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1.
The area of the Middle–Lower Yangtze River valley, Eastern China, extending from Wuhan (Hubei province) to western Zhenjiang (Jiangsu province), hosts an important belt of Cu–Au–Mo and Fe deposits. There are two styles of mineralization, i.e., skarn/porphyry/stratabound Cu–Au–Mo–(Fe) deposits and magnetite porphyry deposits in several NNE-trending Cretaceous fault-bound volcanic basins. The origin of both deposit systems is much debated. We dated 11 molybdenite samples from five skarn/porphyry Cu–Au–Mo deposits and 5 molybdenite samples from the Datuanshan stratabound Cu–Au–Mo deposit by ICP-MS Re–Os isotope analysis. Nine samples from the same set were additionally analyzed by NTIMS on Re–Os. Results from the two methods are almost identical. The Re–Os model ages of 16 molybdenite samples range from 134.7 ± 2.3 to 143.7 ± 1.6 Ma (2σ). The model ages of the five samples from the Datuanshan stratabound deposit vary from 138.0 ± 3.2 to 140.8 ± 2.0 Ma, with a mean of 139.3 ± 2.6 Ma; their isochron age is 139.1 ± 2.7 Ma with an initial Os ratio of 0.7 ± 8.1 (MSWD = 0.29). These data indicate that the porphyry/skarn systems and the stratabound deposits have the same age and suggest an origin within the same metallogenic system. Albite 40Ar/39Ar dating of the magnetite porphyry deposits indicates that they formed at 123 to 125 Ma, i.e., 10–20 Ma later. Both mineralization styles characterize transitional geodynamic regimes, i.e., the period around 140 Ma when the main NS-trending compressional regime changed to an EW-trending lithospheric extensional regime, and the period of 125–115 Ma of dramatic EW-trending lithospheric extension.  相似文献   

2.
The Middle–Lower Yangtze River metallogenic belt (MLYRMB), extending from Daye in Hubei Province in the west to Zhenjiang in Jiangsu Province in the east, hosts a number of large polymetallic (Cu–Au–Mo, Fe, Zn, Pb, and Ag) deposits and constitutes one of the most important metallogenic belts in China. The Cu–Au–Mo deposits in the Jiurui district are an important component of the MLYRMB. In this study we carried out precise and detailed zircon U–Pb dating for all types of magmatic rocks from the Wushan ore deposit in the Jiurui district. Three samples of Cu–Au–Mo-related porphyries from different ore belts at Wushan were analyzed and yielded zircon U–Pb ages of 148.0 ± 1.0 Ma, 145.4 ± 0.9 Ma and 147.3 ± 0.9 Ma, respectively. A series of dykes were emplaced immediately following the Cu–Au–Mo-related porphyries at Wushan. A dark-colored basic dyke which intruded into the granodiorite porphyry at Wujia gold deposit near Wushan was dated at 144.5 ± 1.2 Ma. Two lamprophyre dykes taken from the north ore belt at Wushan underground mining stops were dated at 143.6 ± 0.9 Ma and 144.3 ± 0.9 Ma, respectively. A late-stage dyke which was also taken from the Wushan north ore belt yielded an age of 142.6 ± 1.0 Ma and might represent the end of magmatism in the Wushan ore deposit. These new geochronological data demonstrate that the time range of magmatism in the Wushan ore deposit is approximately between 148 Ma and 143 Ma, showing that the magmatic activity at Wushan was rapid and intensive. The ages of Cu–Au–Mo-related porphyries from other areas in the Jiurui district, such as the Dongleiwan, Yangjishan and Chengmenba ore deposits, were also measured and yielded zircon U–Pb ages of 141.5 ± 1.7 Ma, 143.4 ± 1.4 Ma and 146.6 ± 1.0 Ma, respectively. Combined with those previously reported zircon U–Pb age results from the Jiurui district, the present age data set demonstrates that extensive magmatism in the Jiurui district was coeval and intensive, marked by a magmatic activity in the age range of 148 to 138 Ma and peaked between 148 Ma and 142 Ma. According to the statistics of all those precise zircon U–Pb ages, the Cu–Au–Mo-related porphyries in the Edong and Tongling districts in the MLYRMB show similar ages, and they have a slightly younger peak age and a longer duration than that of the Jiurui district. The geographic shape of the MLYRMB in the Cretaceous shows an arcuate structure, the Jiurui district is located at the transitional point of the arcuate structure and the Edong and Tongling districts are situated on both sides of the arcuate structure. Considering that the Jiurui district has a slightly older peak age and a shorter duration of magmatic activity than that in the Edong and Tongling districts, it seems that the arcuate structure of the MLYRMB played an important role in the formation of these Cu–Au–Mo-related porphyries. Consequently, we suggest that the genesis of the Late Mesozoic magmatic rocks along the MLYRMB may have been due to a tectonic activity developed from southeast to northwest, which probably has a close relationship with the subduction of the paleo-Pacific plate beneath the Eurasian plate in Mesozoic times.  相似文献   

