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1.
A temporary seismological network of broadband three-component stations has been deployed N–S to investigate the crust and upper mantle structure across the Ordos Block and the Yinshan Mountains. P wave receiver functions reveal the Moho depth to be about 41 km beneath the central Ordos Block and down to 45 km beneath the northern Ordos Block, a slight uplifting to 42–43 km beneath the Hetao Graben, increasing to 47–48 km beneath the Yinshan Mountains and then decreasing to 44 km beneath the northern Yinshan Mountains along the profile. In the Ordos Block, the crustal Vp/Vs ratio (about 1.80) south to the Hetao Graben differs from that (about 1.75) beneath the center Ordos Block. The crustal Vp/Vs ratio is significantly lower (about 1.65–1.70) beneath the Yinshan Mountains. The P wave receiver function migration imaging suggests relatively flat discontinuities at 410 and 660 km, indicating the lack of a strong thermal anomaly beneath this profile at these depths, and a low S wave velocity anomaly in the upper mantle beneath the Hetao Graben. We suggest that the low S wave velocity anomaly may be attributable to heat and that the thermal softening advances the evolution of the Hetao Graben, while the lower-crustal ductile flows transfer from the Hetao Graben to the northern Ordos Block, resulting in crustal thickening.  相似文献   

2.
Most rivers in Italy are segmented by dams that need rehabilitation because of (1) safety requirements by increasingly risk-averse societies, (2) changes in the downstream river and riparian system after dams building, (3) poor initial design at the time of completion and (4) modified priorities of watershed management. Safe design of flood spillways is a major concern, and requires to cope with low frequency flood hazard. One must estimate flood figures with high return periods (R  1000–10,000 years) but statistical methods involve large uncertainties because of the short length of the available records. This paper investigates the return period of the design flood of existing spillways RS of large dams in Italy. We used re-normalized flood frequency approach and regionalization using the Generalized Extreme Value distribution. The estimation of the site specific index flood is carried out by simple scaling with basin area at the regional level. The result show that 55% (245) of the 448 examined dams are equipped by spillway with RS > 10,000; and 71% (315) of the dams have RS > 1000. Conversely, 29% (130) of the dams display RS < 1000 years, lower than acceptable hazard. The spillway of 14% (62) of the dams has RS < 100 years, indicating potential exceedance of spillways capacity. Reservoir routing may dampen the outflow hydrograph, but one should carefully account for the need of achieving accurate dam safety assessment of these dams based on site specific investigations, also accounting for global change forcing.  相似文献   

3.
The Pannonian depression is an extensional back-arc basin in central Europe and is an integral part of the Alpine–Carpathian orogenic mountain belts. It can be characterized by thinned lower crust, shallow Moho discontinuity, high surface heat flow and Moho temperature, implying recent active tectonic processes. Imaging the velocity structure of the upper mantle may help us to better understand the structure and formation of the Pannonian region.In this paper, Pn traveltimes from regional earthquakes are used to tomographically image the lateral velocity variations in the uppermost mantle beneath the Pannonian basin. The set of linear tomographic equations, built up of the time term equation for each source–receiver pair, is solved by a truncated singular value decomposition algorithm. The explicit computation of the generalized inverse of the tomographic equations makes it possible to deduce both the resolution matrix and the model covariance matrix, allowing us to estimate the resolution and reliability of the solution.The mean compressional wave velocity in the uppermost mantle beneath the Pannonian basin is 7.9 km/s, substantially lower than the average continental Pn velocity of 8.1 km/s. It is mostly due to the high Moho temperature having values on average 400–500 °C more than those in the surrounding areas. The velocity anomalies range from −0.3 to 0.3 km/s relative to the mean velocity of 7.9 km/s. Due to high Moho temperature, below the North Hungarian range low (7.6–7.7 km/s) velocities can be found. High-velocity anomalies of around 8.1 km/s can be detected along the W-SW boundaries of Hungary and at the junction of the Pannonian basin and the Southern Carpathians. The Great Hungarian Plain shows average (7.9 km/s) Pn velocities.  相似文献   

