共查询到20条相似文献，搜索用时 375 毫秒
1.
Dr. F. Pertlik 《Mineralogy and Petrology》1972,18(3):157-168
Zusammenfassung Emmonsit kristallisiert triklin, RaumgruppeP
, Gitterkonstanten:a
0=7,90 Å,b
0=8,00 Å,c
0=7,62 Å, =96o44, =95o 0, =84o 28,Z=2. Der Strukturtyp wurde aus 3-dimensionalen photographischen Röntgendaten ermittelt. Die Eisenatome werden je von 6 Sauerstoffen verzerrt oktaedrisch koordiniert. Jedes Telluratom wird von 3 Sauerstoffen in einem Abstand <2,0 Å umgeben. Ein vierter Sauerstoff hat bezüglich dieser drei einen um etwa 25–35% größeren Abstand, so daß jedes Telluratom im weiteren Sinne eine (3+1)-Koordination aufweist.
Mit 2 Abbildungen 相似文献
The structure type of emmonsite, {Fe2[TeO3]3·H2O}·xxH2O (x=0–1)
Summary Emmonsite is triclinic with space groupP , and lattice constantsa 0=7.90 Å,b 0=8.00 Å,c 0=7.62 Å, =96o 44, =95o 0, =840 28,Z=2. The structure type is derived from 3-dimensional photographic X-ray data. The iron atoms are coordinated by six oxygens in the form of a distorted octahedron. Each tellurium atom is coordinated to 3 oxygens at a distance <2.0 Å. Compared with these 3 Te–O distance the distance of a fourth oxygen is only 25 to 35% greater; therefore each tellurium atom has a (3+1)-coordination of oxygens.
Mit 2 Abbildungen 相似文献
2.
Dr. Otto Braitsch 《Contributions to Mineralogy and Petrology》1959,6(4):233-247
Zusammenfassung 1Tc-Strontiohilgardit (Ca, Sr)2 [B5O8(OH)2,Cl] mit Ca : Sr etwa 1 : 1 ist ein neues Mineral der Hilgarditgruppe. Fundpunkt: Reyersbausen (9° 59,7 E, 51° 36,6 N), Grube Königshall-Hindenburg, Flöz Staßfurt in sylvinitischer Ausbildung.Konstanten : triklin-pedial,a
0=6,38 Å,b
0=6,480 Å,c
0=6,608 Å, =75,4°,=61,2°, =60,5°; tafelige-gestreckte Links- und Re chtskristalle, farblos, wasserunlöslich, piezoelektrisch. Härte 5–7, Dichte 2,99 g cm–3;n
=1,638,n
=1,639,n
=1,670; 2V
=19°.Neue Daten für die Hilgarditgruppe : 2 M (Cc)-Calciumhilgardit (=Hilgardit) =4 Ca2[B5O3(OH)2Cl], Raumgruppe Cc.3Tc-Calciumhilgardit (=Parahilgardit) = 3 Ca2[B5O3(OH)2Cl]; trinklin-pedial, 0=6,31 Å,b
=6,484 Å,c
0=17,50 Å; =84,0°,=79,6°, =60,9°.Die Polymorphiebeziehungen sind geometrisch deutbar durch eine spezielle Art der Polytropie (Stapelung von Links- und Rechtskristallen im Elementarbereich). 相似文献
3.
Dr. F. Pertlik 《Mineralogy and Petrology》1978,25(2):95-105
Summary The mineral trigonite crystallizes in the monoclinic space groupPn–C
s
2
witha
0=7.26,b
0=6.78,c
0=11.09Å; =91.5°,Z=2. The structure was determined from 1250 X-ray intensities collected on an automatic two circle Weissenberg-type diffractometer. The final residual isR=6.5% using anisotropic temperature factors for Pb, Mn and As, and isotropic temperature factors for O.The structure consists of MnO6 octahedra, sharing all six oxygens with arsenite groups to form a framework. The Pb atoms are attached to this framework with Pb–O distances2.23Å. One oxygen, bound only to an As atom, is interpreted as the donor for a hydrogen bond of 2.75Å.
