共查询到20条相似文献，搜索用时 31 毫秒
1.
2.
末元古系-寒武系底Sr、C同位素对比 总被引：14，自引：0，他引：14
测定了云南永善肖滩前寒武系-寒武系界限Sr同位素组成及湖北省三峡 剖面震旦系碳酸盐岩Sr、C同位素组成,并与蒙古、 加拿大、西伯利亚和纳米 比亚的末元古系Sr和C同位素数据进行了比较,得出末元古纪海水87Sr/86Sr和 δ13C值的演变图。通过该演变图,可以对全球末元古系地层进行对比。 相似文献
3.
湖北徐家山锑矿床方解石C、O、Sr同位素地球化学 总被引：4，自引：0，他引：4
湖北通山的徐家山锑矿床产在上震旦统陡山沱组和灯影组的海相碳酸盐岩中.对该矿床中成矿前和成矿期方解石进行了较系统的C、O、Sr同位素地球化学研究,结果表明,成矿前方解石具相对较高的δ13CPDB(-0.7‰～ 2.0‰)、δ18OSMOW( 18.6‰～ 19.6‰)和Sr含量(2645-8174 μg/g,平均5656μg/g),及较低的87Sr/86Sr比值(0.7096～0.7097);而成矿期方解石具相对较低的δ13CPDB(-3.9‰～-2.1‰)、δ18OSMOW( 11.5‰～ 15.3‰)、Sr含量(785～2563μg/g,平均1571μg/g),和较高的87Sr/86Sr比值(O.7109～0.7154,平均0.7141).分析认为,成矿前方解石的C、O和绝大部分Sr来源于赋矿围岩--震旦系海相碳酸盐岩;而成矿流体为富H2CO3的溶液,它来自或流经富放射成因87Sr的下伏基底碎屑岩--中元古界冷家溪群浅变质岩;该流体与围岩发生水.岩反应导致成矿期方解石和辉锑矿的沉淀. 相似文献
4.
湖南香花岭锡多金属矿床C、O、Sr同位素地球化学 总被引：7，自引：0，他引：7
对湖南香花岭锡多金属矿床成矿早、晚两期方解石进行了系统的C、O、Sr同位素研究。结果表明,成矿早期方解石具有相对较低的δ13CPDB（-5.4‰ ~ -1.4‰）、δ18OSMOW（+6.1‰ ~ +13.9‰）和较高的87Sr/86Sr值（0.7101 ~ 0.7230）;而成矿晚期方解石则具有相对较高的δ13CPDB（+0.2‰ ~ +0.6‰）、δ18OSMOW（+19.4‰ ~ +21.5‰）和较低的87Sr/86Sr值（0.7101）。成矿早期方解石为岩浆热液与海相碳酸盐岩相互作用的产物,成矿流体中的碳源于岩浆碳和海相碳酸盐岩;模拟计算结果显示,成矿早期方解石为成矿溶液发生0.05-0.1摩尔分数的 CO2去气作用的产物。而成矿晚期方解石主要为矿区碳酸盐岩围岩低温淋滤的产物,流体中的碳主要源于矿区碳酸盐岩围岩。成矿流体中Sr源于矿区花岗岩和碳酸盐岩,从成矿早期到晚期,岩浆来源的Sr逐渐减少,而碳酸盐岩围岩提供的Sr比例不断增大。 相似文献
5.
桂林地区岩溶水87Sr/86Sr特征 总被引：2，自引：0，他引：2
锶是岩石圈上部含量最大的微量元素，其元素及其同位素化学性质都比较稳定。不同水岩作用条件下，锶元素含量及其同位素值都不一样。本文通过对桂林地区的两个典型岩溶地下河系统不同类型地下水样87Sr/86Sr值和Sr含量的分析，得出；流经不同岩层的地下水其87Sr/86Sr值和Sr含量不同，同一地下河系统中不同类型地下水的87Sr/86Sr值Sr含量不同，其值的差异由岩性和水岩作用决定。说明87Sr/86Sr值能反映地下水的形成、径流和混合作用，是较理想的示踪剂，在岩溶水研究中具有很广阔的应用前景。 相似文献
6.
7.