4.
Despite that discrete flow features (DFFs, e.g. fractures and faults) are common features in the subsurface, few studies have explored the influence of DFFs on solute plumes in otherwise permeable rocks (e.g. sandstone, limestone), compared to low-permeability rock settings (e.g. granite and basalt). DFFs can provide preferential flow pathways (i.e. ‘preferential flow features’; PFFs), or can act to impede flow (i.e. ‘barrier flow features’; BFFs). This research uses a simple analytical expression and numerical modelling to explore how a single DFF influences the steady-state distributions of solute plumes in permeable aquifers. The analysis quantifies the displacement and widening (or narrowing) of a steady-state solute plume as it crosses a DFF in idealised, 1 × 1 m moderately permeable rock aquifers. Previous research is extended by accounting for DFFs as 2D flow features, and including BFF situations. A range of matrix-DFF permeability ratios (0.01 to 100) and DFF apertures (0.25 mm to 2 cm), typical of sedimentary aquifers containing medium-to-large fractures, are considered. The results indicate that for the conceptual models considered here, PFFs typically have a more significant influence on plume distributions than BFFs, and the impact of DFFs on solute plumes generally increases with increasing aperture. For example, displacement of peak solute concentration caused by DFFs exceeds 20 cm in some PFF cases, compared to a maximum of 0.64 cm in BFF cases. PFFs widen plumes up to 9.7 times, compared to a maximum plume widening of 2.0 times in BFF cases. Plumes crossing a PFF are less symmetrical, and peak solute concentrations beneath PFFs are up to two orders of magnitude lower than plumes in BFF cases. This study extends current knowledge of the attenuating influence of DFFs in otherwise permeable rocks on solute plume characteristics, through evaluation of 2D flow effects in DFFs for a variety of DFF apertures, and by considering BFF situations.  相似文献   

5.
《Continental Shelf Research》2007,27(3-4):489-505
Sediment accumulation over the past century on the continental shelf near the Po delta varies with distance from the most active distributary channels. Near the Pila and Goro distributaries, sediment accumulation is rapid (1–4 cm yr−1) and occurs in pulses. In these areas, the seabed is dominated by physical sedimentary structures that can be related to flood sedimentation. Between the two distributaries and in the southern portion of the dispersal system, sediment accumulation is slower (rates reach a minimum of 0.23 cm yr−1 at ∼50 km from the Pila mouth) and steady-state, reflecting more continuous dispersal of sediment during non-flood periods. Sedimentary strata in these locations are composed of finer (clayey silt), mottled sediment. The similarity in the spatial distribution of long-term (100-yr) sediment accumulation to deposition resulting from the 2000 flood event suggests that the Po shelf is flood-dominated.About half of the sediment delivered by the Po River on a 100-yr time scale can be accounted for in the seabed deposit within ∼50 km of the Pila mouth. The remaining sediment is likely transported southward by the prevailing circulation, and this sediment coalesces with inputs from the Apennine Rivers.  相似文献   

6.
The basic characteristics of the global distribution for the corona plasma and magnetic field near 2.5 Rs are analyzed with the statistical and numerical methods for 136 Carrington Rotations (CRs) covering four different phases of solar activity. By using the observational data and the velocity distribution model in the corona, the statistical average distribution of the magnetic field, density and the coronal mass outputs are analyzed for the four different phases. Then, a numerical study of the global distribution near 2.5 Rs has been made by solving a self-consistent MHD system. Finally, the solar wind speed at 1 AU is given by mapping the speed at 2.5 Rs to that near 1 AU, and the comparison of the numerical results with the observational measurements and the simulation result of the Wang–Sheeley–Arge (WSA) model are made during more than 5 years. The numerical results indicate that the global distributions on the source surface of 2.5 Rs at different phases of solar activity could be used to predict the change of the solar wind in interplanetary space.  相似文献   