3.
Based on previous studies and detailed field investigations of the Dexing porphyry copper deposit, the Yinshan Ag-Pb-Zn deposit and the Jinshan shear zone – hosted gold deposit in the Dele Jurassic volcanic basin, in the northeastern Jiangxi province, East China, we propose that the three deposits share spatial, temporal and genetic relationships and belong to the same metallogenic system. Dexing is a typical porphyry Cu–Au–Mo deposit in which both ore-forming fluid and metals are derived from the granite porphyry. The Yinshan deposit consists of a porphyry copper ore located in the cupola of a quartz porphyry stock, in the lower part, and Ag–Pb–Zn ore veins in the upper part. The hydrothermal fluids were mainly derived from the magma in the early stages of the mineralizing event and became mixed with meteoric waters in the late stages. Its ore metals are magma-derived. Both the Jinshan base metal veins and the Hamashi, Dongjie and Naikeng quartz vein-type gold deposit are hosted by brittle–ductile structures, which are distal in relation to the porphyry intrusions and were formed by mixed magmatic fluids and meteoric water, whereas the gold was mainly leached from the country rocks (Mesoproterozoic Shuangqiaoshan Group phyllite and schist). The deposits show a distinct spatial arrangement from porphyry Cu, to epithermal Ag–Pb–Zn and distal Au. We suggest a porphyry–epithermal–distal vein ore system model for this group of genetically related mineral deposits. They were formed in a back-arc setting in a Middle Jurassic active continental margin, with magmas derived from the subducted slab.  相似文献   

4.
Summary The Cu–Fe–Au–Mo (W) deposits in southeastern Hubei are an important component of the Middle–Lower Yangtze River metallogenic belt. Molybdenite from the Fengshandong Cu- (Mo), Ruanjiawan W–Cu- (Mo), Qianjiawan Cu–Au, Tongshankou Cu–Mo and Tonglüshan Cu- (Fe) deposits yielded Re–Os ages of 144.0 ± 2.1 Ma, 143.6 ± 1.7 Ma, 137.7 ± 1.7 Ma, 142.3 ± 1.8–143.7 ± 1.8 Ma and 137.8 ± 1.7–138.1 ± 1.8 Ma, respectively. Phlogopite from the Tieshan Fe- (Cu) deposit yielded an Ar–Ar age of 140.9 ± 1.2 Ma. These data and other published isotopic ages (Re–Os molybdenite and Ar–Ar mica ages) for the Cu–Fe–Au–Mo (W) deposits in the Middle–Lower Yangtze River metallogenic belt show that Cu–Fe–Au–Mo (W) mineralisation in the Tongling, Anqing, Jiurui and Edong ore districts developed in a narrow time span between 135.5 and 144.9 Ma, reflecting an important regional metallogenic event. An integrated study of available petrological and geochronological data, together with relationships to magmatism and the regional geodynamic framework, indicate that the Cu–Fe–Au–Mo (W) mineralisation in the Middle–Lower Yangtze River belt occurred during a regime of lithospheric extension. This extension is probably related to Late Mesozoic processes of lower crustal delamination and lithospheric thinning in East China.  相似文献   

5.
Many hydrothermal Cu–Mo–Au deposits related to granitoid intrusives were recently discovered in the West Qinling Orogenic Belt (WQOB). These deposits were mainly formed during the late Indosinian epoch (ca. 214 Ma), and the regional geological setting of Cu–Mo ore formation in WQOB during this epoch is poorly understood until now. This paper describes the geochronology and geochemistry of the Wenquan ore-bearing pluton, a composite granite body, to study the geologic background of magmatic emplacement and ore formation. The Mo mineralisation occurs at the contact between a fine-grained biotite monzogranite and a medium- to fine-grained porphyritic monzogranite. Zircon 206Pb/238U ages of 223 ± 3 Ma (biotite monzogranite) and 225 ± 3 Ma (porphyritic monzogranite) were obtained. Geochemical analyses show that the Wenquan pluton is a high-K calc-alkaline to shoshonite series rock with relatively high LREE and low HREE and a moderate to weak negative Eu anomaly. Relatively negative anomalies of Ba, Ti, P, Nb, Ta also exist. These results imply that the Wenquan pluton was emplaced during a transitional process (from collision to extension) between the Yangtze Craton and North China Craton. During the later Indosinian epoch, the East Qinling Orogenic Belt (EQOB) and WQOB had similar tectonic settings, and intensive magmatic activity and Mo mineralisation occurred. The EQOB was then involved in the Mesozoic subduction of the Pacific plate, and its subsequent tectonic evolution was different from that of the WQOB.  相似文献   

