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城市地区大气气溶胶颗粒的物理化学特性复杂,理清单颗粒精细的化学成分和混合状态对于大气污染溯源和精细治理具有重要意义。本研究利用被动式气溶胶采样器分别在山东省日照市城区和钢铁园区两个区域进行了定点采样,并利用智能扫描电镜环境颗粒物分析系统（IntelliSEM EPAS）对采集的大气单颗粒物样品进行分析。结果表明,日照市大气颗粒物主要由不规则碳质颗粒（C-rich）、含硫颗粒（Ca-S、Na-S-Ca）与矿物颗粒组成。其中,城区样品中C-rich颗粒数量贡献为53.5%,是钢铁园区样品的2.5倍,大于1 μm的颗粒物数量为9.0%,是钢铁园区样品的1.7倍,城区居民活动和工业过程是城市中大气颗粒物特别是二次细颗粒的主要来源。钢铁园区样品中含硫颗粒物数量贡献为72.9%,含硫颗粒物质量贡献为30.9%,富铁颗粒物质量贡献为5.3%,分别是城区样品的1.8倍、3.6倍和2.9倍,表明钢铁园区大气颗粒物的主要来源包括钢铁企业排放的一次污染物及其转化生成的二次细颗粒物。 相似文献
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大气气溶胶研究的前沿问题 总被引：60，自引：3，他引：57
从4个方面对大气气溶胶研究的前沿问题作了总结和分析：气溶胶的基本特征、气溶胶的气候效应、沙尘气溶胶以及气溶胶对健康环境的影响。介绍了当前国际上有关的大气气溶胶研究计划,讨论了未来大气气溶胶研究的主要领域及研究方向。 相似文献
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基于对植物生长季大气水汽氢氧稳定同位素组成(δ~(18)O、δD)的原位连续观测数据,研究了青海湖高寒湿地生态系统大气水汽氢氧稳定同位素特征以及大气水汽δ~(18)O与主要环境因子的相关关系。结果显示:大气水汽中δ~(18)O和δD在0.5 m和1.5 m以及0.9 m和1.9 m之间差异性都很小,且季节变化趋势都表现为生长季中期低,前期和后期高。降水量、温度、相对湿度、蒸散和净辐射都是影响大气水汽δ~(18)O变化的重要环境因子,且各环境因子之间存在相互联系协同作用的关系。受研究区环境因子、大气水汽来源以及青海湖蒸发水汽的影响,表征当地大气水汽δ~(18)O和δD相关关系的大气水汽线方程MVL偏离全球大气降水线方程GMWL。 相似文献
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城市热岛效应研究概况 总被引：3，自引：0，他引：3
随着我国城市化进程的不断加快,城市中的环境污染问题也日益严重,表现为城市比周围非城市化地区的地表和大气温度要高的热岛效应作为这些环境问题中的典型代表有着重要的研究意义。近几十年来国内外的有关专家从微观及宏观层面上对城市热岛效应的产生原因、造成影响、变化规律、缓解措施等方面进行了一系列的研究与探索。由于城市测点有限,过去的研究尚不能全面反映出研究区热岛效应。遥感科学和技术的发展,为城市热岛效应的研究提供了有利条件。本文介绍了热红外遥感技术在热岛研究中的应用及城市规划对城市热岛效应的影响,并展望了该领域的发展前景。 相似文献
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城市热岛效应研究概况 总被引：5，自引：1，他引：4
随着我国城市化进程的不断加快,城市中的环境污染问题也日益严重,表现为城市比周围非城市化地区的地表和大气温度要高的热岛效应作为这些环境问题中的典型代表有着重要的研究意义。近几十年来国内外的有关专家从微观及宏观层面上对城市热岛效应的产生原因、造成影响、变化规律、缓解措施等方面进行了一系列的研究与探索。由于城市测点有限,过去的研究尚不能全面反映出研究区热岛效应。遥感科学和技术的发展,为城市热岛效应的研究提供了有利条件。本文介绍了热红外遥感技术在热岛研究中的应用及城市规划对城市热岛效应的影响,并展望了该领域的发展前景。 相似文献
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大气输送的环境背景场 总被引：14，自引：0，他引：14
根据环境管理和控制观点提出大气环境质量属于资源。欲解决在哪些地方开发环境资源有可能得到最大和最长久的持续发展,在哪些地方是开发利用和环境保护相结合的地区,采用环境背景场研究是比较适宜的途径。为此,提出大气环境背景场的网络矩阵输送模型并利用我国大量历史资料制作出全年各季我国大气输送的环境背景场图。根据这些成果对我国各类输送型输送计算方法及各地区大气输送的环境资源背景场的影响进行了分析。 相似文献
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CE318太阳光度计基本结构与安装使用 总被引：1，自引：0，他引：1
CE31 8自动跟踪太阳光度计是由法国CIMEL公司研制生产、用于气溶胶光学特性和大气质量监测的自动测量仪器 ,它不仅能自动跟踪太阳作太阳直射辐射测量 ,而且可以进行太阳等高度角天空扫描、太阳主平面扫描和极化通道天空扫描。CE31 8能自动存储测量数据 ,并可自动传输到计算机保存及发送。 CE31 8测得的直射太阳辐射数据可用来反演计算大气透过率、消光光学厚度、气溶胶光学厚度、大气水汽柱总量和臭氧总量。其天空扫描数据可以反演大气气溶胶粒子尺度谱分布及气溶胶相函数。 CE31 8可用于卫星遥感产品检验和气溶胶气候研究 ,在大气光… 相似文献
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环北京地区积层混合云微物理结构飞机联合探测研究 总被引：6，自引：2，他引：4
利用北京、山西和河北三省市飞机在环北京地区探测的积层混合云微物理结构特征资料,结合卫星等宏观观测资料,分析了环北京地区积层混合云系空间云微物理结构特征。结果显示,冷锋云系前部,云内部微物理参数空间分布不均匀,2700m以上较大,垂直方向云粒子浓度和直径呈正相关关系,浓度极值间差7个量级,大滴粒子浓度差7个量级,降水粒子浓度差6个量级,水平方向云粒子浓度和直径分布不均匀,呈反相关关系。冷锋云系中部,云微物理参数垂直分布不均匀,在2500～3600m和4000m以上高度层出现云粒子峰值,且云粒子浓度和直径呈反相关关系,云滴粒子浓度极值间差6个量级,大滴粒子浓度差7个量级,降水粒子浓度差5个量级,水平方向云粒子分布不均匀,云粒子浓度和直径呈反相关关系。冷锋云系前部,云粒子谱在4800m高度谱型为单峰谱,4200m高度谱型多峰分布,3600m高度谱型为双峰谱。云降水粒子谱三高度层谱型差异不大,4800m高度谱型为单调递减谱,峰值在小粒子端（≤100μm）,4200m和3600m高度谱型相似,为双峰谱,峰值分别在≤小于100μm和230μm处。降水粒子谱三高度层谱型相似,都为单峰谱,峰值相差不大。冷锋云系中部,云粒子谱在三高度层谱型差异较大,4800m高度谱型为单峰谱,峰值在小滴端,4200m高度谱型为单峰谱,峰值在15μm处,3600m高度谱型为双峰谱,峰值分别在7μm和30μm处。云降水粒子谱三高度层谱型差异不大,4800m高度谱型为单调递减谱,峰值在小粒子端（≤100μm）,4200m和3600m高度谱型相似,为双峰谱,峰值分别在≤100μm和200μm处。降水粒子谱三高度层谱型相似,都为单峰谱,峰值相差不大。 相似文献