7.
We performed measurements using an SO2 imaging camera of the SO2 gas mass emitted during five discrete explosive events on Stromboli volcano on 3 October 2006. The SO2 gas mass released during discrete explosions was 15–40 kg per explosion, producing 3–8% of the total daily SO2 gas emission, demonstrating that in terms of gas flux Strombolian explosions are a second-order phenomenon compared with quiescent degassing. Using the typical gas composition measured with OP-FTIR allows us to determine the total gas mass released during an explosion as 360–960 kg with a volume of 1500–4100 m3 at 1 bar. At the probable source pressure of gas slug formation of 75 MPa this gas amount would occupy a volume equivalent to a sphere with a radius of 0.8–1 m, comparable with estimates of Stromboli's conduit geometry.  相似文献   

8.
This study examines the recent evolution of the Greenland ice sheet and its six major drainage basins. Based on laser altimetry data acquired by the Ice, Cloud and Land Elevation Satellite (ICESat), covering the period September–November 2003 to February–March 2008, ice surface height changes and their temporal variations were inferred. Our refined repeat track analysis is solely based on ICESat data and is independent of external elevation models, since it accounts for both ice height changes and the local topography. From the high resolution ice height change pattern we infer an overall mean surface height trend of −0.12 ± 0.006 m yr−1. Furthermore, the largest changes could be identified at coastal margins of the ice sheet, exhibiting rates of more than −2 m yr−1. The total ice volume change of the entire ice sheet amounts to −205.4 ± 10.6 km3 yr−1. In addition, we assessed mass changes from 78 monthly Gravity Recovery and Climate Experiment (GRACE) solutions. The Release-04 gravity field solutions of GeoForschungsZentrum Potsdam cover the period between August 2002 and June 2009. We applied an adjusted regional integration approach in order to minimize the leakage effects. Attention was paid to an optimized filtering which reduces error effects from different sources. The overall error assessment accounts for GRACE errors as well as for errors due to imperfect model reductions. In particular, errors caused by uncertainties in the glacial isostatic adjustment models could be identified as the largest source of errors. Finally, we determined both seasonal and long-term mass change rates. The latter amounts to an overall ice mass change of −191.2 ± 20.9 Gt yr−1 corresponding to 0.53 ± 0.06 mm yr−1 equivalent eustatic sea level rise. From the combination of the volume and mass change estimates we determined a mean density of the lost mass to be 930 ± 11 kg m−3. This value supports our applied density assumption 900 ± 30 kg m−3 which was used to perform the volume–mass-conversion of our ICESat results. Hence, mass change estimates from two independent observation techniques were inferred and are generally in good agreement.  相似文献   

9.
The Late Permian (260 Ma) Emeishan large igneous province of SW China contains numerous magmatic Fe–Ti oxide deposits. The Fe–Ti oxide deposits occur in the lower parts of evolved layered gabbroic intrusions which are spatially and temporally associated with A-type granitic rocks. The 260 Ma Panzhihua layered gabbroic intrusion hosts one of the largest magmatic Fe–Ti oxide deposits in China and is coeval with a peralkaline A-type granitic pluton. The granite has intruded the overlying Emeishan flood basalts and fed at least one dyke which erupted onto the surface producing columnar jointed trachytes. The presence of syenodiorite between the layered gabbro and granite is evidence for compositional evolution from mafic to intermediate to felsic rocks. The syenodiorites have intermediate to felsic composition with SiO2 = 61 to 65 wt.%, MgO = 0.27 to 0.6 wt.% and CaO = 1.0 to 2.5 wt.% as compared to the granite SiO2 = 65 to 72 wt.%, MgO = 0.1 to 0.4 wt.%, CaO = < 1.0 wt.%. Primitive-mantle-normalized incompatible element plots show corresponding reciprocal patterns between the mafic and felsic rocks. The chondrite-normalized REE patterns show Eu anomalies changing from > 1(Eu/Eu? = 1.1 to 2.6) in the gabbroic intrusion, to < 1 in the syenodiorite (Eu/Eu? = 0.75 to 0.83), granites and trachytes (Eu/Eu? = 0.55–0.87). Previously published εNd(T) values from clinopyroxenes (εNd(T) = + 1.1 to + 3.2) of the gabbroic intrusion match the whole-rock values of the syenodiorite (εNd(T) = + 2.1 to + 2.5), granite and trachyte (εNd(T) = + 2.2 to + 2.9), suggesting that all rock types originated from the same mantle source. MELTS and trace element modeling confirm that all rock types can be generated by fractional crystallization of high-Ti Emeishan basalt. The jump in SiO2 from the gabbro to the syenodiorite is attributed to the en masse crystallization of the Fe–Ti oxides. The geological and geochemical data indicate that fractional crystallization of a common parental magma produced the layered gabbroic intrusion and Fe–Ti oxide deposit, the syenodiorite, granites and trachyte of the Panzhihua region, which thus form a genetically related plutonic-hypabyssal-volcanic complex. Other granite–gabbro complexes in the region likely formed in a similar manner.  相似文献   