6.
The East Qinling–Dabie orogenic belt accommodates the largest Mo ore district in the world. It contains 8.43 Mt of proven Mo metal reserves which accounts for 66% of the total proven Chinese Mo reserves. The Mo ore district includes 24 deposits and 12 occurrences, with four major types of Mo mineral systems, i.e., porphyry, porphyry-skarn, skarn and hydrothermal veins. The latter can be further subdivided into quartz vein and carbonatite vein types. Although Mo mineralization in the belt began in the Paleoproterozoic (1680 ± 24 to 2044 ± 14 Ma), all economically significant deposits were formed during the Mesozoic. Re/Os dating of molybdenite has shown that there are three episodes of Mo mineralization, i.e., Late Triassic (233–221 Ma), Late Jurassic to Early Cretaceous (148–138 Ma) and Early to middle Cretaceous (131–112 Ma).Late Triassic Mo deposits developed as molybdenite–quartz veins and carbonatite vein types. Stable isotope systematics (C, O, S) and high contents of Re and Sr indicate that the carbonatite Mo veins are mantle-derived. Porphyry and porphyry–skarn Mo mineral deposits were formed in the Late Jurassic to Early Cretaceous and Early to middle Cretaceous. The Late Jurassic to Early Cretaceous granite porphyries that are associated with the Mo deposits usually occupy less than 1.5 km2 at the surface and are situated in the East Qinling area, far west of China's continental margin. On the other hand, the Early to middle Cretaceous batholiths and granite porphyries, , with associated Mo deposits are located in the Dabieshan area and eastern part of the East Qinling area. The Late Jurassic to Early Creataceous granitoids and related Mo deposits possibly formed in a back-arc extensional setting of the Eurasian continental margin, which was probably triggered by the oblique subduction of the Izanagi plate. The Early to middle Cretaceous batholiths and granite porphyries are linked to the tectonic regime of lithospheric thinning, asthenospheric upwelling and partial melting of the crust, induced by a change in Izanagi Plate motion parallel to the continent margin.In the East Qinling–Dabie belt there are vein type Pb–Zn–Ag deposits surrounding porphyry and/or porphyry–skarn Mo (W) deposits, forming well defined ore clusters. The same spatial arrangement (i.e., porphyry Mo stockworks and outlying Pb–Zn–Ag ore veins) is also observed at the deposit scale. Thus, Mo porphyry stockworks and distal polymetallic veins belong to the same ore system and may reflect an outward temperature decrease from the highly fractionated granite plutons. Both, porphyry stockworks and polymetallic veins, can be used as vectors for further prospecting.  相似文献   

7.
The Gushan deposit is one of the typical magnetite–apatite deposits associated with dioritic porphyries in the Lower Yangtze River Valley belt of the eastern Yangtze craton. The origin of this deposit is still uncertain and remains a controversial issue. Divergent opinions are centered on whether the iron deposits are magmatic or hydrothermal in origin. However, our field observations and mineralogical studies, combined with previous published petrological and geochemical features strongly suggest that the main ore bodies in the Gushan magnetite–apatite deposit are magmatic. Specific evidence includes the existence of gas bubbles, tubes, and miarolitic and amygdaloidal structures, melt flow banding structure and the presence of “ore breccia”. New electron microprobe analyses of the pyroxene phenocrysts of the dioritic porphyry genetically associated with the Gushan magnetite–apatite deposit show that the Fe contents in the evolving magma dramatically decrease, and then gradually increase. Because there is no evidence of mafic magma recharge, this scenario (decreasing Fe) could be plausibly interpreted by Fe-rich melts separated from Fe-poor silicate melts, i.e., liquid immiscibility was triggered by minor addition of phosphorus by crustal contamination. The occurrence of massive iron ore bodies can be satisfactorily explained by the immiscible Fe-rich melt with enormous volatile contents was driven to the top of the magma chamber due to the low density. The hot and volatile-rich iron ore magma was injected along fractures and spaces between the dioritic intrusions and wall-rocks, and led to an explosion near the surface, resulting in the immediate fragmentation of the roof of the intrusion and wall-rocks, forming brecciated ores. Moreover, other types of ores can be considered as a result of post-magmatic hydrothermal activities. Our proposed metallogenic model involving the Kiruna-type mineralization is consistent with the observed phenomenon in the Gushan deposit.  相似文献   

