Rift (NWR) contain 9.3–9.7 wt.% MgO and 0.54–0.58 wt.% K2O, with a more tholeiitic tendency. In oceanitic lavas and crystal-rich lapilli, the olivine xenocrysts are recognisable by the presence of one or more secondary shear plane fracture(s) filled up with CO2 and alkali-rich basaltic melt inclusions. In dunite nodules, olivines present also contain several secondary shear plane fracture(s) filled up with CO2 and high-SiO2 melt inclusions. Secondary CO2-rich fluid inclusions in olivine (Fo85–87) from the NWR samples indicate PCO2 up to 500 MPa whereas, PCO2 ranges from 95 MPa to few tenths of bars in the other samples. Both the primary melt inclusions and the secondary fluid inclusions strongly suggest that the olivine crystallises and accumulates over a wide depth range (15 km). It is envisioned that cumulative pockets with low residual porosity are repeatedly percolated with a CO2-rich fluid phase, possibly associated with basaltic to SiO2-rich melts, and are finally disrupted and entrained to the surface when vigorous magma transfer occurs. The SiO2-rich residual melts in early-formed dunitic or gabbroic bodies may have acted as contaminant agents for the more alkali character of magmas vented through the central feeding system, where a well-developed cumulative system is thought to exist. Finally, the existence of secondary fluid and melt inclusions in olivines implies that the dunitic bodies are weakened on the micrometric scale.  相似文献   

13.
Isotopic compositions were determined for hydrothermal quartz, calcite, and siderite from core samples of the Newberry 2 drill hole, Oregon. The δ15O values for these minerals decrease with increasing temperatures. The values indicate that these hydrothermal minerals precipitated in isotopic equilibrium with water currently present in the reservoirs. The δ18O values of quartz and calcite from the andesite and basalt flows (700–932 m) have isotopic values which require that the equilibrated water δ18O values increase slightly (− 11.3 to −9.2‰) with increasing measured temperatures (150–265°C). The lithic tuffs and brecciated lava flows (300–700 m) contain widespread siderite. Calculated oxygen isotopic compositions of waters in equilibrium with siderite generally increase with increasing temperatures (76–100°C). The δ18O values of siderite probably result from precipitation in water produced by mixing various amounts of the deep hydrothermal water (− 10.5 ‰) with meteoric water (− 15.5 ‰) recharged within the caldera. The δ13C values of calcite and siderite decrease with increasing temperatures and show that these minerals precipitated in isotopic equilibrium with CO2 of about −8 ‰.The δ18O values of weakly altered (<5% alteration of plagioclase) whole-rock samples decrease with increasing temperatures above 100°C, indicating that exchange between water and rock is kinetically controlled. The water/rock mass ratios decrease with decreasing temperatures. The δ18O values of rocks from the bottom of Newberry 2 show about 40% isotopic exchange with the reservoir water.The calculated δ18O and δD values of bottom hole water determined from the fluid produced during the 20 hour flow test are −10.2 and −109‰, respectively. The δD value of the hydrothermal water indicates recharge from outside the caldera.  相似文献   

14.
Shirouma-Oike volcano, a Quaternary composite volcano in central Japan, consists mostly of calc-alkaline andesitic lavas and pyroclastic rocks. Products of the earlier stage of the volcano (older group) are augite-hypersthene andesite. Hornblende crystallized during the later stage of this older group, whereas biotite and quartz crystallized in the younger group.Assemblages of phenocrysts in disequilibrium, such as magnesian olivine(Fo30)/quartz, iron-rich hypersthene(En55)/iron-poor augite(Wo43.5, En42.5, Fs14.0), and two different types of zoning on the rim of clinopyroxene are found in a number of rocks. Detailed microprobe analyses of coexisting minerals reveal that phenocrysts belong to two distinctly different groups; one group includes magnesian olivine + augite which crystallized from a relatively high-temperature (above 1000°C) basaltic magma; the second group, which crystallized from relatively low temperature (about 800°C) dacitic to andesitic magma, includes hypersthene + hornblende + biotite + quartz + plagioclase + titanomagnetite ± ilmenite (in the younger group) and hypersthene + augite + plagioclase + titanomagnetite ± hornblende (in the older group). The temperature difference between the two magmas is clarified by Mg/Fe partition between clinopyroxene and olivine, and Fe-Ti oxides geothermometer. The compositional zoning of minerals, such as normal zoning of olivine and magnesian clinopyroxene, and reverse zoning of orthopyroxene, indicate that the basaltic and dacitic-andesitic magmas were probably mixed in a magma reservoir immediately before eruption. It is suggested that the basaltic magma was supplied intermittently from a deeper part to the shallower magma reservoir, in in which dacitic-andesitic magma had been fractionating.  相似文献   

