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1.
贵州水银洞金矿床成矿流体不混溶的包裹体证据   总被引:10,自引:2,他引:8       下载免费PDF全文
通过对水银洞金矿床中流体包裹体的观测和热力学参数计算,探讨了成矿流体不混溶的热力学条件。研究结果表明,该矿床石英中的流体包裹体分为H_2O包裹体、CO_2包裹体和CO_2-H_2O包裹体三大类,并以富含CO_2-H_2O包裹体为特征,CO_2-H_2O包裹体可进一步划分为富H_2O相CO_2-H_2O包裹体和富CO_2相CO_2-H_2O包裹体。加热时富H_2O相CO_2-H_2O包裹体完全均一成H_2O相;而富CO_2相CO_2-H_2O包裹体完全均一成CO_2相,而且二者的完全均一温度和完全均一压力一致,说明它们是同时期捕获的CO_2-低盐水不混溶流体包裹体组合。它们形成时的热力学条件是:形成温度236℃,形成压力324 bar(1bar=10~5Pa);共存两相流体密度:低盐水相0.900 g/cm~3,CO_2相0.314 g/cm~3;共存两相中CO_2的摩尔分数:低盐水相0.0376,CO_2相0.7337;水溶液含盐度w(NaCl)约为1.3%。  相似文献   

2.
姚泾利  李渭  王亚玲  姜亭  黄锦绣 《地质通报》2014,33(11):1842-1852
通过大量野外地质调查、钻井岩心观察和室内分析测试,对陕北地区长101储层的成岩作用和成岩相进行了研究。结果表明,研究区长101储层处于中成岩A期阶段,压实作用与碳酸盐、粘土(高岭石、伊利石)矿物胶结、浊沸石胶结和硅质胶结作用是造成储层原生孔隙丧失的主要原因;绿泥石胶结抑制孔隙充填,长石、浊沸石矿物的溶蚀作用使孔隙间的连通性得到改善,储层物性得到提高。成岩相类型可划分为8种,优质储层与成岩相关系密切,其中压实相、碳酸盐胶结相、粘土矿物胶结相、石英加大相、浊沸石充填相不利于储层的发育,而长石溶蚀相、绿泥石膜胶结相、浊沸石溶蚀相对储层物性的改善具有重要作用。  相似文献   

3.
沸石类胶结物是准噶尔盆地西北缘玛南地区二叠系乌尔禾组发育的一种特殊胶结物类型。通过岩心观察、薄片鉴定、扫描电镜分析与岩石组分统计,明确了玛南地区乌尔禾组沸石胶结物的矿物特征、空间分布、成因机理与成储机制。研究区乌尔禾组主要发育浊沸石与片沸石,其中片沸石分为两期,早期富铁,晚期贫铁。研究区沸石胶结物的空间分布规律并不明显,仅在垂向上,从乌尔禾组到百口泉组,浊沸石与片沸石含量具有逐渐降低的趋势。沸石类胶结物的形成主要受控于母岩中凝灰岩砾石组分,中酸性火山岩砾石不利于浊沸石的形成,其他火山岩砾石与沸石的形成无明显关系,浊沸石大量发育的次生溶蚀孔隙是研究区油气赋存的主要储集空间类型。沸石类胶结物的沉淀与溶蚀可以简化为两阶段成岩作用过程,早期正常成岩胶结形成各类沸石胶结物,晚期深部成岩流体上涌,对储层进行溶蚀与改造,深部流体改造是成储的关键阶段。  相似文献   

4.
鄂尔多斯盆地东南富县探区延长组长3油层组广泛发育浊沸石胶结作用,其主要成因是富县探区长3油层斜长石含量高,与碱性富钠的孔隙水相互反应形成浊沸石胶结物,包体测温表明,形成温度主要在85~100℃之间,对应于早期成岩的晚期;浊沸石发育受地下流体活动的控制,多发育在三角洲平原及前缘相互叠置的分流河道复合砂体;在晚成岩早期,有机质脱羟作用形成有机酸对浊沸石溶蚀,形成大量次生孔隙.在富县探区东部地区,浊沸石沉淀与溶解总体效应造成孔隙度的增加;而在西部地区,由于浊沸石胶结物含量较小,后期的溶蚀作用不明显,其综合效应是造成孔隙降低.浊沸石溶蚀次生孔隙的发育是控制富县探区延长组长3油层优质储层的主控因素.   相似文献   

5.
富县探区上三叠统延长组成岩作用及孔隙结构特征   总被引:5,自引:1,他引:4  
根据薄片观察、扫描电镜及X—衍射资料的详细分析,富县探区延长组成岩作用已经普遍进入晚成岩A期,主要成岩作用有压实—压溶、胶结充填和溶解作用。压实—压溶及胶结充填作用是导致砂岩孔隙丧失的主要原因。其中碳酸盐、粘土矿物胶结物和石英、长石加大是造成砂岩物性降低的主要原因,碎屑颗粒周围形成的绿泥石衬边阻止了部分石英、长石次生加大及碳酸盐胶结物的沉淀,使部分原生粒间孔隙得以保存。晚期成岩阶段有机质分解形成的酸性流体及表生成岩作用阶段的大气降水使得碎屑部分碎屑长石和早期的浊沸石胶结物溶解是形成次生孔隙的主要原因。浊沸石胶结物主要发育在长3油层组,其原因是该层位长石碎屑含量高,并在成岩过程中蚀变形成浊沸石。高岭石在上部长2、长3油层组含量高,可能是印支期大气淡水淋滤对长石溶蚀并发生了高岭石化。孔隙类型以残余粒间孔和长石溶孔为主,划分出小孔细喉、小孔微细喉、小孔微喉、微细孔微细喉和微细孔微喉型五类孔喉结构,其中最后一种为无效储层。  相似文献   