8.
The Itacaiúnas Belt of the highly mineralised Carajás Mineral Province comprises ca. 2.75 Ga volcanic rocks overlain by sedimentary sequences of ca. 2.68 Ga age, that represent an intracratonic basin rather than a greenstone belt. Rocks are generally at low strain and low metamorphic grade, but are often highly deformed and at amphibolite facies grade adjacent to the Cinzento Strike Slip System. The Province has been long recognised for its giant enriched iron and manganese deposits, but over the past 20 years has been increasingly acknowledged as one of the most important Cu–Au and Au–PGE provinces globally, with deposits extending along an approximately 150 km long WNW-trending zone about 60 km wide centred on the Carajás Fault. The larger deposits (approx. 200–1000 Mt @ 0.95–1.4% Cu and 0.3–0.85 g/t Au) are classic Fe-oxide Cu–Au deposits that include Salobo, Igarapé Bahia–Alemão, Cristalino and Sossego. They are largely hosted in the lower volcanic sequences and basement gneisses as pipe- or ring-like mineralised, generally breccia bodies that are strongly Fe- and LREE-enriched, commonly with anomalous Co and U, and quartz- and sulfur-deficient. Iron oxides and Fe-rich carbonates and/or silicates are invariably present. Rhenium–Os dating of molybdenite at Salobo and SHRIMP Pb–Pb dating of hydrothermal monazite at Igarapé-Bahia indicate ages of ca. 2.57 Ga for mineralisation, indistinguishable from ages of poorly-exposed Archean alkalic and A-type intrusions in the Itacaiúnas Belt, strongly implicating a deep magmatic connection.A group of smaller, commonly supergene-enriched Cu–Au deposits (generally < 50 Mt @ < 2% Cu and < 1 g/t Au in hypogene ore), with enrichment in granitophile elements such as W, Sn and Bi, spatially overlap the Archean Fe-oxide Cu–Au deposits. These include the Breves, Águas Claras, Gameleira and Estrela deposits which are largely hosted by the upper sedimentary sequence as greisen-to ring-like or stockwork bodies. They generally lack abundant Fe-oxides, are quartz-bearing and contain more S-rich Cu–Fe sulfides than the Fe-oxide Cu–Au deposits, although Cento e Dezoito (118) appears to be a transitional type of deposit. Precise Pb–Pb in hydrothermal phosphate dating of the Breves and Cento e Dezoito deposits indicate ages of 1872 ± 7 Ma and 1868 ± 7 Ma, respectively, indistinguishable from Pb–Pb ages of zircons from adjacent A-type granites and associated dykes which range from 1874 ± 2 Ma to 1883 ± 2 Ma, with 1878 ± 8 Ma the age of intrusions at Breves. An unpublished Ar/Ar age for hydrothermal biotite at Estrela is indistinguishable, and a Sm–Nd isochron age for Gameleira is also similar, although somewhat younger. The geochronological data, combined with geological constraints and ore-element associations, strongly implicate a magmatic connection for these deposits.The highly anomalous, hydrothermal Serra Pelada Au–PGE deposit lies at the north-eastern edge of the Province within the same fault corridor as the Archean and Paleoproterozoic Cu–Au deposits, and like the Cu–Au deposits is LREE enriched. It appears to have formed from highly oxidising ore fluids that were neutralised by dolomites and reduced by carbonaceous shales in the upper sedimentary succession within the hinge of a reclined synform. The imprecise Pb–Pb in hydrothermal phosphate age of 1861 ± 45 Ma, combined with an Ar/Ar age of hydrothermal biotite of 1882 ± 3 Ma, are indistinguishable from a Pb–Pb in zircon age of 1883 ± 2 Ma for the adjacent Cigano A-type granite and indistinguishable from the age of the Paleoproterozoic Cu–Au deposits. Again a magmatic connection is indicated, particularly as there is no other credible heat or fluid source at that time.Finally, there is minor Au–(Cu) mineralisation associated with the Formiga Granite whose age is probably ca. 600 Ma, although there is little new zircon growth during crystallisation of the granite. This granite is probably related to the adjacent Neoproterozoic (900–600 Ma) Araguaia Fold Belt, formed as part of the Brasiliano Orogeny.Thus, there are two major and one minor period of Cu–Au mineralisation in the Carajás Mineral Province. The two major events display strong REE enrichment and strongly enhanced LREE. There is a trend from strongly Fe-rich, low-SiO2 and low-S deposits to quartz-bearing and more S-rich systems with time. There cannot be significant connate or basinal fluid (commonly invoked in the genesis of Fe-oxide Cu–Au deposits) involved as all host rocks were metamorphosed well before mineralisation: some host rocks are at mid- to high-amphibolite facies. The two major periods of mineralisation correspond to two periods of alkalic to A-type magmatism at ca. 2.57 Ga and ca. 1.88 Ga, and a magmatic association is compelling.The giant to world-class late Archean Fe-oxide Cu–Au deposits show the least obvious association with deep-seated alkaline bodies as shown at Palabora, South Africa, and implied at Olympic Dam, South Australia. The smaller Paleoproterozoic Cu–Au–W–Sn–Bi deposits and Au–PGE deposit show a more obvious relationship to more fractionated A-type granites, and the Neoproterozoic Au–(Cu) deposit to crustally-derived magmas. The available data suggest that magmas and ore fluids were derived from long-lived metasomatised lithosphere and lower crust beneath the eastern margin of the Amazon Craton in a tectonic setting similar to that of other large Precambrian Fe-oxide Cu–Au deposits.  相似文献   

9.
华南地区中生代主要金属矿床时空分布规律和成矿环境   总被引:141,自引:1,他引:140  
以广泛地质调查和放射性同位素年龄精测数据为基础,总结提出了华南地区中生代主要金属矿床成矿出现于三个阶段,即晚三叠世(230~210 Ma)、中晚侏罗世(170~150 Ma)和早中白垩世(134~80 Ma)。晚三叠世矿化组合为钨锡铌钽;中晚侏罗世的矿化组合进一步分为170~160 Ma斑岩-矽卡岩铜矿和160~150 Ma与花岗岩有关的钨锡多金属矿床;白垩纪矿化虽然持续了54 Ma,但主要峰期在100~90 Ma,主要矿化组合为浅成低温热液型铜金银矿床和花岗岩有关的钨锡铜多金属矿床。晚三叠世钨锡铌钽矿化成因上与过铝质二云母花岗岩有关,是华北、华南和印支三大板块后碰撞过程的成岩成矿响应。在180 Ma左右Izanagi板块向欧亚大陆俯冲,于170~160 Ma期间可能由于俯冲板片局部多处撕裂而形成Ⅰ型或埃达克质岩石和有关的的斑岩铜矿,紧接着在南岭地区于160~150 Ma期间俯冲板块开天窗,软流圈物质直接涌入上地壳,形成了一种壳幔混合型高分异花岗质岩石及其钨锡多金属矿床。在135 Ma左右由于俯冲板块改变了运动方向,由斜向俯冲调整到几乎平行大陆边缘沿NE方向走滑,造成大陆岩石圈大面积伸展而形成了大量白垩纪断陷盆地和变质核杂岩,并伴随大规模的火山活动和花岗质岩浆侵位及其浅成低温热液铜金银矿化系统、与花岗岩有关的钨锡多金属矿化系统和热液型铀矿的形成。  相似文献   