15.
Volcanism in the Taupo Volcanic Zone (TVZ) and the Kermadec arc-Havre Trough (KAHT) is related to westward subduction of the Pacific Plate beneath the Indo-Australian Plate. The tectonic setting of the TVZ is continental whereas in KAHT it is oceanic and in these two settings the relative volumes of basalt differ markedly. In TVZ, basalts form a minor proportion (< 1%) of a dominant rhyolite (97%)-andesite association while in KAHT, basalts and basaltic andesites are the major rock types. Neither the convergence rate between the Pacific and Indo-Australian Plates nor the extension rates in the back-arc region or the dip of the Pacific Plate Wadati-Benioff zone differ appreciably between the oceanic and continental segments. The distance between the volcanic front and the axis of the back-arc basin decreases from the Kermadec arc to TVZ and the distance between trench and volcanic front increases from around 200 km in the Kermadec arc to 280 km in TVZ. These factors may prove significant in determining the extent to which arc and backarc volcanism in subduction settings are coupled.All basalts from the Kermadec arc are porphyritic (up to 60% phenocrysts) with assemblages generally dominated by plagioclase but with olivine, clinopyroxene and orthopyroxene. A single dredge sample from the Havre Trough back arc contains olivine and plagioclase microphenocrysts in glassy pillow rind and is mildly alkaline (< 1% normative nepheline) contrasting with the tholeiitic nature of the other basalts. Basalts from the TVZ contain phenocryst assemblages of olivine + plagioclase ± clinopyroxene; orthopyroxene phenocrysts occur only in the most evolved basalts and basaltic andesites from both TVZ and the Kermadec Arc.Sparsely porphyritic primitive compositions (Mg/(Mg+Fe2) > 70) are high in Al2O3 (>16.5%), and project in the olivine volume of the basalt tetrahedron. They contain olivine (Fo87) phenocrysts and plagioclase (> An60) microphenocrysts. These magmas have ratios of CaO/Al2O3, A12O3/TiO2 and CaO/TiO2 in the range of MORB and MORB picrites and can evolve to the low-pressure MORB cotectic by crystallisation of olivine±plagiociase. Such rocks may be the parents of other magmas whose evolutionary pathways are complicated by interaction of crystal fractionation, crystal accumulation and mixing processes and the filtering action of crust of variable density and thickness. The interplay of these processes likely accounts for the scatter of data about the cotectic. More evolved rocks from both TVZ and KAHT contain clinopyroxene and orthopyroxene phenocrysts and their compositions merge with basaltic andesites and andesites. Stepwise least-squares modelling using phenocryst assemblages in proportions observed in the rocks suggest that crystal fractionation and accumulation processes can account for much of the diversity observed in the major-element compositions of all lavas.We conclude that the parental basaltic magmas for volcanism in the TVZ and KAHT segments are similar thereby implying grossly similar source mineralogy. We attribute the diversity to secondary processes influencing liquids as they ascended through complex plumbing systems in the sub arc mantle and cross.  相似文献   