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Primary biological aerosol particles including pollen, spores, plant debris, epithelial cells, bacteria, algae, protozoa and viruses, are an ubiquitous component of the atmospheric aerosol, they are most probably present in all size ranges. Besides their effects on air hygiene and health, biological particles play an important role in cloud physics, for example some bacteria are able to accumulate water and act as ice nuclei. To sample aerosols a two-stage-slit-impactor and a wing-impactor are used to collect particles for a following single particle analysis. The coarse particles are sampled on dyed glycerine jelly. The biological particles become stained and can be distinguished in contrast to the non-dyed particles using a light microscope.The small particles are examined in a scanning-electron-microscope equipped with an energy dispersive X-ray spectrometer after sampling on graphitic foils. Three criteria were used to characterize the particles: the morphology, the elemental composition and the behaviour during the microanalysis.With this method the size distributions of the primary biological aerosol particles were determined in an urban/rural influenced region. Considering all measurements we calculated a mean number concentration of 1.9 cm−3 of biological aerosol particles ≈30% of the total aerosol particles. The mean volume concentration was about 15% of the total volume. A model size distribution for primary biological aerosol particles was obtained by performing a non-linear fitting procedure. 相似文献
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Nucleation scavenging and the formation of a cloud interstitial aerosol (CIA) were theoretically studied in terms of the chemical composition of atmospheric aerosol particles. For this study, we used our air-parcel cloud model, which includes the entrainment of air and detailed microphysics, for determining the growth and interaction of aerosol particles and drops. Maritime and remote continental aerosol particle spectrums were used whose size distributions were superpositions of three log-normal distributions, each of a prescribed chemical composition. Our results show (1) that the CIA exhibits a size distribution with a distinctive cut-off at a specific radius of the dry as well as of the wet particle size distribution. All particles above this limiting size become activated to cloud drops and, thus, are not present in the CIA spectrum. This limiting size was found to be independent of the chemical composition of the particles and only dependent on the prevailing supersaturation. Below this specific size, the CIA spectrum becomes depleted of dry aerosol particles in a manner which does depend on their chemical composition and on the supersaturation in the air. (2) The number of aerosol particles nucleated to cloud drops depends critically on the chemical composition of the particles and on the prevailing supersaturation. 相似文献