10.
Anhydrite–pyrite–magnetite–pyroxene–type deposits occur in the Mesozoic volcanic areas of the Middle–Lower Yangtze Valley in China. These deposits are hosted in alkaline basaltic rocks, and are generally accompanied by melanocratic and leucocratic alteration zones, both of which are characterized by a distinct vertical zonation pattern. Investigation of these zones indicates that the chemical compositions of solid solutions and polymorphs of various minerals vary spatially in the alteration profile, upwards from the lowest level, and outwards from the center.Here we report a case study on the Luohe deposit. In the melanocratic-alteration zone, the composition of magnetite (including trace elements Ti, V, Mg, Mn), pyroxene (Mg, Fe2+, Fe3+, Al2O3), plagioclase (AnxAb1 − x), pyrite (Co, Ni) and apatite (F, CeO2 + Y2O3 + La2O3) changes with depth. The isotherms of hydrothermal fluids determined from fluid inclusion data, including homogenization temperature and salinity, also vary with depth.Activity diagrams were constructed from mineral and isotherm analysis to estimate the chemical constraints on the alteration-mineral assemblages and the coexisting hydrothermal solutions for the Na2O–K2O–CaO–MgO–FeO–Fe2O3–A12O3–SiO2–H2SO4–H2S–HCI–H2O system at 350 to 600 °C and 500 bars (50 MPa), assuming that the major alteration mineral assemblages along the profile reflect the nature of the coexisting hydrothermal solutions. The activity diagrams adopted the major minerals as buffers to fix the activities of the aqueous species in the system, simulating the physicochemical conditions of the magnetite–anhydrite–pyroxene equilibrium and of solid solutions of diopside–hedenbergite, grossular–andradite and anorthite–albite found in the profile.This study provides an approach to modeling the chemical constraints of coexisting fluids in ore-alteration zones based on field observations.  相似文献   

11.
In the Cretaceous Ningwu volcano-sedimentary basin in the Yangtze River Valley metallogenic belt, eastern China, there are three areas with a dense distribution of magnetite or hematite deposits: the Meishan deposit in the north; Washan, Nanshan and Taocun deposits in the center; and the Zhongjiu and Gushan deposits in the south. The mineralization in the Ningwu basin is associated mainly with subvolcanic intrusions, consisting of gabbro–diorite porphyry and/or gabbro–diorite. Alteration zoning of these deposits is pronounced, and includes: (1) an upper light colored zone of argillic, kaolinite, silica, carbonate and pyritic alteration (2) a middle dark colored zone of diopside, fluorapatite–magnetite, phlogopite, and garnet with fluorapatite–magnetite; (3) a lower light colored zone of extensive albitic alteration. However, at the Gushan iron deposit, the lower light colored zone and the middle dark colored zone are absent, whereas the principal alteration is represented by silicification, kaolinization, and carbonatization.The iron oxide–apatite deposits in the Ningwu basin are typically magmatic–metasomatic origin and are similar to the Kiruna-type deposits in Scandinavia, particularly with respect to mineral assemblages, fabric and structure of the iron ores, occurrence of the orebodies and wall rock alteration. The iron oxide–apatite deposits of the Ningwu basin contain magnetite and/or hematite, with diopside or actinolite and apatite gangue. They were formed in a rift or extensional environment and the mineralization is associated with alkaline magmatism. The time interval between magmatism and related mineralization is very short.  相似文献   

12.
The Gaijing Pb–Zn–Mo deposit and Shapinggou Mo deposit in the Yinshan region, Jinzhai, Anhui province, China, are hosted in various granitic intrusions with 40Ar/39Ar ages obtained for biotite and hornblende of 136.8 ± 1.6 Ma (medium-grained monzogranite), 130.4 ± 1.2 Ma (fine-grained granite), and 125.4 ± 1.0 Ma (fine-grained diorite). The modes of occurrence and cross-cutting relationships among the igneous intrusions indicate that alkali quartz-syenite and quartz-syenite porphyry (cryptoexplosive breccia) formed later than the calc-alkali monzogranite, granite, and diorite. Molybdenum mineralization occurs in pipe-like bodies hosted in cryptoexplosive breccia (pipe), quartz-syenite (porphyry), monzogranite, and granite, whereas Pb–Zn mineralization occurs in veins distally from the Mo mineralization. The Re–Os isotopic model ages of molybdenite from the Gaijing Pb–Zn–Mo deposit are 112.6 ± 1.3 and 113.5 ± 1.3 Ma, consistent with the ages of other molybdenum deposits throughout the East Qinling–Dabie metallogenic belt. The geological characteristics and isotopic ages of the Gaijing Pb–Zn–Mo and Shapinggou Mo deposits indicate a genetic relationship to the emplacement of the quartz-syenite (porphyry) and to shallow-seated porphyry–cryptoexplosive breccia intrusions. The present results, combined with existing data, suggest that the Pb–Zn–Mo deposits and related igneous rocks were formed in a geodynamic setting of regional lithospheric thinning, delamination, and thermal erosion in East China. The deposits are part of the East Qinling–Dabie molybdenum belt, which in turn is part of a large-scale E–W-trending metallogenic belt in East China.  相似文献   