10.
The combined use of Lu–Hf and Sm–Nd isotope systems potentially offers a unique perspective for investigating continental erosion, but little is known about whether, and to what extent, the Hf–Nd isotope composition of sediments is related to silicate weathering intensity. In this study, Hf and Nd elemental and isotope data are reported for marine muds, leached Fe-oxide fractions and zircon-rich turbidite sands collected off the Congo River mouth, and from other parts of the SE Atlantic Ocean. All studied samples from the Congo fan (muds, Fe-hydroxides, sands) exhibit indistinguishable Nd isotopic composition (εNd ~ ? 16), indicating that Fe-hydroxides leached from these sediments correspond to continental oxides precipitated within the Congo basin. In marked contrast, Hf isotope compositions for the same samples exhibit significant variations. Leached Fe-hydroxide fractions are characterized by εHf values (from ? 1.1 to + 1.3) far more radiogenic than associated sediments (from ? 7.1 to ? 12.0) and turbidite sands (from ? 27.2 to ? 31.6). εHf values for Congo fan sediments correlate very well with Al/K (i.e. a well-known index for the intensity of chemical weathering in Central Africa). Taken together, these results indicate that (1) silicate weathering on continents leads to erosion products having very distinctive Hf isotope signatures, and (2) a direct relationship exists between εHf of secondary clay minerals and chemical weathering intensity.These results combined with data from the literature have global implications for understanding the Hf–Nd isotope variability in marine precipitates and sediments. Leached Fe-hydroxides from Congo fan sediments plot remarkably well on an extension of the ‘seawater array’ (i.e. the correlation defined by deep-sea Fe–Mn precipitates), providing additional support to the suggestion that the ocean Hf budget is dominated by continental inputs. Fine-grained sediments define a diffuse trend, between that for igneous rocks and the ‘seawater array’, which we refer to as the ‘zircon-free sediment array’ (εHf = 0.91 εNd + 3.10). Finally, we show that the Hf–Nd arrays for seawater, unweathered igneous rocks, zircon-free and zircon-bearing sediments (εHf = 1.80 εNd + 2.35) can all be reconciled, using Monte Carlo simulations, with a simple weathering model of the continental crust.  相似文献   

11.
《Continental Shelf Research》2007,27(10-11):1408-1421
Particle size distribution and size-specific settling velocity are critical parameters for understanding the transport of fine sediment on continental margins. In this study, observed floc size versus settling velocity, volume distributions of particles 2 μm–1 cm in diameter, and calculated effective densities for all particle sizes provided estimates of the mass distribution in suspension, which is used to apportion mass among component particles, microflocs, and macroflocs. Measurements were made during relatively quiescent environmental conditions. Observations of size distributions based on mass demonstrate an increase in the component particle fraction through time. The increase in the percentage of component particles in suspension had implications on water column properties, as small changes in the component particle fraction affected water column optical transmission in a way that was not as easily detected by changes in the volume concentration distribution or total mass concentration. Flocs larger than 133 μm in diameter only comprised one quarter to one third of the mass in suspension. This finding may explain why suspension bulk clearance rates are often an order of magnitude lower than those predicted by other methods.  相似文献   