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北京市大气细粒子的质量浓度特征研究 总被引：24，自引：2，他引：24
大气能见度的降低是当今国际上比较突出的城市环境问题。北京近年的监测结果表明 ,大气中通过消光作用使大气能见度下降的气溶胶细粒子的污染程度呈现上升趋势。从 2 0 0 1年对北京市气溶胶细粒子 (空气动力学直径小于 2 .5μm的粒子 ) 4个季节的采样监测结果分析 (有效采样天数为 50d)得出 ,北京市细粒子质量浓度年平均值已超过美国国家标准的 7倍以上。研究发现细粒子的质量浓度不仅与环境条件有关 ,而且与气象条件也有着密切的关系。文中以细粒子的观测数据为基础 ,结合当时的气象条件进行细粒子浓度与气象条件定量关系的研究 相似文献
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Thin film methods and X ray energy dispersive technique were applied to analyze sulfate-containing particles in Beijing in order to examine their features and sources. Atmospheric aerosol particles were collected on electron mi-croscope meshes according to two size ranges: coarse particles (r>0.5μm) and fine particles (0.5μm≥r≥0.1μm) by using a two-stage impactor. It was found fiat more than seventy percent of the fine particles and about twenty percent of the coarse particles were sulfate-containing particles. These particles were formed mainly through heterogeneous nucleation. The element composition analyses revealed that the atmospheric aerosol particles in Beijing were domi-nated by crustal particles and construction dust. 相似文献
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Ka Man Chan Dan Dan Huang Yong Jie Li Man Nin Chan John H. Seinfeld Chak K. Chan 《Journal of Atmospheric Chemistry》2013,70(1):1-18
Methyl vinyl ketone (MVK) is a key first-generation product from atmospheric isoprene photo-oxidation, especially under high-NOx conditions. In this work, acid-catalyzed reactions of gas-phase MVK with ammonium sulfate (AS), ammonium bisulfate (ABS), and sulfuric acid (SA) particles were investigated in a flow reaction system at relative humidity (RH) of 40 % and 80 %. Ultra-performance liquid chromatography with electrospray ionization time-of-flight mass spectrometry (UPLC/ESI-TOFMS) and gas chromatography-mass spectrometry (GC-MS) are utilized to identify particle-phase products for developing the reaction mechanisms. High-order oligomers such as dimers and tetramers were detected when ABS and SA particles were used, while no oligomeric products were found when AS particles were used. Particle-phase oligomeric products were formed via i) acid-catalyzed aldol reaction with or without dehydration and/or ii) acid-catalyzed hydration followed by oligomerization. Reactions on SA particles yield more abundant and higher-order oligomers up to hexamers than on ABS particles. Moreover, aldol reaction occurred only on SA particles, but hydration followed by oligomerization occurred in both ABS and SA particles. The high RH condition with the same type of acidic particles was found to favor hydration and facilitate the subsequent oligomerization, while the low RH condition with the same type of acidic particles was found to favor aldol reaction with dehydration (aldol condensation). Overall, the findings suggest acidic particles can facilitate the formation of high-order oligomers in the particle phase, with particle acidity and RH as key factors. 相似文献