R. Moritz L. Fontboté J. Spangenberg S. Rosas Z. Sharp D. Fontignie 《Mineralium Deposita》1996,31(3):147-162
A combined Sr, O and C isotope study has been carried out in the Pucará basin, central Peru, to compare local isotopic trends of the San Vicente and Shalipayco Zn-Pb Mississippi Valley-type (MVT) deposits with regional geochemical patterns of the sedimentary host basin. Gypsum, limestone and regional replacement dolomite yield 87Sr/86Sr ratios that fall within or slightly below the published range of seawater 87Sr/86Sr values for the Lower Jurassic and the Upper Triassic. Our data indicate that the Sr isotopic composition of seawater between the Hettangian and the Toarcian may extend to lower 87Sr/86Sr ratios than previously published values. An 87Sr-enrichment is noted in (1) carbonate rocks from the lowermost part of the Pucará basin, and (2) different carbonate generations at the MVT deposits. This indicates that host rocks at MVT deposits and in the lower-most part of the carbonate sequence interacted with 87Srenriched fluids. The fluids acquired their radiogenic nature by interaction with lithologies underlying the carbonate rocks of the Pucará basin. The San Ramón granite, similar Permo-Triassic intrusions and their clastic derivatives in the Mitu Group are likely sources of radiogenic 87Sr. The Brazilian shield and its erosion products are an additional potential source of radiogenic 87Sr. Volcanic rocks of the Mitu Group are not a significant source for radiogenic 87Sr; however, molasse-type sedimentary rocks and volcaniclastic rocks cannot be ruled out as a possible source of radiogenic 87Sr. The marked enrichment in 87Sr of carbonates toward the lower part of the Pucará Group is accompanied by only a slight decrease in
18O values and essentially no change in
13C values, whereas replacement dolomite and sparry carbonates at the MVT deposits display a coherent trend of progressive 87Sr-enrichment, and 18O- and 13C-depletion. The depletion in 18O in carbonates from the MVT deposits are likely related to a temperature increase, possibly coupled with a 18O-enrichment of the ore-forming fluids. Progressively lower
13C values throughout the paragenetic sequence at the MVT deposits are interpreted as a gradually more important contribution from organically derived carbon. Quantitative calculations show that a single fluid-rock interaction model satisfactorily reproduces the marked 87Sr-enrichment and the slight decrease in
18O values in carbonate rocks from the lower part of the Pucará Group. By contrast, the isotopic covariation trends of the MVT deposits are better reproduced by a model combining fluid mixing and fluid-rock interaction. The modelled ore-bearing fluids have a range of compositions between a hot, saline, radiogenic brine that had interacted with lithologies underlying the Pucará sequence and cooler, dilute brines possibly representing local fluids within the Pucará sequence. The composition of the local fluids varies according to the nature of the lithologies present in the neighborhood of the different MVT deposits. The proportion of the radiogenic fluid in the modelled fluid mixtures interacting with the carbonate host rocks at the MVT deposits decreases as one moves up in the stratigraphic sequence of the Pucará Group. 相似文献
8.
辽南与苏皖北部新元古代地层Sr和C同位素对比及年龄界定 总被引：13，自引：0，他引：13
采用Sr,C同位素地层学方法,对苏皖北部和辽南地区新元古代地层中碳酸盐岩进行了系统的采样和测试,并将其测试结果与新元古代海水Sr,C同位素组成演变曲线相比较,试图从中获得研究区有关地层自然层序、形成时限范围及其有关同位素年龄数据取舍等方面新的信息。研究结果表明,研究区的新元古代淮南群、徐淮群、宿县群和细河群、五行山群、金县群等,均形成于南沱冰期或Sturtian冰期之前,为900～700Ma。并且进一步印证了淮南生物群应该属于前伊迪卡拉期的一次重要的生物大爆发。 相似文献
9.
碳酸盐岩C,O,Sr同位素研究是地球化学重要的示踪手段之一,它可以为研究古气候、古环境的变化提供定量的依据.研究结果表明:δ(13C)的高值对应海平面的上升和有机碳埋藏速率的增加,δ(13C)的低值则对应了海平面的下降和有机碳埋藏速率的降低;87Sr/86Sr比值与海平面变化呈负相关性;δ(18O)常作为判断碳酸盐是否受后期变化的标志之一.用海相碳酸盐岩C,O,Sr同位素示验古气候,古海洋环境,一般要求(Mn/Sr)＜-10×10-3,δ(13C)与δ(18O)不呈正相关关系. 相似文献
10.