12.
Inversion of local earthquake travel times and joint inversion of receiver functions and Rayleigh wave group velocity measurements were used to derive a simple model for the velocity crustal structure beneath the southern edge of the Central Alborz (Iran), including the seismically active area around the megacity of Tehran. The P and S travel times from 115 well-located earthquakes recorded by a dense local seismic network, operated from June to November 2006, were inverted to determine a 1D velocity model of the upper crust. The limited range of earthquake depths (between 2 km and 26 km) prevents us determining any velocity interfaces deeper than 25 km. The velocity of the lower crust and the depth of the Moho were found by joint inversion of receiver functions and Rayleigh wave group velocity data. The resulting P-wave velocity model comprises an upper crust with 3 km and 4 km thick sedimentary layers with P wave velocities (Vp) of ~5.4 and ~5.8 km s?1, respectively, above 9 km and 8 km thick layers of upper crystalline crust (Vp ~6.1 and ~6.25 km s?1 respectively). The lower crystalline crust is ~34 km thick (Vp  6.40 km s?1). The total crustal thickness beneath this part of the Central Alborz is 58 ± 2 km.  相似文献   

13.
Electrical conductivity and seismic velocity are studied for plausible pore geometries in the Earth's interior for reliable quantitative analysis of experimental data such as seismic tomography and magnetotelluric explorations. Electrical conductivity of a two-phase system with equilibrium, interfacial energy-controlled phase geometry is calculated for the dihedral angles θ = 40°–100° that are typical for rock–aqueous fluid and θ = 20°–60° for rock–melt systems of lower crust and upper mantle for the case of tetrakaidecahedral grains. Electrical conductivity vs. seismic velocity correlations are acquired by combining of the simulated electrical conductivities with the seismic velocity calculated with the help of equilibrium geometry model Takei [Takei, Y., Effect of pore geometry on VP/VS: From equilibrium geometry to crack. J. Geophys. Res. 107 (2002): 10.1029/2001JB000522.] for the same pore geometries. The results show that electrical conductivity gradually decreases reaching zero when seismic velocities reach seismic velocities of intact rock for rock–melt systems, while for rock–aqueous fluid systems with θ  60° conductivity drops to zero at velocities up to 10% smaller. This can explain the seeming discrepancy of the low seismic velocity region, attributed to the high fluid fraction, and the low electrical conductivity of the same region, which is sometimes faced at collocated electromagnetic and seismic experiments.  相似文献   

14.
《Advances in water resources》2005,28(11):1230-1239
Taylor’s hypothesis (TH) for rainfall fields states that the spatial correlation of rainfall intensity at two points at the same instant of time can be equated with the temporal correlation at two instants of time at some fixed location. The validity of TH is tested in a set of 12 storms developed in Rondonia, southwestern Amazonia, Brazil, during the January–February 1999 Wet Season Atmospheric Meso-scale Campaign. The time Eulerian and Lagrangian Autocorrelation Functions (ACF) are estimated, as well as the time-averaged space ACF, using radar rainfall rates of storms spanning between 3.2 and 23 h, measured at 7–10-min time resolution, over a circle of 100 km radius, at 2 km spatial resolution. TH does not hold in 9 out of the 12 studied storms, due to their erratic trajectories and very low values of zonal wind velocity at 700 hPa, independently from underlying atmospheric stability conditions. TH was shown to hold for 3 storms, up to a cutoff time scale of 10–15 min, which is closely related to observed features of the life cycle of convective cells in the region. Such cutoff time scale in Amazonian storms is much shorter than the 40 min identified in mid-latitude convective storms, due to much higher values of CAPE and smaller values of storm speed in Amazonian storms as compared to mid-latitude ones, which in turn contribute to a faster destruction of the rainfall field isotropy. Storms satisfying TH undergo smooth linear trajectories over space, and exhibit the highest negative values of maximum, mean and minimum zonal wind velocity at 700 hPa, within narrow ranges of atmospheric stability conditions. Non-dimensional parameters involving CAPE (maximum, mean and minimum) and CINE (mean) are identified during the storms life cycle, for which TH holds: CAPE mean/CINE mean = [30–35], CAPE max/CINE mean = [32–40], and CAPE min/CINE mean = [22–28]. These findings are independent upon the timing of storms within the diurnal cycle. Also, the estimated Eulerian time ACF’s decay faster than the time-averaged space and the Lagrangian time ACF’s, irrespectively of TH validity. The Eulerian ACF’s exhibit shorter e-folding times, reflecting smaller correlations over short time scales, but also shorter scale of fluctuation, reflecting less persistence in time than over space. No significant associations (linear, exponential or power law) were found between estimated e-folding times and scale of fluctuation, with all estimates of CAPE and CINE. Secondary correlation maxima appear between 50 and 70 min in the Lagrangian time ACF’s for storms satisfying TH. No differences were found in the behavior of each of the three ACF’s for storms developed during either the Easterly or Westerly zonal wind regimes which characterize the development of meso-scale convective systems over the region. These results have important implications for modelling and downscaling rainfall fields over tropical land areas.  相似文献   