6.
为探讨丫他金矿床成矿流体的特征和矿床成因,对热液成矿阶段中石英中的流体包裹体进行了岩相学、显微测温、激光拉曼分析以及H、O同位素研究。结果表明,丫他金矿床中存在H_2O包裹体、CO_2-H_2O包裹体和CO_2包裹体三类流体包裹体;其中同一阶段同一视域中富H_2O相CO_2-H_2O包裹体在加热中完全均一到H_2O相,以及富CO_2相CO_2-H_2O包裹体完全均一到CO_2相,它们的均一温度和形成压力基本一致,说明同时捕获了富CO_2和富H_2O两种流体;流体包裹体的H、O同位素组成特征显示,成矿流体主要来源为大气降水或与大气降水有关的盆地流体;热液成矿阶段流体发生相分离,CO_2-H_2O不混溶作用导致热液中Au的溶解度迅速降低并沉淀形成矿床。  相似文献   

7.
李荫清  艾永德 《矿物学报》1991,11(4):346-354
含金石英脉产于角闪斜长片麻岩的内蒙古红花沟和莲花山金矿床。石英中流体包裹体以气液比为(5~30)%的两相H_2O包裹体为主,很少见到富气H_2O包裹体,有少量CO_2-H_2O包裹体,其初熔温度为-56.6~-56.3℃,CO_2临界温度平均为+16.1℃,CO_2水合物消失温度为+5.6℃。成矿流体主要为含少量CO_2的均一的NaCl-H_2O溶液。盐度平均为(4.75~6.73)wt%NaCl,包裹体δD为(-85.5~-97.7)‰,δ~(18)O_(H_2O)为(-2.0~+2.1)‰,δ~(13)C_(co_2)为(-8.3~-2.2)‰,表明成矿流体来源于岩浆水和天水。引起金氯络合物分解的主要因素是温度的变化,成矿过程中多量天水的渗入,使体系温度下降至180~240℃,并导至溶液由酸性向中性(pH=5~6)转化,在f_(02)约为10~(-35)~10~(-41)Pa,Eh约为0.5时,产生自然金的沉淀,  相似文献   

8.
鄂尔多斯盆地安塞油田长10期发育以细砂岩和中砂岩为主的长石砂岩,胶结物主要有浊沸石、石英加大等硅质胶结物、绿泥石和方解石;在早成岩早期酸性地层水大量溶蚀颗粒间胶结物,压实作用强烈,在中成岩早期,湖相泥岩中生成的酸性介质溶蚀砂岩颗粒间的胶结物及长石和岩屑颗粒碎屑,形成次生溶蚀孔隙,从而形成优质储层.纵向上,在不整合面和层序界面附近,储层溶蚀作用强烈,次生孔隙发育,是优质储层发育部位,向上溶蚀作用逐渐变弱;在平面上,越靠近湖盆中心溶蚀作用越强,越远离湖盆中心溶蚀作用越弱.鄂尔多斯盆地安塞油田长10优质储层主要发育在三角洲平原高能分流河道发育带,溶蚀作用形成的浊沸石溶蚀孔隙、方解石溶蚀孔隙、长石溶蚀孔隙等次生孔隙成为优质储层形成的有利相带.  相似文献   

9.
芹菜洋金矿床中含金石英与无矿石英经常相伴产出。研究结果表明,含金石英系晚阶段产物,其颜色多种,粒度细小,富含Au、Ag、As、Al、K、Na等元素,无矿石英则相反。石英含金性及气相包体成分(CO_2+H_2+CH_4)/N_2比值可用来指示本区金矿化程度和规模,当石英含金量大于0.5×10~(-6)时指示该区有金矿床存在,含金量小于0.1×10~(-6)者可视为该区无矿,介于两者之间时有金矿化显示;气相包体成分(CO_2+H_2+CH_4)/N_2比值在0.08左右,可指示出现金矿床,当无矿时石英中的(CO_2+H_2+CH_4)/N_2比值明显高一个数量级。金矿石英脉无论是重矿物——磁铁矿、赤铁矿、黄铁矿等含量,还是成矿元素Au、Ag、Bi、Mn、S含量,抑或Cu+Pb+Zn,Cr+Ni+Co+V总量,都比无矿石英脉高出1—3个数量级,可作为金矿石英脉和无矿石英脉的判别标志。  相似文献   

10.
陕北延长组成岩圈闭油藏的形成及其重要意义   总被引:10,自引:2,他引:10  
陕甘宁盆地南部陕北地区的上三叠统延长组,是一套湖盆三角洲体系的碎屑岩沉积。延长组油气资源丰富,但砂体储油物性极差。近期研究发现了一些富含浊沸石胶结物的砂体中,由于浊沸石胶结物的溶蚀而形成的渗透性砂岩,以及浊沸石胶结物再沉淀而成的成岩致密带和压溶嵌合作用形成的致密带。砂体溶蚀带与上倾方向的致密带配套,构成了大型成岩圈闭油藏,并已在此类油藏中探明了可观的石油储量和生成了多量石油。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

15.
HYDROGEOLOGY     
正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level  相似文献   

16.
正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),  相似文献   

17.
18.
正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-  相似文献   

19.
正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-  相似文献   

20.
正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)  相似文献   

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