13.
祁连山在构造上是一条经历了多期构造旋回叠加的早古生代复合型造山带,花岗质岩浆作用研究对揭示其构造演化具有重要意义。锆石U-Pb年代学统计结果表明,祁连地区花岗质岩浆活动可以分为7个大的阶段,包括古元古代早期(2 470~2 348 Ma)、古元古代晚期(1 778~1 763 Ma)、中元古代晚期-新元古代早期(1 192~888 Ma)、新元古代中期(853~736 Ma)、中寒武世-志留纪(516~419 Ma),泥盆纪-早石炭世(418~350 Ma)以及中二叠世-晚三叠世(271~211 Ma)。其中古元古代早期发育强过铝质高钾钙碱性S型和准铝质低钾拉斑-高钾钙碱性I型花岗岩,记录了早期的陆壳增生及改造事件。古元古代晚期为准铝质-弱过铝质高钾钙碱性-钾玄质A型花岗岩,是Columbia超大陆裂解事件的产物。中元古代晚期-新元古代早期以过铝质-强过铝质钙碱性-钾玄质S型花岗岩为主,新元古代中期以准铝质-强过铝质钙碱性-高钾钙碱性A型花岗岩为主,分别对应Rodinia超大陆的汇聚和裂解事件。中寒武世-志留纪花岗岩是洋陆转换过程中的产物,约440 Ma加厚基性下地壳部分熔融形成的低Mg埃达克岩的广泛出现指示祁连地区全面进入碰撞造山阶段。泥盆纪-早石炭世花岗岩代表后碰撞伸展阶段岩浆岩组合,发育准铝质-强过铝质低钾拉斑-钾玄质等一系列花岗岩。中二叠世-晚三叠世花岗岩以准铝质-弱过铝质钙碱性-高钾钙碱性I型花岗岩为主,有少量弱过铝质高钾钙碱性A型花岗岩,是宗务隆洋俯冲消减以及碰撞后伸展过程的产物。  相似文献   

14.
The southern Jiangxi Province is a major part of the Nanling W–Sn metallogenic province of southern China, where all W–Sn ore deposits are temporally and spatially related to Mesozoic granitic intrusions. The Tianmenshan–Hongtaoling orefield is a recently explored territory endowed by several styles of W–Sn mineralization. The orefield comprises three composite granitic plutons: Tianmenshan, Hongtaoling and Zhangtiantang associated with several tens of W–Sn-polymetallic ore deposits (Maoping, Baxiannao, Niuling, Zhangdou, Yaolanzhai and others) along their contacts. In this study, four new SHRIMP zircon U–Pb ages were determined for three composite granitic plutons, and 33 molybdenite samples from five W–Sn deposits were analysed by ICP-MS Re–Os isotopic method. SHRIMP zircon U–Pb ages for both medium to coarse-gained biotite granite and porphyritic biotite monzogranite from the Tianmenshan composite pluton are 157.2 ± 2.2 Ma and 151.8 ± 2.9 Ma, respectively. Molybdenite Re–Os isochron ages for the related Baxiannao fracture-controlled tungsten deposits are 157.9 ± 1.5 Ma. Maoping greisens-type tungsten deposits were emplaced at 155.3 ± 2.8 Ma and the Maoping wolframite–quartz veins at 150.2 ± 2.8 Ma, respectively. The SHRIMP U–Pb age of zircons from the Hongtaoling biotite granite is 151.4 ± 3.1 Ma whereas the molybdenite Re–Os isochron ages of the genetically related Niuling endocontact tungsten quartz veins and Zhangdou exocontact tungsten quartz veins are 154.9 ± 4.1 to 154.6 ± 9.7 Ma and 149.1 ± 7.1 Ma, respectively. The SHRIMP zircon U–Pb age of the Zhangtiantang fine-grained muscovite granite is 156.9 ± 1.7 Ma, whereas the molybdenite Re–Os isochron age for the related Yaolanzhai greisens-type tungsten deposit is 155.8 ± 2.8 Ma. These new age data, combined with those available from the literature, indicate that the ages of W–Sn ores and related granites are Late Jurassic with a peak at 150 to 160 Ma, which corresponds to the widespread Mesozoic metallogenic event in southern China. Molybdenites from this group of tungsten deposits have quite low Re contents (29.1 to 2608 ppb), suggesting continental crustal provenance of the ore metals.  相似文献   