15.
Siberian gas venting and the end-Permian environmental crisis   总被引:1,自引:0,他引:1  
The end of the Permian period is marked by global warming and the biggest known mass extinction on Earth. The crisis is commonly attributed to the formation of the Siberian Traps Large Igneous Province although the causal mechanisms remain disputed. We show that heating of Tunguska Basin sediments by the ascending magma played a key role in triggering the crisis. Our conclusions are based on extensive field work in Siberia in 2004 and 2006. Heating of organic-rich shale and petroleum bearing evaporites around sill intrusions led to greenhouse gas and halocarbon generation in sufficient volumes to cause global warming and atmospheric ozone depletion. Basin scale gas production potential estimates show that metamorphism of organic matter and petroleum could have generated > 100,000 Gt CO2. The gases were released to the end-Permian atmosphere partly through spectacular pipe structures with kilometre-sized craters. Dating of a sill intrusion by the U–Pb method shows that the gas release occurred at 252.0 ± 0.4 million years ago, overlapping in time with the end-Permian global warming and mass extinction. Heating experiments to 275 °C on petroleum-bearing rock salt from Siberia suggests that methyl chloride and methyl bromide were significant components of the erupted gases. The results indicate that global warming and ozone depletion were the two main drivers for the end-Permian environmental crisis. We demonstrate that the composition of the heated sedimentary rocks below the flood basalts is the most important factor in controlling whether a Large Igneous Provinces causes an environmental crisis or not. We propose that a similar mechanism could have been responsible for the Triassic-Jurassic (~ 200 Ma) global warming and mass extinction, based on the presence of thick sill intrusions in the evaporite deposits of the Amazon Basin in Brazil.  相似文献   

16.
Experimental measurements of fracture-induced seismic waves velocity variations at frequencies ~ 1 kHz, ~ 40 kHz and ~ 1 MHz were performed directly in the field at the rocky outcrop and in the laboratory on specific rock samples collected from the outcrops. The peridotite–lherzolite outcrop appeared macroscopically uniform and contained three systems of visible parallel sub-vertical fractures. This rock has substantial bulk density and higher than average value of seismic wave velocity. The presence of fracture systems gives rise to its velocity anisotropy. The seismic waves passing through the rock fractures are subject to velocity dispersion and frequency dependent attenuation. Our data, obtained from field and laboratory measurements, were compared with theoretical model predictions. In this model we successfully used displacement discontinuity approach. For the velocity dispersion evaluation we used multi-frequency measurements. The a priori observation of orientations and densities of fracture sets allowed evaluation of their stiffness. Our approach revealed that the first arrivals of seismic waves can be used for evaluation of P-wave group velocities, the specific case, in which we expect anomalous velocity dispersion. Our observations contribute to the issue of up-scaling of well-log derived velocities in fractured rock to the scale of standard seismic exploration frequencies.  相似文献   