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Light extinction by atmospheric particles is strongly dependent on their chemical composition and water content. Since light extinction directly impacts climate, optical measurements of atmospherically relevant aerosols at varying relative humidities (RH) are needed. Recent studies have highlighted the possibility that some atmospheric aerosols are glassy under ambient conditions. Here, the particle optical growth factor, fRHext, was measured for liquid and glassy particles using cavity ring-down aerosol extinction spectroscopy. The particles were composed of ammonium sulfate (AS), 1,2,6-hexanetriol, sucrose, raffinose, and mixed particles containing AS and either sucrose or raffinose. Both sucrose and raffinose can be glassy at room temperature. For the pure organics, the highly viscous sucrose and raffinose particles have similar optical growth curves to the liquid 1,2,6 hexanetriol particles. However, for particles composed of sucrose or raffinose mixed with AS, optical growth depends on the AS weight-percent, which in turn controls the phase state of the AS and ultimately the water uptake. 相似文献
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Elena D. Kireeva Olga B. Popovicheva Natalia M. Persiantseva Mikhail A. Timofeyev Natalia K. Shonija 《Journal of Atmospheric Chemistry》2009,64(2-3):129-147
Combustion-derived particles emitted by various transport engines are analyzed with respect to their morphology and composition. Soot particles collected behind an aircraft gas turbine engine combustor, in the diesel engine exhaust pipe, and at the end of ship pipe demonstrate heterogeneous morphological structures and different chemical identities. Individual particle analysis allows the characterization of emitted soot particles into three fractions, namely C-O, C-O-S, and Fe-C-O, with the dominant presence of chain soot agglomerates, irregular internally mixed soot, and particles of distinct morphology, respectively. The influence of oxygen and sulfur concentrations on the ability of soot to uptake water is proposed as a method for categorizing transport engine-generated particles. Categories of hydrophobic and hydrophilic particles within non-hygroscopic soots can be defined based on the amount of water uptake relative to several reference laboratory-made soots comparable to transport engine emissions. This method of characterizing hydrophobic/hydrophilic and hygroscopic soots in combustion emissions will help to determine the potential impacts of the combustion emissions on CCN/IN formation in the atmosphere. 相似文献
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利用NCEP FNL再分析资料为初始场,通过WRF中尺度数值模式(V3.9.1版本)对2015年8月26~27日青藏高原那曲地区一次对流云降水过程进行了模拟,分析了不同积云对流参数化方案和云微物理参数化方案组合对本次降水过程中降水量、环流场、雷达反射率以及云微物理特征模拟效果的影响。结果表明:WRF模式能较好地模拟出本次降水的时空变化特征,但不同参数化方案组合各有优势,总体而言,Grell-Devenyi+SUBYLIN和Grell-Freitas+SUBYLIN组合模拟性能最优。本次对流云降水以冰相过程为主,雪粒子贡献最大,暖云粒子对降水的影响并不明显。从云微物理过程的时间演变可看出,性能最好的SUBYLIN方案能合理模拟降水过程中雪粒子与冰晶粒子间的转换过程,雪粒子可在凝结过程中释放潜热促使对流运动发展,也可通过融化过程促进降水发生,对流层高层冰晶粒子凝华产生的潜热释放亦为深对流的发展创造了有利条件。 相似文献