Middle Miocene peralkaline ignimbrites in the Hermosillo region (Sonora, Mexico): Geodynamic implications     

Jesús Vidal Solano  Francisco A. Paz Moreno  Alexander Iriondo  Alain Demant  Jean-Jacques Cochem 《Comptes Rendus Geoscience》2005,337(16):314

Scattered ignimbritic mesas crop out in the Hermosillo region (Sonora, Mexico). These rocks that have been dated at 12.5 Ma (Middle Miocene) have the petrography and chemical characteristics of comendites. Such a flare-up of peralkaline acidic volcanism, after a long period of subduction-related arc volcanism, emphasises an important change in the source of volcanism. It corresponds to the latest stage of continental extension prior to the marine invasion and the development of spreading centres in the Gulf of California. To cite this article: J. Vidal Solano et al., C. R. Geoscience 337 (2005).  相似文献   

Comportement de l'oscillateur DORIS/Jason au passage de l'anomalie sud-atlantique     

Pascal Willis  Bruce Haines  Jean-Paul Berthias  Pierre Sengenes  Jean-Louis Le Mouël 《Comptes Rendus Geoscience》2004,336(9):839-846

We point out an acceleration of the DORIS clock on-board the Jason satellite during passes over the South Atlantic Anomaly (SAA). When this effect is ignored in the current geodetic positioning of the DORIS stations, derived coordinates show almost linear trends in time, corresponding to anomalous horizontal and vertical velocities of the order of 1 m yr^?1. We propose a simple scientific explanation of this physical phenomenon that is corroborated by direct Jason/TOPEX clock comparisons with respect to the DORIS master beacons in Kourou and Toulouse. To cite this article: P. Willis et al., C. R. Geoscience 336 (2004).  相似文献   

Applications géodésiques du système DORIS à l'Institut géographique national     

Pascal Willis  Claude Boucher  Hervé Fagard  Zuheir Altamimi 《Comptes Rendus Geoscience》2005,337(7):653-662

IGN is in charge of the installation and maintenance of the DORIS orbit determination network. More recently, in collaboration with JPL, precise geodetic computations were performed. The goal of this paper is to recall the various historic contributions of IGN to the DORIS system in their international context and then to describe a new estimation technique developed for a multi-satellite mode, making full profit of a better modeling for satellites and ground clocks as well as tropospheric correction parameters. Derived geodetic results demonstrate a precision in the order of 1 cm for station positions. To cite this article: P. Willis et al., C. R. Geoscience 337 (2005).  相似文献   

Growing mountain ranges and quenched river networks     

Sbastien Castelltort  Guy Simpson 《Comptes Rendus Geoscience》2006,338(16):1184-1193

River networks in mountain ranges owe their existence to the competing effects of tectonic uplift and climate-controlled erosion. However, paradoxically, the universal geometric properties of river networks are independent of both tectonics and climate. Currently, this paradox has still not been resolved. Here we propose a solution that consists in considering that the geometry of river networks is established on the lowland margins of incipient uplifts, and is quenched into the erosion zone as the mountain belts widen with time. In our model, the geometry of river networks simply reflects the downward coalescence of alluvial rivers on un-dissected surfaces outside of mountain belts, and is therefore independent of erosion processes. To cite this article: S. Castelltort, G. Simpson, C. R. Geoscience 338 (2006).  相似文献   

Évolution récente et actuelle de la côte basque française (analyse et perspectives)     

Antonin Genna  Jean-Pierre Capdeville  Jacques Dubreuilh  Cyril Mallet 《Comptes Rendus Geoscience》2005,337(16):1474

A recent multidisciplinary study, comprising existing data analysis and geomorphological and geological fieldwork, has helped clarify marine erosion processes of Pyrenean formations along the Basque Coast. An important discovery was made during our study of an alterite of regional extent, which calls into question recent and present evolution of the Basque Coast and the processes leading to coastline retreat. Modelling these factors has made it possible to propose a predictive scenario for future coastal evolution. To cite this article: A. Genna et al., C. R. Geoscience 337 (2005).  相似文献   

A Late Hauterivian short-lived anoxic event in the Mediterranean Tethys: the ‘Faraoni Event’     