17.
40Ar / 39Ar incremental heating ages for twenty one grains of cryptomelane, collected at 0, 42, 45, and 60 m depths in the Cachoeira Mine weathering profile, Minas Gerais, permit calculating long-term (10 Ma time scale) weathering rate (saprolitization rate) in SE Brazil. Pure well-crystallized cryptomelane grains with high K contents (3–5 wt.%) yield reliable geochronological results. The 40Ar / 39Ar plateau ages obtained decrease from the top to the bottom of the profile (12.7 ± 0.1 to 7.6 ± 0.1 Ma at surface; 7.6  ± 0.2 to 6.1 ± 0.2 Ma at 42 m; and 7.1 ± 0.2 to 5.9 ± 0.1 Ma at 45 m; 6.6 ± 0.1 to 5.2 ± 0.1 Ma at 60 m), yielding a weathering front propagation rate of 8.9 ± 1.1 m/m.y. From the geochronological results and the mineral transformations implicit by the current mineralogy in the weathering profiles, it is possible to calculate the saprolitization rate for the Cachoeira Mine lithologies and for adjacent weathering profiles developed on granodiorites and schists. The measured weathering front propagation rate yields a saprolitization rate of 24.9 ± 3.1 t/km2/yr. This average long-term (> 10 Ma) saprolitization rate is consistent with mass balance calculations results for present saprolitization rates in weathering watersheds. These results are also consistent with long-term saprolitization rates estimated by combining cosmogenic isotope denudation rates with mass balance calculations.  相似文献   

18.
Os–Hf–Sr–Nd isotopes and PGE were determined in peridotite xenoliths carried to the surface by Quaternary alkali basaltic magmas in the Tokinsky Stanovik Range on the Aldan shield. These data constrain the timing and nature of partial melting and metasomatism in the lithospheric mantle beneath SE Siberian craton. The xenoliths range from the rare fertile spinel lherzolites to the more abundant, strongly metasomatised olivine-rich (70–84%) rocks. Hf–Sr–Nd isotope compositions of the xenoliths are mainly within the fields of oceanic basalts. Most metasomatised xenoliths have lower 143Nd / 144Nd and 176Hf / 177Hf and higher 87Sr / 86Sr than the host basalts indicating that the metasomatism is older and has distinct sources. A few xenoliths have elevated 176Hf / 177Hf (up to 0.2838) and plot above the Hf–Nd mantle array defined by oceanic basalts.187Os / 188Os in the poorly metasomatised, fertile to moderately refractory (Al2O3  1.6%) Tok peridotites range from 0.1156 to 0.1282, with oldest rhenium depletion ages being about 2 Ga. The 187Os / 188Os in these rocks show good correlations with partial melting indices (e.g. Al2O3, modal cpx); the intercept of the Al–187Os / 188Os correlation with lowest Al2O3 estimates for melting residues (∼0.3–0.5%) has a 187Os / 188Os of ∼0.109 suggesting that these peridotites may have experienced melt extraction as early as 2.8 Gy ago. 187Os / 188Os in the strongly metasomatised, olivine-rich xenoliths (0.6–1.3% Al2O3) ranges from 0.1164 to 0.1275 and shows no apparent links to modal or chemical compositions. Convex-upward REE patterns and high abundances of heavy to middle REE in these refractory rocks indicate equilibration with evolved silicate melts at high melt / rock ratios, which may have also variably elevated their 187Os / 188Os. This inference is supported by enrichments in Pd and Pt on chondrite-normalised PGE abundance patterns in some of the rocks. The melt extraction ages for the Tok suite of 2.0 to 2.8 Ga are younger than oldest Os ages reported for central Siberian craton, but they must be considered minimum estimates because of the extensive metasomatism of the most refractory Tok peridotites. This metasomatism could have occurred in the late Mesozoic to early Cenozoic when the Tok region was close to the subduction-related Pacific margin of Siberia and experienced large-scale tectonic and magmatic activity. This study indicates that metasomatic effects on the Re–Os system in the shallow lithospheric mantle can be dramatic.  相似文献   