15.
复合成矿与构造转换——以长江中下游成矿带为例   总被引:15,自引:9,他引:6  
常印佛  周涛发  范裕 《岩石学报》2012,28(10):3067-3075
复合成因矿床分布广泛,把它们单独划分出来进行研究,对于深入认识成矿过程、发展成矿理论和指导找矿勘探,均有重要意义.鉴于中国大陆东部中生代岩浆作用强烈,对前期成矿作用的影响也很明显,因此本文以长江中下游成矿带为例,评介了复合成矿作用的几种主要机理,认同前人提出的叠加和改造是其基本类型,但预富集作用也应重视,同时也不能忽视继承成矿和再生成矿,特别是继承和预富集联合多次出现时,可以形成区域性成矿元素大规模富集.同时,本文还将它们放在区域构造体制和机制转化演化过程中加以考察,进一步明确它们在中生代构造体制转换以前主要以沉积(含热水沉积)成因的含矿建造、矿源层或矿(胚)层产出,而矿床的最终形成与就位则主要与新构造体制下由挤压向引张转化的过渡环境中构造-岩浆活动有关,呈现出“成矿大爆发”的现象.其中早期( 145~136Ma)构造机制是以走滑挤压作用为主,形成与高钾钙碱性岩系有关的铜金矿化.晚期(135 ~ 127Ma)以走滑引张作用为主,形成了与橄榄安粗岩系有关的铁硫矿化.但这两期都有广泛发育的以叠加改造为主的复合成因铜、金、铁、硫及铅锌矿床,从而在典型的岩浆热液矿床和沉积矿床之间形成了一套过渡性矿床序列(层控矽卡岩型→沉积热液叠加型→层控叠改型→迁移式改造型→原地式改造型),构建了一个矿床“家族”.末期( 126 ~ 123Ma)以引张作用为主,出现碱性火山岩和A型花岗岩类,伴随铁、金、钼、铀等矿化,成矿带的成矿活动随之进入尾声.  相似文献   

16.
The Dabaoshan polymetallic deposit in northern Guangdong Province contains iron, copper, lead, zinc, molybdenum, tungsten and sulfur mineral resources. Porphyry-type Mo(W) and skarn-type Mo-W mineralization occurs along the internal and external contact zones of the granodioritic porphyry, respectively. LA-ICP-MS U–Pb dating of zircons from two granodioritic porphyry samples yielded a weighted mean 206Pb/238U age of 175.8 ± 1.5 Ma (MSWD = 0.037) and 175.0 ± 1.7 Ma (MSWD = 0.41). They can be pooled together to yield a combined weighted age of 175.4 ± 1.6 Ma (MSWD = 0.26), which is interpreted as the emplacement age of the granodioritic porphyry. Re–Os dating of three molybdenite samples from porphyry and skarn ores yielded consistent model ages of 163.2 ± 2.3 Ma to 165.2 ± 2.4 Ma, with a weighted mean of 163.9 ± 1.3 Ma (MSWD = 0.81), which is the age of Mo–W mineralization. These ages are consistent with the molybdenite Re–Os model age (164.7 ± 3 Ma) measured by Mao et al. (2004a) for the stratiform Cu–Pb–Zn orebody, and they can yield a weighted mean of 164.0 ± 2.5 Ma (MSWD = 0.16). This implies that Mo–W and Cu–Pb–Zn mineralization in the Dabaoshan polymetallic deposit are the products of one mineralization event. The mineralization in the deposit coincides closely with that of Mo-polymetallic mineralization (164–149 Ma) elsewhere in the Nanling region, comprising an important polymetallic metallogenic belt of south China, and corresponds to the second episode of Mesozoic metallogenesis in South China. Combined with previous studies, we suggest that the Dabaoshan polymetallic deposit is related to post-collisional lithosphere extension in the Nanling region of South China. Geological data and Pb isotopic evolution diagrams, together with stable isotopic data of fluid inclusions (δ18O = − 3.75–7.0‰, δD = − 50.7 to − 56.1‰) and ore sulfides (δ34S = − 2–3‰), suggest a genetic relationship between the Dabaoshan polymetallic deposit, the granodioritic porphyry and the dacitic porphyry. These data, combined with the Re content (64.7 to 102.4 ppm) of molybdenite, indicate that the ore-forming components were derived from mixed crustal and mantle sources.  相似文献   

17.
This paper deals with the tectonic control on the hydrothermal system that gave rise to Sb–Hg ore deposits in the Monte Amiata area that was one of the most relevant mining district for the exploitation of mercury in Italy. The study area (Selvena mining district) is located in southern Tuscany (inner Northern Apennines) one of the most important mineralized area in the western Mediterranean region. Southern Tuscany was severely affected by Middle–Late Miocene low-angle normal faults, later dissected by Pliocene–Pleistocene faults, coeval magmatism (Late Miocene–Pleistocene) and hydrothermal activity (Pliocene–Present). The Selvena mining district is located south of Middle Pleistocene Monte Amiata volcanic complex. Our structural and kinematic study is based on the integration among fieldwork, borehole and mine data. The results highlight two Pleistocene–Holocene left-lateral transtensional shear zones linked by normal faults, defining a coeval pull-apart structure. Here, the Sb–Hg mineralization, transported by meteoric hydrothermal fluids mainly, is particularly diffuse and concentrated in the cataclasites and in damage zones of the normal faults. Furthermore, a widespread mineralization also occurs in the cataclasites of Miocene low-angle normal faults. Mine evidence suggests that ore-bearing fluids percolated through structural conduits located along the fault planes and resulting parallel to the intermediate stress axis. Geological structures and ore deposit distribution are related to a single hydrothermal circuit, with meteoric water channelled to depth through conduits parallel to the intermediate stress axis of the transcurrent shear zones; then, hydrothermal fluids mainly ascended through the almost vertical deformation zones located at the intersection between normal and strike-slip faults. Thus, hydrothermal fluids permeated also the Middle–Late Miocene cataclasites. This study shed light on the relationships between geological structures and mineralization in southern Tuscany and underlines the importance to investigate mine areas to understand hydrothermal fluids path.  相似文献   