塔中地区寒武系-奥陶系碳酸盐岩Sr元素和Sr同位素特征 总被引：5，自引：3，他引：2
使用VG354固体同位素质谱仪对中1、中4井的25个碳酸盐岩样品做了Sr同位素测试, 并利用电感耦合等离子质谱仪(ICP-MS) 对塔中地区4口井共109个碳酸盐岩样品测试了Sr、Mn元素的含量.通过对Sr、Mn元素含量分析, 及中1、中4井碳酸盐岩的Sr同位素组成分析, 对比全球奥陶系海相碳酸盐的Sr同位素分析结果及演化趋势, 得出了如下认识: (1) 塔中地区奥陶纪87Sr/86Sr比值与全球海水Sr同位素演化趋势基本一致, 具有随时间下降的总体趋势, 这与广阔陆表海和有关的沉积物对放射性成因锶的封存作用有关, 说明海平面变化和白云岩化作用仍然是该区海相碳酸盐岩锶同位素组成与演化的主要控制因素; (2) 塔中地区早奥陶世的87Sr/86Sr比值与全球海水Sr同位素比值相当, 说明该区早奥陶世碳酸盐岩成岩环境为正常海水, 且早奥陶世87Sr/86Sr比值有单调降低的规律, 说明与海平面变化有关; (3) 塔中地区晚奥陶世87Sr/86Sr比值比全球海水高, 其原因是白云岩化作用和晚奥陶世盆地抬升近地表水带来高87Sr/86Sr比值, 且晚奥陶世87Sr/86Sr比值为整体升高的趋势; (4) 塔中地区奥陶纪碳酸盐岩中Mn元素含量变化不大, 反映了塔中地区奥陶纪成岩环境主要为浅水相, 但也有深水相, 白云岩化对其影响不大; (5) 塔中地区奥陶纪碳酸盐岩中Sr元素含量变化较大, 反映该时期该区碳酸盐岩成岩流体主要为海水, 但也有混合水, 白云岩主要为Ⅲ类白云岩和Ⅰ类白云岩. 相似文献
11.
C、O、Sr同位素及微量元素组成在生物礁礁体环境研究中的应用 总被引：4，自引：1，他引：3
分析生物礁灰岩中C,O,Sr同位素及微量元素组成有助于研究生物礁体的形成环境.研究表明:δ 13C值的变化与生物埋藏量、埋藏速率、海平面的变化有着很密切的关系;海平面上升,δ 13C值增大,同时表明造礁生物大量繁殖;δ 18O值的变化反映古环境的温度变化,δ 18O升高,温度降低; 87Sr/ 86Sr的比值与海平面的升降变化表现一种负相关性,海平面上升, 87Sr/ 86Sr的比值降低.Sr, Mn等微量元素可以间接指示礁体环境变化,并且验证了所采集的样品数据的准确性.环境变化是决定生物礁发育的重要影响因素. 相似文献
12.
13.
Joshua D. Cocker 《Australian Journal of Earth Sciences》2013,60(1-2):139-158
Biotite igneous ages and well‐defined isochron ages of plutons from the composite Blue Tier Batholith and the Coles Bay area in northeastern Tasmania range from 395 to 370 Ma. The older limit of this range, for the George River granodiorite, is considerably older than any age previously recorded for NE Tasmania. The ages of the youngest plutons (Mt Paris and Anchor granites), which host cassiterite ores, record pervasive hydrothermal alteration events. The initial 87Sr/80Sr ratios of the granitoids range from 0.7061 to 0.7136 and suggest different protolith compositions, consistent with mineralogical and geochemical characteristics of each pluton. The S‐type garnetbiotite granites (Ansons Bay and Booby alia granites) have initial ratios greater than 0.7119, indicative of enriched, high Rb/Sr ratio, crustal source‐rocks of Proterozoic age (1700–800 Ma). The S‐type biotite granites (Poimena and Pearson granites) have relatively high initial 87Sr/86Sr ratios (0.7070, 0.7105) but overlap with those of the I‐type granodiorites (George River, Scamander Tier, Pyengana and Coles Bay granodiorites) which are in the range of 0.7061 to 0.7073. The initial ratios of the enriched altered plutons are poorly constrained, and on both hand‐specimen and thin‐section scales, reveal open‐system Sr isotopic patterns. Isochron ages for the arenite‐lutite and lutite sedimentary associations of the Mathinna Beds, which are intruded by the granitoids, reflect an approach to Sr isotopic equilibrium during regional metamorphism. The metamorphic age (401 ± 7 Ma) of the early Pragian arenite‐lutite association indicates a relatively small time interval between deposition, regional metamorphism and granitoid intrusion. The isotopic age for the lutite sedimentary association (423 ± 22 Ma) is tentatively correlated with a Benambran‐age burial metamorphic event that has not previously been recorded in Tasmania. 相似文献
14.