Franois Baudin 《Comptes Rendus Geoscience》2005,337(16):1

A Late Hauterivian interval (127.5 Ma), called the ‘Faraoni Event’, which is characterised by the deposition of deep-marine black shales in the Mediterranean Tethys, is demonstrably of sufficient geological brevity to be qualified as an anoxic event. This event lies within the Pseudothurmannia catulloi ammonite subzone, coincides with the extinction of the calcareous nannofossil species Lithraphidites bollii, and records an increase in a globular planktonic foraminifer. High quantities of marine organic matter were preserved in pelagic successions from northern and central Italy, Switzerland, southeastern France, southern Spain and probably elsewhere in the Mediterranean Tethys and Atlantic Ocean. Carbon-isotope stratigraphy from Tethyan and Atlantic sections shows a minor positive excursion in the uppermost part of the Hauterivian and Lowermost Barremian, suggesting accelerated extraction of organic carbon from the ocean reservoir just after the ‘Faraoni Event’. The duration of this short event is less than 100 ka according to cyclostratigraphy and coincides with a third-order sea-level rise. It is likely that similar forcing mechanisms responsible for global OAEs operated during this short time interval. To cite this article: F. Baudin, C. R. Geoscience 337 (2005).  相似文献   

Usable Values of Nickel Ore and Nickel Concentrate Certified Reference Materials          下载免费PDF全文

Zhizhong Cheng  Mei Liu  Hongku Huang  Tiexin Gu  Weidong Yan  Hongli Wen 《Geostandards and Geoanalytical Research》2015,39(2):221-232

The preparation and characterisation of three nickel ores and two nickel concentrate certified reference materials are described in this paper. The samples of nickel ore and nickel concentrate were collected from the Hongqiling nickel deposit in Jilin province. The raw materials were crushed and passed through a 2.0‐mm sieve. The rough samples were then ground for 48 hr in a high‐alumina ball mill to a final size of < 0.074 mm. Homogeneity of the samples was tested by X‐ray fluorescence spectrometry (WD‐XRF) and inductively coupled plasma‐atomic emission spectrometry (ICP‐AES). The relative standard deviations (RSD) of results on mass fraction measurements by WD‐XRF were < 1.0% m/m for eighteen components. F‐tests showed that all five samples were homogeneous. Nineteen laboratories contributed with measurement results (2127 in total) for the certification of mass fractions for twenty‐three elements and compounds. Twenty‐three components in the nickel ores and twenty components in the nickel concentrates were characterised as certified values, while the Ni mass fractions ranges from 0.1 to 9.02% m/m in these certified reference materials. These five samples were approved as national certified reference materials by the National Organisation of Reference Materials of China in 2012.  相似文献   

A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance     

Delphine Aran  Armand Maul  Jean-Franois Masfaraud 《Comptes Rendus Geoscience》2008,340(12):865-871

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH₃)₆³⁺ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.  相似文献   

Contribution of stable isotopes to the understanding of the unsaturated zone of a carbonate aquifer (Nerja Cave, southern Spain)     

Francisco Carrasco  Bartolom Andreo  Cristina Lin  Jacques Mudry 《Comptes Rendus Geoscience》2006,338(16):1203-1212

We analysed the stable isotopes (¹⁸O and ²H) of rainwater and drip water within a cave (Nerja Cave) located in the unsaturated zone of a carbonate aquifer. Rainfall is more abundant and presents lower isotopic content in winter, while the volume of drip water is greater and its isotopic content is lower in summer. The flow analysis of ¹⁸O through the unsaturated zone confirms the seasonal lag between rainfall and the appearance of drip water in the cave and reveals that the unsaturated zone of the aquifer, in the sector of the cave, behaves like an inertial system with a strong capability to modulate the input signal. To cite this article: F. Carrasco et al., C. R. Geoscience 338 (2006).  相似文献   

Determination of Cr,Cu, Ni,Sn, Sr and Zn Mass Fractions in Geochemical Reference Materials by Isotope Dilution ICP‐MS     

Aloísio J.B. Cotta  Jacinta Enzweiler 《Geostandards and Geoanalytical Research》2013,37(1):35-50

Isotope dilution (ID) mass spectrometry is a primary method of analysis suited for the accurate and precise measurement of several trace elements in geological matrices. Here we present mass fractions and respective uncertainties for Cr, Cu, Ni, Sn, Sr and Zn in 10 silicate rock reference materials (BCR‐2, BRP‐1, BIR‐1, OU‐6, GSP‐2, GSR‐1, AGV‐1, RGM‐1, RGM‐2 and G‐3) obtained by the double ID technique and measuring the isotope ratios with an inductively coupled plasma‐mass spectrometer equipped with collision cell. Test portions of the samples were dissolved by validated procedures, and no further matrix separation was applied. Addition of spikes was designed to achieve isotope ratios close to unity to minimise error magnification factors, according to the ID theory. Radiogenic ingrowth of ⁸⁷Sr from the decay of ⁸⁷Rb was considered in the calculation of Sr mass fractions. The mean values of our results mostly agree with reference values, considering both uncertainties at the 95% confidence level, and also with ID data published for AGV‐1. Considering all results, the means of the combined uncertainties were < 1% for Sr, approximately 2% for Sn and Cu, 4% for Cr and Ni and almost 6% for Zn.  相似文献   