16.
In order to understand the origin of iron-rich olivine in the matrices of type 3 ordinary chondrites, the reaction of metallic iron and enstatite, with and without forsterite and SiO2, has been experimentally reproduced at temperatures between 1150° and 800°C and PO2 between 10−11 and 10−16 atm (between the IQF and MW buffers). The olivine produced ranges from Fo58 to Fo34 and this composition does not change significantly with temperature and time of the runs. The magnesian olivine which forms does become more magnesian with increasing forsterite/enstatite ratio of the starting materials. Iron-rich olivine (Fo< 35) cannot be formed by the reaction of enstatite and metallic iron, with or without forsterite as starting materials but it can be formed in the presence of free silica. The composition of olivine becomes more iron-rich with increasing silica/enstatite ratio. The compositional range of olivine formed from each mixture is 25–30 mole% Fo regardless of the temperature, composition, mineral assemblage, and run duration.From these experimental results, two possibilities suggested for the origin of the iron-rich olivine in the matrices of type 3 ordinary chondrites: (1) free silica must have been present if the iron-rich olivine was formed by solid-state reactions under oxidizing condition in the solar nebula; (2) reaction of silicon-rich gas with metallic iron took place under oxidizing condition in the solar nebula. Though it is difficult to define which alternative was dominant, the formation of free silica or silicon-rich gas may be a result of fractional condensation. This is possible if there is a reaction relation between forsterite and gas to produce enstatite. The suggested fractional condensation is supported by the fact that the compositions of the fine-grained matrices of type 3 ordinary chondrites are more silica-rich than the bulk compositions of the chondrites. Though it is not known whether such conditions were established all over the nebula or locally in the nebula, both fractionation and more oxidizing conditions than the average solar nebula are required for the formation of matrix olivine.  相似文献   

17.
Crystallization paths of basaltic (1763 eruption) and hawaiitic (1865 and 1329 eruptions) scoria from Etna were deduced from mineralogy and melt inclusion chemistry. The volatile behaviour was investigated through the study of melt inclusions trapped in the phenocrysts and those of the whole rocks and the matrix glasses. The results from the 1763 eruption point to the early crystallization of olivine Fo 81.7 from a water-rich alkaline basalt, with high Cl (1750–2000 ppm) and S (2100–2400 ppm) concentrations. The hawaiitic melt inclusions trapped in olivine Fo 74, salite and plagioclase are characterized by a decrease in Cl/K2O and S/K2O ratios. In each investigated system there is good correlation between K2O and P2O5. In the whole rocks, Cl ranges from 980 to 1680 ppm, from basaltic to hawaiitic lavas, whereas S (110–136 ppm) remains low. Cl and S behaviour in the 1763 magma suggests an early degassing stage of Cl and S, with CO2 and a water-rich gaseous phase for a pressure close to 100 MPa, consistent with a permanent outgassing at the summit craters of Etna. During the eruption, the sulphur remaining in the hawaiitic liquid is lost, and the degassing of chlorine is limited. Such a degassing model can be extended to the 1865 and 1329a.d. eruptions.  相似文献   

18.
Submersible investigations along the East Rift segments, the Pito Deep and the Terevaka transform fault of the Easter microplate eastern boundary, and on a thrust-fault area of the Nazca Plate collected a variety of basalts and dolerites. The volcanics consist essentially of depleted (N-MORB), transitional (T-MORB) and enriched (E-MORB) basalts with low (0.01−0.1, < 0.7), intermediate (0.12–0.25, 0.7–1.2) and high (> 0.25, > 1.2–2) K/Ti and(La/Sm)N ratios, respectively. The Fe-Ti-rich ferrobasalt encountered among the N-MORBs are found on the Pito Deep Central volcano, on the Terevaka intra-transform ridge, on the ancient (< 2.5 Ma) Easter microplate (called EMP, comprising the East Rift Inner pseudofaults and Pito Deep west walls) and on thrust-fault crusts. The most enriched (T- and E-MORB) volcanics occur along the East Rift at 25 °50′–27 °S (called 26 °S East Rift) and on the Pito seamount located near the tip of the East Rift at 23 °00′–23 °40′S (called 23 °S East Rift). The diversity in incompatible element ratios of the basalts in relation to their structural setting suggests that the volcanics are derived from a similar heterogenous mantle which underwent variable degrees of partial melting and magma mixing. In addition the Pito seamount volcanics have undergone less crystal fractionation (< 20%) than the lavas from the other Easter microplate structures (up to 35–45%). The tectonic segmentation of the East Rift observed between 23 and 27 °S corresponds to petrological discontinuities related to Mg# variations and mantle melting conditions. The highest Mg# (> 61) are found on topographic highs (2000–2300 m) and lower values (Mg# < 56) at the extremities of the East Rift segments (2500–5600 m depths). The deepest area (5600 m) along the East Rift is located at 23 °S and coincides with a Central volcano constructed on the floor of the Pito Deep. Three major compositional variabilities of the volcanics are observed along the East Rift segments studied: (1) the 26 °S East Rift segment where the volcanics have intermediate Na8 (2.5–2.8%) and Fe8 (8.5–11%) contents; (2) the 23 °S East Rift segment (comprising Pito seamount and Pito Deep Central volcano) which shows the highest (2.9–3.4%) values of Na8 and a low (8–9%) Fe8 content; and (3) the 25 °S (at 24 °50′–26 °10′S) and the 24 °S (at 24 °10′–25 °S) East Rift segments where most of the volcanics have low to intermediate Na8 (2.6–2.0%) and a high range of Fe8 (9–13%) contents. When modeling mantle melting conditions, we observed a relative increase in the extent of partial melting and decreasing melting pressure. These localized trends are in agreement with a 3-D type diapiric upwelling in the sense postulated by Niu and Batiza (1993). Diapiric mantle upwelling and melting localized underneath the 26, 25 and 23 °S (Pito seamount and Central volcano) East Rift segments are responsable for the differences observed in the volcanics. The extent of partial melting varies from 14 to 19% in the lithosphere between 18 and 40 km deep as inferred from the calculated initial (Po=16kbar) and final melting (Pf=7kbar) pressures along the various East Rift segments. The lowest range of partial melting (14–16%) is confined to the volcanics from 23 °S East Rift segment including the Pito seamount and the Central volcano. The Thrust-fault area, and the Terevaka intra-transform show comparable mantle melting regimes to the 25 and 26 °S East Rift segments. The older lithosphere of the EMP interior is believed to have been the site of high partial melting (17–20%) confined to the deeper melting area (29–50 km). This increase in melting with increasing pressure is similar to the conditions encountered underneath the South East Pacific Rise (13–20 °S).  相似文献   