With 2 Figures 相似文献
Die Kristallstruktur des Trigonits, Pb3Mn(AsO3)2(AsO2OH)
Zusammenfassung Das Mineral Trigonit kristallisiert monoklin, RaumgruppePn–C s 2 ,a 0=7,26,b 0=6,78,c 0=11,09Å; =91,5°;Z=2. Die Strukturermittlung erfolgte anhand von 1250 Röntgenintensitäten, die auf einem automatischen Zweikreis-Weissenbergdiffraktometer gesammelt wurden. Mit anisotropen Temperaturfaktoren für Pb, Mn und As sowie isotropen für die O-Atome ergibt sich einR-Wert von 6,5%.Die MnO6-Oktaeder werden über die sechs Sauerstoffe mit Arsenitgruppen zu einem dreidimensionalen Gerüst verknüpft. Über Pb-O-Abstände2,23 Å sind die Pb-Atome in dieses Gerüst eingebaut. Ein Sauerstoff, nur an ein As-Atom gebunden, wird als Donator einer H-Brücke von 2,75 Å interpretiert.
With 2 Figures 相似文献
4.
Summary Barylite has been identified for the first time in Greenland in several specimens from the nepheline syenite pegmatite pockets at Narssârssuk. The crystals are orthorhombic, showing the forms {100}, {210} and {201}, and form thin plates parallel to {100}. Electron microprobe analysis and emission spectrography show a composition close to the ideal formula. The refined unit cell paramters are:a=9.835(2) Å,b=11.654(3) Å andc=4.673(1) Å. The barylite is biaxial negative, 2V
=66o±2o,n
=1.694,n
= 1.697 andn
calc.=1.698.
Das erste grönländische Vorkommen des seltenen Minerales Barylith
Zusammenfassung Der seltene Barylith wurde zum ersten Mal in Grönland in verschiedenen Proben aus Nephelin-Syenit-Pegmatit-Drusen bei Narssârssuk identifiziert. Die Kristalle sind orthorhombisch mit den Formen {100}, {210} und {201}, sie bilden dünne Tafeln nach {100}. Elektronensonden-Analyse und Emissions-Spektrographie ergeben eine chemische Zussammensetzung, die der Idealform nahekommt. Die verfeinerten Zellparameter sind folgende:a=9,835(2) Å,b=11,654(3) Å undc=4,673(1) Å. Barylith ist zweiachsig negativ, 2V =66o±2o,n =1,694,n =1.697 undn calc.= 1,698.相似文献
5.
Th. G. Sahama Martti Lehtinen Pentti Rehtijärvi 《Contributions to Mineralogy and Petrology》1973,39(2):171-174
Single crystals of boehmite, up to 0.1 mm in size, were found in open cavities inside a corundum crystal from the Ratnapura area gem gravels in Ceylon. The unit cell parameters are (X-ray powder pattern): a
0=3.695 Å b
0=12.212 Å, c
0=2.867 Å. The crystallographic orientation is based on X-ray single-crystal precession photographs. The crystals show the faces (it010), (001), (101), and (221). Systematic extinctions agree with the space group Amam. Optical orientation: a, b, c. Refractive indices are given. The mineral is optically positive with a large optic axial angle. 相似文献
6.
Dr. Otto Braitsch 《Contributions to Mineralogy and Petrology》1959,6(6):366-370
Zusammenfassung Strontioginorit (Sr, Ca)2B14O23 8 H2O mit Sr: Ca1,3:0,7 tritt in gut ausgebildeten Kristallen im Alteren Steinsalz von Reyershausen bei Göttingen auf. Es ergaben sich folgende Daten :
0 = 12,850 Å,b
0 = 14,48 Å,c
0, = 12,855, Å, = 101° 35, RaumgruppeP 2I/a,Z = 4, Dichte=2,25 gcm–3,n
= 1,512,n
/b
= 1,524,n
//[101] = 1,577. 相似文献
7.
Fabrizio Nestola Tiziana Boffa Ballaran Mario Tribaudino Haruo Ohashi 《Physics and Chemistry of Minerals》2005,32(3):222-227
A single-crystal of composition CaNiSi2O6 (space group C2/c) was investigated at high pressure up to about 7.8 GPa by X-ray diffraction. The unit-cell parameters were measured at 18 different pressures. The P-V data were fitted by a third-order Birch-Murnaghan equation of state V0=435.21(1) Å3, K 0=117.6(3) GPa and K=6.4(1). The linear axial compressibilities a, b, c and a sin are 2.14(1), 3.00(1), 2.43(1) and 1.63(1) × 10–3 GPa–1. Comparing the compressibility data with other CaM1Si2O6 pyroxenes we suggest that the empirical K × V = constant relationships are followed in C2/c pyroxenes only if the same valence electron character is shared. 相似文献
8.