19.
This study was conducted to determine the vertical and horizontal distribution of selected metals and magnetic susceptibility (χlf) in an industrial site located in Isfahan province, central Iran. For this purpose, we used a grid sampling methodology and excavated 202 profiles. Soil samples were then collected from 0–30, 60–90, and 120–150 cm depths. The mass magnetic susceptibility (χ) of the soil samples was measured at both low and high frequencies (χlf and χhf) using the Bartington MS2 dual frequency sensor; and χfd was also calculated. Soil samples were also analyzed for iron (Fe), manganese (Mn), lead (Pb), zinc (Zn), copper (Cu), nickel (Ni), chromium (Cr) and cobalt (Co) concentrations. The results showed that there were positive significant correlations among selected metals including Zn, Pb, Fe and Mn, which were mainly added through coal fly ash from an iron smelting factory at the studied site, while the concentration of Ni, Cr and Co was mainly controlled by the parent material of the soils. The trends in results at the site of study were similar in vertical and horizontal distribution for the industrial originated metals as judged by pollution load index (PLI) using χlf. The results of SEM/EDX also confirmed the presence of spheroid of magnetic particles in the surface soil samples taken in close proximity of the factory. Based on the results using the contamination factors (CF) determined for selected metals, the following order was observed: Pb > Zn > Mn > Fe > Cu > Ni  Co > Cr. The results also suggested that magnetic methods could be used to estimate the metal contamination from anthropogenic sources in industrial soils.  相似文献   

20.
New geochemical and isotopic data are presented from the oldest part of the Cumbre Vieja volcano, La Palma (Canary Islands), located near the assumed emergence of the Canary mantle plume. The volcanics comprise a suite dominated by basanite flows with subordinate amounts of phono-tephrite, tephri-phonolite and phonolite flows and intrusives. Two compositionally different basanite groups have been identified, both with HIMU (high-μ)-type incompatible trace element characteristics: Primitive high-MgO basanites (10.7–12.1% MgO), found only at the base of a stratigraphic profile near Fuencaliente on the south coast, and intermediate-MgO basanites (6.0–7.3% MgO), exposed in the upper part of the profile and widespread on the east coast of La Palma. The high-MgO basanites are interpreted as near-primary mantle melts (primary composition 14–15% MgO) derived by progressive melting (2.9% to 4.5%) of a common lithospheric mantle source. Model calculations indicate that it is not possible to generate the intermediate-MgO basanites from the high-MgO group by crystal fractionation of observed phenocrysts. Relative to intermediate-MgO basanites, the high-MgO flows have lower concentrations of LIL and HFS elements, except for Ti, which is markedly enriched in the primitive rocks (3.7–4.7% TiO2 vs 3.4–3.9% TiO2). Fuencaliente volcanics display limited temporal isotopic variations suggested to be a result of mixing of melts originating from the rising plume and the metazomatized lithospheric mantle. 87Sr / 86Sr and 143Nd / 144Nd ratios range 0.70305–0.70311 and 0.51285–0.51291, respectively, while the corresponding ranges in Pb-isotope ratios are 206Pb / 204Pb = 19.46–19.64, 207Pb / 204Pb = 15.55–15.61, and 208Pb / 204Pb = 39.16–39.53. The overall variation of the Cumbre Vieja isotopic data can be accounted for by mixtures of three mantle components in the proportions 72–79% plume source (LVC = low velocity component), 9–16% depleted mantle (DM) and up to 12% enriched mantle (EMI). Negative Δ7 / 4 Pb (− 0.6 to − 5.4) in the Cumbre Vieja volcanics suggest derivation from a young HIMU mantle source. The relative abundance of plume source material increase in younger rocks in the Fuencaliente section, suggesting waning plume–lithosphere interaction during the emplacement of this part of the Cumbre Vieja volcano. The high-MgO volcanics define regular and systematic geochemical trends, interpreted as partial melting trends, when plotted against abundances of highly incompatible elements (P, Ce). Evaluation of minor and trace element variation in consecutive melts suggests control by residual amphibole, phlogopite, garnet and a Ti-bearing phase, possibly ilmenite. The melting mode changed gradually, allowing increasing input from residual phlogopite during partial melting. The residual mineralogy constrains the source region of the high-MgO basanites to the lowermost oceanic lithospheric mantle, presumably around 100 km depths.  相似文献   

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