OH incorporation in nearly pure MgAl₂O₄ natural and synthetic spinels     

Davide Lenaz  Henrik Skogby  Francesco Princivalle 《Geochimica et cosmochimica acta》2008,72(2):475-479

Four nearly pure MgAl₂O₄ spinels, of both natural and synthetic occurrence, have been studied by means of X-ray single crystal diffraction and FTIR spectroscopy in order to detect their potential OH content. Absorption bands that can be assigned to OH incorporated in the spinel structure were only observed in spectra of a non-stoichiometric synthetic sample. The absorption intensity of two bands occurring at 3350 and 3548 cm⁻¹ indicate an OH content of 90 ppm H₂O. Based on correlations of OH vibrational frequencies and O-H?O distances, the observed absorption bands correspond to O-H?O distances of 2.77 and 2.99 Å, respectively, which is close to the values obtained by the structure refinements for ^VIO-O_unsh (2.825 Å) and ^IVO-O (3.001 Å). This indicates that one probable local position for hydrogen incorporation is the oxygens coordinating a vacant tetrahedral site. The present spectra demonstrate that the detection limit for OH in Fe-free spinels is in the range 10-20 ppm H₂O. However, at appreciable Fe²⁺ levels, the detection of OH bands becomes hampered due to overlap with strong absorption bands caused by electronic d-d transitions in Fe²⁺ in the tetrahedral position.  相似文献   

A meta-analysis of the status of ICES fish stocks during the past half century   总被引：2，自引：0，他引：2  

Sparholt  Henrik; Bertelsen  Mette; Lassen  Hans 《ICES Journal of Marine Science》2007,64(4):707-713

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Mud and fluid migration in active mud volcanoes in Azerbaijan   总被引：7，自引：2，他引：7  

S. Planke  H. Svensen  M. Hovland  D. A. Banks  B. Jamtveit 《Geo-Marine Letters》2003,23(3-4):258-268

Mud volcanic eruptions in Azerbaijan normally last for less than a few hours, and are characterized by vigorous extrusion of mud breccias, hydrocarbon gases, and waters. Recent fieldwork and mapping on four active mud volcanoes show that dormant period activity ranges from quiet to vigorous flow of mud and fluids. Geochemical analyses of expelled waters show a wide range in solute concentrations, suggesting the existence of a complex plumbing system. The mud and fluids have a deep origin, but are sometimes stored in intermediate-depth mud chambers. A mixing model between deep-seated saline waters and shallow meteoric water is proposed.  相似文献   

Using size-based indicators to evaluate the ecosystem effects of fishing   总被引：12，自引：9，他引：12  

Shin  Yunne-Jai; Rochet  Marie-Joelle; Jennings  Simon; Field  John G.; Gislason  Henrik 《ICES Journal of Marine Science》2005,62(3):384-396

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Regional variation in maturation of sandeels in the North Sea   总被引：1，自引：0，他引：1  

Boulcott  Philip; Wright  Peter J.; Gibb  Fiona M.; Jensen  Henrik; Gibb  Iain M. 《ICES Journal of Marine Science》2007,64(2):369-376

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Plankton distribution and vertical flux of biogenic matter during high summer stratification in the Krka estuary (Eastern Adriatic)     

C. Svensen  D. Vili i&#x;  P. Wassmann  E. Arashkevich  T. Ratkova 《Estuarine, Coastal and Shelf Science》2007,71(3-4):381-390