Doz. Dr. F. Pertlik 《Mineralogy and Petrology》1984,33(3):203-212
Zusammenfassung Mikrosondenanalysen und die Verfeinerung der Kristallstruktur zeigen, daß Sylvanit, AuAgTe4, aus Baia de Arie (=Offenbánya), Rumänien, eine stöchiometrische Zusammensetzung und eine geordnete Kristallstruktur besitzt (a=8,95(1) Å,b=4,478(5) Å,c=14,62(2) Å; =145,35(5)°;Z=2; RaumgruppeP2/c–C
2h
4
). Das Au-Atom ist von sechs Te-Atomen in einer für die Oxidationszahl III charakteristischen [4+2]-Koordination umgeben. Um das Ag-Atom (Oxidationszahl I) sind ebenfalls sechs Te-Atome, jedoch in einer [2+2+2]-Koordination, angeordnet. Über gemeinsame Kanten bauen AuTe6- und AgTe6-Polyeder Schichten parallel (100) auf. Diese Schichten werden über Te2-Hanteln (Te–Te=2,82 Å) zu einem Gerüst verknüpft.
Mit 2 Abbildungen 相似文献
Crystal chemistry of natural tellurides. I: Refinement of the crystal structure of sylvanite, AuAgTe4
Summary Electron microprobe analyses and the refinement of the crystal structure indicate, that sylvanite, AuAgTe4, from Baia de Arie (=Offenbánya), Romania, has a stoichiometric composition and an ordered crystal structure (a=8.95(1) Å,b=4.478(5) Å,c=14.62(2) Å; =145.35(5)°;Z=2; space groupP2/c–C 2h 4 ). The Au atom is surrounded by six Te atoms in a [4+2] coordination as characteristic for oxidation state III. Around the Ag atom (oxidation state I) are also six Te atoms, but arranged in a [2+2+2] coordination. Via common edges the AuTe6 and AgTe6 polyhedra build up sheets parallel to (100). These sheets are combined to a network of Te2 dumbbells (Te–Te=2.82 Å).
Mit 2 Abbildungen 相似文献
9.
DC and AC electrical conductivities were measured on samples of two different crystals of the mineral aegirine (NaFeSi2O6) parallel () and perpendicular () to the [001] direction of the clinopyroxene structure between 200 and 600 K. Impedance spectroscopy was applied (20 Hz–1 MHz) and the bulk DC conductivity DC was determined by extrapolating AC data to zero frequency. In both directions, the log DC – 1/T curves bend slightly. In the high- and low-temperature limits, differential activation energies were derived for measurements [001] of EA 0.45 and 0.35 eV, respectively, and the numbers [001] are very similar. The value of DC [001] with DC(300 K) 2.0 × 10–6 –1cm–1 is by a factor of 2–10 above that measured [001], depending on temperature, which means anisotropic charge transport. Below 350 K, the AC conductivity () (/2=frequency) is enhanced relative to DC for both directions with an increasing difference for rising frequencies on lowering the temperature. An approximate power law for () is noted at higher frequencies and low temperatures with () s, which is frequently observed on amorphous and disordered semiconductors. Scaling of () data is possible with reference to DC, which results in a quasi-universal curve for different temperatures. An attempt was made to discuss DC and AC results in the light of theoretical models of hopping charge transport and of a possible Fe2+ Fe3+ electron hopping mechanism. The thermopower (Seebeck effect) in the temperature range 360 K < T <770 K is negative in both directions. There is a linear – 1/T relationship above 400 K with activation energy E 0.030 eV [001] and 0.070 eV [001]. 57Fe Mössbauer spectroscopy was applied to detect Fe2+ in addition to the dominating concentration of Fe3+. 相似文献
10.