La prévision du climat : de l'échelle saisonnière à l'échelle décennale     

Jean-Claude Andr  Jean-Yves Caneill  Michel Dqu  Philippe Rogel  Laurent Terray  Yves Tourre 《Comptes Rendus Geoscience》2002,334(16):1115

The atmosphere and the ocean are subject to many dynamical instabilities, which limit the time during which their behaviour can be deterministically forecasted. At longer timescales, the atmosphere can be predicted at best using statistical methods, as a response to external forcing linked to sea- and land-surface anomalies. Climate being defined as the mean of atmospheric states, it appears that it can be predicted up to a few months in advance, which is the characteristic time of the so-called slow components of the climate system. Forecasting can sometimes be extended to longer time ranges, especially when the coupled ocean–atmosphere system exhibits internal variability modes, with characteristic times of a few years. Seasonal climate forecasting is most often based upon Monte-Carlo simulations, where the various realisations correspond to slightly different initial conditions. The present sate-of-the-art in Europe (ECMWF) and/or in the USA (IRI) allows to forecast such major phenomena, as El Niño, up to six months in advance. Finally, some parameters may exhibit predictability at still longer time-ranges (inter-annual to decadal), but only for certain regions. The example of electricity production is used to underline the potentially large economical benefit of seasonal climate forecasting. To cite this article: J.-C. André et al., C. R. Geoscience 334 (2002) 1115–1127.

Résumé

L'atmosphère et l'océan sont le siège d'instabilités dynamiques, qui limitent la durée pendant laquelle il est possible d'en prévoir l'évolution de façon déterministe. Au-delà, l'atmosphère n'est plus prévisible, au mieux, que de façon statistique, en fonction du forçage externe qu'exerce(nt) sur elle l'océan et/ou la surface des continents. Le climat (au sens d'une moyenne des états atmosphériques) se révèle ainsi prévisible jusqu'à des échéances temporelles de quelques mois, échelle de temps caractéristique des composantes dites « lentes » du système climatique. La prévision peut s'étendre à des échéances parfois plus longues, dans le cas où le système couplé océan–atmosphère posséderait des modes de variabilité temporelle de périodes caractéristiques de quelques années. La prévision climatique saisonnière est très souvent construite à partir de simulations de type Monte-Carlo, avec des ensembles de réalisations utilisant des conditions initiales légèrement différentes. Dans l'état actuel de ces prévisions, qu'elles soient réalisées en Europe (CEPMMT) ou aux États-Unis (IRI), il est possible de prévoir environ six mois à l'avance un certain nombre de phénomènes climatiques, en particulier ceux liés aux épisodes dits « El Niño », pour lesquels l'amplitude des variations est suffisamment importante. Il existe, par ailleurs, une prévisibilité à encore plus longue échéance (inter-annuelle à décennale), mais seulement pour certains paramètres et certaines régions. L'exemple de la production d'électricité montre l'importance économique potentielle très grande de la prévision climatique saisonnière. Pour citer cet article : J.-C. André et al., C. R. Geoscience 334 (2002) 1115–1127.  相似文献   

Discrimination between primary magmatic biotites, reequilibrated biotites and neoformed biotites   总被引：11，自引：0，他引：11  

Hassane Nachit  Abderrahmane Ibhi  El Hassan Abia  Mohcine Ben Ohoud 《Comptes Rendus Geoscience》2005,337(16):367

The ternary diagram TiO₂–FeO*–MgO (FeO* = FeO + MnO) is proposed as a quantitative objective tool for distinguishing between primary magmatic biotites and those that are more or less reequilibrated, or possibly neoformed, by or within a hydrothermal fluid. The limit of the domains of the primary magmatic biotites, the reequilibrated biotites and the neoformed biotites were determined on the basis of optical, paragenetic and chemical criteria. To cite this article: H. Nachit et al., C. R. Geoscience 337 (2005).  相似文献   

Calpionellid zonation of the Jurassic–Cretaceous transition in North-Atlasic Tunisia. Updated Upper Jurassic stratigraphy of the ‘Tunisian trough’ and regional correlations     