19.
Here we present the first species-specific study of boron isotopes in the epibenthic foraminifer species Cibicidoides wuellerstorfi. Coretop samples from a water depth profile from 1000 to 4500 m on the northern flank of the Walvis Ridge are 4.4‰ lower than the values expected, based on calculations of the δ11Bborate of ambient seawater. Similar values for this foraminifer species are presented from ODP site 668B at the Sierra Leone Rise, in the equatorial Atlantic. The consistency between data of the same species suggests the offsets are primary, rather than diagenetic. Glacial C. wuellerstorfi from ODP 668B and Walvis Ridge have boron isotope compositions only slightly different to interglacial samples, that is no larger than + 0.10 pH units, or + 23 µmol kg− 1 in [CO32−] above the reconstructed glacial lysocline, and − 0.07 pH units, or − 14 µmol kg− 1 in [CO32−] below. We use these results to suggest that glacial deep water pH in the Atlantic was similar to interglacial pH. The new data resolve the inconsistency between the previously reported high bottom water pH and the lack of significant carbonate preservation of the glacial deep ocean.  相似文献   

20.
Appalachian Deep Core Hole 2 (ADCOH-2) penetrated part of one of the most persistent and important tectonostratigraphic belts in the southern Appalachians—the Brevard-Chauga belt in South Carolina. The Brevard-Chauga belt is a subdivision of the Inner Piedmont and it includes the Brevard fault zone. The 307 m core contains four imbricated slices of Early Ordovician Henderson Gneiss and metasedimentary rocks of the Chauga River Formation. Aqueous (NaCl–CaCl2) inclusions and CO2–CH4-rich inclusions present in syntectonic quartz veins in the metasedimentary units, together with garnet-biotite geothermometry, provide information on the P-T conditions during uplift. Garnet-biotite geothermometry in the Brevard metasiltstone indicates a crystallization temperature of 466±52 °C, which together with published 40Ar/39Ar hornblende data from the Chauga belt, are interpreted as a Neoacadian (late Devonian) garnet crystallization age. High-density CO2-rich fluid inclusion isochores indicate a pressure of 4.5 kbar at 466±52 °C at this time. A Rb–Sr muscovite model age of 302 Ma in retrograde mylonitic Henderson Gneiss is interpreted as an Alleghanian recrystallization age. Fluid inclusions record a 2.5 kbar decompression event at this time, consistent with thrust assembly of the tectonostratigraphic units in the core.  相似文献   

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