Dr. H. Effenberger 《Mineralogy and Petrology》1987,36(1):3-12
Summary Based on a X-ray structure analysis it was proved that the mineral schmiederite contains both selenite and selenate groups [a = 9.922(3)Å,b = 5.712(2)Å,c = 9.396(3)Å, = 101.96(3)°, space group P21/m,Z = 2 {Pb2Cu2(OH)4(SeO3)(SeO4)},R
w = 0.055 for 1131 reflections up to sin / = 0.65 Å–1]. The crystal structure is closely related to that of linarite [a = 9.701(2) Å,b = 5.650(2) Å,c= 4.690(2)Å, = 102.65(2)°, space group P21/m,Z = 2 {PbCu(OH)2(SO4)},R
w = 0.034 for 1991 reflections up to sin / = 1.0 Å–1].The Pb atom in linarite and the Pb(1) atom in schmiederite have each three Pb-O bonds < 2.45 Å with trigonal pyramidal arranged ligands; the Pb(2) atom in schmiederite has only one such near O atom. The Cu atoms are approximately square planar coordinated by hydroxil groups. In addition two further O atoms complete the coordination figure to a strongly distorted octahedron. All the anion groups have the usual geometry.
Kristallstruktur und chemische Formel von Schmiederit, Pb2Cu2(OH)4(SeO3)(SeO4), mit einem Vergleich zu Linarit, PbCu(OH)2(SO4)
Zusammenfassung Basierend auf einer Röntgen-Strukturuntersuchung konnte das Vorliegen von Selenit-und Selenatgruppen im Mineral Schmiederit belegt werden [a=9,922(3) Å,b = 5,712(2) Å,c = 9,396(3) Å, = 101,96(3)°, Raumgruppe P21/m,Z=2 {Pb2Cu2(OH)4(SeO3)(SeO4)},R w = 0,055 für 1131 Reflexe bis sin /, = 0,65 Å–1]. Die Kristallstruktur weist enge Beziehungen zu jener des Linarits auf [a = 9,701(2) Å,b = 5,650(2) Å,c = 4,690(2) Å, = 102,65(2)°, Raumgruppe P21/m,Z=2 {PbCu(OH)2(SO4)},R w = 0,034 für 1991 Reflexe bis sin / = 1,0 Å–1].Das Pb-Atom im Linarit sowie das Pb(1)-Atom im Schmiederit haben jeweils drei Pb-O-Bindungen <,45 Å, wobei die Liganden trigonal pyramidal angeordnet sind; das Pb(2)-Atom im Schmiederit hat hingegen nur ein derart nahes O-Atom. Die Cu-Atome sind etwa quatratisch planar von Hydroxilgruppen koordiniert; zwei weitere O-Atome ergänzen die Koordinationsfigur zur einem stark verzerrten Oktaeder. Die Aniongruppen haben die üblichen Dimensionen.相似文献
11.
Summary The refined lattice parameters of beryllonite are:a=8.178 (3) Å,b=7.818 (2) Å,c=14.114 (6) Å, =90.00° (2); space groupP21/n,Z=12. Integrated Weissenberg photographs were taken by using CuK radiation and multiple film packs. The anisotropic refinement of the crystal structure by means of least-square methods gave a finalR value of 0.063 for the 1388 observed reflections. In the crystal structure PO4 and BeO4 tetrahedra, linked by shared oxygen atoms in a three-dimensional network, form pseudo-ditrigonal rings perpendicular to theb axis. The independent Na atoms lying in the channels formed by the rings are coordinated as an irregular nine-cornered polyhedron and as distorted octahedra.
With 2 Figures 相似文献
Verfeinerung der Kristallstruktur des Beryllonits,NaBePO 4
Zusammenfassung Verfeinerte Gitterkonstanten des Beryllonits lauten:a=8,178 (3) Å,b=7,818 (2) Å,c=14,114 (6) Å, =90,00 (2)°; Raumgruppe:P21/n,Z=12. Integrierte Weissenbergaufnahmen wurden mit CuK-Strahlung und multiplen Filmpaketen aufgenommen. Die anisotrope Verfeinerung der Kristallstruktur nach der Methode der kleinsten Quadrate ergab für 1388 beob. Reflexe einen abschließendenR-Wert von 0,063. In der Kristallstruktur bilden PO4-und BeO4-Tetraeder, die über gemeinsame Sauerstoffe zu einem dreidimensionalen Gerüst verknüpft sind, pseudo-ditrigonale Ringe senkrecht zurb-Achse. Die kristallographisch unabhängigen Arten von Na-Atomen, welche in den aus Ringen gebildeten Kanälen liegen, sind in der Form eines unregelmäßigen neuneckigen Polyeders bzw. in der Form verzerrter Oktaeder koordiniert.