Mabrouk Boughdiri  Houaïda Sallouhi  Kamel Malaoui  Mohamed Soussi  Fabrice Cordey 《Comptes Rendus Geoscience》2006,338(16):1250-1259

The analysis of calpionellid associations from jebels Amar and Jédidi sections in North-Atlasic Tunisia provides, for the first time, a precise biozonation of the Jurassic–Cretaceous transition succession. In the light of the new data obtained and considering recently published results, the age of Upper Jurassic formations is clarified, allowing correlations with the Tunisian ‘Dorsale’ and the North–South Axis successions. Within the Maghrebides' range, sections from the external zones correlated to the Tunisian successions are quite distinctive from their equivalent in the internal zones. Both have evolved in different palaeogeographic domains related to the early structuration of the northwestern and southwestern Tethys margins. To cite this article: M. Boughdiri et al., C. R. Geoscience 338 (2006).  相似文献   

A Review of the IAG GeoPT™ and Certification Programmes,their Protocols,and the Differences between the Original and Potential Modifications to the Certification Protocol          下载免费PDF全文

Jean S. Kane 《Geostandards and Geoanalytical Research》2015,39(4):419-432

The IAG conducts two programmes, the GeoPT ^? proficiency test and a certification programme that are closely interconnected. Both support the quality control/quality assurance activities of geochemical laboratories. Each derives an estimate of ‘true value’ for a number of samples, but arrives at that estimate, and its uncertainty, differently. This review discusses the history of the two programmes and compares the ‘true values’ and their uncertainties obtained through each. It then considers ‘fitness‐for‐purpose’ issues related to both GeoPT ^? and certification uncertainties. Issues related to potential modification of the IAG protocol for certification are also considered.  相似文献   

SEM–EDS analysis of western Mediterranean obsidians: a new tool for Neolithic provenance studies     

Franois-Xavier Le Bourdonnec  Grard Poupeau  Carlo Lugli 《Comptes Rendus Geoscience》2006,338(16):1150-1157

The contents of Na, Al, Si, K, Ca and Fe of 99 obsidians from the western Mediterranean islands of Lipari, Palmarola, Pantelleria and Sardinia were determined with the energy-dispersive spectrometer of a scanning electron microscope (SEM–EDS). The Na and in a lesser way other elements contents characterize any obsidian source-island. In Sardinia (80 samples), the four Monte Arci obsidian geochemical types can be discriminated from binary diagrams of element contents or by a discriminant analysis based on the six elements measured. It is concluded that SEM–EDS offers a new option for Neolithic obsidian provenance studies in this region. To cite this article: F.-X. Le Bourdonnec et al., C. R. Geoscience 338 (2006).  相似文献   

Determination of Mercury in One Hundred and Sixteen Geological and Environmental Reference Materials Using a Direct Mercury Analyser          下载免费PDF全文

Barbara Marie  Luc Marin  Pierre‐Yves Martin  Tioga Gulon  Christophe Cloquet 《Geostandards and Geoanalytical Research》2015,39(1):71-86

The mercury content of 116 reference materials (RMs) from ten international organisations was determined in this study, which focused on variability within and between batches of RMs. Direct mercury analysis (DMA) was applied to RMs having Hg contents between 1 and 6300 ng g^?1 and provided good precision and accuracy. Accuracy was demonstrated by the agreement of our results with certified values, while replicates were made to establish the precision. Low within‐batch variability was noted, with precision from 0.1 to 23% (n = 3–5) apparently depending on Hg content and homogeneity, whereas systematic offsets were detected among several batches. Thanks to the analysis of different batches; the homogeneity or heterogeneity of several RMs was shown, and thus, suitable RMs for quality control for Hg determinations could be recommended.  相似文献   

High‐Precision Iron Isotope Analysis of Geological Reference Materials by High‐Resolution MC‐ICP‐MS          下载免费PDF全文

Yongsheng He  Shan Ke  Fang‐Zhen Teng  Tiantian Wang  Hongjie Wu  Yinhuai Lu  Shuguang Li 《Geostandards and Geoanalytical Research》2015,39(3):341-356