Processes controlling hydrogeochemistry in the Yuncheng Basin, China, were characterised using major-ion chemistry, 87Sr/86Sr ratios and ??13C values. Evapotranspiration during recharge increased solute concentrations by factors of ??5?C50 in deep palaeowaters, while higher degrees of evapotranspiration have occurred in shallow, modern groundwater. Aquifer sediments (loess) contain approximately 15 weight% calcite; trends in groundwater HCO3 concentrations and ??13C values (ranging from ?16.4 to ?8.2??) indicate that carbonate weathering is a significant source of DIC. Groundwater 87Sr/86Sr ratios (0.7110?C0.7162, median of 0.7116) are similar to those in both loess carbonate (0.7109?C0.7116) and local rainfall (0.7112), and are significantly lower than Sr in aquifer silicates (0.7184?C0.7251). Despite evidence for substantial carbonate dissolution, groundwater is generally Ca-poor (<?10% of total cations) and Na-rich, due to cation exchange. Saturation with respect to carbonate minerals occurs during or soon after recharge (all calcite and dolomite saturation indices are positive). Subsequent carbonate dissolution in the deep aquifer must occur as a second-stage process, in response to Ca loss (by ion exchange) and/or via incongruent dissolution of dolomite and impure calcite. The latter is consistent with positive correlations between ??13C values and Mg/Ca and Sr/Ca ratios (r 2?=?0.32 and 0.34). 相似文献
15.
CHEN Haoru ZHENG Rongcai WEN Huaguo LI Shilin LI Shuang ZHOU Gang WEN Longbin 《《地质学报》英文版》2014,88(6):1852-1862
Karst rocks from the Huanglong Formation exposed at the margin of the Eastern Sichuan Basin can be divided into four types:slightly corroded, moderately corroded porous, intensely corroded brecciated and intensely corroded and replaced secondary calcic karstic rocks. The carbon, oxygen and strontium isotope compositions of the various karst rocks are analyzed systematically and compared to rocks without karst corrosion. The results indicate that(1) the Huanglong Formation in the eastern Sichuan Basin was a restricted bay supplied and controlled by freshwater in which mudmicrite and mud-dolomicrite exhibit low δ13C and δ18O values and high 87Sr/86 Sr ratios;(2) all types of karstic rocks in the paleokarst reservoirs of the Huanglong Formation in the research area are affected by atmospheric freshwater with the δ13C and δ18O values and 87Sr/86 Sr ratios in the original formation approaching those of atmospheric freshwater, which reflects ancient hydrological conditions, fluid properties, isotopic source and the fractionation effect;(3) the intensely corroded and replaced secondary limestone is affected by a variety of diagenetic fluids, often reflected by δ13C and δ18O values, while the 87Sr/86 Sr ratios exhibit the strong degree of the corrosion;(4) after comparing the 87Sr/86 Sr ratios of each type of karst rock, the diagenetic fluids are determined to be mainly atmospheric freshwater, and depending on the strength of corrosion, and the low 87Sr/86 Sr ratio fluids in the layer will participate in the karst process. The carbon, oxygen, and strontium isotopes of different karstic reservoirs can provide meaningful geochemical information for forecasting and evaluating the development and distribution rules of the Huanglong Formation at the margin of the eastern Sichuan Basin in time and space. 相似文献
16.
近年来,在塔里木盆地塔中地区奥陶系发现了深埋溶蚀的油气藏,然而,形成该溶蚀储层的流体的来源还存在一些争议,一些研究认为该流体来源于火山热液[1],而其他研究者则认为可能为大气淡水循环热液[2-3].由于确定深部流体的来源是理解该储层形成机制的重要因素之一,因此,本文主要通过对储层中自生矿物以及围岩进行稀土元素、锶同位素进行分析测试,以推断出塔中地区是否存在热液流体,并分析其来源. 相似文献
17.