With 2 Figures 相似文献
12.
Dr. Dora Bedlivy Dr. E. J. Llambías Lic. J. F. H. Astarloa 《Mineralogy and Petrology》1972,17(2):65-75
Zusammenfassung Rooseveltit findet sich in der Oxidationszone der Lagerstätten San Francisco de los Andes und Cerro Negro de la Aguadita, in der Provinz San Juan, Argentinien, auf 30°22 S und 69°33 W. Er bildet sehr feinkörnige, weiß-graue, nach Bismuthinit pseudomorphe Aggregate. Die Brechungsindizes liegen zwischenn=2,10 und 2,30. Die Vickershärte beträgt 513 (4–5 der Mohs'schen Härteskala). Mittels Elektronenmikrosonde wurde folgende chemische Zusammensetzung bestimmt: As=21,5±1%, Bi=60,9±2%. Rooseveltit ist monoklin mita
0=6,878(1)Å, b0=7,163(1) Å, c0=6,735(1) Å, =104° 46±1, Z=4, calc.=6,94 g·cm–3, RaumgruppeP 21/n.Rooseveltit wurde nach drei verschiedenen Methoden synthetisiert. Die Pulverdiagramme der synthetischen Produkte stimmen mit dem des Minerals überein. Die Brechungsindizes wurden mitn
=2,13(2) bzw. n=2,25(2) und die Dichte mit obs.=7,01 g·cm–3 bestimmt. Zellparameter: a0-6,882(1) Å, b0=7,164(1) Å, c0=6,734(1) Å, =104° 50,5±0,7, calc.=6,94 g·cm–3. Das synthetische Material schmilzt um 950°C. Selbst nach mehrstündigem Erhitzen auf 920°C läßt sich keine Veränderung im Pulverdiagramm des Minerals festellen.Es wird versucht, die natürliche Bildung des Rooseveltits zu erklären.
Mit 2 Abbildungen 相似文献
Rooseveltite from San Francisco de los Andes and Cerro Negro de la Aguadita, San Juan, Argentina
Summary Rooseveltite occurs in the weathering zone of the San Francisco de los Andes and Cerro Negro de la Aguadita mines, located in the San Juan Province, Argentina, at 30° 22S and 69° 33W. It appears in grey, finegrained aggregates pseudomorph after bismuthinite. Refraction index ranges fromn=2.10 to 2.30. The Vickers microhardness is 513 (4–5 of Mohs' scale). Chemical composition from electron micro probe measurements is As 21.5±1% and Bi 60.9±2%. Rooseveltite is monoclinic, with a0=6.878(1) Å, b0=7.163(1) Å, c0=6.735(1) Å, =104° 46±1, Z=4, calc.=6,94 g·cm–3, space groupP 21/n.The synthetic compound was prepared by three different methods. The powder pattern are the same as that of the mineral. Refraction index n=2.13(2) and n=2.25(2). The measured specific gravity is pobs.=7,01 g·cm–3. Cell parameters: a0=6.882(1) Å, b0=7.164(1) Å,c 0=6.734(1) Å, =104° 50.5±0.7, calc.=6,94 g·cm–3. The synthetic material melts at about 950°C. After heating to 920°C no variations were observed in the powder diagram of the mineral.It is tried to explain the formation of rooseveltite in natural environment.
Mit 2 Abbildungen 相似文献
13.
P. A. Kokkoros 《Mineralogy and Petrology》1965,10(1-4):45-51
Zusammenfassung Wasserfreies Eisen(III)sulfat, Fe2(SO4)3, existiert in zwei Modifikationen. Nach Einkristallaufnahmen kristallisiert die eine wahrscheinlich in Raumgruppe
(arh=8,791±0,004 Å, =55°52±2; Z=2), die andere in Raumgruppe C
2h
5
–P21/n (a=8,296±0,002 Å, b=8,515±0,002 Å, c=11,60±0,002 Å, =90°30; Z=4). Von Cr2(SO4)3 und Ga2(SO4)3 konnten für die rhomboedrischen Modifikationen, die isotyp zu jener von Fe2(SO4)3 sind, aus Pulveraufnahmen die Gitterkonstanten bestimmt werden.