The aim of this study was to investigate phytoplankton abundance, composition and vertical export in the highly stratified Krka estuary, Croatia. The estuary is stratified throughout the year, and an interface between fresh- and brackish water plays an important role in production and degradation of biogenic matter. Vertical export of particulate organic carbon (POC), phytoplankton carbon (PPC) and faecal pellet carbon (FPC) was studied by deploying sediment traps in the middle and lower reach of the estuary and in the adjacent coastal zone. Zooplankton faecal pellet (FP) production experiments were conducted to provide additional information on the potential contribution of FP to the total carbon flux. High suspended concentrations of POC, chlorophyll a and phytoplankton was found in the lower reaches of the Krka estuary, adjacent to a source of anthropogenic eutrophication. The fraction of organic detritus to the total POC flux was 61–69% inside the estuary but only 7% at the marine station. This indicates that the primary producers in the surface layer of the Krka estuary are decomposed in and below the interface and then settle as detritus to the bottom. Low sedimentation rates in the coastal zone outside the estuary revealed that the eutrophication does not spread out of the estuary. Mesozooplankton played a modest role in vertical flux regulation, due to their low abundance and dominance of smaller forms as well as low faecal pellet production rates. It is concluded that processes taking place at the freshwater-seawater interface are of major importance for the vertical carbon flux in the investigated area.  相似文献   

The petroleum generation potential and effective oil window of humic coals related to coal composition and age   总被引：1，自引：0，他引：1  

Henrik I. Petersen   《International Journal of Coal Geology》2006,67(4):221-248

A worldwide data set of more than 500 humic coals from the major coal-forming geological periods has been used to analyse the evolution in the remaining (Hydrogen Index, HI) and total (Quality Index, QI) generation potentials with increasing thermal maturity and the ‘effective oil window’ (‘oil expulsion window’). All samples describe HI and QI bands that are broad at low maturities and that gradually narrow with increasing maturity. The oil generation potential is completely exhausted at a vitrinite reflectance of 2.0–2.2%R_o or T_max of 500–510 °C. The initial large variation in the generation potential is related to the original depositional conditions, particularly the degree of marine influence and the formation of hydrogen-enriched vitrinite, as suggested by increased sulphur and hydrogen contents. During initial thermal maturation the HI increases to a maximum value, HI_max. Similarly, QI increases to a maximum value, QI_max. This increase in HI and QI is related to the formation of an additional generation potential in the coal structure. The decline in QI with further maturation is indicating onset of initial oil expulsion, which precedes efficient expulsion. Liquid petroleum generation from humic coals is thus a complex, three-phase process: (i) onset of petroleum generation, (ii) petroleum build-up in the coal, and (iii) initial oil expulsion followed by efficient oil expulsion (corresponding to the effective oil window). Efficient oil expulsion is indicated by a decline in the Bitumen Index (BI) when plotted against vitrinite reflectance or T_max. This means that in humic coals the vitrinite reflectance or T_max values at which onset of petroleum generation occurs cannot be used to establish the start of the effective oil window. The start of the effective oil window occurs within the vitrinite reflectance range 0.85–1.05%R_o or T_max range 440–455 °C and the oil window extends to 1.5–2.0%R_o or 470–510 °C. For general use, an effective oil window is proposed to occur from 0.85 to 1.7%R_o or from 440 to 490 °C. Specific ranges for HI_max and the effective oil window can be defined for Cenozoic, Jurassic, Permian, and Carboniferous coals. Cenozoic coals reach the highest HI_max values (220–370 mg HC/g TOC), and for the most oil-prone Cenozoic coals the effective oil window may possibly range from 0.65 to 2.0%R_o or 430 to 510 °C. In contrast, the most oil-prone Jurassic, Permian and Carboniferous coals reach the expulsion threshold at a vitrinite reflectance of 0.85–0.9%R_o or T_max of 440–445 °C.  相似文献   

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis   总被引：8，自引：0，他引：8  

Lisbeth M. Ottosen  Anne J. Pedersen  Alexandra B. Ribeiro  Henrik K. Hansen 《Engineering Geology》2005,77(3-4):317-329

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.  相似文献   

Climatic and societal impacts of a volcanic double event at the dawn of the Middle Ages     

Matthew Toohey  Kirstin Krüger  Michael Sigl  Frode Stordal  Henrik Svensen 《Climatic change》2016,136(3-4):401-412

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Thermally induced cation redistribution in Fe-bearing oxy-dravite and potential geothermometric implications     

Ferdinando Bosi  Henrik Skogby  Ulf Hålenius 《Contributions to Mineralogy and Petrology》2016,171(5):47

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