We report high‐precision iron isotopic data for twenty‐two commercially available geological reference materials, including silicates, carbonatite, shale, carbonate and clay. Accuracy was checked by analyses of synthetic solutions with known Fe isotopic compositions but different matrices ranging from felsic to ultramafic igneous rocks, high Ca and low Fe limestone, to samples enriched in transition group elements (e.g., Cu, Co and Ni). Analyses over a 2‐year period of these synthetic samples and pure Fe solutions that were processed through the whole chemistry procedure yielded an average δ⁵⁶Fe value of ?0.001 ± 0.025‰ (2s, n = 74), identical to the expected true value of 0. This demonstrates a long‐term reproducibility and accuracy of < 0.03‰ for determination of ⁵⁶Fe/⁵⁴Fe ratios. Reproducibility and accuracy were further confirmed by replicate measurements of the twenty‐two RMs, which yielded results that perfectly match the mean values of published data within quoted uncertainties. New recommended values and associated uncertainties are presented for interlaboratory calibration in the future.  相似文献   

Isotope Dilution Determinations of Lu,Hf, Zr,Ta and W,and Hf Isotope Compositions of NIST SRM 610 and 612 Glass Wafers   总被引：1，自引：0，他引：1  

Oliver Nebel  Melanie L.A. Morel  Pieter Z. Vroon 《Geostandards and Geoanalytical Research》2009,33(4):487-499

Isotope dilution determinations of Lu, Hf, Zr, Ta and W are reported for nine test portions (five for W) of NIST SRM 610 and 612 glass wafers. Additionally, all test portions were analysed for their Hf isotope compositions. In general, high field strength elemental (HFSE) distributions in NIST SRM 610 and 612 were reproducible to ～± 1%, except for Zr (± 5%) in NIST SRM 612, and absolute reported concentrations agreed with previously published values, but with higher precision. The slightly worse reproducibility of Zr in NIST SRM 612 compared to other HFSE is interpreted to result from analytical scatter, rather than sample inhomogeneity. The analyses demonstrated elemental homogeneity for both glass wafers for samples of 1–2 mg with respect to the precision of the method, i.e., ± 1% or better. Average Hf isotope compositions for both glass wafers agreed within uncertainty and the weighted average of all determinations yielded a mean ¹⁷⁶Hf/¹⁷⁷Hf ratio of 0.282111 ± 0.000009 (95% confidence level). However, although mean values for NIST SRM 610 and 612 agreed within analytical limits, NIST SRM 610 test portions showed a tendency of systematically elevated isotope composition of ～ 0.5 _?Hf units when compared to NIST SRM 612, which may indicate a slightly more radiogenic Hf isotope composition of NIST SRM 610. The results of this study suggest that NIST SRM 610 and 612 are valuable calibrators for HFSE in situ analyses within the given uncertainties.  相似文献   

Paléoclimat des Petites Antilles depuis 4000 ans BP : l'enregistrement de la lagune de Grand-Case à Saint-Martin     

Pascal Bertran  Dominique Bonnissent  Daniel Imbert  Pierre Lozouet  Nathalie Serrand  Christian Stouvenot 《Comptes Rendus Geoscience》2004,336(16):14

A 2.5-m-thick sequence of lake sediments at the Étang de Grand-Case, Saint Martin (French West Indies) is studied here. Significant hydrological budget fluctuations allows distinction of three main climatic periods: (1) an overall dry period (4200 BP–2300 BP), characterised by carbonated mud, gypsum and storm sand layers; (2) a wet phase (2300 BP–1150 BP) dominated by organic mud; and (3) a more complex phase (1150 BP to present), with detrital inputs due to human activities. Comparison with other regional high-resolution records shows that similar climate modifications typify the whole Mesoamerican and Caribbean area. The climatic phenomena that are implicated in the variations of both precipitation and hurricane frequency over the Lesser Antilles are due to the latitudinal displacement of the inter-tropical convergence zone. These data give new support to the hypothesis of the existence of a correlation between peopling phases and climate variations in the Caribbean as previously proposed by some archaeologists. To cite this article: P. Bertran et al., C. R. Geoscience 336 (2004).  相似文献   

L'érosion des chaînes de montagnes : influence de la sédimentation de piedmont     

Julien Babault  Jean Van Den Driessche   《Comptes Rendus Geoscience》2005,337(16):1431

The applanation of mountain belts that results in peneplain is generally considered to be caused by the long-term activity of erosion. Peneplanation has been previously defined as the lowering of an elevated topography and the concomitant subduing of its relief. We propose a model following which piedmont sedimentation induces the base level rise, allowing applanation to develop at high elevation and resulting in an elevated ‘peneplain’. This model is illustrated by the morphological evolution of the southern flank of the Pyrenees during the Cainozoic. To cite this article: J. Babault, J. Van Den Driessche, C. R. Geoscience 337 (2005).  相似文献