Herrn Professor Dr.F. Machatschki zum 70. Geburtstag gewidmet. 相似文献
Summary Anhydrous iron(III)sulfate exists in two modifications. From single-crystal work, one of the modifications crystallizes probably in space group (arh=8.791±0.004 Å, =55°52±2; Z=2), whereas the other in space group C 2h 5 –P21/n (a=8.296±0.002 Å, b=8.515±0.002 Å, c=11.60±0,002 Å, =90°30; Z=4). The lattice constants of the rhombohedral modifications of Cr2(SO4)3 and Ga2(SO4)3, which are isomorphous with rhombohedral Fe2(SO4)3, have been determined from powder photographs.
Herrn Professor Dr.F. Machatschki zum 70. Geburtstag gewidmet. 相似文献
14.
Zusammenfassung Röntgenographische Untersuchungen an Einkristallen von Arsenbrackebuschit, Pb2(Fe, Zn)(OH, OH2) (AsO4)2 (mit FeZn21), ergaben die RaumgruppeP21/m mita
0=7,763(1) Å,b
0=6.046(1) Å,c
0=9.022(1)Å, =112,5(1)°,V=391,2(1) Å3,Z=2 und
x
=6,54 g/cm3. Dreidimensionale Fouriersynthesen und Verfeinerungen nach der Methode der kleinsten Quadrate bis zu einemR-Wert von 0,073 zeigten, daß das neue Mineral strukturell einer Gruppe von Blei-Mineralen der allgemeinen Formel Pb2
Me(Z) (XO4) (YO4) — mitMe=Cu2+, Mn2+, Zn2+, Fe3+;X=S, Cr, V, As;Y=P, As, V;Z=OH, OH2 — zuzuordnen ist. Vertreter dieser Gruppe sind z. B. Tsumebit Pb2Cu(OH) (SO4) (PO4), Vauquelinit Pb2Cu(OH) (CrO4) (PO4) und auch Brackebuschit Pb2(Mn, Fe) (OH2) (VO4)2. Strukturelle Verwandtschaft besteht mit Tsumcorit Pb(Zn, Fe)2(OH, OH2)2(AsO4)2, einem weiteren Blei-Arsenat der gleichen Lagerstätte.
Mit 2 Abbildungen 相似文献
Structural investigation of arsenbrackebuschite
Summary X-ray single crystal work on arsenbrackebuschite, Pb2(Fe, Zn) (OH, OH2) (AsO4)2 (with FeZn21), gave space groupP21/m witha 0=7.763(1),b 0=6.046(1),c 0=9.022(1) Å, =112.5(1)°,V=391.2(1) Å3,Z=2 and x =6,54 g/cm3. 3-dimensional Fourier syntheses and least-squares refinement (finalR=0.073) showed that the new mineral belongs to a group of lead minerals with the general formula Pb2 Me(Z) (XO4) (YO4)Me=Cu2+, Mn2+, Zn2+, Fe2+, Fe3+;X=S, Cr, V, As; Y=P, As, V;Z=OH, OH2. Members of this group, are for example tsumebite, Pb2Cu(OH) (SO4)(PO4), vauquelinite, Pb2Cu(OH) (CrO4) (PO4), and brackebuschite, Pb2 (Mn, Fe) (OH2) (VO4)2. A structural relationship exists to tsumcorite, Pb(Zn, Fe)2(OH, OH2)2 (AsO4)2, another lead-arsenate from Tsumeb.
Mit 2 Abbildungen 相似文献
15.
Summary The crystal structure of synthetic KMn[SeO4]2 was determined by single crystal X-ray diffraction methods in space group
, a = 4.827(2) Å, b = 4.988(2) Å, c = 7.981(3) Å, = 83.18(1)°, = 85.32(2)°, = 67.92(1)°, V = 176.66 Å3, Z = 1; 1564 unique data, measured up to 2 = 70° (MoK-radiation); R, R(I)w = 0.034, 0.074.KMn[SeO4]2 is closely related to monoclinic yavapaiite, KFe[SO4]2, and isotypic compounds. Jahn-Teller distorted MnO6 octahedra are alternately linked with KO10 polyhedra along [001]. The mean values of the Mn-O and Se-O distances are 2.007 Å and 1.637 Å, respectively.