位于极端干旱区的额济纳盆地，是我国内陆地区代表性的盆地之一。这里不仅具有典型的大陆性气候、脆弱的生态系统，而且在平缓的戈壁滩下面，沉积有厚达200-400余米的古湖相地层。盆地东南与最高达近500m沙丘的巴丹吉林沙漠比邻，构成了特征性的盆地-沙漠系统，是世界少有的自然景观，也是目前研究热点之一。
考察研究工作揭示，巴丹吉林沙漠在蹑今30000a左右存在一湿润时期（Wunnemann等，1998；杨小平，2002；杨小平等，2003），并与临区腾格里沙漠相应时期发育的大湖期可以对比（Zhang等，2002，2004）。
新近的考察工作发现，在盆地东南部古日乃与巴丹吉林沙漠过渡区，存在有多级古沙丘被水夷平的、高度不等的平台，在这些平台之上，保存有水体快速蒸发环境条件下沙粒物质被钙质胶结的坚硬、类似砂岩的顶盖，其高度在大范围内可以对比，同时伴有湖相碳酸盐沉积、根管等。这些地貌、沉积与盆地北部沙砾石层中大量出现的贝壳化石和湖相地层，构成了古湖泊存在的地质证据。
14C测年结果表明，分布于第二级平台上的碳酸盐结核其形成年代为距今25000a前（25630±270a、25530±230a、25640±220a，半衰期5568a，下同），掰鳃类贝壳化石的年代为距今28000a(28530±430a、28630±320a、28780±340a、28560±280a)。
对这两组样品进行87Sr/86Sr分析结果表明（表1），碳酸盐沉积的87Sr/86Sr比值变化较为显著而贝壳化石的87Sr/86Sr比值变化相对较小，且贝壳化石的87Sr/86Sr比值的平均值小于碳酸盐沉积的87Sr/86Sr比值。
由于贝壳化石和碳酸盐沉积的87Sr/86Sr比值在一定意义上代表了古湖水的锶同位素比值，而87Sr/86Sr比值又与湖泊水体盐度相关（刘秀明等，2000），因此可以推测，贝壳化石所代表的古湖泊发育时期的水体较碳酸盐结核形成时期的盐度要低，也就是说古湖泊发育早期的为淡水，后期水体盐度有所增高。这是与贝壳化石本身代表的淡水种属相一致。由于后期湖泊水拉的快速下降和水体的快速蒸发，使得碳酸盐结核沉积的87Sr/86Sr比值增高，而这种古湖泊水位的快速下降和结核的形成是直接与气候变化相关联的。反映了该时期额济纳盆地古湖泊高湖面的存在和气候快速变化的历史。 相似文献
18.
19.
在冷泉的研究中,确定富甲烷流体的来源是非常重要的,Sr同位素对流体来源、混合模式和水岩反应等具有很好的示踪作用。近年来,国际上对冷泉碳酸盐岩Sr同位素的示踪研究越来越关注。本文系统总结了现代和古代冷泉碳酸盐岩Sr同位素的研究进展,简要归纳了Sr同位素分析测试方法,并对化学前处理过程中采用的不同酸溶液溶解样品的方法进行了对比,指出了建立标准化学前处理方法的必要性。现代和古代冷泉碳酸盐岩Sr同位素组成的变化范围较大,不同碳酸盐矿物具有不同的Sr同位素特征。冷泉碳酸盐岩Sr同位素的示踪研究集中在现代和古代冷泉流体来源的定性研究、混合流体来源的定量模型计算、以及古代冷泉碳酸盐岩的Sr同位素定年等方面。尽管取得了一系列进展,但是定量计算端元流体混合比例的准确性还有待提高,同时利用Sr同位素对古代样品进行定年存在不确定因素,其适用条件也需要进一步研究。 相似文献
20.
紫木凼金矿床是黔西南卡林型金矿区一个重要的大型金矿床,其成矿物质来源尚不明确.对紫木凼金矿床不同类型矿石和赋矿围岩进行了S、C、O、Pb和Sr同位素组成对比研究.矿石中硫化物的δ34S值为-13.49‰~17.91‰（主要为-0.99‰~3.58‰）,赋矿围岩的δ34S值为-26.23‰~-19.63‰,矿床成矿期硫主要来源于岩浆,部分来源于赋矿地层中成矿前黄铁矿.热液期方解石的δ13C和δ18O分别为-9.10‰~0.59‰和15.65‰~23.82‰,与赋矿围岩、区域地层的碳、氧同位素组成差别较大,成矿流体的碳、氧部分来源于碳酸盐岩溶解,部分可能来源于岩浆.矿石中硫化物的206Pb/204Pb、207Pb/204Pb和208Pb/204Pb比值分别为18.064~18.973、15.585~15.670和38.219~39.054,赋矿围岩的206Pb/204Pb、207Pb/204Pb和208Pb/204Pb比值分别为18.136~18.650、15.574~15.656和38.423~38.812,矿石铅的来源较复杂,赋矿地层和岩浆可能都为其提供了部分铅.矿石中石英和方解石（87Sr/86Sr）i比值为0.707 26~0.708 11,赋矿围岩的（87Sr/86Sr）i比值为0.707 28~0.707 31,成矿流体中的锶主要来源于赋矿地层.紫木凼金矿床成矿物质具壳幔混合来源特征,成矿物质主要来自矿床深部隐伏岩浆岩,部分来自二叠系-三叠系赋矿地层. 相似文献