18.
Abstract: From the southernmost part of Jiangsu province to the northeastern part of Jiangxi province, China, the Northeast Jiangxi Deep Fault runs for about 400 km length with a width of 30 to 40 km. This fault marks the suture zone of two ter-ranes of Proterozoic age. At the both sides of the fault, Yanshanian granitic activity is recognized. That is, the Dexing-Wuyuan porphyry belt on the NW side of the fault, and the Damaoshan-Lingshan granite belt on the SE side. The former activity is characterized by the occurrence of small stocks of granodioritic composition, rich in siderophile elements but poor in LIL elements. No distinct Eu anomaly is recognized in the REE pattern, and a low initial 87Sr/86Sr ratio is reported. Magnetite, sphene and apatite are observed as accessory minerals. On the contrary, granitic activity on the SE side of the fault is characterized by the occurrence of composite batholiths, in general of granitic to monzogranitic composition, rich in LIL and alkali elements but poor in siderophile and alkali earth elements. A strong Eu anamaly is recognized in the REE pattern, and initial 87Sr/86Sr ratios are as high as 0. 716. Fluorite, zircon and REE minerals are observed as accessory minerals. These two contrasting granitic activities are refered to as syntexis– and transformation–types, respectively, following the classification commonly used in China, and have similar petrochemical characteristics to those defined for the magnetite– and ilmenite–series, and I– and S-type granitoids. Considering that the above igneous activity occurred far from the supposed subduction zone along the East Coast of China, intracontinental A-type (continent to continent) subduction is proposed to have occurred northwestwards along the NE Jiangxi Deep Fault during Yanshanian time due to a strong compressional stress from SE to NW. A-type subduction introduced the continental slab to some depth, and resulted in the production of the paired granitic activity observed on both sides of the fault. Many mineral deposits are associated with both granitic belts. In the Dexing-Wuyuan porphyry belt, the Dexing porphyry Cu and Yinshan polymetallic deposits are representative, whereas in the Damaoshan-Lingshan granite belt, several tens of rare metal deposits are known such as the Geyuan Nb–Ta–W–Sn deposits. Metal assemblages of those deposits reflect the source materials of magmas in both granitic belts.  相似文献   

19.
We present new Re–Os molybdenite age data on three porphyry Cu–Mo–Au deposits (Yulong, Machangqing, and Xifanping). These deposits are associated with the Himalayan adakitic magmatism that occurred in a continental collision environment, controlled by large-scale Cenozoic strike-slip faults in the eastern Indo–Asian collision zone. Three distinct episodes of Cu–Mo–Au mineralization are recognized. At Yulong, Re–Os isotopic data of four molybdenite samples from sulfide-quartz veins in the quartz–sericite alteration zone yield an isochron with an age of 40.1±1.8 Ma (2σ), coincident to a zircon sensitive high-mass resolution ion microprobe (SHRIMP) age of 40.9±0.1 Ma for the host monzogranite. The molybdenite Re–Os dates, together with K–Ar, Rb–Sr, U–Pb, and 40Ar/39Ar dates on the pre- and intra-ore porphyries, suggest that Cu–Mo–Au mineralization formed during the late stage (∼40 Ma) of regional porphyry magmatism, but hydrothermal activity probably lasted to at least ∼36 Ma. At Machangqing, molybdenite Re–Os data from the K–silicate and quartz–sericite alteration zones yield an isochron with an age of 35.8±1.6 Ma (2σ), which is identical to the zircon SHRIMP and bulk-rock Rb–Sr ages (35∼36 Ma) of the host granite, but older than bulk-rock K–Ar dates (31∼32 Ma) for associated Au-bearing quartz syenite with advanced argillic alteration. At Xifanping, five molybdenite samples from the K–silicate alteration zone yield the youngest Re–Os isochron age in the area, at 32.1±1.6 Ma (2σ). The Re–Os molybdenite dates here are younger than K–Ar ages (33.5∼34.6) for hydrothermal biotite and actinolite. There is a positive correlation between the absolute age of the deposits and their Cu and Au reserves in the eastern Indo–Asian collisional zone. Episodic stress relaxation probably caused multiple magmatic intrusions, which most likely resulted in three episodes of Cu–Mo–Au mineralization in the eastern Indo–Asian collision zone.  相似文献   

20.
The giant East China Mesozoic metallogenic province hosts some of the World’s largest resources of tungsten, tin, molybdenum, antimony and bismuth. Ores of gold, silver, mercury, lead, zinc, copper, uranium and iron are also of major importance. The province and its constituent metallogenic belts or regions (South China; Middle–Lower Yangtze River Valley; East Qinling–Dabie; Interior of North China Craton; Yan-Liao and North-east China) are the products of several pulses of igneous activity and mineralisation between ~240 and ~80 Ma. Each successive stage has produced a distinctive suite of deposits that can be readily related to the geodynamic evolution of the region during the Mesozoic. This geodynamic evolution is linked to a complex series of tectonic events, involving far-field-subduction, plate collisions, crustal thickening, post-collision collapse and rifting.  相似文献   

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