With 1 Figure 相似文献
Die Kristallstruktur vonKMn 3+[SeO4]-einem triklin verzerrten Vertreter der Yavapaiite-Familie
Zusammenfassung Die Kristallstruktur von synthetisch dargestelltem KMn[SeO4]2 wurde mittels Einkristallröntgenmethoden in der Raumgruppe bestimmt: a = 4.827(2) Å, b = 4.988(2) Å, c = 7.981(3) Å, = 83.18(1)°, = 85.32(2)°, = 67.92(1)°, V = 176.66 Å3, Z = 1; 1564 unabhängige Daten bis 2 = 70° (MoK-Strahlung); R, R(I)w = 0.034, 0.074.KMn[SeO4]2 ist eng mit dem monoklinen Mineral Yavapaiit, KFe[SO4]2 und einer Reihe damit isotyper Verbindungen verwandt. Jahn-Teller verzerrte MnO6 Oktaeder sind alternierend mit KO10 Polyedern parallel [001] verbunden. Die Mittelwerte der Mn-O und Se-O Abstände sind 2.007 Å bzw. 1.637 Å.
With 1 Figure 相似文献
16.
Because multidimensional ARMA processes have great potential for the simulation of geological parameters such as aquifer permeability, it was important to resolve which of two proposed alternative methods should be used for determining the two-dimensional weighting parameter, , for a unilateral ARMA (1, 0) process on a square net. Practical simulations demonstrates that the correct formulation is: =10/(1+
10
2
where r,s is the correlation between lattice points at lagsr and s. When the simulations are performed with correlations of 0.8 or more a residual bias was detected which was found to be caused by a difference in the variance between the one- and two-dimensional models. This can be rectified by modifying the two- dimensional model as follows: zij=(zi–1, j + zi, j–1) + aij where
2=1/(1 +
10
2
). 相似文献
17.
M. Auernhammer H. Effenberger G. Hentschel Th. Reinecke E. Tillmanns 《Mineralogy and Petrology》1993,48(2-4):153-166
Summary Nickenichite is a new mineral found close to the village of Nickenich at the Nickenicher Sattel, Eifel, Germany. The chemical composition is NaxCayCuz(Mg, Fe, Al)3(AsO4)3, x 0.8, y 0.4, 0.4 and was derived by means of electron microprobe analyses and by a crystal structure investigation. The latter was determined from single-crystal X-ray data:a = 11.882(4)Å,b = 12.760(4)Å,c = 6.647(2)Å, = 112.81(2)°, space group C2/c,Z = 4;R = 0.053 andR
w
= 0.033 from 984 observed data and 102 free variables. Nickenichite is structurally related to the minerals o'danielite and johillerite. The two crystallographically different octahedrally coordinated cation positionsMe = (Mg, Fe, Al) have averageMe-O distances of 2.108 Å and 2.056 Å, octahedra share edges to form zig-zag chains in
; the chains are interconnected by AsO4 tetrahedra. In addition the compound is characterized by partially occupied Na[4+4], Ca[6+2] and Cu[4] positions.
With 2 Figures 相似文献
Nickenichit, ein neues Arsenat aus der Eifel, Deutschland
Zusammenfassung Nickenichit ist ein neues Mineral, das nahe dem Ort Nickenich, am Nickenicher Sattel, Eifel, Deutschland, gefunden wurde. Die chemische Formel ist NaxCayCuz, (Mg, Fe, Al)3(AsO4)3, x 0,8, y 0,4, z 0,4 und wurde mittels Elektronenstrahl-Mikrosondenanalysen und einer Kristallstrukturuntersuchung ermittelt. Letztere wurde mit Einkristall-Röntgendaten durchgeführt:a = 11,882(4) Å,b = 12,760(4) Å,c = 6,647(2) Å, = 112,81(2)°, Raumgruppe C2/c,Z = 4;R = 0,053 undR w = 0,033 für 984 beobachtete Daten und 102 freie Variable. Nickenichit zeigt enge strukturelle Beziehungen zu den Mineralen O'Danielit und Johillerit. Die zwei kristallographisch verschiedenen oktaedrisch koordinierten KationpositionenMe = (Mg, Fe, Al) haben mittlereMe-O-Abstände von 2,108 Å und 2,056 Å, die Oktaeder werden über Kanten zu zick-zack-artigen Ketten in verknüpft, diese werden untereinander über AsO4-Tetraeder vernetzt. Des weiteren ist die Verbindung durch partiell besetzte Na[4+4]-, Ca[6+2]- und Cu[4]-Positionen charakterisiert.
With 2 Figures 相似文献
18.
The polymorphic transformation between synthetic pyroxmangite and rhodonite of MnSiO3 composition has been reversibly bracketed in the presence of water at 3 kbar (between 425 ° and 450 ° C), 6 kbar (between 475 ° and 525 ° C), 20 kbar (between 500 ° and 900 ° C), 25 kbar (between 800 ° and 900 ° C) and 30 kbar (between 900 ° and 1,000 ° C), using standard cold-seal pressure vessels and piston cylinder apparatus. Oxygen fugacities buffered by the bomb walls and piston-cylinder cell assemblies sufficed to keep manganese in the divalent state. Pyroxmangite of MnSiO3 composition is shown to be the high-pressure, low-temperature polymorph with respect to rhodonite of the same composition. It is a stable phase at atmospheric pressure below 350–405 ° C.X-ray data for synthetic pyroxmangite are presented. The unit-cell parameters (a0=6.717(2) Å, b0=7.603(1)Å, c0=17.448(5) Å, =113 °50(1), = 82 °21(2), =94 °43(1); space group P-1) give a unit-cell volume (807.5(0.3) Å3) which, in accordance with other recent least squares lattice refinements of hydrothermally synthesized material, is slightly smaller than that obtained by single-crystal work on anhydrously synthesized material.Application of the present results to natural rocks is severely restricted due to the great variety and extent of cationic substitutions observed in natural pyroxenoids. The univariant polymorphic transformation determined for the MnSiO3 composition is thus replaced in natural systems by a divariant field in which pyroxmangite and rhodonite of differing composition will stably coexist. 相似文献
19.
Yu Nishihara Keisuke Nakayama Eiichi Takahashi Tomohiro Iguchi Ken-ìchi Funakoshi 《Physics and Chemistry of Minerals》2005,31(10):660-670
In-situ synchrotron X-ray diffraction experiments were conducted using the SPEED-1500 multi-anvil press of SPring-8 on stishovite SiO2 and pressure-volume-temperature data were collected at up to 22.5 GPa and 1,073 K, which corresponds to the pressure conditions of the base of the mantle transition zone. The analysis of room-temperature data yielded V0=46.56(1) Å3, KT 0=296(5) GPa and K T =4.2(4), and these properties were consistent with the subsequent thermal equation of state (EOS) analyses. A fit of the present data to high-temperature Birch-Murnaghan EOS yielded (KT /T) P =–0.046(5) GPa K–1 and = a + bT with values of a =1.26(11)×10–5 K–1 and b =1.29(17)×10–8 K–2. A fit to the thermal pressure EOS gives 0=1.62(9)×10–5 K–1, ( K T / T) V =–0.027(4) GPa K–1 and (2P /T 2) V =27(5)×10–7 GPa K–2. The lattice dynamical approach by Mie-Grüneisen-Debye EOS yielded 0=1.33(6), q =6.1(8) and 0=1160(120) K. The strong volume dependence of the thermal pressure of stishovite was revealed by the analysis of present data, which was not detectable by the previous high-temperature data at lower pressures, and this yields ( K T / T) V 0 and q 1. The analyses for the fictive volume for a and c axes show that relative stiffness of c axis to a axis is similar both on compression and thermal expansion. Present EOS enables the accurate estimate of density of SiO2 in the deep mantle conditions. 相似文献
20.
Stefano Merlino 《Contributions to Mineralogy and Petrology》1973,41(1):23-29
Sapphirine-1Tc, a polymorph of sapphirine, was found in granulites near Wilson Lake, Labrador. It is triclinic with unit cell data: a=10.04, b=10.38, c=8.65 Å, =107°33, =95°07, =123°55. The X-ray diffraction patterns of several crystals of sapphirine from Wilson Lake were investigated and evidence was found of solid state reactions that lead from the ordered polymorph-1Tc to a disordered arrangement of domains with the structure of sapphirine-2M, that is normal sapphirine. 相似文献